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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Buffering of stratospheric circulation by changing amounts of tropical ozone - A Pinatubo case study

Stratospheric aerosol from Mount Pinatubo heated the tropical lower stratosphere by about 0.3 K/day mainly due to absorption of terrestrial infrared radiation. This heating was dissipated by: (1) an observed increase in stratospheric temperatures, which enhanced the radiation cooling; (2) additional mean upward motion, observed for the aerosol cloud, which led to adiabatic cooling; and (3) reductions in ozone concentrations resulting from enhanced upward motions. Each of these processes operated on a different time scale: maximum temperatures were observed after about 90 days; maximum ozone losses of about -1.5 ppm occurred after 140 days when the enhanced vertical velocities effectively lifted the ozone profile by about 2 km. We believe this shows that ozone plays an important role in buffering vertical motion in the tropical lower stratosphere, and hence the residual Brewer Dobson circulation of the whole stratosphere.

Kinne, S.↗
DOE OSTI2025

New Methods for Predicting Non-Born-Oppenheimer Chemistry

Current methods for modeling non-adiabatic molecular dynamics face fundamental limitations when treating geometric phase effects: quantum mechanical phenomena where nuclear wavepackets acquire phase shifts when encircling conical intersections. Existing approaches either neglect these effects entirely or rely on potential energy surfaces arising from the Born-Oppenheimer approximation, which introduce artificial singularities and can overestimate geometric phase contributions. This project developed a new theoretical framework based on exact factorization (XF) methods to overcome these limitations. We derived mathematical formulations for hybrid quantum-classical XF dynamics that selectively treat critical nuclear degrees of freedom quantum mechanically while propagating others classically. This approach addresses the computational intractability that has previously limited exact methods to toy systems. Key innovations include a new approach to systematically identifying nuclear coordinates requiring quantum treatment, as well as novel implementation strategies that interface with existing quantum chemistry codes. The project also developed a proof-of-concept code for treating Jahn-Teller systems and creation of educational materials on non-adiabatic dynamics geared at the graduate level. The theoretical framework developed will enable future systematically improvable calculations of nuclear quantum effects in realistic molecular systems, filling a critical gap in non-adiabatic dynamics methods. This foundation supports future development of predictive tools for designing energy-relevant photochemical processes where quantum coherence effects may be exploited to control reaction outcomes.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
NASA NTRS1983

Fast magnetospheric echoes of energetic electron beams

Electron beam experiments using rocket-borne instrumentation confirmed earlier observations of fast magnetospheric echoes of artificially injected energetic electrons. A total of 234 echoes were observed in a pitch angle range from 9 to 110 deg at energies of 1.87 and 3.90 keV. Of these, 102 echoes could unambiguously be identified with known accelerator operations at 2, 4 or 8 keV energy and highest current levels resulting in the determination of transit times of typically 300 to 400 ms. In most cases, when echoes were present in both energy channels, the higher energy electrons led the lower energy ones by 50 to 70 ms. Adiabatic theory applied to these observations yields a reflection height of 3000 to 4000 km. The injection process is discussed as the strong beam-plasma interaction that occurred near the electron accelerator appears to be instrumental in generating the source of heated electrons required for successful echo detection.

Wilhelm, K.↗
NASA NTRS1979

Release adiabat measurements on minerals: The effect of viscosity

The current inversion of pressure-particle velocity data for release from a high pressure shock state to a pressure-density path is analyzed. It is assumed that the release process is isentropic. It was shown that for geological materials below stresses of 150 GPa, the effective viscosity must be 1000 kg/m/s in order that the viscous (irreversible) work carried out on the material in the shock state remains small compared to the mechanical work recovered upon adiabatic rarefaction. The available data pertaining to the offset of the Rayleigh line from the Hugoniot for minerals, the magnitude of the shear stress in the high pressure shock state for minerals, and the direct measurements of the viscosities of several engineering materials shocked to pressures below 150 GPa yield effective viscosities of 1000 kg/m/s or less. An inferance that this indicates that the conditions for isentropic release of minerals from shock states are achieved, and a conclusion that the application of the Riemann integral to obtain pressure-density states along the release adiabats of minerals in shock experiments is valid are made.

