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At least 127 records · Page 7

Geochemical Modeling of F Area Seepage Basin Composition and Variability

From the 1950s through 1989, the F Area Seepage Basins at the Savannah River Site (SRS) received low level radioactive wastes resulting from processing nuclear materials. Discharges of process wastes to the F Area Seepage Basins followed by subsequent mixing processes within the basins and eventual infiltration into the subsurface resulted in contamination of the underlying vadose zone and downgradient groundwater. For simulating contaminant behavior and subsurface transport, a quantitative understanding of the interrelated discharge-mixing-infiltration system along with the resulting chemistry of fluids entering the subsurface is needed. An example of this need emerged as the F Area Seepage Basins was selected as a key case study demonstration site for the Advanced Simulation Capability for Environmental Management (ASCEM) Program. This modeling evaluation explored the importance of the wide variability in bulk wastewater chemistry as it propagated through the basins. The results are intended to generally improve and refine the conceptualization of infiltration of chemical wastes from seepage basins receiving variable waste streams and to specifically support the ASCEM case study model for the F Area Seepage Basins. Specific goals of this work included: (1) develop a technically-based 'charge-balanced' nominal source term chemistry for water infiltrating into the subsurface during basin operations, (2) estimate the nature of short term and long term variability in infiltrating water to support scenario development for uncertainty quantification (i.e., UQ analysis), (3) identify key geochemical factors that control overall basin water chemistry and the projected variability/stability, and (4) link wastewater chemistry to the subsurface based on monitoring well data. Results from this study provide data and understanding that can be used in further modeling efforts of the F Area groundwater plume. As identified in this study, key geochemical factors affecting basin chemistry and variability included: (1) the nature or chemistry of the waste streams, (2) the open system of the basins, and (3) duration of discharge of the waste stream types. Mixing models of the archetype waste streams indicated that the overall basin system would likely remain acidic much of the time. Only an extended periods of predominantly alkaline waste discharge (e.g., >70% alkaline waste) would dramatically alter the average pH of wastewater entering the basins. Short term and long term variability were evaluated by performing multiple stepwise modeling runs to calculate the oscillation of bulk chemistry in the basins in response to short term variations in waste stream chemistry. Short term (1/2 month and 1 month) oscillations in the waste stream types only affected the chemistry in Basin 1; little variation was observed in Basin 2 and 3. As the largest basin, Basin 3 is considered the primary source to the groundwater. Modeling showed that the fluctuation in chemistry of the waste streams is not directly representative of the source term to the groundwater (i.e. Basin 3). The sequence of receiving basins and the large volume of water in Basin 3 'smooth' or nullify the short term variability in waste stream composition. As part of this study, a technically-based 'charge-balanced' nominal source term chemistry was developed for Basin 3 for a narrow range of pH (2.7 to 3.4). An example is also provided of how these data could be used to quantify uncertainty over the long term variations in waste stream chemistry and hence, Basin 3 chemistry.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

sRecovery Act: Geologic Characterization of the South Georgia Rift Basin for Source Proximal CO 2 Storage

This study focuses on evaluating the feasibility and suitability of using the Jurassic/Triassic (J/TR) sediments of the South Georgia Rift basin (SGR) for CO 2 storage in southern South Carolina and southern Georgia The SGR basin in South Carolina (SC), prior to this project, was one of the least understood rift basin along the east coast of the U.S. In the SC part of the basin there was only one well (Norris Lightsey #1) the penetrated into J/TR. Because of the scarcity of data, a scaled approach used to evaluate the feasibility of storing CO 2 in the SGR basin. In the SGR basin, 240 km (~149 mi) of 2-D seismic and 2.6 km2 3-D (1 mi2) seismic data was collected, process, and interpreted in SC. In southern Georgia 81.3 km (~50.5 mi) consisting of two 2-D seismic lines were acquired, process, and interpreted. Seismic analysis revealed that the SGR basin in SC has had a very complex structural history resulting the J/TR section being highly faulted. The seismic data is southern Georgia suggest SGR basin has not gone through a complex structural history as the study area in SC. The project drilled one characterization borehole (Rizer # 1) in SC. The Rizer #1 was drilled but due to geologic problems, the project team was only able to drill to 1890 meters (6200 feet) instead of the proposed final depth 2744 meters (9002 feet). The drilling goals outlined in the original scope of work were not met. The project was only able to obtain 18 meters (59 feet) of conventional core and 106 rotary sidewall cores. All the conventional core and sidewall cores were in sandstone. We were unable to core any potential igneous caprock. Petrographic analysis of the conventional core and sidewall cores determined that the average porosity of the sedimentary material was 3.4% and the average permeability was 0.065 millidarcy. Compaction and diagenetic studies of the samples determined there would not be any porosity or permeability at depth in SC. In Georgia there appears to be porosity in the J/TR section based on neutron log porosity values. The only zones in Rizer #1 that appear to be porous were fractured diabase units where saline formation water was flowing into the borehole. Two geocellular models were created for the SC and GA study area. Flow simulation modeling was performed on the SC data set. The injection simulation used the newly acquired basin data as well as the Petrel 3-D geologic model that included geologic structure. Due to the new basin findings as a result of the newly acquired data, during phase two of the modeling the diabase unit was used as reservoir and the sandstone units were used as caprock. Conclusion are: 1) the SGR basin is composed of numerous sub-basins, 2) this study only looked at portions of two sub-basins, 3) in SC, 30 million tonnes of CO 2 can be injected into the diabase units if the fracture network is continuous through the units, 4) due to the severity of the faulting there is no way of assuring the injected CO 2 will not migrate upward into the overlying Coastal Plain aquifers, 5) in Georgia there appears to porous zones in the J/TR sandstones, 6) as in SC there is faulting in the sub-basin and the seismic suggest the faulting extends upward into the Coastal Plain making that area not suitable for CO 2 sequestration, 7) the complex faulting observed at both study areas appear to be associated with transfer fault zones (Heffner 2013), if sub-basins in the Georgia portion of the SGR basin can be located that are far away from the transfer fault zones there is a strong possibility of sequestering CO 2 in these areas, and 9) the SGR basin covers area in three states and this project only studied two small areas so there is enormous potential for CO 2 sequestration in other portions the basin and further research needs to be done to find these areas.

