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At least 1,243 records · Page 69
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Investigations on the Thermal Stability and Kinetics of Biolubricants Synthesized from Different Types of Vegetable Oils

Petroleum-based lubricants raise environmental concerns due to their non-biodegradability and toxicity, whereas biobased lubricants underperform owing to low thermal stability. This study examined and compared three vegetable oils, along with their chemically modified versions, to better understand their suitability as biolubricants. High oleic soybean oil (HOSOY), regular soybean oil (RSOY), and waste cooking oil (WCO) were subjected to chemical modification, where isopropyl groups were attached to the fatty acid chains of the oils to produce branched oils, i.e., b-HOSOY, b-RSOY, and b-WCO. The detailed kinetic study of each regular and modified sample was investigated using thermogravimetric analysis. The kinetic parameters, such as the activation energies, reaction rate, and pre-exponential factor, were generated via Friedman methods. The differential thermal gravimetric (DTG) analysis showed low volatilization at the onset temperature in each modified oil as compared with the unmodified samples under an oxidative environment. Furthermore, the comparative kinetic studies demonstrated the enhanced thermoxidative stability of the modified products relative to their unaltered counterparts. Among the tested oils, the b-RSOY showed an average activation energy of 325 kJ/mol, followed by the b-WCO: 300 kJ/mol and the b-HOSOY: 251 kJ/mol, indicating the most stable modified product under an oxidative environment. For all the samples, the pre-exponential factors were in good agreement with the activation energies, which validates that finding the pre-exponential components is crucial to the kinetic analysis.

Sarker, Majher I. (ORCID:0000000299509274)↗
DOE OSTI2025

Untargeted GC-MS Metabolic Profiling of Anaerobic Gut Fungi Reveals Putative Terpenoids and Strain-Specific Metabolites

Background/Objectives: Anaerobic gut fungi (Neocallimastigomycota) are biotechnologically relevant, lignocellulose-degrading microbes with under-explored biosynthetic potential for secondary metabolites. Untargeted metabolomic profiling with gas chromatography–mass spectrometry (GC-MS) was applied to two gut fungal strains, Anaeromyces robustus and Caecomyces churrovis, to establish a foundational metabolomic dataset to identify metabolites and provide insights into gut fungal metabolic capabilities. Methods: Gut fungi were cultured anaerobically in rumen-fluid-based media with a soluble substrate (cellobiose), and metabolites were extracted using the Metabolite, Protein, and Lipid Extraction (MPLEx) method, enabling metabolomic and proteomic analysis from the same cell samples. Samples were derivatized and analyzed via GC-MS, followed by compound identification by spectral matching to reference databases, molecular networking, and statistical analyses. Results: Distinct metabolites were identified between A. robustus and C. churrovis, including 2,3-dihydroxyisovaleric acid produced by A. robustus and maltotriitol, maltotriose, and melibiose produced by C. churrovis. C. churrovis may polymerize maltotriose to form an extracellular polysaccharide, like pullulan. GC-MS profiling potentially captured sufficiently volatile products of proteomically detected, putative non-ribosomal peptide synthetases and polyketide synthases of A. robustus and C. churrovis. The triterpene squalene and triterpenoid tetrahymanol were putatively identified in A. robustus and C. churrovis. Their conserved, predicted biosynthetic genes—squalene synthase and squalene tetrahymanol cyclase—were identified in A. robustus, C. churrovis, and other anaerobic gut fungal genera. Conclusions: This study provides a foundational, untargeted metabolomic dataset to unmask gut fungal metabolic pathways and biosynthetic potential and to prioritize future efforts for compound isolation and identification.

Biochemistry & Molecular Biology↗
DOE OSTI2022

Monitoring Xenon Capture in a Metal Organic Framework Using Laser-Induced Breakdown Spectroscopy

Molten salt reactor operation will necessitate circulation of a cover gas to remove certain evolved fission products and maintain an inert atmosphere. The cover gas leaving the reactor core is expected to contain both noble and non-noble gases, aerosols, volatile species, tritium, and radionuclides and their daughters. To remove these radioactive gases, it is necessary to develop a robust off-gas system, along with novel sensors to monitor the gas stream and the treatment system performance. In this study, a metal organic framework (MOF) was engineered for the capture of Xe, a major contributor to the off-gas source term. The engineered MOF column was tested with a laser-induced breakdown spectroscopy (LIBS) sensor for noble gas monitoring. The LIBS sensor was used to monitor breakthrough tests with various Xe, Kr, and Ar mixtures to determine the Xe selectivity of the MOF column. This study offers an initial demonstration of the feasibility of monitoring off-gas treatment systems using a LIBS sensor to aid in the development of new capture systems for molten salt reactors.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

