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At least 1,243 records · Page 69

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NASA NTRS1974

Deformation characteristics and time-dependent notch sensitivity of Udimet 700 at intermediate temperatures

Time dependent notch sensitivity was observed in Udimet 700 sheet, bar, and investment castings between 1000 and 1400 F (538 -760 C), but not at 1600 F (871 C). As was the case for modified Waspaloy, Waspaloy and Inconel 718, it occurred in notched specimens loaded below the yield strength when the creep deformation was localized. For each alloy and notched specimen geometry, a stress-average particle size zone can be defined that characterizes the notch sensitive behavior.

Wilson, D. J.↗

NASA NTRS1985

Cell Partition in Two Polymer Aqueous Phases

In a reduced gravity environment the two polymer phases will not separate via density driven settling in an acceptably short length of time. It is to be expected that a certain amount of phase separation will take place, however, driven by the reduction in free energy gained when the interfacial area is reduced. This stage of separation process will therefore depend directly on the magnitude of the interfacial tension between the phases. In order to induce complete phase separation in a short time, electric field-induced separation which occurs because the droplets of one phase in the other have high electrophoretic mobilities which increase with droplet size was investigated. These mobilities are significant only in the presence of certain salts, particularly phosphates. The presence of such salts, in turn has a strong effect on the cell partition behavior in dextran-poly (ethylene glycol) (PEG) systems. The addition of the salts necessary to produce phase drop mobilities has a large effect on the interfacial tensions in the systems.

Brooks, D. E.↗

NASA NTRS1991

Gyro-phase effects near the storm-time boundary of energetic plasma

The nonadiabatic acceleration of plasma sheet ions during the expansion phase of substorms is examined by means of single-particle codes. It is shown that, in the near-earth plasma sheet, the gyration phase at substorm onset controls the net ion energization, as the gyro-period is locally comparable to the field variation time scale. This can yield a particularly significant decrease of the particle magnetic moment. It is accordingly argued that, via adiabatic invariant violation, the dipolarization of magnetospheric field lines can induce a 'de-trapping' of inner plasma sheet populations and, hence, give rise to short-lived precipitation enhancements over the auroral zone. As this effect depends upon cyclotron frequency, it is expected to occur at distinct latitudes for different ion species. This contrasts with nonadiabatic ion behavior further out into the geotail, which is characterized by intense perpendicular heating and a likely collective trapping.

Delcourt, D. C.↗

NASA NTRS1998

Prediction of Natural Frequency and Buckling Load Variability due to Uncertainty in Material Properties by Convex Modeling

Composite materials are widely used in various types of engineering structures. To a large extent, the properties of composite materials are dependent on the fabrication process. But even the composite materials manufactured by the same process may demonstrate differences in their elastic properties. For design purposes, one should be aware of the potential variations in load-carrying capacity and dynamic behavior of such structures that can arise due to the uncertainty in elastic moduli. A more realistic analysis of composite structures should be performed with the variations of the elastic moduli being taken into consideration at the same time. The present paper is a generalization of a study where the influence of uncertainty in elastic moduli on the axial buckling load was discussed. Here, we consider another case of buckling, shells under uniform external pressure. In addition, this paper deals with the variability of natural frequencies by use of convex modeling, which is apparently the first study of this kind in the literature. A numerical approach to the uncertainty problem is nonlinear programming, which we apply to solve the same problem to generate a set of comparable numerical data. The results from both methods show good agreement throughout. Thus, the effectiveness of the analytic convex modeling is clearly demonstrated. The bounds of he natural frequency and the buckling load provide the designer with a better view of the vibrational behavior and the actual load carrying capacities possessed by the composite structure.

