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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Coeval Ar-40/Ar-39 ages of 65.0 million years ago from Chicxulub crater melt rock and Cretaceous-Tertiary boundary tektites

Ar-40/Ar-39 dating of drill-core samples of a glassy melt rock recovered from beneath a massive impact breccia contained with the 180-kilometer subsurface Chicxulub crater yields well-behaved incremental heating spectra with a mean plateau age of 64.98 +/- 0.05 million years ago (Ma). The glassy melt rock of andesitic composition was obtained from core 9 (1390 to 1393 meters) in the Chicxulub 1 well. The age of the melt rock is virtually indistinguishable from Ar-40/Ar-39 ages obtained on tektite glass from Beloc, Haiti, and Arroyo el Mimbral, northeastern Mexico, of 65.01 +/- 0.08 Ma (mean plateau age for Beloc) and 65.07 +/- 0.10 Ma (mean total fusion age for both sites). The Ar-40/Ar-39 ages, in conjunction with geochemical and petrological similarities, strengthen the suggestion that the Chicxulub structure is the source for the Haitian and Mexican tektites and is a viable candidate for the Cretaceous-Tertiary boundary impact site.

Swisher, Carl C., III↗
NASA NTRS1993

Ar-40/Ar-39 age spectra of Apollo 15 impact melt rocks by laser step-heating and their bearing on the history of lunar basin formation

Results are reported on 26 high-resolution (16-51 steps) Ar-40/Ar-39 age spectra obtained on 12 Apollo-15 melt rocks of different composition using a continuous laser system on submg fragments of recrystallized melt and single-crystal plagioclase clasts from impact melt rocks collected at the Apennine Front where the Imbrium and Serenitatis basins intersect. A table is presented with the summary of the Ar-40/Ar-39 spectrum data, which represent 891 individual temperature step analyses. Also presented are 20 of the 26 age spectra along with their respective K/Ca plots. Melt rock fragments and plagioclase clasts from seven of the 12 samples analyzed yielded reproducible, intermediate-T Ar-40/Ar-39 age spectrum plateaus, which were interpreted as crystallization ages that represent the times of impact of bolides onto the lunar surface.

Dalrymple, G. B.↗
NASA NTRS1995

A generic interface element for COMET-AR

The implementation of an interface element capability within the COMET-AR software system is described. The report is intended for use by both users of currently implemented interface elements and developers of new interface element formulations. Guidance on the use of COMET-AR is given. A glossary is provided as an Appendix to this report for readers unfamiliar with the jargon of COMET-AR. A summary of the currently implemented interface element formulation is presented in Section 7.3 of this report.

Mccleary, Susan L.↗
NASA NTRS2000

Mass Spectrometric and Langmuir Probe Measurements in Inductively Coupled Plasmas in Ar, CHF3/Ar and CHF3/Ar/O2 Mixtures

Absolute fluxes and energy distributions of ions in inductively coupled plasmas of Ar, CHF3/Ar, and CHF3/Ar/O2 have been measured. These plasmas were generated in a Gaseous Electronics Conference (GEC) cell modified for inductive coupling at pressures 10-50 mTorr and 100-300 W of 13.56 MHz radio frequency (RF) power in various feedgas mixtures. In pure Ar plasmas, the Ar(+) flux increases linearly with pressure as well as RF-power. Total ion flux in CHF3 mixtures decreases with increase in pressure and also CHF3 concentration. Relative ion fluxes observed in the present studies are analyzed with the help of available cross sections for electron impact ionization and charge-exchange ion-molecule reactions. Measurements of plasma potential, electron and ion number densities, electron energy distribution function, and mean electron energy have also been made in the center of the plasma with a RF compensated Langmuir probe. Plasma potential values are compared with the mean ion energies determined from the measured ion energy distributions and are consistent. Electron temperature, plasma potential, and mean ion energy vary inversely with pressure, but increase with CHF3 content in the mixture.