The Anaerobic Fungi: Challenges and Opportunities for Industrial Lignocellulosic Biofuel Production

Lignocellulose is a promising feedstock for biofuel production as a renewable, carbohydrate-rich and globally abundant source of biomass. However, challenges faced include environmental and/or financial costs associated with typical lignocellulose pretreatments needed to overcome the natural recalcitrance of the material before conversion to biofuel. Anaerobic fungi are a group of underexplored microorganisms belonging to the early diverging phylum Neocallimastigomycota and are native to the intricately evolved digestive system of mammalian herbivores. Anaerobic fungi have promising potential for application in biofuel production processes due to the combination of their highly effective ability to hydrolyse lignocellulose and capability to convert this substrate to H2 and ethanol. Furthermore, they can produce volatile fatty acid precursors for subsequent biological conversion to H2 or CH4 by other microorganisms. The complex biological characteristics of their natural habitat are described, and these features are contextualised towards the development of suitable industrial systems for in vitro growth. Moreover, progress towards achieving that goal is reviewed in terms of process and genetic engineering. In addition, emerging opportunities are presented for the use of anaerobic fungi for lignocellulose pretreatment; dark fermentation; bioethanol production; and the potential for integration with methanogenesis, microbial electrolysis cells and photofermentation.

pretreatment↗
DOE OSTI2023

Single Crystal Growth of Synthetic Sulfide- and Phosphide-Based Minerals for Physical Measurements

In this work, we review recent advances in the use of high-temperature solution growth that allow for the growth of single crystalline samples of synthetic minerals. We outline how low-melting binary or ternary solutions are attractive solvents for solution growth and provide examples of the growth of bismuthinite (Bi 2 S 3 ), galena (PbS) and parkerite (Ni 3 Bi 2 S 2 ). We then focus on the Rh-S, Pd-S and Ni-P phase spaces to discuss how the low-melting regions near transition metal-main group eutectic compositions make excellent solvents for crystal growth of several binary and ternary minerals containing both high melting and volatile elements as well as for the discovery of new materials. We end by discussing the growth of synthetic canfieldite (Ag 8 SnS 6 ) and argyrodite (Ag 8 GeS 6 ) from Ag 2 S–Sn-S-based solutions.

58 GEOSCIENCES↗
DOE OSTI2023

HPTLC Analysis and Chemical Composition of Selected Melaleuca Essential Oils

Tea tree oil (TTO) is a volatile essential oil obtained by distillation, mainly from the Australian native plant Melaleuca alternifolia (Maiden & Betche) Cheel (Myrtaceae). In this study, a comparative analysis of the chemical constituents of seven tea tree oils (M. alternifolia) and four other Melaleuca spp. oils (M. cajuputi, (M Ca ), two chemotypes of M. quinquenervia, (M Ne and M Ni ), and M. ericifolia (M Ro )) was carried out using gas chromatography–mass spectrometry (GC-MS) and high-performance thin-layer chromatography (HPTLC). Among the seven TTOs, terpinen-4-ol (37.66–44.28%), γ-terpinene (16.42–20.75%), α-terpinene (3.47–12.62%), α-terpineol (3.11–4.66%), and terpinolene (2.75–4.19%) were the most abundant compounds. On the other hand, the most abundant compounds of the other Melaleuca oils varied, such as 1,8-cineole (64.63%) in M Ca oil, (E)-nerolidol (48.40%) and linalool (33.30%) in M Ne oil, 1,8-cineole (52.20%) in M Ni oil, and linalool (38.19%) and 1,8-cineole (27.57%) in M Ro oil. HPTLC fingerprinting of Melaleuca oils enabled the discrimination of TTO oils from other Melaleuca spp. oils. Variation was observed in the profile of the R f values among EOs. The present study shows that HPTLC is one of the best ways to identify and evaluate the quality control in authenticating TTOs, other Melaleuca EOs, or EOs from other species within the Myrtaceae.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Ferroelectricity in Si-Doped Hafnia: Probing Challenges in Absence of Screening Charges