Jeanloz, R.↗
NASA NTRS1997

Nonguiding Center Motion and Substorm Effects in the Magnetotail

Thick and thin models of the middle magnetotail were developed using a consistent orbit tracing technique. It was found that currents carried near the equator by groups of ions with anisotropic distribution functions are not well approximated by the guiding center expressions. The guiding center equations fail primarily because the calculated pressure tensor is not magnetic field aligned. The pressure tensor becomes field aligned as one moves away from the equator, but here there is a small region in which the guiding center equations remain inadequate because the two perpendicular components of the pressure tensor are unequal. The significance of nonguiding center motion to substorm processes then was examined. One mechanism that may disrupt a thin cross-tail current sheet involves field changes that cause ions to begin following chaotic orbits. The lowest-altitude chaotic region, characterized by an adiabaticity parameter kappa approx. equal to 0.8, is especially important. The average cross-tail particle drift is slow, and we were unable to generate a thin current sheet using such ions. Therefore, any process that tends to create a thin current sheet in a region with kappa approaching 0.8 may cause the cross-tail current to get so low that it becomes insufficient to support the lobes. A different limit may be important in resonant orbit regions of a thin current sheet because particles reach a maximum cross-tail drift velocity. If the number of ions per unit length decreases as the tail is stretched, this part of the plasma sheet also may become unable to carry the cross-tail current needed to support the lobes. Thin sheets are needed for both resonant and chaotic orbit mechanisms because the distribution function must be highly structured. A description of current continuity is included to show how field aligned currents can evolve during the transition from a two-dimensional (2-D) to a 3-D configuration.

Kaufmann, Richard L.↗
DOE OSTI2025

Adiabatic and radiative cooling are both important causes of aerosol activation in simulated fog events in Europe

Aerosol–fog interactions affect the visibility in, and life cycle of, fog and are difficult to represent in weather and climate models. Here we explore processes that impact the simulation of fog droplet number concentrations (N d ) at sub-kilometer scale horizontal grid resolutions in the UK Met Office Unified Model. We modify the parameterization of aerosol activation to include droplet activation by radiative cooling in addition to adiabatic cooling and determine the relative importance of the two cooling mechanisms. We further test the sensitivity of simulated N d to: (a) interception of droplets by trees and buildings, (b) overestimation of updrafts in temperature inversions (which leads to artificially high N d values), and (c) potential mechanisms for droplet deactivation due to downward fluctuations in supersaturation. We evaluate our model against observations from the ParisFog and LANFEX field campaigns, building on evaluation described in the companion paper. Including radiative cooling in the activation mechanism improves how accurately we represent the liquid water path and the vertical structure of the fog in our LANFEX case study. However, with radiative cooling, the N d are overestimated for most of the ParisFog cases and for the LANFEX case. The time-averaged overestimate exceeds a factor of three (the normalized mean bias factor exceeds 2.0) in 4 out of 11 ParisFog cases. Our sensitivity studies demonstrate how these overestimates can be mitigated. Assuming the overestimate affects both radiative and adiabatic cooling, we find that although radiative cooling is more often the dominant source, both cooling sources can sometimes dominate activation.

Ghosh, Pratapaditya [Carnegie Mellon University, P↗
NASA NTRS1966

Source of outer zone protons.

