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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Agricultural Impacts on Nitrogen Cycling: Climate and Air Pollution (Final Technical Report)

We have successfully added a parameterization of ammonia emissions from synthetic fertilizer and manure from agriculture to Earth System Models. We have evaluated how emissions change in the future and the processes driving these changes. We have examined the impact of agricultural ammonia emissions on present-day air quality and have evaluated the impact of resolving the emissions with high temporal resolution. We have also examined the impact of how Earth System Models treat the cycling of emissions in soils. Our code, the Flows of Agricultural Nitrogen – version 2 – model (FANv2) has been run in both the CLM framework and the ELM framework. To my knowledge the code has not yet been fully implemented into ELM. Volatilization of ammonia (NH3) from fertilizers and livestock wastes forms a significant pathway of nitrogen losses in agricultural ecosystems and constitutes the largest source of atmospheric emissions of NH3. We have provided a major update to the process model FAN (Flow of Agricultural Nitrogen), which evaluates NH3 emissions interactively within an Earth system model; in this work, the Community Earth System Model (CESM) is used. The updated version (FANv2) includes a more detailed treatment of both physical and agricultural processes, which allows the model to differentiate between the volatilization losses from animal housings, manure storage, grazed pastures, and the application of manure and different types of mineral fertilizers. The modeled ammonia emissions are first evaluated at a local scale against experimental data for various types of fertilizers and manure, and they are subsequently run globally to evaluate NH3 emissions for 2010–2015 based on gridded datasets of fertilizer use and livestock populations. Comparison of regional emissions shows that FANv2 agrees with previous inventories for North America and Europe and is within the range of previous inventories for China. However, due to higher NH3 emissions in Africa, India, and Latin America, the global emissions simulated by FANv2(48 Tg N) are 30 %–40 % higher than in the existing inventories.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2005

Using Microwave and Infrared Radiances from Off-Nadir Pixels: Application of Radiative Transfer to Slanted Line-of-Sight and Comparisons with NASA EOS Aqua Data

The passive infrared and microwave nadir sounders such as (A)TOVS observe the atmosphere from a polar orbit by directing their scan pointed at the ground up to about 49 degrees from nadir. Except for the pixels located right on the satellite ground track, the radiance measurements collected by these instruments characterize hence atmospheric emission paths which are slanted with respect to the zenithal direction at the ground. At the outer swath edges, the deviations from nadir reach about 60 degrees in terms of Satellite Zenith Angle (SZA). The radiative transfer codes used in operational Numerical Weather Prediction applications make the appropriate corrections to account for the extra path induced by the non-zero SZA. However, no corrections are made to account for the fact that the atmospheric profiles along the slanted line-of-sight (LOS) are different from the vertical because of horizontal gradients in the atmosphere. Using NASA EOS Aqua satellite's orbits, zenith and azimuth angles, as well as three-dimensional fields of temperature, water vapor, and ozone produced by the NASA Global Modeling and Assimilation Office, we extracted slanted atmospheric profiles for actual soundings performed by the AIRS and AMSU-A instruments onboard EOS Aqua. We will present the results of our study comparing the calculated brightness temperatures along slanted LOS and vertical LOS with AIRS and AMSU-A observations.

Poli, Paul↗
NASA NTRS2006

An Improved Algorithm for Retrieving Surface Downwelling Longwave Radiation from Satellite Measurements

