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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

Effects of Deep Convection on Atmospheric Chemistry

This presentation will trace the important research developments of the last 20+ years in defining the roles of deep convection in tropospheric chemistry. The role of deep convection in vertically redistributing trace gases was first verified through field experiments conducted in 1985. The consequences of deep convection have been noted in many other field programs conducted in subsequent years. Modeling efforts predicted that deep convection occurring over polluted continental regions would cause downstream enhancements in photochemical ozone production in the middle and upper troposphere due to the vertical redistribution of ozone precursors. Particularly large post-convective enhancements of ozone production were estimated for convection occurring over regions of pollution from biomass burning and urban areas. These estimates were verified by measurements taken downstream of biomass burning regions of South America. Models also indicate that convective transport of pristine marine boundary layer air causes decreases in ozone production rates in the upper troposphere and that convective downdrafts bring ozone into the boundary layer where it can be destroyed more rapidly. Additional consequences of deep convection are perturbation of photolysis rates, effective wet scavenging of soluble species, nucleation of new particles in convective outflow, and the potential fix stratosphere-troposphere exchange in thunderstorm anvils. The remainder of the talk will focus on production of NO by lightning, its subsequent transport within convective clouds . and its effects on downwind ozone production. Recent applications of cloud/chemistry model simulations combined with anvil NO and lightning flash observations in estimating NO Introduction per flash will be described. These cloud-resolving case-study simulations of convective transport and lightning NO production in different environments have yielded results which are directly applicable to the design of lightning parameterizations for global chemical transport models. The range of mean values (factor of 3) of NO production per flash (or per meter of lightning channel length) that have been deduced from the model will be shown and compared with values of production in the literature that have been deduced using other methods, Results show that on a per flash basis, IC flashes are nearly as productive of NO as CG flashes. When combined with the global flash rate of 44 flashes per second from NASA's Optical Transient Detector (OTD) measurements, these estimates and the results from other techniques yield global NO production rates of 2-9 TgN/year. Vertical profiles of lightning NOx mass at the end of the 3-D storm simulations have been summarized to yield suggested profiles for use in global models. Simulations of the photochemistry over the 24 hours following a storm have been performed to determine the additional ozone production which can be attributed to lightning NO.

Pickering, Kenneth E.↗
NASA NTRS2009

Production of NOx by Lightning and its Effects on Atmospheric Chemistry

Production of NO(x) by lightning remains the NO(x) source with the greatest uncertainty. Current estimates of the global source strength range over a factor of four (from 2 to 8 TgN/year). Ongoing efforts to reduce this uncertainty through field programs, cloud-resolved modeling, global modeling, and satellite data analysis will be described in this seminar. Representation of the lightning source in global or regional chemical transport models requires three types of information: the distribution of lightning flashes as a function of time and space, the production of NO(x) per flash, and the effective vertical distribution of the lightning-injected NO(x). Methods of specifying these items in a model will be discussed. For example, the current method of specifying flash rates in NASA's Global Modeling Initiative (GMI) chemical transport model will be discussed, as well as work underway in developing algorithms for use in the regional models CMAQ and WRF-Chem. A number of methods have been employed to estimate either production per lightning flash or the production per unit flash length. Such estimates derived from cloud-resolved chemistry simulations and from satellite NO2 retrievals will be presented as well as the methodologies employed. Cloud-resolved model output has also been used in developing vertical profiles of lightning NO(x) for use in global models. Effects of lightning NO(x) on O3 and HO(x) distributions will be illustrated regionally and globally.

Pickering, Kenneth E.↗
NASA NTRS2002

Atmospheric Chemistry and Transport from Space Observations

This lecture will cover the basic ideas of space observations of chemical constituents, modern analysis techniques and results. I will show analysis using TOMS, UARS, SAGE, Terra. I will show some of the planned missions for the US that will launch in the next few years.