Li, Y. W.↗

NASA NTRS1992

Combustion noise and combustion instabilities in propulsion systems

This paper is concerned with some aspects of non-linear behavior of unsteady motions in combustion chambers. The emphasis is on conditions under which organized oscillations having discrete frequencies may exist in the presence of random motions. In order to treat the two types of motions together, and particularly to investigate coupling between noise and combustion instabilities, the unsteady field is represented as a synthesis of acoustic modes having time-varying amplitudes. Each of the amplitudes are written as the sum of two parts, one associated with the random field and the remainder representing the organized oscillations. After spatial averaging, the general problem is reduced to solution of a set of second-order ordinary differential equations whose structure depends on the sorts of nonlinear processes accounted for. This formulation accommodates any physical process; in particular, terms are included to represent noise sources, although only limited modeling is discussed. Our results suggest that random sources of noise have only small effects on combustion instabilities and seem not to be a cause of unstable motions. However, the coupling between the two sorts of unsteady motions may be important as an essential process in a proposed scheme for noise control. It is now a familiar observation that many nonlinear deterministic systems are capable of exhibiting apparently random motions called 'chaos.' This is a particularly interesting possibility for systems which also executed non-deterministic random motions. In combustion chambers, a nonlinear deterministic system (acoustical motions) exists in the presence of noise produced by flow separation, turbulent motions, and energy released by combustion processes. The last part of the paper is directed to the matter of discovering whether or not chaotic motions exist in combustion systems. Analysis has not progressed sufficiently far to answer the question. We report here recent results of processing data taken in one combustor to determine the dimensions of any attractors in the motions. No evidence has been found for chaos in the strict sense, but the method seems to be an important means of investigating the nonlinear behavior of combustion systems.

F. E. C. Culick↗

DOE OSTI2021

Explaining an unusual electromigration behavior—A comprehensive experimental and theoretical analysis using finite element method

In metallic interconnects, it is generally assumed that electromigration (EM) failure location is independent of the applied electrical current and always occurs at the highest-current-density area. Our experiments show otherwise. We designed an Al interconnect that alters its failure location by only varying the applied current density. The failure occurs near the high for a current above 2 × 10 7 A/cm 2 , but at a location with 59% of the maximum for lower current densities. Thermoreflectance thermal imaging is employed to gather time-dependent high-resolution spatial temperature distributions of the Al interconnect during EM. More importantly, we propose a computationally inexpensive 2D finite element method that tracks EM evolution in time and matches well with the observations from different experimental conditions. A detailed analysis covering the major driving forces of EM is carried out to understand the complex physics behind EM. The atomic depletion rate contributed by each force is quantitatively studied. By examining the results from every tested experimental condition, the model reveals that the temperature gradient is the key reason causing atomic depletion near the failure location. Graphical illustrations and qualitative analysis are provided to intuitively show the key findings of our work.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2025

Preferential adsorption of noble gases in zeolitic tuff with variable saturation: A modeling study of counter-intuitive diffusive-adsorptive behavior

Noble gas transport through geologic media has important applications in the prediction and characterization of measured gas signatures related to underground nuclear explosions (UNEs). Retarding processes such as adsorption can cause significant species fractionation of radionuclide gases, which has implications for measured and predicted signatures used to distinguish radioxenon originating from civilian nuclear facilities or from UNEs. Accounting for the effects of variable water saturation in geologic media on tracer transport is one of the most challenging aspects of modeling gas transport because there is no unifying relationship for the associated tortuosity changes between different rock types, and reactive transport processes such as adsorption that are affected by the presence of water likewise behave differently between gas species. In this study, we perform numerical diffusive-adsorptive transport simulations to estimate gas transport parameters associated with bench-scale laboratory diffusion cell experiments measuring breakthrough in zeolitic and non-zeolitic rocks for a gaseous mixture of xenon, krypton, and SF 6 at varying degrees of water saturation (S w ). Counter-intuitive transport behavior was observed in the zeolitic rock experiments whereby breakthrough concentrations were significantly higher when the core was partially saturated (S w = 17 %) than under dry (S w = 0 %) conditions. Breakthrough of xenon was especially retarded in the dry core – likely due to comparatively high affinity of xenon for zeolitic adsorption sites – and estimated effective diffusion coefficients for all gases were approximately an order of magnitude lower than what is predicted by porosity-tortuosity models. We propose the counter-intuitive behavior observed is because water infiltration of zeolite nanopores reduces both the adsorptive capacity of the rock and the tortuosity of connected flow paths. We developed a two-site competitive kinetic Langmuir adsorption reaction for the porous media transport simulator in order to constrain transport parameters within zeolitic tuff, where differential adsorption to zeolite and non-zeolite pores was observed. We determined that liquid saturation-dependent diffusive-adsorptive transport is affected by subtle and at times competing processes that are specific to different gases, which have a significant overall influence on effective transport parameters.