Kim, J. S.↗
NASA NTRS1996

The Infrared Spectra of Nitriles and Related Compounds Frozen in Ar and H2O

We present the 2320-2050/cm (4.31-4.88 micron) infrared spectra of 16 solid state nitrites, isonitriles, and related compounds in order to facilitate the assignment of absorption features in a spectral region now becoming accessible to astronomers for the first time through the Infrared Space Observatory (ISO). This frequency range spans the positions of the strong C(is congruent to)N stretching vibration of these compounds and is inaccessible from the ground due to absorption by CO2 in the terrestrial atmosphere. Band positions, profiles, and intrinsic strengths (A values) were measured for compounds frozen in Ar and H2O matrices at 12 K. The molecular species examined included acetonitrile, benzonitrile phenylcyanide) 9-anthracenecarbonitrile, dimethylcyanamide, isopropy1nitrile (isobutyronitrile), methylacrylonitrile, crotononitrile, acrylonitrile (vinyl cyanide), 3-aminocrotononitrile, pyr-uvonitrile, dicyandiamide, cyanamide, n-butyfisocyanide, methylisocyanoacetate, dilsopropylcarbodiimide, and hydrogen cyanide. The C(is congruent to)N stretching bands of the majority of nitrites fall in the 2300-2200/cm (4.35-4.55 micron) range and have similar positions in both Ar and H2O matrices, although the bands are generally considerably broader in the H2O matrices. In contest, the isonitriles and a few exceptional nitrites and related species produce bands at lower frequencies spanning the 2200-2080/cm (4.55-4.81 micron) range. These features also have similar positions in both Am and H2O matrices and the bands are broader in the H2O matrices. Three of the compounds (pyruvonitrile, dicyandiamide, and cyanamide) show unusually large shifts of their C(is congruent to)N stretching frequencies when changing from Ar to H2O matrices. We attribute these shifts to the formation of H2O:nitrile complexes with these compounds. The implications of these results for the identification of the 2165/cm (4.62 micron) "XCN" interstellar feature and the 4550/cm (2.2 micron) feature of various objects in the solar system are discussed.

Bernstain, Max P.↗
NASA NTRS2014

Ar-40/Ar-39 Age of Hornblende-bearing R Chondrite LAP 04840

Chondrites have a complex chronology due to several variables affecting and operating on chondritic parent bodies such as radiogenic heating, pressure and temperature variation with depth, aqueous alteration, and shock or impact heating [1]. Unbrecciated chondrites can record ages from 4.56 to 4.4 Ga that represent cooling in small parent bodies. Some brecciated chondrites exhibit younger ages (<<4 to 4.4 Ga) that may reflect the age of brecciation, disturbance, or shock and impact events (<< 4 Ga). A unique R chondrite was recently found in the LaPaz Icefield of Antarctica - LAP 04840 [2]. This chondrite contains approx.15% hornblende and trace amounts of biotite, making it the first of its kind. Studies have revealed an equigranular texture, mineral equilibria yielding equilibration near 650-700 C and 250-500 bars, hornblende that is dominantly OH-bearing (very little Cl or F), and high D/H ratios [8,9,10]. To help gain a better understanding of the origin of this unique sample, we have measured the Ar-40/Ar-39 age. Age of 4.290 +/- 0.030 Ga is younger than one would expect for a sample that has cooled within a small body [4], and one might instead attribute the age to a younger shock event, On the other hand, there is no evidence for extensive shock in this meteorite (shock stage S2; [3]), so this sample may have been reannealed after the shock event. This age is similar to Ar-Ar ages determined for some other R chondrites

Righter, K.↗
NASA NTRS1972

Vibrationally inelastic low-energy CO/+/ - Ar collisions.

Examination of relative differential cross sections for inelastic scattering of CO(+) by Ar with a high-resolution ion-beam apparatus in which a CO(+) beam interacts with a neutral-Ar beam, and the energy, mass, and angular distribution of scattered ions are measured. Maxima in the inelastic energy-loss spectra occur at energies corresponding to CO(+) spectroscopic vibrational spacings. Weakly inelastic processes are observed below the threshold for vibrational energy loss, corresponding to rotational excitation with the relative importance of rotational transitions increasing with decreasing energy and scattering angle.