Schoeberl, Mark R.↗
NASA NTRS2012

An Overview of the Lightning - Atmospheric Chemistry Aspects of the Deep Convective Clouds and Chemistry (DC3) Experiment

Some of the major goals of the DC3 experiment are to determine the contribution of lightning to NO(x) in the anvils of observed thunderstorms, examine the relationship of lightning NO(x) production to flash rates and to lightning channel lengths, and estimate the relative production per flash for cloud-to-ground flashes and intracloud flashes. In addition, the effects of lightning NO(x) production on photochemistry downwind of thunderstorms is also being examined. The talk will survey the observation types that were conducted during DC3 relevant to these goals and provide an overview of the analysis and modeling techniques which are being used to achieve them. NO(x) was observed on three research aircraft during DC3 (the NCAR G-V, the NASA DC-8, and the DLR Falcon) in flights through storm anvils in three study regions (NE Colorado, Central Oklahoma to West Texas, and northern Alabama) where lightning mapping arrays (LMAs) and radar coverage were available. Initial comparisons of the aircraft NOx observations in storm anvils relative to flash rates have been conducted, which will be followed with calculations of the flux of NO(x) through the anvils, which when combined with observed flash rates can be used to estimate storm-average lightning NOx production per flash. The WRF-Chem model will be run for cloud-resolved simulations of selected observed storms during DC3. Detailed lightning information from the LMAs (flash rates and flash lengths as a function of time and vertical distributions of flash channel segments) will be input to the model along with assumptions concerning NO(x) production per CG flash and per IC flash. These assumptions will be tested through comparisons with the aircraft NOx data from anvil traverses. A specially designed retrieval method for lightning NO2 column amounts from the OMI instrument on NASA fs Aura satellite has been utilized to estimate NO2 over the region affected by selected DC3 storms. Combined with NO(x) to NO2 ratios from the aircraft data and WRF-Chem model and observed flash rates, average NO(x) production per flash can be estimated. Ozone production downwind of observed storms can be estimated from the WRF-Chem simulations and the specific downwind flights.

Pickering, K. E.↗
NASA NTRS2016

Role of Atmospheric Chemistry in the Climate Impacts of Stratospheric Volcanic Injections

The climate impact of a volcanic eruption is known to be dependent on the size, location and timing of the eruption. However, the chemistry and composition of the volcanic plume also control its impact on climate. It is not just sulfur dioxide gas, but also the coincident emissions of water, halogens and ash that influence the radiative and climate forcing of an eruption. Improvements in the capability of models to capture aerosol microphysics, and the inclusion of chemistry and aerosol microphysics modules in Earth system models, allow us to evaluate the interaction of composition and chemistry within volcanic plumes in a new way. These modeling efforts also illustrate the role of water vapor in controlling the chemical evolution, and hence climate impacts, of the plume. A growing realization of the importance of the chemical composition of volcanic plumes is leading to a more sophisticated and realistic representation of volcanic forcing in climate simulations, which in turn aids in reconciling simulations and proxy reconstructions of the climate impacts of past volcanic eruptions. More sophisticated simulations are expected to help, eventually, with predictions of the impact on the Earth system of any future large volcanic eruptions.

Disrupting↗
NASA NTRS2016

Prebiotic Chemistry and Atmospheric Warming of Early Earth by an Active Young Sun

Nitrogen is a critical ingredient of complex biological molecules. Molecular nitrogen, however, which was outgassed Into the Earth's early atmosphere, is relatively chemically inert and nitrogen fixation into more chemically reactive compounds requires high temperatures. Possible mechanisms of nitrogen fixation include lightning, atmospheric shock heating by meteorites, and solar ultraviolet radiation. Here we show that nitrogen fixation in the early terrestrial atmosphere can be explained by frequent and powerful coronal mass ejection events from the young Sun -- so-called superflares. Using magnetohydrodynamic simulations constrained by Kepler Space Telescope observations, we find that successive superflare ejections produce shocks that accelerate energetic particles, which would have compressed the early Earth's magnetosphere. The resulting extended polar cap openings provide pathways for energetic particles to penetrate into the atmosphere and, according to our atmospheric chemistry simulations, initiate reactions converting molecular nitrogen, carbon dioxide and methane to the potent greenhouse gas nitrous oxide as well as hydrogen cyanide, an essential compound for life. Furthermore, the destruction of N2, C02 and CH, suggests that these greenhouse gases cannot explain the stability of liquid water on the early Earth. Instead, we propose that the efficient formation of nitrous oxide could explain a warm early Earth.