58 GEOSCIENCES↗

Ma'adim Vallis Estuarine Delta in Elysium Basin and Its Relevance as a Landing Site for Exobiology Exploration on Mars

The debouche of Ma'adim Vallis in the Elysium Basin generated a transitional transported sediment structure, which planimetric shape is controlled by the enclosing topography of a deep reentrant gulf of the Basin into the highland. We defined it as an estuarine delta. The location and the importance of this estuarine delta is supported by the theoretical model of graded profile constructed for Ma'adim Vallis, and by two approaches: (i) the reconstruction of Ma'adim Vallis downstream course from Gusev to Elysium Basin, and (ii) the survey of the sediment deposit in the alleged estuary. The longitudinal graded profile of Ma'adim Vallis finds its base-level in the Elysium Basin, at a about 1000 m elevation, which is in agreement with the observed Basin shoreline. This model is supported by observational evidence of flow between the northern rim of Gusev crater, and the Elysium Basin shoreline. This downstream course of Ma'adim Vallis can be divided into three hydrogeologic regions. into three hydrogeologic regions. (a) The first region is a flooded plain (Zephiria Mensae), consisting in chaotic terrain formed by highland rocks, and disintegrated lava of the western flank of Apollinaris. Morphologic indicators of the flood process are: (1) the sediment deposit over the Gusev crater northern rim that reflects the overspilling of the crater-lake water through a 40-km wide gap provided by an ancient impact crater, (2) the tear-drop shaped feature on the northeastern flank of Apollinaris Patera, and (3) the chaotic terrain that suggest the emergence of ground water generated by the seepage of the crater lake through high-permeable broken rampart material. This underground water circulation sustained by the hydrostatic pressure of the crater-lake has likely generated a hydrothermal system in the volcanic environment of Apollinaris Patera. The stratigraphy of the flooded area is identified as Hesperian age, with occurrences of Noachian hilly individual features, and as Amazonian flooded plain and chaotic material, (b) The second region is located on the western flank of Apollinaris Patera. It is surrounded by relics of deep valleys that suggest a former downstream course of Ma'adim Vallis. The geologic setting of this region (Lucus Planum) is interpreted to be an Amazonian formation composed by the middle and lower members of the Medusae Formation., c) The third region corresponds to the convergence of the west and east branches of Ma'adirn Vallis into a deep re-entrant wide gulf that penetrates about 100 km into the highland. This topographic depression is delineated by the 1000 in elevation contour. This gulf has formed an estuarine configuration centered at 3S/190W within the Elysium Basin. This configuration has favored the formation of a estuarine sedimentary delta, because of topographically controlled lateral migration. This estuarine structure is strongly dominated by the incoming supply of Ma'adim Vallis fluvial sediment extracted from Zephiria Mensae and Lucus Planum. The obtuse-angle geometry of the estuary increases the sedimentation rate, which is higher than in the course of the channel. The sediment deposition process is governed by the estuarine water circulation. The inflowing loaded fluvial water enters the estuary as a bottom current, and mixes with the relatively less-loaded water of the receiving basin. When they mixed. the inflowing fluvial material, and the landward basin circulating water generate an accumulation of highly-diversified estuarine deposit stratification. This accumulation of material is mostly centered in the transitional zone of the delta. The sediment trapping efficiency of the estuary is function of the energy balance between the inflowing fluvial water, and the ingoing basin current. The submergence of the delta by the rising of the water-level increases the estuary water-depth, and consequently the sediment entrapment is favored. The locus of sediment accumulation moves landward in the zone of inflowing fluvial water. This results in the rising of the channel base-level, thus in the increase of the length of the longitudinal graded-profile. The sediment deposit facies of the zone A shows a generally smooth surface. The longitudinal deposit is bordered by alluvial terraces that reflect the variations of the channel level. The waning of the Elysium Basin caused the erosion of the Basin estuarine zone by small channels, this episode being characterized by dissected tear-drop shaped mesa-like morphologies in the delta. Our estuarine delta model predicts a lithostratigraphic depositional sequence associated with the water submergence and the transgression of Elysium Basin. The thickness of the estuarine sediment corresponds to the Elysium Basin levels changes relatively to the bed floor of the estuary, The depositional sequence of Ma'adim Vallis are described: (1) a pro-current filled region (A), where fluvial are longitudinally accumulated by the inflowing water, (2) inverse current from Elysium Basin (B), where fluvial and lacustrine sediments are accumulated, and (3) zone of current equilibrium (C), where the sediments are distributed as a shoreline at the boundary of the estuarine delta. The estuary sedimentology dynamics collects and keeps the record of the geologic unit material crossed by Ma'adim Vallis, and those of the lakebed deposit of Elysium Basin. The predicted mixed stratigraphic sequence from fluvial and lacustrine sediment makes this site an exceptional environment to concentrate potential multi-origin biologic records. We envision four possible strategies to explore this sedimentologic record: (1) longitudinal surface and subsurface traverses in region A to investigate outcrop levees, (2) exploration of the mesa walls in region B, (3) deep drilling hole lodging of the sequential deposits in the zones A and B, and (4) surface and subsurface exploration of the shoreline delta. The expected results for each of these strategies are: (1) in the deepest layers of region A are predicted frequent and abundant coarse material, sandy lenses lamination grading downward from sand to cobbles. Volcanic debris from the Noachian crustal Plateau unit material, hydrothermal altered rocks, carbonates, Hesperian and possibly Amazonian volcanic material, from Apollinaris Patera, altered rocks and carbonates from Zephiria Mensae are expected. As a favorable environment for inception of life, possible biological records are expected in transported rock, (2) At the surface, and subsurface (<=100 m), large deposits sandy to silted material from Elysium paleolake basin mixed with fine-grained sediments from Ma'adim Vallis are expected mostly in the upstream part of region B, (3) on the shoreline of the estuarine delta, abundant fine material from Elysium paleolake basin (evaporites, carbonates), mostly Amazonian in age are expected. The Ma'adini estuary is a favorable landing site for all the above mentioned science aspects, and .for its location. The site lies near the equator, which is favorable for the rover solar power supply, and at 1000m elevation, which is a favorable configuration for the descent system braking. Another advantage is the extent of the area of high scientific interest (33,000 sq km), which provides a good ellipse, and potential long study traverses.