Retrieving surface longwave radiation from space has been a difficult task since the surface downwelling longwave radiation (SDLW) are integrations from radiation emitted by the entire atmosphere, while those emitted from the upper atmosphere are absorbed before reaching the surface. It is particularly problematic when thick clouds are present since thick clouds will virtually block all the longwave radiation from above, while satellites observe atmosphere emissions mostly from above the clouds. Zhou and Cess developed an algorithm for retrieving SDLW based upon detailed studies using radiative transfer model calculations and surface radiometric measurements. Their algorithm linked clear sky SDLW with surface upwelling longwave flux and column precipitable water vapor. For cloudy sky cases, they used cloud liquid water path as an additional parameter to account for the effects of clouds. Despite the simplicity of their algorithm, it performed very well for most geographical regions except for those regions where the atmospheric conditions near the surface tend to be extremely cold and dry. Systematic errors were also found for areas that were covered with ice clouds. An improved version of the algorithm was developed that prevents the large errors in the SDLW at low water vapor amounts. The new algorithm also utilizes cloud fraction and cloud liquid and ice water paths measured from the Cloud and the Earth's Radiant Energy System (CERES) satellites to separately compute the clear and cloudy portions of the fluxes. The new algorithm has been validated against surface measurements at 29 stations around the globe for the Terra and Aqua satellites. The results show significant improvement over the original version. The revised Zhou-Cess algorithm is also slightly better or comparable to more sophisticated algorithms currently implemented in the CERES processing. It will be incorporated in the CERES project as one of the empirical surface radiation algorithms.

Zhou, Yaping↗
NASA NTRS2000

Determination of Surface and Atmospheric Parameters from AIRS/AMSU/HSB Data

AIRS (Atmospheric Infra Red Sounder) is the first of a series of next generation high spectral resolution infrared sounders which will fly on satellite missions in the next decade. AIRS is a 2368 channel grating spectrometer, with spectral resolving power of roughly upsilon /Delta(upsilon) = 1200, which will fly on the EOS Aqua platform in December 2000 accompanied by AMSU A and HSB, which is similar to AMSU B. New methodology has been developed by the AIRS Science Team to analyze AIRS/AMSU/HSB data in the presence of multilayer broken clouds. The baseline AIRS/AMSU products include surface skin temperature, surface spectral emissivity, atmospheric temperature-moisture-ozone profiles and cloud heights and amounts. Research products include CO and CH4 profiles, total CO2 burden, and OLR. This methodology will be briefly described and results will be shown of AIRS Science Team simulations, based on one day of simulated global data.. RMS errors of atmospheric temperature profiles are expected to be better than 1 K for 1 km layer mean temperatures in up to 80% multilayer fractional cloud cover and RMS errors for moisture profiles are better than 15% for 2 km layers throughout the troposphere.

Susskind, Joel↗
NASA NTRS2000

Determination of Surface and Atmospheric Parameters from AIRS/AMSU/HSB Data

AIRS (Atmospheric Infra Red Sounder) is the first of a series of next generation high spectral resolution infrared sounders which will fly on satellite missions in the next decade. AIRS is a 2368 channel grating spectrometer, with spectral resolving power of roughly upsilon / DELTA upsilon) = 1200, which will fly on the Earth Observing System (EOS) Aqua platform in December 2000 accompanied by Advanced Micowave Sounding Unit (AMSU) A and High Spatial Bandwidth (HSB), which is similar to AMSU B. New methodology has been developed by the AIRS Science Team to analyze AIRS/AMSU/HSB data in the presence of multilayer broken clouds. The baseline AIRS/AMSU products include surface skin temperature, surface spectral emissivity, atmospheric temperature-moisture-ozone profiles and cloud heights and amounts. Research products include CO and CH4 profiles, total CO2 burden, and OLR. This methodology will be briefly described and results will be shown of AIRS Science Team simulations, based on one day of simulated global data. RMS errors of atmospheric temperature profiles are expected to be better than 1 K for 1 km layer mean temperatures in up to 80% multilayer fractional cloud cover and RMS errors for moisture profiles are better than 15% for 2 km layers throughout the troposphere.