Airapetian, V. S.↗
DOE OSTI2022

Analytical advances to study the air – water interfacial chemistry in the atmosphere

Formation of aqueous secondary organic aerosol (aqSOA) at the air – liquid interface recently has attracted a lot of attention in atmospheric chemistry. The discrepancies in mass distributions, aerosol oxidative capacity, liquid water content, hygroscopic growth of aerosols, and formation of clouds and fogs suggest that interfacial chemistry play a more important role than previously deemed. However, detailed mechanisms at the air–water interface remain unclear owing to the lack of comprehensive understanding that underpins complicated interfacial phenomena, which are not easily measurable from field campaigns, laboratory measurements, or computational simulations. Here, this review highlights relevant and recent technical advancement employed to study aqSOA encompassing spectroscopy and mass spectrometry. The current knowledge on the aqSOA processes is digested with an emphasis on recent research of interfacial aqSOA formation including laboratory studies and model simulations. Finally, future directions of the interfacial chemistry are recommended for field and laboratory studies as well as theoretical efforts to resolve interfacial challenges in atmospheric chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

CMIP7 Data Request: atmosphere priorities and opportunities

This paper presents a comprehensive overview of the Coupled Model Intercomparison Project Phase 7 (CMIP7) request for data unlocking key research avenues in atmospheric science and provides justification for the resources needed to produce this data. Topics within the CMIP7 Atmosphere Theme centre around processes and feedbacks in atmospheric science such as clouds, aerosols and atmospheric chemistry, atmospheric circulation, temperature variability and extremes, radiative forcings, and Earth system model evaluation. These topics are summarised in this paper as scientific “opportunities” which will be realised through CMIP7 experiments and Earth system model outputs. These opportunities were submitted by a thematic group of atmospheric science community representatives combined with an extended consultation process. The production of these variables will close key gaps and uncertainties identified during previous rounds of CMIP, and will be broadly used by scientific, policy, governmental, industry, and other communities that rely on climate model projections for research and decision making, including supporting the 7th Intergovernmental Panel on Climate Change Assessment Report (AR7). As an author group, we also reflect on the process used to collate this data request and make recommendations to future CMIP governance on implementing a consultation on this scale in the future.

58 GEOSCIENCES↗
NASA NTRS1997

Accomplishments in Support of NASA ACMAP Under NRA-97-MTPE-07

Over the past three years, the primary foci of our research have been on studies of stratospheric processes and the potential effects of natural perturbations and human related activities on global stratospheric ozone, on interactions between atmospheric chemistry, atmospheric composition and concerns about climate change, and, to a lesser degree, on studies of tropospheric processes. Published research articles are listed.

Wuebbles, Donald J.↗
NASA NTRS2018

Investigating Hydrometeorological Conditions Associated with Increasing Dust Events in Southwestern United States

A recent study (Tong et al. 2017) shows a rapid intensification of dust storm activity over the southwestern United States in the past decades. For example, the frequency of windblown dust storms has increased 240 percent from 1990s to 2000s. Increasing dust storms can worsen air quality in the region. The study also finds that the intensification of dust events has a close connection with a fast-rising infectious disease (valley fever) caused by inhaling soil-dwelling fungi (Coccidioides immitis and C. posadasii) in the southwestern United States. Hydrometeorological conditions play an important role in dust storm activity, including winds, precipitation, soil moisture, atmospheric boundary stability, land surface types, etc. In this presentation, we describe our preliminary results of linking the dust trends to variations of hydrometeorological conditions at regional and global scales, using a number of Earth observations, including products from NLDAS (North American Land Data Assimilation System), TRMM (Tropical Rainfall Measuring Mission), and MERRA (Modern Era Retrospective-analysis for Research and Applications) datasets, from NASA Goddard Earth Sciences (GES) Data and Information Services Center (DISC). The GES DISC, one of the 12 NASA data centers, is home to multidisciplinary data archives such as precipitation, hydrology, atmospheric chemistry, atmospheric dynamics, etc. We demonstrate that multidisciplinary datasets and services at GES DISC can be used for interdisciplinary investigation to understand the interactions of Earth system components from an observational perspective.