Grin, E. A.↗

The Transition from Complex Crater to Peak-Ring Basin on the Moon: New Observations from the Lunar Orbiter Laser Altimeter (LOLA) Instrument

Impact craters on planetary bodies transition with increasing size from simple, to complex, to peak-ring basins and finally to multi-ring basins. Important to understanding the relationship between complex craters with central peaks and multi-ring basins is the analysis of protobasins (exhibiting a rim crest and interior ring plus a central peak) and peak-ring basins (exhibiting a rim crest and an interior ring). New data have permitted improved portrayal and classification of these transitional features on the Moon. We used new 128 pixel/degree gridded topographic data from the Lunar Orbiter Laser Altimeter (LOLA) instrument onboard the Lunar Reconnaissance Orbiter, combined with image mosaics, to conduct a survey of craters >50 km in diameter on the Moon and to update the existing catalogs of lunar peak-ring basins and protobasins. Our updated catalog includes 17 peak-ring basins (rim-crest diameters range from 207 km to 582 km, geometric mean = 343 km) and 3 protobasins (137-170 km, geometric mean = 157 km). Several basins inferred to be multi-ring basins in prior studies (Apollo, Moscoviense, Grimaldi, Freundlich-Sharonov, Coulomb-Sarton, and Korolev) are now classified as peak-ring basins due to their similarities with lunar peak-ring basin morphologies and absence of definitive topographic ring structures greater than two in number. We also include in our catalog 23 craters exhibiting small ring-like clusters of peaks (50-205 km, geometric mean = 81 km); one (Humboldt) exhibits a rim-crest diameter and an interior morphology that may be uniquely transitional to the process of forming peak rings. Comparisons of the predictions of models for the formation of peak-ring basins with the characteristics of the new basin catalog for the Moon suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. In particular, a power-law model of growth of an interior melt cavity with increasing crater diameter is consistent with power-law fits to the peak-ring basin data for the Moon and Mercury. We suggest that the relationship between the depth of melting and depth of the transient cavity offers a plausible control on the onset diameter and subsequent development of peak-ring basins and also multi-ring basins, which is consistent with both planetary gravitational acceleration and mean impact velocity being important in determining the onset of basin morphological forms on the terrestrial planets.

Baker, David M. H.↗

Lunar impact basins: New data for the nearside northern high latitudes and eastern limb from the second Galileo flyby

During the December 1992 Galileo Earth/Moon encounter the northern half of the nearside, the eastern limb, and parts of the western farside of the Moon were illuminated and in view, a geometry that was complementary to the first lunar encounter in December, 1990, which obtained images of the western limb and eastern farside. The Galileo Solid State Imaging System (SSI) obtained multispectral images for these regions during the second encounter and color ratio composite images were compiled using combinations of band ratios chosen on the basis of telescopic spectra and laboratory spectra of lunar samples. Ratios of images taken at 0.41 and 0.76 micron are sensitive to changes in the slope in the visible portion of the spectrum, and ratios of 0.99 and 0.76 micron relate to the strength of near-infrared absorptions due to iron-rich mafic minerals (0.76/0.99 ratio) such as olivine and pyroxene. Results of the analyses of the compositional diversity of the crust, maria, and Copernican craters are presented elsewhere. Primary objectives for lunar basin analysis for the second encounter include analysis of: the north polar region and the Humboldtianum basin; the characteristics of the Imbrium basin along its northern border and the symmetry of associated deposits; the origin of light plains north of Mare Frigoris and associated with several other basins; the nature and significance of pre-basin substrate; the utilization of the stereo capability to assess subtle basis structure; the identification of previously unrecognized ancient basins; basin deposits and structure for limb and farside basins; and assessment of evidence for proposed ancient basins. These data and results will be applied to addressing general problems of evaluation of the nature and origin of basin deposits, investigation of mode of ejecta emplacement and ejecta mixing, analysis of the origin of light plains deposits, analysis of basin deposit symmetry/asymmetry, investigation of basin depth of excavation and crustal stratigraphy, and assessment of models for basin formation and evolution. Here we discuss some preliminary results concerning lunar impact basins, their deposits, and prebasin substrates, using the same approaches that we employed for the Orientale and South Pole-Aitken basins using the data from the first encounter.