The ability to develop ferroelectric materials using binary oxides is critical to enable novel low-power, high-density non-volatile memory and fast switching logic. The discovery of ferroelectricity in hafnia-based thin films, has focused the hopes of the community on this class of materials to overcome the existing problems of perovskite-based integrated ferroelectrics. However, both the control of ferroelectricity in doped-HfO2 and the direct characterization at the nanoscale of ferroelectric phenomena, are increasingly difficult to achieve. The main limitations are imposed by the inherent intertwining of ferroelectric and dielectric properties, the role of strain, interfaces and electric field-mediated phase, and polarization changes. In this work, using Si-doped HfO2 as a material system, we performed a correlative study with four scanning probe techniques for the local sensing of intrinsic ferroelectricity on the oxide surface. Putting each technique in perspective, we demonstrated that different origins of spatially resolved contrast can be obtained, thus highlighting possible crosstalk not originated by a genuine ferroelectric response. By leveraging the strength of each method, we showed how intrinsic processes in ultrathin dielectrics, i.e., electronic leakage, existence and generation of energy states, charge trapping (de-trapping) phenomena, and electrochemical effects, can influence the sensed response. We then proceeded to initiate hysteresis loops by means of tip-induced spectroscopic cycling (i.e., “wake-up”), thus observing the onset of oxide degradation processes associated with this step. Finally, direct piezoelectric effects were studied using the high pressure resulting from the probe’s confinement, noticing the absence of a net time-invariant piezo-generated charge. Our results are critical in providing a general framework of interpretation for multiple nanoscale processes impacting ferroelectricity in doped-hafnia and strategies for sensing it.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Glancing Angle Deposition in Gas Sensing: Bridging Morphological Innovations and Sensor Performances

Glancing Angle Deposition (GLAD) has emerged as a versatile and powerful nanofabrication technique for developing next-generation gas sensors by enabling precise control over nanostructure geometry, porosity, and material composition. Through dynamic substrate tilting and rotation, GLAD facilitates the fabrication of highly porous, anisotropic nanostructures, such as aligned, tilted, zigzag, helical, and multilayered nanorods, with tunable surface area and diffusion pathways optimized for gas detection. This review provides a comprehensive synthesis of recent advances in GLAD-based gas sensor design, focusing on how structural engineering and material integration converge to enhance sensor performance. Key materials strategies include the construction of heterojunctions and core–shell architectures, controlled doping, and nanoparticle decoration using noble metals or metal oxides to amplify charge transfer, catalytic activity, and redox responsiveness. GLAD-fabricated nanostructures have been effectively deployed across multiple gas sensing modalities, including resistive, capacitive, piezoelectric, and optical platforms, where their high aspect ratios, tailored porosity, and defect-rich surfaces facilitate enhanced gas adsorption kinetics and efficient signal transduction. These devices exhibit high sensitivity and selectivity toward a range of analytes, including NO2, CO, H2S, and volatile organic compounds (VOCs), with detection limits often reaching the parts-per-billion level. Emerging innovations, such as photo-assisted sensing and integration with artificial intelligence for data analysis and pattern recognition, further extend the capabilities of GLAD-based systems for multifunctional, real-time, and adaptive sensing. Finally, current challenges and future research directions are discussed, emphasizing the promise of GLAD as a scalable platform for next-generation gas sensing technologies.

Chemistry↗
DOE OSTI2025

Characterizing the Excited States and Electronic Absorption Spectra of Small Alkylperoxy (RO 2 •) and Hydroperoxy (•QOOH) Radicals