Acceleration processes of outer zone protons investigated, using Kellogg hypothesis of radiation belt formation through magnetic disturbances where third adiabatic invariant is violated

OUTER RADIATION BELT↗
NASA NTRS1972

Model development of supersonic trough wind with shocks

The time dependent one dimensional hydrodynamic equations describe the evolution of the thermal plasma flow along closed magnetic field lines outside of the plasmasphere. The convection of the supersonic polar wind onto a closed fieldline results in the assumed formation of collisionless plasma shocks. These shocks move earthward as the field line with its frozen-in plasma remains fixed or contracts with time to smaller L coordinates. The high equatorial plasma temperature (of the order of electron volts) produced by the shock process decreases with time if the flow is isothermal but it will increase if the contraction is under adiabatic conditions. Assuming adiabaticity a peak in the temperature forms at the equator in conjunction with a depression in the ion density. After an initial contraction, if the flux tube drifts to higher L coordinates the direction of the shock motion can be reversed so that the supersonic region will expand along the field line towards the state characterizing the supersonic polar wind. A rapid expansion will lower the equatorial density while the temperature decreases with time under adiabatic but not isothermal conditions.

Grebowsky, J. M.↗
NASA NTRS1972

Model development of supersonic trough wind with shocks.

The time-dependent one dimensional hydrodynamic equations describe the evolution of the thermal plasma flow along closed magnetic field lines outside of the plasmasphere. The convection of the supersonic polar wind onto a closed field line results in the assumed formation of collisionless plasma shocks. These shocks move earthward as the field line with its 'frozen-in' plasma remains fixed or contracts with time to smaller L coordinates. The high equatorial plasma temperature (of the order of electron volts) produced by the shock process decreases with time if the flow is isothermal, but it will increase if the contraction is under adiabatic conditions. Assuming adiabaticity a peak in the temperature forms at the equator in conjunction with a depression in the ion density. After an initial contraction, if the flux tube drifts to higher L coordinates, the direction of the shock motion can be reversed so that the supersonic region will expand along the field line toward the state characterizing the supersonic polar wind.

Grebowsky, J. M.↗
NASA NTRS1979

Molecular collision processes in the presence of picosecond laser pulses

Radiative transitions in molecular collision processes taking place in the presence of picosecond pulses are studied within a semiclassical formalism. An expression for adiabatic potential surfaces in the electronic-field representation is obtained, which directly leads to the evaluation of transition probabilities. Calculations with a Landau-Zener-type model indicate that picosecond pulses can be much more effective in inducing transitions than a single long pulse of the same intensity and the same total energy, if the intensity is sufficiently high that the perturbation treatment is not valid.

Lee, H. W.↗
NASA NTRS1990

Air motions accompanying the development of a planetary wave critical layer

The horizontal air motions accompanying the development of a planetary wave critical layer are presently investigated on the sphere, in terms of wave amplitude, the characteristics of the zonal flow, and dissipation. While attention is given to adiabatic motions, which should furnish an upper bound on the redistribution of conserved quantities by eddy stirring, nonconservative processes may be important in determining how large a role eddy stirring actually plays in the redistribution of atmospheric constituents. Nonconservative processes may also influence tracer distributions by directly affecting dynamics.

Salby, Murry L.↗
NASA NTRS1993

Quasi-decadal variability of the stratosphere: Influence of long-term solar ultraviolet variations

A multiple regression statistical model is applied to investigate the existence of upper-stratospheric ozone, temperature, and zonal wind responses to long-term (solar cycle) changes in solar ultraviolet radiation using 11.5 years of reprocessed Nimbus-7 Solar Backscattered Ultraviolet (SBUV) data and 12.4 years of National Meteorological Center (NMC) data. A positive solar cycle variation of independently measured ozone and temperature occurs with maximum amplitude near the low-latitude stratopause. The seasonal solar regression coefficients near 1 mb for both ozone and temperature occur at low latitudes supporting a role for photochemical and radiative forcing in their origin. Zonal wind perturbations that correlate with long-term solar ultraviolet variations are a strong function of season and pressure level. Above approximately 2 mbar, the largest solar-correlated zonal wind enhancements occur at middle winter latitudes near the time of winter solstice in both hemispheres. The Northern Hemisphere December enhancement at 1 mb was especially large, 23 +/- 9 m/s from solar minimum to maximum during the last solar cycle. The derived ozone, temperature, and zonal wind increases with increasing solar ultraviolet flux near the stratopause are larger than predicted by models that consider primarily photochemical and radiative processes. The higher ozone and temperature response amplitudes at low latitudes may be due to modified ozone transport and adiabatic temperature changes induced by the dynamical response. If the midlatitude winter solstice wind enhancements are solar induced, their high amplitudes require a positive feedback due to wave-mean flow interaction such that the planetary wave drag on the flow is reduced under solar maximum conditions.