Head, J. W.↗

Morphology and Distribution of Volcanic Vents in the Orientale Basin from Chandrayaan-1 Moon Mineralogy Mapper (M3) Data

One of the most fundamental questions in the geological and thermal evolution of the Moon is the nature and history of mantle melting and its relationship to the formation and evolution of lunar multi-ringed basins. Mare volcanic deposits provide evidence for the nature, magnitude and composition of mantle melting as a function of space and time [1]. Many argue that mantle partial melts are derived from depths well below the influence of multiringed basin impact events [1], while others postulate that the formation of these basins can cause mantle perturbations that are more directly linked to the generation ascent and eruption of mare basalts [2,3]. In any case, longer-term basin evolution will considerably influence the state and orientation of stress in the lithosphere, and the location of mare volcanic vents in basins as a function of time [4]. Thus, the location, nature and ages of volcanic vents and deposits in relation to multi-ringed impact basins provides evidence for the role that these basins played in the generation of volcanism or in the influence of the basins on surface volcanic eruption and deposit concentration. Unfortunately, most lunar multi-ringed impact basins have been eroded by impacts or filled with lunar mare deposits [5-8], with estimates of the thickness of mare fill extending up to more than six km in the central part of some basins [9-11]. The interior of most basins (e.g., Crisium, Serenitatis, Imbrium, Humorum) are almost completely covered and obscured. Although much is known about the lava filling of multi-ringed basins, and particularly the most recent deposits [5-8], little is known about initial stages of mare volcanism and its relationship to the impact event. One multi-ringed basin, Orientale, offers substantial clues to the relationships of basin interiors and mare basalt volcanism.

Head, James↗

Geological Carbon Sequestration Storage Resource Estimates for the Ordovician St. Peter Sandstone, Illinois and Michigan Basins, USA

The Cambro-Ordovician strata of the Midwest of the United States is a primary target for potential geological storage of CO2 in deep saline formations. The objective of this project is to develop a comprehensive evaluation of the Cambro-Ordovician strata in the Illinois and Michigan Basins above the basal Mount Simon Sandstone since the Mount Simon is the subject of other investigations including a demonstration-scale injection at the Illinois Basin Decatur Project. The primary reservoir targets investigated in this study are the middle Ordovician St Peter Sandstone and the late Cambrian to early Ordovician Knox Group carbonates. The topic of this report is a regional-scale evaluation of the geologic storage resource potential of the St Peter Sandstone in both the Illinois and Michigan Basins. Multiple deterministic-based approaches were used in conjunction with the probabilistic-based storage efficiency factors published in the DOE methodology to estimate the carbon storage resource of the formation. Extensive data sets of core analyses and wireline logs were compiled to develop the necessary inputs for volumetric calculations. Results demonstrate how the range in uncertainty of storage resource estimates varies as a function of data availability and quality, and the underlying assumptions used in the different approaches. In the simplest approach, storage resource estimates were calculated from mapping the gross thickness of the formation and applying a single estimate of the effective mean porosity of the formation. Results from this approach led to storage resource estimates ranging from 3.3 to 35.1 Gt in the Michigan Basin, and 1.0 to 11.0 Gt in the Illinois Basin at the P10 and P90 probability level, respectively. The second approach involved consideration of the diagenetic history of the formation throughout the two basins and used depth-dependent functions of porosity to derive a more realistic spatially variable model of porosity rather than applying a single estimate of porosity throughout the entire potential reservoir domains. The second approach resulted in storage resource estimates of 3.0 to 31.6 Gt in the Michigan Basin, and 0.6 to 6.1 Gt in the Illinois Basin. The third approach attempted to account for the local-scale variability in reservoir quality as a function of both porosity and permeability by using core and log analyses to calculate explicitly the net effective porosity at multiple well locations, and interpolate those results throughout the two basins. This approach resulted in storage resource estimates of 10.7 to 34.7 Gt in the Michigan Basin, and 11.2 to 36.4 Gt in the Illinois Basin. A final approach used advanced reservoir characterization as the most sophisticated means to estimating storage resource by defining reservoir properties for multiple facies within the St Peter formation. This approach was limited to the Michigan Basin since the Illinois Basin data set did not have the requisite level of data quality and sampling density to support such an analysis. Results from this approach led to storage resource estimates of 15.4 Gt to 50.1 Gt for the Michigan Basin. The observed variability in results from the four different approaches is evaluated in the context of data and methodological constraints, leading to the conclusion that the storage resource estimates from the first two approaches may be conservative, whereas the net porosity based approaches may over-estimate the resource.

Barnes, David↗

Oil Biodegradation in Deep Marine Basins

Nine important hydrocarbon (oil) basins where offshore petroleum leases have been licensed are compared. These nine basins (Gulf of Mexico, Eastern Mediterranean’s Nile Deep-Sea Fan, Central Mediterranean and the Sirte Basin, North Sea, Caspian Sea, Angola, Trinidad and Tobago, Great Australian Bight, and Brazil’s Amazonian Deep-Sea Basin) are geographically separated and are impacted by very different water masses. The geochemical parameters of these basins are quite distinct, for example, salinities ranging from 39 psu in the Eastern Mediterranean to 12 psu in the Caspian. Additionally, parameters like temperatures of the bottom water are also very distinct, with the temperature in the deep water of the Eastern Mediterranean being between 12 °C and 14 °C and the temperature of the deep water in the North Sea being -2 °C. Each basin represents a unique ecosystem in which distinct microbes may thrive. These distinct environmental parameters may act to constrain the extent of hydrocarbon degradation in these basins. Another potential constraint on hydrocarbon degradation is the extent of natural hydrocarbon seeps in the area. Though many basins have similar if not 16S rRNA identical strains of oil-degrading bacteria, Colwellia psychrerythraea from different basins showed that a mixture of natural selection and neutral evolution has contributed to the divergence of these. Most if not all deep ocean basin microbial communities are dominated by Thaumarchaeota below 200 m. These microaerophilic, ammonium oxidizer, psychrophiles are very adapted to an oligotrophic lifestyle, and though many in this group will degrade oil, they are rapidly outcompeted by other bacteria in oil or high hydrocarbon intrusions, thus the virtual “canary in the coal mine.” Cometabolic biodegradation of oil is well documented but could be an important natural attenuation mechanism for oil in deep marine basins with episodic methane seeps. Microbial community structure can also predict concentrations of oil in deep basins. Many other synergistic effects require more research in environmental systems biology in deep marine basins.