Susskind, J.↗
NASA NTRS2021

Contribution of the World's Main Dust Source Regions to the Global Cycle of Desert Dust

Even though desert dust is the most abundant aerosol by mass in Earth's atmosphere, the relative contributions of the world's major source regions to the global dust cycle remain poorly constrained. This problem hinders accounting for the potentially large impact of regional differences in dust properties on clouds, the Earth's energy balance, and terrestrial and marine biogeochemical cycles. Here, we constrain the contribution of each of the world's main dust source regions to the global dust cycle. We use an analytical framework that integrates an ensemble of global aerosol model simulations with observationally informed constraints on the dust size distribution, extinction efficiency, and regional dust aerosol optical depth (DAOD). We obtain a dataset that constrains the relative contribution of nine major source regions to size-resolved dust emission, atmospheric loading, DAOD, concentration, and deposition flux. We find that the 22–29 Tg (1 standard error range) global loading of dust with a geometric diameter up to 20 µm is partitioned as follows: North African source regions contribute ∼ 50 % (11–15 Tg), Asian source regions contribute ∼ 40 % (8–13 Tg), and North American and Southern Hemisphere regions contribute ∼ 10 % (1.8–3.2 Tg). These results suggest that current models on average overestimate the contribution of North African sources to atmospheric dust loading at ∼ 65 %, while underestimating the contribution of Asian dust at ∼ 30 %. Our results further show that each source region's dust loading peaks in local spring and summer, which is partially driven by increased dust lifetime in those seasons. We also quantify the dust deposition flux to the Amazon rainforest to be ∼ 10 Tg yr−1, which is a factor of 2–3 less than inferred from satellite data by previous work that likely overestimated dust deposition by underestimating the dust mass extinction efficiency. The data obtained in this paper can be used to obtain improved constraints on dust impacts on clouds, climate, biogeochemical cycles, and other parts of the Earth system.

Dust↗
NASA NTRSDate not supplied

The Surface Longwave Downward Fluxes of the NASA GEWEX SRB Release 4.0 IP Products: Validation Against the Surface-Based BSRN and PMEL Observed Data

Since the NASA Global Energy Water Exchanges (GEWEX) Surface Radiation Budget (SRB) project released its 3rd version of products in 2010, the GEWEX Data Assessments Panel (GDAP) has been working on integrating various data products to address issues in the closing of the global energy and water cycles. The 4th version of the SRB products, Rel. 4.0-IP, has integrated data products from the cloud, aerosol, atmosphere, ocean surface, and land surface projects, coordinating within GDAP, to produce a long-term time series of TOA and surface radiative estimates. The Rel. 4-IP shortwave products span 34 years continuously from July 1983 to June 2017 on a quasi-equal-area 1degree longitude by 1degree latitude grid system. The longwave products are for land only from 1983-07 to 1987-12; for both land and ocean from 1988-01 to 2009-12; and ocean only from 2010-01 to 2017-06. The data are provided at 3 hourly, 3-hourly-monthly, daily and monthly means. The ISCCP HXS clouds and radiances are the key cloud input of the current GEWEX SRB algorithms. In addition, the longwave algorithm has also made changes in cloud microphysical property, surface skin temperature input, surface emissivity, atmospheric profile, adding longwave aerosol optical properties, revising cloud overlap procedure, and so on. Details of changes in both inputs and algorithms are documented in a NASA Algorithm Theoretical Basis Document (ATBD). We have validated the surface longwave downward fluxes against the surface-based Baseline Surface Radiation Network (BSRN) and the Pacific Marine Environmental Laboratory (PMEL) buoy data. As of 2020, the BSRN archive has 12,116 site-months of observed records from 73 stations on all seven continents, and as of 2017, PMEL archive has 4389 buoy months of observed records from 64 buoys deployed in the tropics of Pacific, Atlantic and Indian Oceans. This paper presents how the SRB Rel. 4.0-IP surface longwave downward fluxes compare with these surface-based measurements and how the comparison statistics differ from that of Rel. 3.0.