Petty, F.↗
NASA NTRS1972

Thermal release characteristics of spallogenic He, Ne, and Ar from the Carbo iron meteorite.

Analysis of the thermal release patterns of He, Ne, and Ar from samples of the Carbo iron meteorite, showing that virtually no fractionation of He 3, He 4, Ne 21, and Ar 38 occurs. Thus conclusions about iron meteorites based on measured noble gas ratios will be unaffected by gas loss, and measurement of these ratios cannot yield information about possible loss. Further, noble gas loss cannot explain the abnormal elemental and isotopic patterns observed in some iron meteorites, notably hexahedrites. The release of He and Ne was continuously observed throughout the stepwise heating sequence, and ratios of diffusion coefficients at two consecutive temperatures have been determined from measurements of the relative degassing rates at these temperatures at the time of temperature increase. Effective activation energies of 100 plus or minus 20 kcal/mol for both He 3 and Ne 21 are calculated from the diffusion coefficient ratios at temperatures above 1050 C. A sharp maximum at 750 C in both the effective activation energy and the gas release is correlated with the alpha, gamma-phase transition.

Nyquist, L. E.↗
NASA NTRS1972

K-Ar dating of lunar fines - Apollo 12, Apollo 14, and Luna 16.

K-Ar ages were determined on a 6-in. double-focus mass spectrometer in fines of less than 1 mm from Apollo 14 and 16, and Luna 16 lunar soil samples. Age estimates of about 2.8 AE and about 4.0 AE are suggested for the two low-K components whose presence in the samples must be assumed to accommodate the age data. An average value of 0.1849 plus or minus 0.0008 was obtained for the Ar-18/Ar-36 ratio in the solar wind from ordinate intercept correlations for the Apollo 14 and Luna 16 samples. Cosmic ray exposure ages were close to 440 m.y. for both Apollo 14 samples and close to 840 m.y. for both Luna 16 samples.

Pepin, R. O.↗
NASA NTRS1973

He, Ne and Ar in chondritic Ni-Fe as irradiation hardness sensors.

Noble gas analyses of the Ni-Fe of 9 L, 5 H, and 2 LL chondrites quantitatively support previous suggestions of radiogenic He-4 recoil and He-3 deficits. Furthermore, noble gases in the Ni-Fe show evidence for in situ produced radiogenic He-4 and in some cases for recoil loss of Ar-38 and gain of Ne-21. The ratio of spallogenic Ar-38 and Ne-21 in the metal phase is found to correlate strongly with He-3/Ne-21 and Ne-22/Ne-21 in bulk samples of these chondrites. This is proof of the dependence of these ratios on the irradiation hardness experienced by the meteoroid in space. 'Hardness indices' n equals 1.9-2.2 are found, indicating that on the average the stone meteoroids from which the samples came were smaller in mass than iron meteoroids. The spallogenic Ne-21/Ar-38 ratio in metallic Ni-Fe can be used with the semi-empirical production model deduced from the Grant iron meteorite to calibrate spallogenic He-3/Ne-21 and Ne-21/Ar-38 in bulk samples of L, LL and H chondrites for meteoroid size and sample location allowing the estimation of minimal meteoroid masses.

Nyquist, L.↗
NASA NTRS1974

Multiplet effects on the L/sub 2,3/ fluorescence yield of multiply ionized Ar

The 2p fluorescence yield of Ar in the presence of zero to six 3p holes has been calculated by statistically averaging the fluorescence yields of initial states that consist of individual multiplet configurations, formed by coupling the 2p vacancy to the partially filled 3p shell. The L(sub 2,3) fluorescence yields for the (2p)-1 (3p)-n configurations of Ar are found to be 1.48, 17.97, 24.83, 37.84, 79.61, 112.16, and 121.48 x .0001 for n = 0, 1, 2, 3, 4, 5, and 6, respectively. Results agree reasonably well with experimental fluorescence yields deduced from ion-atom collision measurements.