Hazen, Terry C.↗

RECONNAISSANCE ASSESSMENT OF CO2 SEQUESTRATION POTENTIAL IN THE TRIASSIC AGE RIFT BASIN TREND OF SOUTH CAROLINA, GEORGIA, AND NORTHERN FLORIDA

A reconnaissance assessment of the carbon dioxide (CO{sub 2}) sequestration potential within the Triassic age rift trend sediments of South Carolina, Georgia and the northern Florida Rift trend was performed for the Office of Fossil Energy, National Energy Technology Laboratory (NETL). This rift trend also extends into eastern Alabama, and has been termed the South Georgia Rift by previous authors, but is termed the South Carolina, Georgia, northern Florida, and eastern Alabama Rift (SGFAR) trend in this report to better describe the extent of the trend. The objectives of the study were to: (1) integrate all pertinent geologic information (literature reviews, drilling logs, seismic data, etc.) to create an understanding of the structural aspects of the basin trend (basin trend location and configuration, and the thickness of the sedimentary rock fill), (2) estimate the rough CO{sub 2} storage capacity (using conservative inputs), and (3) assess the general viability of the basins as sites of large-scale CO{sub 2} sequestration (determine if additional studies are appropriate). The CO{sub 2} estimates for the trend include South Carolina, Georgia, and northern Florida only. The study determined that the basins within the SGFAR trend have sufficient sedimentary fill to have a large potential storage capacity for CO{sub 2}. The deeper basins appear to have sedimentary fill of over 15,000 feet. Much of this fill is likely to be alluvial and fluvial sedimentary rock with higher porosity and permeability. This report estimates an order of magnitude potential capacity of approximately 137 billion metric tons for supercritical CO{sub 2}. The pore space within the basins represent hundreds of years of potential storage for supercritical CO{sub 2} and CO{sub 2} stored in aqueous form. There are many sources of CO{sub 2} within the region that could use the trend for geologic storage. Thirty one coal fired power plants are located within 100 miles of the deepest portions of these basins. There are also several cement and ammonia plants near the basins. Sixteen coal fired power plants are present on or adjacent to the basins which could support a low pipeline transportation cost. The current geological information is not sufficient to quantify specific storage reservoirs, seals, or traps. There is insufficient hydrogeologic information to quantify the saline nature of the water present within all of the basins. Water data in the Dunbarton Basin of the Savannah River Site indicates dissolved solids concentrations of greater than 10,000 parts per million (not potential drinking water). Additional reservoir characterization is needed to take advantage of the SGFAR trend for anthropogenic CO{sub 2} storage. The authors of this report believe it would be appropriate to study the reservoir potential in the deeper basins that are in close proximity to the current larger coal fired power plants (Albany-Arabi, Camilla-Ocilla, Alamo-Ehrhardt, and Jedburg basin).

01 COAL, LIGNITE, AND PEAT↗

MERIT-Plus Dataset: Delineation of endorheic basins in 5 and 15 min upscaled river networks

Endorheic drainage basins, those inland basins not connected directly to ocean, are essential for hydrological modeling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. Within many hydrological model frameworks, river basins are defined by digital river networks through their flow direction and connectivity datasets. Here we present an improvement to gridded flow direction data and its derivatives produced from upscaled global 5 and 15 arc minute MERIT networks. We explicitly label endorheic and exorheic drainage basins and alter the delineation of endorheic basins by merging small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion of those basins since most of the merged catchments were inside other larger endorheic areas. We developed and present here the endorheic basin delineation method. This method performs an analysis of the contributing river and basin geometry relative to the location of the flow end point (i.e. potential endorheic lake), proximity of the latter to the drainage basin boundary and the elevation difference between the basin's lowest point and potential spillover location at the basin boundary. The new digital river network was validated using the University of New Hampshire Water Balance Model by comparing the water balance of endorheic inland depressions with modeled accumulation of water in their inland lakes based on the observed historical climate drivers used by WBM.

Earth Systems↗

MERIT-Plus Dataset: Delineation of endorheic basins in 5 and 15 min upscaled river networks

Endorheic drainage basins, those inland basins not connected directly to ocean, are essential for hydrological modeling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. Within many hydrological model frameworks, river basins are defined by digital river networks through their flow direction and connectivity datasets. Here we present an improvement to gridded flow direction data and its derivatives produced from upscaled global 5 and 15 arc minute MERIT networks. We explicitly label endorheic and exorheic drainage basins and alter the delineation of endorheic basins by merging small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion of those basins since most of the merged catchments were inside other larger endorheic areas. We developed and present here the endorheic basin delineation method. This method performs an analysis of the contributing river and basin geometry relative to the location of the flow end point (i.e. potential endorheic lake), proximity of the latter to the drainage basin boundary and the elevation difference between the basin's lowest point and potential spillover location at the basin boundary. The new digital river network was validated using the University of New Hampshire Water Balance Model by comparing the water balance of endorheic inland depressions with modeled accumulation of water in their inland lakes based on the observed historical climate drivers used by WBM.

