First-Principles Analysis of Potential-Dependent Proton Coupled Electron Transfer between Polypyridyl–Ruthenium Complexes and Oxygen-Modified Graphene Electrodes
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We extend and correct a recently proposed maximum-likelihood halo-independent method to analyze unbinned direct dark matter detection data. Instead of the recoil energy as independent variable we use the minimum speed a dark matter particle must have to impart a given recoil energy to a nucleus. This has the advantage of allowing us to apply the method to any type of target composition and interaction, e.g. with general momentum and velocity dependence, and with elastic or inelastic scattering. We prove the method and provide a rigorous statistical interpretation of the results. As first applications, we find that for dark matter particles with elastic spin-independent interactions and neutron to proton coupling ratio f{sub n}/f{sub p}=−0.7, the WIMP interpretation of the signal observed by CDMS-II-Si is compatible with the constraints imposed by all other experiments with null results. We also find a similar compatibility for exothermic inelastic spin-independent interactions with f{sub n}/f{sub p}=−0.8.
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Here, labdane-related diterpenoids are natural products with potential pharmaceutical applications that are rarely found in bacteria. Here, a putative class I labdane-related diterpene synthase (LrdC) identified by genome mining in a streptomycete was successfully crystallized using the microbatch method. Crystals of the LrdC enzyme were obtained in a holo form with its natural cofactor Mg 2+ (LrdC-Mg 2+ ) and in complex with inorganic pyrophosphate (PP i ) (LrdC-Mg 2+ –PP i ). Crystals of native LrdC-Mg 2+ diffracted to 2.50 Å resolution and belonged to the trigonal space group P3 2 21, with unit-cell parameters a = b = 107.1, c = 89.2 Å. Crystals of the LrdC-Mg 2+ –PP i complex grown in the same conditions as the native enzyme with PEG 8000 diffracted to 2.36 Å resolution and also belonged to the trigonal space group P3 2 21. Crystals of the LrdC-Mg 2+ –PP i complex grown in a second crystallization condition with PEG 3350 diffracted to 2.57 Å resolution and belonged to the monoclinic space group P2 1 , with unit-cell parameters a = 49.9, b = 104.1, c = 66.5 Å, β = 111.4°. The structure was determined by the single-wavelength anomalous dispersion (SAD) technique using the osmium signal from a potassium hexachloroosmate (IV) derivative.
As the power grid incorporates increasing amounts of distributed energy resources (DER) that provide new generation sources, new opportunities are created for improving operation of the grid while large challenges also arise for preserving grid reliability and security. To improve grid performance, DERs can be utilized to provide important support functionality, such as supporting frequency and voltage levels, especially if they are assisted by communication schemes as part of an advanced distribution management system (ADMS). Unfortunately, such connectivity and grid support functionality also creates additional cyber security risk with the potential for degradation of grid services, especially under conditions with high amounts of distributed generation. This paper will first discuss the communications needed by DERs to support system and interoperability objectives, as well as the security requirements and impact of securing these communications. Some common security mechanisms are discussed in relation to DERs, and a simulated 15-bus model of a distribution feeder is used to demonstrate aspects of the DER communications and impact to grid performance. These results help to advance understanding of the benefits, requirements, and mechanisms for securely implementing DER communications while ensuring that grid reliability is maintained.
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This study demonstrates a systematic methodology for establishing the design loads of a wave energy converter (WEC). The proposed design load methodology incorporates existing design guidelines, where they exist, and follows a typical design progression; namely, advancing from many, quick, order-of-magnitude accurate, conceptual stage design computations to a few, computationally intensive, high-fidelity, design validation simulations. The goal of the study is to streamline and document this process based on quantitative evaluations of the design loads' accuracy at each design step and consideration for the computational efficiency of the entire design process. For the WEC, loads, and site conditions considered, this study demonstrates an efficient and accurate methodology of evaluating the design loads.
Calculated frequency distributions of atom probe tomography reconstructions (∼80 nm field of view) of very thin Al{sub x}Ga{sub 1−x}N (0.18 ≤ x ≤ 0.51) films grown via metalorganic vapor phase epitaxy on both (0001) GaN/AlN/SiC and (0001) GaN/sapphire heterostructures revealed homogeneous concentrations of Al and chemically abrupt Al{sub x}Ga{sub 1−x}N/GaN interfaces. The results of scanning transmission electron microscopy and selected area diffraction corroborated these results and revealed that neither superlattice ordering nor phase separation was present at nanometer length scales.
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