Organic peroxy (ROO•) and hydroperoxy (•QOOH) radicals are key reactive intermediates that are formed via the oxidation of volatile organic compounds during combustion or in the Earth’s atmosphere. Their primary fate is continued unimolecular decay or bimolecular chemistry, the relative branching for which is heavily structure- and temperature-dependent. This article outlines a combined single- and multi-reference quantum chemical study to characterize the near-UV accessible electronically excited states of the prototypical ROO• and •QOOH intermediates, tert-butyl peroxy and hydroperoxy-tert-butyl radicals—the ground-state chemistries of which have been well studied both experimentally and computationally. Additionally, we simulate the electronic absorption profiles of these ROO• and •QOOH intermediates with a variety of multi- and single-reference methods. The results show an interesting conformer dependence on the electronically excited-state character and electronic absorption maxima of •QOOH. The results show promise for electronic absorption spectroscopy to be used as a selected probe for determining •QOOH conformers. Additionally, electronic absorption may contribute to the daytime removal of long-lived •QOOH intermediates formed in the troposphere. We expect that our studies will motivate experiments on the electronic absorption spectra of experimentally achievable ROO• and •QOOH.

excited states↗
DOE OSTI2024

A Two-Stage Stochastic Programming Approach for the Design of Renewable Ammonia Supply Chain Networks

This work considers the incorporation of renewable ammonia manufacturing sites into existing ammonia supply chain networks while accounting for ammonia price uncertainty from existing producers. We propose a two-stage stochastic programming approach to determine the optimal investment decisions such that the ammonia demand is satisfied and the net present cost is minimized. We apply the proposed approach to a case study considering deploying in-state renewable ammonia manufacturing in Minnesota’s supply chain network. We find that accounting for price uncertainty leads to supply chains with more ammonia demand met via renewable production and thus lower costs from importing ammonia from existing producers. These results show that the in-state renewable production of ammonia can act as a hedge against the volatility of the conventional ammonia market.

Mitrai, Ilias (ORCID:0000000289896864)↗
DOE OSTI2022

Demonstration of VOC Fenceline Sensors and Canister Grab Sampling near Chemical Facilities in Louisville, Kentucky

Experimental fenceline sensor pods (SPods) fitted with 30 s duration canister grab sampling (CGS) systems were deployed at a site near chemical facilities in Louisville, KY, from 4 June 2018 to 5 January 2020. The objective of the study was to better understand lower cost 10.6 eV photoionization detector (PID)-based volatile organic compound (VOC) sensors and investigate their utility for near-source emissions detection applications. Prototype SPods containing PID sensor elements from two different manufacturers yielded between 78% and 86% valid data over the study, producing a dataset of over 120,000 collocated pair fenceline measurements averaged into 5-min datapoints. Ten-second time-resolved SPod data from an elevated fenceline sensor signal day are presented, illustrating source emission detections from the direction of a facility 500 m west of the monitoring site. An SPod-triggered CGS acquired in the emission plume on this day contained elevated concentrations of 1,3-butadiene and cyclohexane (36 parts per billion by volume (ppbv) and 637 ppbv, respectively), compounds known to be emitted by this facility. Elevated concentrations of these compounds were observed in a subset of the 61 manual and triggered CGS grab samples acquired during the study, with winds from the west. Using novel wind-resolved visualization and normalization approaches described herein, the collocated pair SPod datasets exhibited similarity in emission source signature. With winds from the west, approximately 50% of SPod readings were above our defined theoretical detection limit indicating persistent measurable VOC signal at this site. Overall, this 19-month study demonstrated reasonable prototype SPod operational performance indicating that improved commercial forms of lower cost PID sensors could be useful for select VOC fenceline monitoring applications.

1,3-butadiene↗
DOE OSTI2025

Extraction of Terpenoids from Pine Needle Biomass Using Dimethyl Ether

Pine needles are an industrial feedstock for extracts used in a variety of applications, but conventional extraction methods often result in a degradation of the terpenoid compounds that naturally occur in loblolly pine ( Pinus taeda ). Separation of these compounds from pine biomass is an energy-intensive operation, typically requiring a significant input of thermal energy. An alternative separation approach with potential energy savings is extraction with a condensable gas, namely, dimethyl ether. Biomass materials are exposed to liquid dimethyl ether under pressure, which mobilizes the organics. The extract is then separated from the insoluble pine matter, and dimethyl ether is volatilized away from the separated organic species. A variety of terpene derivatives were extracted from pine needle biomass using this approach, including monoterpenes, sesquiterpenes, and related oxygenates, which were identified using two-dimensional gas chromatography/mass spectrometry. Additionally, the dimethyl ether-treated needles resemble needles subjected to low-temperature drying, whereas needles treated with a high-temperature drying method appear to have shrunken structures. The results suggest that dimethyl ether extraction has significant potential for separating valuable organics from complex matrices without the application of thermal energy during treatment.