Earth Systems↗

MERIT-Plus Dataset: Delineation of endorheic basins in 5 and 15 min upscaled river networks

Endorheic drainage basins, those inland basins not connected directly to ocean, are essential for hydrological modeling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. Within many hydrological model frameworks, river basins are defined by digital river networks through their flow direction and connectivity datasets. Here we present an improvement to gridded flow direction data and its derivatives produced from upscaled global 5 and 15 arc minute MERIT networks. We explicitly label endorheic and exorheic drainage basins and alter the delineation of endorheic basins by merging small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion of those basins since most of the merged catchments were inside other larger endorheic areas. We developed and present here the endorheic basin delineation method. This method performs an analysis of the contributing river and basin geometry relative to the location of the flow end point (i.e. potential endorheic lake), proximity of the latter to the drainage basin boundary and the elevation difference between the basin's lowest point and potential spillover location at the basin boundary. The new digital river network was validated using the University of New Hampshire Water Balance Model by comparing the water balance of endorheic inland depressions with modeled accumulation of water in their inland lakes based on the observed historical climate drivers used by WBM.

Earth Systems↗

MERIT-Plus Dataset: Delineation of endorheic basins in 5 and 15 min upscaled river networks

Endorheic drainage basins, those inland basins not connected directly to ocean, are essential for hydrological modeling of global and regional water balances, land surface water storage, gravity anomalies, sea level rise, etc. Within many hydrological model frameworks, river basins are defined by digital river networks through their flow direction and connectivity datasets. Here we present an improvement to gridded flow direction data and its derivatives produced from upscaled global 5 and 15 arc minute MERIT networks. We explicitly label endorheic and exorheic drainage basins and alter the delineation of endorheic basins by merging small inland watersheds to the adjacent host basins. The resulting datasets have a significantly reduced number of endorheic basins while preserving the total land portion of those basins since most of the merged catchments were inside other larger endorheic areas. We developed and present here the endorheic basin delineation method. This method performs an analysis of the contributing river and basin geometry relative to the location of the flow end point (i.e. potential endorheic lake), proximity of the latter to the drainage basin boundary and the elevation difference between the basin's lowest point and potential spillover location at the basin boundary. The new digital river network was validated using the University of New Hampshire Water Balance Model by comparing the water balance of endorheic inland depressions with modeled accumulation of water in their inland lakes based on the observed historical climate drivers used by WBM.

Earth Systems↗

N(50) Crater Retention Ages for an Expanded Inventory of Lunar Basins: Evidence for an Early Heavy Bombardment and a Late Heavy Bombardment?

LOLA topography and LOLA-derived crustal thickness data provide evidence for a population of impact basins on the Moon that is likely a factor 2 larger than the classical lists based on photogeology. Frey (2012) determined N(50) crater retention ages (CRAs) for 83 candidate basins > 300 km in diameter by counting LOLA-identified craters superimposed over the whole area of the basins. For some basins identified in topography or model crustal thickness it is not possible to unambiguously identify the crater rim as is traditionally done. Also, Quasi-Circular Depressions (QCDs) > 50 km in diameter are recognizable in the mare-filled centers of many basins. Even though these are not apparent in image data, they likely represent buried impact craters superimposed on the basin floor prior to mare infilling and so should be counted in determining the age of the basin. Including these as well as the entire area of the basins improves the statistics, though the error bars are still large when using only craters > 50 km in diameter. The distribution of N(50) CRAs had two distinct peaks which did not depend on whether the basins were named (based on photogeology) or recognized first in topography or crustal thickness data. It also did not depend on basin diameters (both larger and smaller basins made up both peaks) and both peaks persisted even when weaker candidates were excluded. Burgess (2012, unpublished data) redid the counts for 85 basins but improved on the earlier effort by adjusting the counting area where basins overlap. The two peak distribution of N(50) ages was confirmed, with a younger peak at N(50) ~ 40-50 and an older peak at N(50) ~ 80-90 (craters > 50 km diameter per million square km). We suggest this could represent two distinct populations of impactors on the Moon: one producing an Early Heavy Bombardment (EHB) that predates Nectaris and the second responsible for the more widely recognized Late Heavy Bombardment (LHB).

Frey, Herbert↗

Basin-Scale Opportunity Assessment Initiative Background Literature Review

As called for in the March 24, 2010, Memorandum of Understanding (MOU) for Hydropower, the U.S. Department of Energy (DOE), the U.S. Department of the Interior (DOI), the U.S. Army Corps of Engineers (USACE), environmental stakeholders, and the hydropower industry are collaborating to identify opportunities to simultaneously increase electricity generation and improve environmental services in river basins of the United States. New analytical tools provide an improved ability to understand, model, and visualize environmental and hydropower systems. Efficiencies and opportunities that might not be apparent in site-by-site analyses can be revealed through assessments at the river-basin scale. Information from basin-scale assessments could lead to better coordination of existing hydropower projects, or to inform siting decisions (e.g., balancing the removal of some dams with the construction of others), in order to meet renewable energy production and environmental goals. Basin-scale opportunity assessments would inform energy and environmental planning and address the cumulative effects of hydropower development and operations on river basin environmental quality in a way that quantifies energy-environment tradeoffs. Opportunity assessments would create information products, develop scenarios, and identify specific actions that agencies, developers, and stakeholders can take to locate new sustainable hydropower projects, increase the efficiency and environmental performance of existing projects, and restore and protect environmental quality in our nation's river basins. Government agencies and non-governmental organizations (NGO) have done significant work to understand and assess opportunities for both hydropower and environmental protection at the basin scale. Some initiatives have been successful, others less so, and there is a need to better understand the legacy of work on which this current project can build. This background literature review is intended to promote that understanding. The literature review begins with a discussion in Section 2.0 of the Federal regulatory processes and mission areas pertaining to hydropower siting and licensing at the basin scale. This discussion of regulatory processes and mission areas sets the context for the next topic in Section 3.0, past and ongoing basin-scale hydropower planning and assessment activities. The final sections of the literature review provide some conclusions about past and ongoing basin-scale activities and their relevance to the current basin-scale opportunity assessment (Section 4.0), and a bibliography of existing planning and assessment documents (Section 5.0).