GEWEX SRB↗
NASA NTRS2016

Highlights from 4STAR Sky-Scanning Retrievals of Aerosol Intensive Optical Properties from Multiple Field Campaigns with Detailed Comparisons of SSA Reported During SEAC4RS

The 4STAR (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research) instrument combines airborne sun tracking capabilities of the Ames Airborne Tracking Sun Photometer (AATS-14) with AERONET (Aerosol Robotic Network)-like sky-scanning capability and adds state-of-the-art fiber-coupled grating spectrometry to yield hyperspectral measurements of direct solar irradiance and angularly resolved sky radiance. The combination of sun-tracking and sky-scanning capability enables retrievals of wavelength-dependent aerosol optical depth (AOD), mode-resolved aerosol size distribution (SD), asphericity, and complex refractive index, and thus also the scattering phase function, asymmetry parameter, single-scattering albedo (SSA), and absorption aerosol optical thickness (AAOT). From 2012 to 2014 4STAR participated in four major field campaigns: the U.S. Dept. of Energy's TCAP (Two-Column Aerosol Project) I & II campaigns, and NASA's SEAC4RS (Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys) and ARISE (Arctic Radiation - IceBridge Sea & Ice Experiment) campaigns. Establishing a strong performance record, 4STAR operated successfully on all flights conducted during each of these campaigns. Sky radiance spectra from scans in either constant azimuth (principal plane) or constant zenith angle (almucantar) were interspersed with direct beam measurements during level legs. During SEAC4RS and ARISE, 4STAR airborne measurements were augmented with flight-level albedo from the collocated Shortwave Spectral Flux Radiometer (SSFR) providing improved specification of below-aircraft radiative conditions for the retrieval. Calibrated radiances and retrieved products will be presented with particular emphasis on detailed comparisons of ambient SSA retrievals and measurements during SEAC4RS from 4STAR, AERONET, HSRL2 (High Spectral Resolution Lidar), and from in situ measurements.

Radiance↗
NASA NTRSDate not supplied

Accelerating TEMPO Air Quality Science Through STAQS

Soon after the launch of Tropospheric Emissions: Monitoring of Pollution (TEMPO) mission, NASA is supporting the Synergistic TEMPO Air Quality Science field study (STAQS) in summer 2023. This study’s main objective is to accelerate science with geostationary air quality observations from TEMPO to better understand its use in air pollution research and applications. Science objectives include, but are not limited to, TEMPO L2 product evaluation, the interpretation of the spatiotemporal evolution of TEMPO data during air quality events, assessment of anthropogenic emissions, contributions to chemical transport modeling, and environmental justice applications. These objectives can be accomplished through the integration of satellite data with systematically repeated high-resolution aircraft- and ground-based measurements in multiple urban environments. The primary urban cities considered include Los Angeles, New York City, and Chicago in June-August 2023. Measurements consist of airborne remote sensing observations of air quality constituents of nitrogen dioxide (NO2), formaldehyde (HCHO), ozone, and aerosols using the GeoCape Airborne Simulator and High-Spectral Resolution Lidar 2/Differential Absorption Lidar (HSRL2/DIAL) on the NASA JSC G-V aircraft, greenhouse gas observations from Airborne Visible InfraRed Imaging Spectrometer - Next Generation (AVIRIS-NG) and High Altitude Lidar Observatory (HALO) on the NASA LaRC G-III aircraft, and ground-based remote sensing and in situ observations of ozone, NO2, and HCHO from the Tropospheric Ozone Lidar Network (TOLNet), Pandora spectrometers, and ground-based monitoring networks. Key partnership studies providing in situ airborne observations include the NOAA Atmospheric Emissions and Reactions Observed from Megacities to Marine Areas (AEROMMA) field study on the NASA DC-8 in the same primary target areas as STAQS and Greater New York Oxidant, Tropospheric Halogens, and Aerosol Measurements and Modeling (GOTHAMM) field study on the NSF C-130 near New York City. This presentation will include a current status update of the STAQS mission and an overview of its measurement strategies and science objectives with the goal of promoting continued discussions for building and strengthening collaborations prior to the mission.