dimethyl ether (DME) extraction↗
DOE OSTI2020

High-resolution Optical Spectroscopic Observations of Comet 21P/Giacobini–Zinner in Its 2018 Apparition

Comet 21P/Giacobini–Zinner is a peculiar comet from the viewpoints of the chemical and physical properties of its dust grains. We conduct optical high-resolution spectroscopic observations of the comet. The intensity ratios of forbidden oxygen lines (at 557.7, 630.0, and 636.4 nm) and ortho-to-para abundance ratios (OPRs) of water cations (H{sub 2}O{sup +}) and amidogen radicals (NH{sub 2}) are obtained while only the upper limit for {sup 14}N/{sup 15}N in the amidogen radical is restricted. The OPRs of H{sub 2}O{sup +} and NH{sub 2} are similar to those of other comets, although the real meaning of these OPRs is still debated. Based on the observation of the forbidden emission lines of oxygen atoms, it can be concluded that the comet is depleted in CO{sub 2}. In consideration with the depletion in other highly volatile species found in the near-infrared region and the presence of complex organics in comet 21P/Giacobini–Zinner, this comet might form in a warmer region in the solar nebula compared with other comets.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Mars Upper Atmospheric Temperature and Atomic Oxygen Density Derived from the O i 130.4 nm Emission Observed by NASA’s MAVEN Mission

The abundance of atomic oxygen is a major unknown for the Mars upper atmosphere, and systematic measurements of this key species is a primary objective of NASA’s Mars Atmosphere and Volatile Evolution (MAVEN) mission. Moreover, the Martian dayside temperature structure and its variability has been a subject of considerable debate in the past. In this study, an inversion analysis of the periapsis limb scans of the O i 130.4 nm emission observed by MAVEN is performed to quantify the neutral temperature and atomic oxygen abundance in the Mars upper atmosphere. Our analysis yields unprecedented resolution of the spatial variation of Mars atomic oxygen, showing that its exobase density decreases with the solar zenith angle (SZA) from ∼0° to 60° by about an order of magnitude, from ∼10{sup 8} to ∼10{sup 7} cm{sup −3} near perihelion (2015 April) and from ∼10{sup 7} to ∼10{sup 6} cm{sup −3} near aphelion (2017 November). For a given SZA the exobase densities near perihelion are about an order of magnitude higher than those near aphelion. The [O]/[CO{sub 2}] mixing ratio at 130 km altitude can vary from ∼0.1% to 4.6%, which also decreases with increasing SZA. Moreover, it is shown that the Mars exobase temperature does not vary significantly with SZA from ∼0° to ∼60°, which is estimated to be ∼239.2 ± 27.6 K near perihelion and ∼162.4 ± 19.9 K near aphelion, with a difference of 76.8 K between these two seasonal extremes.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Lyα Observations of Comet C/2013 A1 (Siding Spring) Using MAVEN IUVS Echelle

The close approach of comet C/2013 A1 (Siding Spring) to Mars in 2014 October provided a unique opportunity to observe a dynamically new Oort cloud comet with potential for interaction with a planet’s atmosphere. The water-originating hydrogen coma of the comet extended to over 20 million km from the nucleus. Determining the properties of this coma contributes to characterizing the comet’s water content and production rate. The present study analyzes a unique data set of high spectral resolution UV observations of comet C/2013 A1 Siding Spring measured by the Mars Atmosphere and Volatile Evolution spacecraft. The Siding Spring observations capture Lyα emissions from the Martian corona, the interplanetary medium, as well as the cometary H and D reservoirs. The isolated cometary spectra are analyzed to reveal a velocity distribution of H atoms that are consistent with model estimates of H{sub 2}O photodissociated H emissions and of OH photodissociated H emissions, Doppler shifted from the main comet H emission line center by 18 km s{sup −1} and 8 km s{sup −1}, respectively. The variations in comet H brightness with distance from the nucleus are used to constrain cometary water production to a rate of 0.5 × 10{sup 28} molecules s{sup −1} at a time when Siding Spring was at 1.5 au, pre-perihelion.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Characterization of the Nucleus, Morphology, and Activity of Interstellar Comet 2I/Borisov by Optical and Near-infrared GROWTH, Apache Point, IRTF, ZTF, and Keck Observations