13 HYDRO ENERGY↗

Strong Influence of Irrigation on Water Budget and Land Surface Temperature in Indian Subcontinental River Basins

Irrigation modulates the terrestrial water budget, especially in intensively irrigated regions such as Indian sub-continent river basins, where 35% of agricultural land has been irrigated during 2010. Here, we investigate the impact of irrigation on water budget components and land surface temperature (LST), as well as seasonal and annual trends of irrigation water demand in response to climate variability over the Indian sub-continental region. We use the Variable Infiltration Capacity (VIC) model coupled with an irrigation scheme (VIC-IRR) to represent the irrigation activities. The VIC-IRR model was calibrated and evaluated against in-situ and remote sensing observations including streamflow from India-Water Resource Information System (WRIS), Terrestrial Water Storage Change (TWSC) from Gravity Recovery and Climate Experiment (GRACE), LST from Advanced Along-Track Scanning Radiometer (AATSR), and observed gravimetric soil moisture data from India Meteorology Department (IMD). We conducted two simulations (i.e., with and without irrigation) over 18 Indian sub-continental basins at 0.25° spatial resolution from 1951 to 2012. The comparison between the two simulations indicates that as a result of irrigation, evapotranspiration (ET) increases in all the basins. We find that mean annual ET of Indus and Ganges basins increases by 47% and 12%, respectively due to irrigation. After irrigation, basin averaged total runoff (TR) was increased in the most irrigated basins (i.e., Sabarmati, Ganges, and Indus) by 4.62%, 11.87% and 7.06% in the monsoon, pre-monsoon, and post-monsoon seasons, respectively. The land surface temperature was cooled down in range of 0.2-0.65 °C in the Indian sub-continental basins especially in Ganges and Indus basins. Compare to other basins; irrigation water demand was high in Indus and Ganges basins during the post-monsoon season. Using the nonparametric Mann–Kendall trend test we find that in the pre-monsoon and monsoon seasons over the study period, irrigation demand decreased by 8.25 mm/year in 13 basins. Whereas for the post-monsoon season, irrigation water demand increased in 12 out of the 18 basins. Changes in irrigation demands are largely driven by changes in soil moisture due to decline in the summer monsoon precipitation.

54 ENVIRONMENTAL SCIENCES↗

Synthesis of Post-fire Monitoring Activities in the Great Basin Desert, Mojave Desert, and Transition Zones