Laura Judd↗
NASA NTRS2014

The Lunar Atmosphere and Dust Environment Explorer (LADEE): Initial Science Results

On September 6, 2013, a near-perfect launch of the first Minotaur V rocket successfully carried NASA's Lunar Atmosphere and Dust Environment Explorer (LADEE) into a high-eccentricity geocentric orbit. LADEE arrived at the Moon on October 6, 2013, dur-ing the government shutdown. The spacecraft impact-ed the lunar surface on April 18, 2014, following a completely successful mission. LADEE's science objectives were twofold: (1) De-termine the composition and variability of the lunar atmosphere; (2) Characterize the lunar exospheric dust environment, and its variability. The LADEE science payload consisted of the Lunar Dust Experiment (LDEX), which sensed dust impacts in situ, for parti-cles between 100 nm and 5 micrometers; a neutral mass spectrometer (NMS), which sampled lunar exo-spheric gases in situ, over the 2-150 Dalton mass range; an ultraviolet/visible spectrometer (UVS) ac-quired spectra of atmospheric emissions and scattered light from tenuous dust, spanning a 250-800 nm wave-length range. UVS also performed dust extinction measurements via a separate solar viewer optic. The following are preliminary results for the lunar exosphere: (1) The helium exosphere of the Moon, first observed during Apollo, is clearly dominated by the delivery of solar wind He++. (2) Neon 20 is clearly seen as an important constituent of the exosphere. (3) Argon 40, also observed during Apollo and arising from interior outgassing, exhibits variations related to surface temperature-driven condensation and release, and is also enhanced over specific selenographic longi-tudes. (4) The sodium abundance varies with both lu-nar phase and with meteoroid influx, implicating both solar wind sputtering and impact vaporization process-es. (5) Potassium was also routinely monitored and exhibits some of the same properties as sodium. (6) Other candidate species were seen by both NMS and UVS, and await confirmation. Dust measurements have revealed a persistent "shroud" of small dust particles between 0.7 and sev-eral micrometers in size, present over the pre-dawn and morning sector of the Moon. This tenuous dust exosphere, with densities of approximately 10(exp -5) m(exp -3), appears to be sustained by the ejecta of micrometeoroid impacts.

lunar atmosphere↗
DOE OSTI2026

RuKY Catalyst‐Packed Permeation Membrane for Quantitative Ammonia and d3‐Ammonia Dehydrogenation to Ultrapure Hydrogen

Ammonia is a promising carbon-free hydrogen carrier, but incomplete ammonia dehydrogenation (cracking) generates atmospheric emissions of NO x , a potent greenhouse gas. Additionally, incomplete cracking of ammonia leads to regulatory challenges in nuclear and fusion power, where tritiated ammonia (NT 3 ) emissions are strictly controlled. Therefore, we report the use of low-temperature ammonia dehydrogenation catalysts (3%Ru/1%Y/12%K/Al 2 O 3 ) in a palladium alloy H 2 permeation membrane for quantitative conversion of ammonia into hydrogen and nitrogen at industry-relevant conditions. This catalytic membrane reactor system achieved an astonishing effluent concentration of <1 ppm at 450°C under a 100% NH 3 stream, which is far beyond the 99.6% conversion target required for the adoption of ammonia as a vehicle fuel. The low-temperature ammonia dehydrogenation catalyst was tested in a packed bed reactor with NH 3 and ND 3 to both elucidate the reaction mechanism and to quantify the kinetic isotope effect of the membrane reactor. The rate-limiting step at temperatures relevant to the palladium membrane are isotope independent, indicating that the isotopologue content will not modify the desired reaction kinetics. By reducing emissions to below-trace levels with no additional separation, this work provides a path to greatly simplified and miniaturized ammonia cracking processes.

ammonia decomposition↗
DOE OSTI2024

Conversion of Site-Specific Meteorological Data for use in CAP-88 PC

CAP-88 PC is a commonly used radiological atmospheric dispersion model. This US EPA-approved model is used to demonstrate compliance with atmospheric emission regulations for radionuclides. While the model includes a large library of meteorological data for use across the United States, there are applications when users may wish to use onsite meteorological data as an input to the CAP-88 PC model. Here, in this work, we present a work-around process for preparing and converting onsite data for use in CAP-88 PC. However, the use of local data should provide a more realistic estimate of doses to members of the public in the immediate vicinity of a facility, although the regulatory agency having jurisdiction may not accept the use of local data for compliance. Additionally, the historical meteorological records from 20+ years ago (at a site many kilometers away) might not be representative of current local weather patterns, highlighting another benefit of using local meteorological data.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Fermentation‐mediated growth, signaling, and defense in plants