We present visible and near-infrared (NIR) photometric and spectroscopic observations of interstellar object (ISO) 2I/Borisov taken from 2019 September 10 to 2019 December 20 using the GROWTH, the Apache Point Observatory Astrophysical Research Consortium 3.5 m, and the NASA Infrared Telescope Facility 3.0 m combined with pre- and postdiscovery observations of 2I obtained by the Zwicky Transient Facility from 2019 March 17 to 2019 May 5. Comparison with imaging of distant solar system comets shows an object very similar to mildly active solar system comets with an outgassing rate of ∼10{sup 27} mol s{sup −1}. The photometry, taken in filters spanning the visible and NIR range, shows a gradual brightening trend of ∼0.03 mag day{sup −1} since 2019 September 10 UTC for a reddish object becoming neutral in the NIR. The light curve from recent and prediscovery data reveals a brightness trend suggesting the recent onset of significant H{sub 2}O sublimation with the comet being active with super volatiles such as CO at heliocentric distances >6 au consistent with its extended morphology. Using the advanced capability to significantly reduce the scattered light from the coma enabled by high-resolution NIR images from Keck adaptive optics taken on 2019 October 4, we estimate a diameter for 2I’s nucleus of ≲1.4 km. We use the size estimates of 1I/’Oumuamua and 2I/Borisov to roughly estimate the slope of the ISO size distribution, resulting in a slope of ∼3.4 ± 1.2, similar to solar system comets and bodies produced from collisional equilibrium.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Physical Characterization of Interstellar Comet 2I/2019 Q4 (Borisov)

We present a study of interstellar comet 2I/2019 Q4 (Borisov) using both preperihelion and postperihelion observations spanning late September 2019 through late January 2020. The intrinsic brightness of the comet was observed to continuously decline throughout the timespan, likely due to the decreasing effective scattering cross-section as a result of volatile sublimation with a slope of −0.43 ± 0.02 km{sup 2} d{sup −1}. We witnessed no significant change in the slightly reddish color of the comet, with mean values of 〈g−r〉=0.68±0.04, 〈r−i〉=0.23±0.03, and the normalized reflectivity gradient across the g and i bands (S{sup ′})-bar (g,i)=(10.6±1.4)% per 10{sup 3} Å, all unremarkable in the context of solar system comets. Using the available astrometric observations, we confidently detect the nongravitational acceleration of the comet following a shallow heliocentric distance dependence of r{sub H}{sup −1±1}. Accordingly, we estimate that the nucleus is most likely ≲0.4 km in radius, and that a fraction of ≳0.2% of the total mass of the nucleus has been eroded due to the sublimation activity since the earliest observation of the comet in 2018 December by the time of perihelion. Our morphology simulation suggests that the dust ejection speed increased from ∼4 m s{sup −1} in 2019 September to ∼7 m s{sup −1} around perihelion for the optically dominant dust grains with β∼0.01, and that the observable dust grains are no smaller than micron size.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

TESS Reveals a Short-period Sub-Neptune Sibling (HD 86226c) to a Known Long-period Giant Planet

The Transiting Exoplanet Survey Satellite mission was designed to find transiting planets around bright, nearby stars. Here, we present the detection and mass measurement of a small, short-period (≈4 days) transiting planet around the bright (V = 7.9), solar-type star HD 86226 (TOI-652, TIC 22221375), previously known to host a long-period (∼1600 days) giant planet. HD 86226c (TOI-652.01) has a radius of 2.16 ± 0.08 R {sub ⊕} and a mass of 7.25{sub −1.12}{sup +1.19} M {sub ⊕}, based on archival and new radial velocity data. We also update the parameters of the longer-period, not-known-to-transit planet, and find it to be less eccentric and less massive than previously reported. The density of the transiting planet is 3.97 g cm{sup −3}, which is low enough to suggest that the planet has at least a small volatile envelope, but the mass fractions of rock, iron, and water are not well-constrained. Given the host star brightness, planet period, and location of the planet near both the “radius gap” and the “hot Neptune desert,” HD 86226c is an interesting candidate for transmission spectroscopy to further refine its composition.

79 ASTRONOMY AND ASTROPHYSICS↗