satellite↗
NASA NTRS2020

An Update on Global Satellite-Based Precipitation Products and Services at NASA GES DISC

The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) is home to major NASA satellite precipitation measurement missions including the Tropical Rainfall Measuring Mission (TRMM) and the Global Precipitation Measurement (GPM) as well as other NASA projects. Accurate and timely available global and regional precipitation products play an important role in research and applications around the world. The GES DISC provides near-real-time, near-global precipitation products (e.g.IMERG) to support a wide variety of interdisciplinary research and operational activities including flood modeling, landslides, crop monitoring and assessment, vector-borne diseases, etc. Climate data record products (e.g.GPCP3) are essential for climate research, assessment, model evaluation and applications. To facilitate data access and exploration, the GES DISC has developed data services such asGiovanni, an online visualization and analysis tool for easy access to over 2000 satellite- and model-based variables. Established in the mid 1980s, the GES DISC also distributes data in other disciplines including hydrology, atmospheric chemistry, atmospheric dynamics, etc. In this presentation, we will present an update on global precipitation products and data services including the new IMERG V06B suite, the latest version of GPCP (Version 3) and value-added data subsetting services (L34RS, L2S).

Liu, Zhong↗
NASA NTRS2004

Atmospheric Pseudohalogen Chemistry

Hydrogen cyanide is not usually considered in atmospheric chemical models. The paper presents three reasons why hydrogen cyanide is likely to be significant for atmospheric chemistry. Firstly, HCN is a product and marker of biomass burning. Secondly, it is also likely that lightning is producing HCN, and as HCN is sparingly soluble it could be a useful long-lived "smoking gun" marker of lightning activity. Thirdly, the chemical decomposition of HCN leads to the production of small amounts of the cyanide (CN) and NCO radicals. The NCO radical can be photolyzed in the visible portion of the spectrum yielding nitrogen atoms (N). The production of nitrogen atoms is significant as it leads to the titration of total nitrogen from the atmosphere via N+N->N2, where N2 is molecular nitrogen.

Lary, David John↗
NASA NTRS2012

Atmospheric Prebiotic Chemistry and Organic Hazes

Earth's atmospheric composition at the time of the origin of life is not known, but it has often been suggested that chemical transformation of reactive species in the atmosphere was a significant source of pre biotic organic molecules. Experimental and theoretical studies over the past half century have shown that atmospheric synthesis can yield molecules such as amino acids and nucleobases, but these processes are very sensitive to gas composition and energy source. Abiotic synthesis of organic molecules is more productive in reduced atmospheres, yet the primitive Earth may not have been as reducing as earlier workers assumed, and recent research has reflected this shift in thinking. This work provides a survey of the range of chemical products that can be produced given a set of atmospheric conditions, with a particular focus on recent reports. Intertwined with the discussion of atmospheric synthesis is the consideration of an organic haze layer, which has been suggested as a possible ultraviolet shield on the anoxic early Earth. Since such a haze layer - if formed - would serve as a reservoir for organic molecules, the chemical composition of the aerosol should be closely examined. The results highlighted here show that a variety of products can be formed in mildly reducing or even neutral atmospheres, demonstrating that contributions of atmospheric synthesis to the organic inventory on early Earth should not be discounted. This review intends to bridge current knowledge of the range of possible atmospheric conditions in the prebiotic environment and pathways for synthesis under such conditions by examining the possible products of organic chemistry in the early atmosphere.

Trainer, Melissa G.↗