Summary While traditionally considered important mainly in hypoxic roots during flooding, upregulation of fermentation pathways in plants has recently been described as an evolutionarily conserved drought survival strategy, with acetate signaling mediating reprograming of transcription and cellular carbon and energy metabolism from roots to leaves. The amount of acetate produced directly correlates with survival through potential mechanisms including defense gene activation, biosynthesis of primary and secondary metabolites, and aerobic respiration. Here, we review root ethanolic fermentation responses to hypoxia during saturated soil conditions and summarize studies highlighting acetate fermentation under aerobic conditions coupled with respiration during growth and drought responses. Recent work is discussed demonstrating long‐distance transport of acetate via the transpiration stream as a respiratory substrate. While maintenance and growth respiration are often modeled separately in terrestrial models, here we propose the concept of ‘Defense Respiration’ fueled by acetate fermentation in which upregulation of acetate fermentation contributes acetate substrate for alternative energy production via aerobic respiration, biosynthesis of primary and secondary metabolites, and the acetylation of proteins involved in defense gene regulation. Finally, we highlight new frontiers in leaf‐atmosphere emission measurements as a potential way to study acetate fermentation responses of individual leaves, branches, ecosystems, and regions.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

An improved mechanistic model for ammonia volatilization in Earth system models: Flow of Agricultural Nitrogen version 2 (FANv2)

Abstract. Volatilization of ammonia (NH 3 ) from fertilizers and livestock wastes forms a significant pathway of nitrogen losses in agricultural ecosystems and constitutes the largest source of atmospheric emissions of NH 3 . This paper describes a major update to the process model FAN (Flow of Agricultural Nitrogen), which evaluates NH 3 emissions interactively within an Earth system model; in this work, the Community Earth System Model (CESM) is used. The updated version (FANv2) includes a more detailed treatment of both physical and agricultural processes, which allows the model to differentiate between the volatilization losses from animal housings, manure storage, grazed pastures, and the application of manure and different types of mineral fertilizers. The modeled ammonia emissions are first evaluated at a local scale against experimental data for various types of fertilizers and manure, and they are subsequently run globally to evaluate NH3 emissions for 2010–2015 based on gridded datasets of fertilizer use and livestock populations. Comparison of regional emissions shows that FANv2 agrees with previous inventories for North America and Europe and is within the range of previous inventories for China. However, due to higher NH 3 emissions in Africa, India, and Latin America, the global emissions simulated by FANv2 (48 Tg N) are 30 %–40 % higher than in the existing inventories.

Vira, Julius↗
NASA NTRS1972

Post-sunset cooling behavior of the lunar surface.

Differential IR flux scans at 22 microns have been made across the nighttime lunar surface over a range of phases before and after new moon. The differential chopping technique effectively cancels atmospheric emission in the beam path but records the flux difference between adjacent resolution elements on the lunar disk. The scans show that the brightness temperature gradient across the highlands after sunset is much greater than that across the western maria. The large gradients consistently disappear approximately 3.5 days after sunset. The postsunset enhancement could be due to surface roughness in the highlands or to a significant surface rock population with a mean size of approximately 0.5 m.

Mendell, W. W.↗
NASA NTRS1973

Photodissociation continuums of N2 and O2.

Dissociation continuum cross sections for N2 and O2 have been determined from previously measured total absorption and ionization cross sections. Several dissociation continuums were found for each molecule. Some of these continuums were attributed to specific dissociation products in which the dissociation products are in excited states. The upper-atmosphere emission rates resulting from these photodissociative excitation processes have been calculated for the N I 10,400-A and O I 1356-A lines. The results indicate, particularly for the oxygen line, that these photodissociative processes may be important in the dayglow.

Cook, G. R.↗