Chen, M. H.↗
NASA NTRS1974

K-Ar analysis of Apollo 11 fines 10084

Regolithic history of Mare Tranquillitatus is studied with rare gas and mass spectrometric techniques. Grain size-ordinate intercept analysis is applied to bulk soil, ilmenite, and plagioclase separates obtained from 1 mm or smaller fines sample 10084,48. K-Ar ages for ilmenite, plagioclase, and total soil separates are determined to be 2.80, 3.38 and 4.00 AE, respectively. It appears that 10084,48 may consist primarily of two components. In this view, the first is locally derived, forms 65-75% of the present day regolith and may show that a local degassing event(s) occurred between 2.8 and 3.5 AE ago. The second component is similar to material from the lunar highlands. It may be local or foreign in origin and contributes the remaining 25-35% of the soil. This component exhibits an age of 4.00 AE and is either slightly older than, or contemporaneous with, the oldest of the returned Apollo 11 basalts. Within the limits of experimental error, the trapped Ar-38/Ar-36 ratio is constant at 0.1890 for all the soil components examined.

Basford, J. R.↗
NASA NTRS1974

Episodic release of Ar-40 from the interior of the moon

Measurements of lunar atmosphere made by the mass spectrometer at the Apollo 17 landing site during the first 9 lunations of 1973 show an apparently cyclical variation of radiogenic Ar-40, with maximum to minimum abundance ratio of about 2. There seems to be a 6-7 month periodicity in the oscillation, but the limited data base makes a fixed oscillatory pattern uncertain. The significance of the variation of atmospheric argon lies in the implication that its source is episodic in nature, ranging in strength from about 1% of the total rate of production of Ar-40 in the moon to near zero. This requires a presently active mechanism for transient venting of gas from deep within the moon.

Hodges, R. R., Jr.↗
NASA NTRS1976

Adsorption of Ar on a nonuniform MgO surface

Data are presented for the adsorption of Ar and N2 on a strongly heterogeneous MgO surface at 84 K and for Ar at a range of temperatures between 130 and 250 K. The high-temperature data are analyzed according to a model which separates the contributions to the potential into bulk and surface terms, providing a method for the determination of the surface area from parameters characteristic of the bulk material. A solid-gas energy parameter and parameters indicating the strength of the impurity sites are also evaluated.

Hinman, D. C.↗
NASA NTRS1976

Ar-40/Ar-39 dating of collisional events in chondrite parent bodies

Ar-40/Ar-39 age dating of a number of shocked ordinary chondrites is interpreted in terms of collisional degassing events of meteorite parent bodies, probably in the asteroid belt. Examples of L, H, and at least one LL chondrite show episodic degassing. Degassing ages suggest several distinct events ranging from about 0.03 aeon to 0.7 aeon and probably higher. All specimens of either the H or L chondrites are not consistent with a single age event. A direct correlation exists between the degree of shock heating and the fraction of argon lost during degassing. However, no chondrite yet analyzed shows complete degassing of its high-temperature phase. Consequently, whole rock K-Ar ages are not accurate monitors of the time of the shock event.

Bogard, D. D.↗
NASA NTRS1977

Studies of Ar and N2 using threshold photoelectron spectroscopy by electron attachment /TPSA/

Threshold photoelectron spectra of Ar and N2 are studied by a technique called threshold photoelectron spectroscopy by electron attachment, which involves the attachment of the threshold electron to SF6 followed by the detection of SF6(-). Studies on Ar provide a measure of the rejection ratio for nonthreshold electrons of this technique. A rotational propensity rule is given which states that an autoionizing N2 state prefers to decay to N2(+) states with a minimum change in rotational angular momentum.

Chutjian, A.↗