Hood, L. L.↗
NASA NTRS1979

Release adiabat measurements on minerals - The effect of viscosity

The paper examines the effect of viscosity in the release adiabat measurements on minerals. The current inversion of pressure-particle velocity data for release from a high-pressure shock state to a pressure-density path usually depends critically upon the assumption that the release process is isentropic. It has been shown that the effective viscosity for geological materials below stresses of 150 GPa must be at least 1000 kg/m/s so that viscous work in the shock state remains small compared to mechanical work recovered upon adiabatic rarefaction. The magnitude of the shear stress in the shock state in minerals and viscosities of engineering materials shocked to pressures below 150 GPa show effective viscosities of about 1000 kg/m/s or less indicating that the conditions for isentropic release of materials from shock states are achieved and that the Riemann integral can be applied to obtain pressure-density states along the release adiabats of minerals.

Jeanloz, R.↗
NASA NTRS1991

Cold equation of state in a strong magnetic field - Effects of inverse beta-decay

The influence of a high magnetic field (B is greater than 10 exp 12 G) on the degenerate matter equation of state appropriate to a neutron star is studied. The regime dominated by relativistic electrons up to the neutron drip density is highlighted. The equilibrium matter composition and equation of state, allowing for inverse beta-decay. Two different equilibrium models are determined: an ideal neutron-proton-electron (npe) gas and the more realistic model of Baym, Pethick, and Sutherland (1971) consisting of a Coulomb lattice of heavy nuclei embedded in an electron gas. For a sufficiently high field strength, the magnetic field has an appreciable effect, changing the adiabatic index of the matter and the nuclear transition densities. The influence of a strong field on some simple nonequilibrium processes, including beta-decay and inverse beta-decay (electron capture) is also considered. The effects produced by the magnetic field are mainly due to the changes in the transverse electron quantum orbits and the allowed electron phase space induced by the field.

Lai, Dong↗
NASA NTRS1993

Combustion synthesis of ceramic and metal-matrix composites

Combustion synthesis or self-propagating high temperature synthesis (SHS) is effected by heating a reactant mixture, to above the ignition temperature (Tig) whereupon an exothermic reaction is initiated which produces a maximum or combustion temperature, Tc. These SHS reactions are being used to produce ceramics, intermetallics, and composite materials. One of the major limitations of this process is that relatively high levels of porosity, e.g., 50 percent, remain in the product. Conducting these SHS reactions under adiabatic conditions, the maximum temperature is the adiabatic temperature, Tad, and delta H (Tad) = 0, Tad = Tc. If the reactants or products go through a phase change, the latent heat of transformation needs to be taken into account.