In the deserts of the American Southwest, fire return intervals of centuries to millennia are being replaced by fire return intervals of decades. This increased burn frequency has implications for post-closure management and long-term stewardship for Soils Corrective Action Units (CAUs) and Corrective Action Sites (CASs) on the Nevada National Security Site (NNSS), Tonopah Test Range, and Nevada Test and Training Range for which the U.S. Department of Energy (DOE), Environmental Management-Nevada (EM-NV) is responsible. For many CAUs and CASs, where closure-in-place alternatives were implemented or are being considered, there is a chance that these sites could burn over while they still pose a risk to the environment or human health given the long half-lives of some of the radionuclide contaminants of concern (COCs) (Shafer et al., 2007; Shafer and Gomes, 2009). Although it would have been ideal to conduct a fire-related study at a radionuclide contaminated site on the NNSS to determine how contaminated soils are transported post-fire, it was more practical to examine fires in environments analogous to where Soils Activity CAUs and CASs exist. Therefore, a series of studies were initiated at three radiologically uncontaminated analog sites to better understand the possible effects of wildfire on erosion and sediment transport by wind and water should vegetation at contaminated sites burn at the NNSS. The studies took place at the sites of the Gleason Fire, a prescribed burn that occurred near Ely, Nevada, which is in the Great Basin ecoregion; the White Rock Fire that occurred near Mesquite, Nevada, which is in the Mojave Desert ecoregion; and the Jacob Fire that occurred near Hiko, Nevada, in the transitional zone between the Great Basin Desert and the Mojave Desert. Each site was representative of one of the three ecoregions found on the NNSS. Erosion and vegetation characteristics were measured multiple times post-fire on both burned and unburned test plots at these study sites to compare and monitor the effects of fire over time. However, at the Mojave Desert site, there was an additional burn from nearly 25 years ago that was also compared with the more recent burned areas from 2013. Also, the time elapsed after the fire and the time when sampling began differed among the ecoregions. For example, at the Great Basin site, samples were collected prior to the fire and less than one month after the fire, whereas data collected at the Mojave Desert site did not occur until 22 months after the fire. The differences between the sample measurements and the time that elapsed after the fire may contribute to the variability in the data and the interpretations of the data. Runoff and water erosion were quantified through a series of rainfall and runoff simulation tests in which controlled amounts of water were delivered to the soil surface. Runoff data were collected from different microhabitats (e.g., undercanopies, interspace soils, ridges, and drainage areas). The data showed soil hydrophobicity (i.e., water repellency) on the Great Basin site for up to 12 months after the fire. The soil structure remained changed and weaker on the burned areas compared with the unburned areas for the three-year study period. Although runoff data at both the Great Basin site and transition zone site were highly variable, the post-fire runoff potential did not generally increase at either location after three years of monitoring. Mojave runoff did not differ much between fire ages or between burned and unburned areas, possibly because of the amount of vegetation growing on all three surfaces and because the fire intensity was likely lower relative to other ecoregions due to the amount of space between plants. Additionally, the measurements conducted on the Mojave fire occurred several years after the fire had burned and not within several months of the burn, which may also account for the lack of differences in runoff between burned and unburned locations. Wind erosion was assessed and quantified with a Portable In-Situ Wind ERosion Lab (PI-SWERL) on both the burned and unburned soils of different microhabitats (e.g., ridges, drainages, interspaces between plants, and plant undercanopies). Estimates of emissions (e.g., particulate matter with aerodynamic diameters less than or equal to 10 micrometers, or PM10) at different wind speeds were collected and filter samples were analyzed for chemical composition. The measurements among the fires were similar and the results of the wind erosion measurements indicate that there were seasonal influences on many parameters, but the potential for PM10 windblown dust emissions was higher on burned areas compared with unburned areas. Among the burned areas, drainages produced the most dust emissions, whereas burned ridges were the least emissive. Emissions at the Mojave site and transition zone site were similar between burned and unburned areas approximately three years after the respective fires. Emissions remained much greater on burned soils at the Great Basin site. However, site selection may have also contributed to the differences of emissions among the three study locations. Post-fire vegetation responses were documented for three years following each fire in different microhabitats (e.g., ridge, drainage, undercanopy, and interspace) at the Great Basin and transition zone sites. In 2013, at the Mojave fire site, random permanent plots were established in newly burned areas, areas that burned approximately 25 years ago, and an unburned control area. At each fire site, the regeneration of native plant species dominated the burned areas, but invasive annual grasses were present at each fire site. During the course of each three-year study, the invasive annual grasses increased in density or percentage at both the Great Basin and transition fire sites but not at the Mojave site, where annual invasive grasses remained high throughout the study period. However, the chronosequence data from the Mojave site indicate a transition to different invasive grass species with time. The post-burn vegetation at all three ecoregions is still in the early stages of succession, and shrub size should increase over time and shrub density should decrease over time. However, the recovery of the plant communities to pre-burn compositions may not occur for decades or centuries, or may not occur because of changes in climate and the presence of invasive annual grasses. Results from the three study locations suggested that contaminated soils on the NNSS that experienced wildfire had the potential for soil erosion and transport of contaminated soils. Both wind and soil runoff studies indicated that locations in the Great Basin and transition zone ecoregions were more susceptible to erosion than the Mojave Desert ecoregion, but the highest levels of erosion occurred during the early portions of the study (the first 24 months) and the Mojave Desert was not measured until 22 months after the burn. Additionally, data from the Great Basin indicated deeper soils may increase susceptibility to wind erosion. Historically, the Great Basin and transition zone ecoregions burned more frequently than the Mojave Desert because of fuel abundance and connectivity—and they continue to burn more frequently, particularly after the introduction of invasive grasses (Davies and Nafus, 2013). However, both ecoregions and the transition zone have burned with extensive, high-severity fires when certain weather and fuel conditions are met. For example, the high abundance and productivity of annual grasses and forbs—which are usually produced by above average winter precipitation—combined with early spring and summer warm, dry conditions. Future climate scenarios predict increased temperatures, variable to reduced precipitation, and larger, more extreme wildfires throughout western North America. These predictions suggest that future fires on the NNSS could increase in frequency, intensity, and severity similar to their analog ecosystems throughout the Great Basin and Mojave Desert (Dennison et al., 2014; Abatzoglou andWilliams, 2016; Westerling, 2016).

54 ENVIRONMENTAL SCIENCES↗

Tectonic controls on rift basin morphology: Evolution of the northern Malawi (Nyasa) rift

Radiometric (K-Ar and Ar-40/Ar-39) age determinations of volcanic and volcaniclastic rocks, combined with structural, gravity, and seismic reflection data, are used to constrain the age of sedimentary strata contained within the seismically and volcanically active northern Malawi (Nyasa) rift and to characterize changes in basin and flank morphologies with time. Faulting and volcanism within the Tukuyu-Karonga basin began at approximately 8.6 Ma, when sediments were deposited in abroad, initially asymmetric lake basin bounded on its northeastern side by a border fault system with minor topographic relief. Extensions, primarily by a slip along the border fault, and subsequent regional isostatic compensation led to the development of a 5-km-deep basin bounded by broad uplifted flanks. Along the low-relief basin margin opposite border fault, younger stratigraphic sequences commonly onlap older wedge-shaped sequences, although their internal geometry is often progradational. Intrabasinal faulting, flankuplift, and basaltic and felsic volcanism from centers at the northern end of the basin became more important at about 2.5 Ma when cross-rift transfer faults developed to link the Tukuyu-Karonga basin to the Rukwa basin. Local uplift and volcanic construction at the northern end of the basin led to a southeastward shift in the basin's depocenter. Sequence boundaries are commonly erosional along this low-relief (hanging wall) margin and conformable in the deep lake basin. The geometry of stratigraphic sequences and the distribution of the erosion indicate that horizontal and vertical crustal movements both across and along the length of the rift basin led to changes in levels of the lake, irrespective of paleoclimatic fluctuations.

Ebinger, C. J.↗