Moore, John J.↗
NASA NTRS1994

Ion Chemistry in Atmospheric and Astrophysical Plasmas

There are many differences and also remarkable similarities between the ion chemistry and physics of planetary ionospheres and the ion chemistry and physics of astronomical environments beyond the solar system. In the early Universe, an expanded cooling gas of hydrogen and helium was embedded in the cosmic background radiation field and ionized by it. As the Universe cooled by adiabatic expansion, recombination occurred and molecular formation was driven by catalytic reactions involving the relict electrons and protons. Similar chemical processes are effective in the ionized zones of gaseous and planetary nebulae and in stellar winds where the ionization is due to radiation from the central stars, in the envelopes of supernovae where the ionization is initiated by the deposition of gamma-rays, in dissociative shocks where the ionization arises from electron impacts in a hot gas and in quasar broad-line region clouds where the quasar is responsible for the ionization. At high altitudes in the atmospheres of the Jovian planets, the main constituents are hydrogen and helium and the ion chemistry and physics is determined by the same processes, the source of the ionization being solar ultraviolet radiation and cosmic rays. After the collapse of the first distinct astronomical entities to emerge from the uniform flow, heavy elements were created by nuclear burning in the cores of the collapsed objects and distributed throughout the Universe by winds and explosions. The chemistry and physics became more complicated. Over 90 distinct molecular species have been identified in interstellar clouds where they are ionized globally by cosmic ray impacts and locally by radiation and shocks associated with star formation and evolution. Complex molecules have also been found in circumstellar shells of evolved stars. At intermediate and low altitudes in the Jovian atmospheres, the ion chemistry is complicated by the increasing abundance of heavy elements such as carbon, and an extensive array of complex molecules has been predicted. Reactions involving heavy elements dominate the structure of the ionspheres of the terrestrial planets and the satellites Titan and Triton.

Dalgarno, A.↗
NASA NTRS2005

Processes of Equatorial Thermal Structure: An Analysis of Galileo Temperature Profile with 3-D Model

The Jupiter Thermosphere General Circulation Model (JTGCM) calculates the global dynamical structure of Jupiter's thermosphere self-consistently with its global thermal structure and composition. The main heat source that drives the thermospheric flow is high-latitude Joule heating. A secondary source of heating is the auroral process of particle precipitation. Global simulations of Jovian thermospheric dynamics indicate strong neutral outflows from the auroral ovals with velocities up to approximately 2 kilometers per second and subsequent convergence and downwelling at the Jovian equator. Such circulation is shown to be an important process for transporting significant amounts of auroral energy to equatorial latitudes and for regulating the global heat budget in a manner consistent with the high thermospheric temperatures observed by the Galileo probe. Adiabatic compression of the neutral atmosphere resulting from downward motion is an important source of equatorial heating (less than 0.06 microbar). The adiabatic heating continues to dominate between 0.06 and 0.2 microbar, but with an addition of comparable heating due to horizontal advection induced by the meridional flow. Thermal conduction plays an important role in transporting heat down to lower altitudes (greater than 0.2microbar) where it is balanced by the cooling associated with the wind transport processes. Interestingly, we find that radiative cooling caused by H3(+), CH4, and C2H2 emissions does not play a significant role in interpreting the Galileo temperature profile.

Majeed, T.↗
NASA NTRS2005

Integrated Modeling Study of the Effects of the Magnetospheric Forcing on the Jovian Ionosphere-Thermosphere System

The Jupiter Thermosphere General Circulation Model (JTGCM) calculates the global dynamical structure of Jupiter s thermosphere self-consistently with its global thermal structure and composition. The main heat source that drives the thermospheric flow is high-latitude Joule heating. A secondary source of heating is the auroral process of particle precipitation. Global simulations of Jovian thermospheric dynamics indicate strong neutral outflows from the auroral ovals with velocities up to approx.2 km/s and subsequent convergence and downwelling at the Jovian equator. Such circulation is shown to be an important process for transporting significant amounts of auroral energy t o equatorial latitudes and for regulating the global heat budget in a manner consistent with the high thermospheric temperatures observed by the Galileo probe. Adiabatic compression of the neutral atmosphere resulting from downward motion is an important source of equatorial heating (< 0.06 microbar). The adiabatic heating continues to dominate between 0.06 and 0.2 microbar, but with an addition of comparable heating due to horizontal advection induced by the meridional flow. Thermal conduction plays an important role in transporting heat down to lower altitudes (>0.2microbar) where it is balanced by the cooling associated with the wind transport processes. Interestingly, we find that radiative cooling caused by H3(+), CH4, and C2H2 emissions does not play a significant role in interpreting the Galileo temperature profile.

Bogan, Denis↗