58 GEOSCIENCES↗

DOE OSTI2020

A collective elastic fluctuation mechanism for decoupling and stretched relaxation in glassy colloidal and molecular liquids

We propose a microscopic theory for the decoupling of self-diffusion and structural relaxation in glass-forming liquids within the Elastically Collective Nonlinear Langevin Equation (ECNLE) activated dynamics framework. Our central hypothesis is that the heterogeneity relevant to this problem is static fluctuations of local density on the scale of 3–4 particle diameters and how this changes local packing correlations. These fluctuations modify the degree of dynamical cage expansion that mechanistically couples intracage large amplitude hopping and longer range collective elasticity in ECNLE theory. Decoupling only emerges in the deeply supercooled regime where the strongly temperature dependent elastic barrier becomes non-negligible relative to its noncooperative local analog. The theory makes predictions for various aspects of the decoupling phenomenon, including apparent fractional power law Stokes-Einstein behavior, that appear to be consistent with experiments and simulations on hard sphere fluids and molecular liquids. Of central importance is a microscopic connection between the barrier fluctuation variance and most probable barrier height. Sensible results are also obtained for the nonexponential stretching of a generic relaxation time correlation function and its temperature evolution. Nonuniversality can arise from the relative importance of the local and collective barriers (related to fragility) and the precise magnitude of the length scale that defines the transition from local cage to elastic physics. Comparison is made with a traplike model based on a Gaussian distribution of barriers.

Xie, Shi-Jie (ORCID:0000000333174720)↗

DOE OSTI2021

Water Migration and Swelling in Engineered Barrier Materials for Radioactive Waste Disposal

Deep, underground repositories are needed to isolate radioactive waste from the biosphere. Because bentonite is an integral component of many multibarrier repository systems, information on the hydraulic behavior of bentonite is crucial for modeling the long-term viability of such systems. In this paper the hydraulic behavior of bentonite samples was analyzed as a function of aggregate size, and samples were subjected to hydrothermal treatments involving contact with NaCl, KCl, and deionized water. Neutron and X-ray imaging were used to quantify water sorption into packed bentonite samples and bentonite swelling into the water column. The distance between the original clay-water interface and the wetting front was determined as a function of time. Average water uptake exhibited a square-root-of-time dependence in freshly prepared samples, but more variable rates were observed for samples previously in contact with water. The radiography was supported by small-angle neutron scattering analysis and ultra-small-angle neutron scattering analysis of aggregate size distributions and by inelastic neutron scattering to understand the physicochemical environment of the sorbed water. Results showed that hydrothermal treatment with KCl had the greatest effect of increased water transport in the bentonite, possibly as a result of the interaction of K + with smectite layers in the clay.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2024

Evaluation of SPARC divertor conditions in H-mode operation using SOLPS-ITER

The predicted divertor conditions for the SPARC tokamak are calculated using SOLPS-ITER for a range of scrape-off-layer (SOL) heat flux widths λ q , input powers, and particle fueling locations. Under H-mode scenario conditions with an upstream separatrix density of 1 x 10 20 m -3 , the most conservative range of λ q extrapolations ( 0.15 mm) results in extremely high unmitigated particle and energy fluxes to the divertor, both under full field (12.2 T) and power (P SOL = 29 MW) conditions, and 2/3 field with P SOL = 10 MW. Increasing the cross-field SOL diffusivities by 2–10× reduces the magnitude of the mitigation challenge, however strategies such as impurity seeding or strike-point-sweeping will likely still be required. A combination of steady-state and time-dependent SOLPS-ITER simulations are used to map out phase space diagrams of upstream and divertor conditions. The simulations include parallel currents but neglect cross-field drifts. At low upstream density the inner and outer divertor conditions are highly asymmetric, with a large temperature difference and significant heat fluxes driven by parallel currents. The solution has sharp bifurcations with a region of hysteresis, depending on whether the initial state is at a low or high density. This behavior is observed even when the fueling location, cross-field diffusivity, and impurity level is changed, although the density window with asymmetry is reduced with increasing diffusivity. The addition of neon impurity seeding reduces the divertor heat fluxes, but also causes a drop in the upstream electron density with fixed particle throughput. This drop can be counteracted by increased main ion throughput, however too much neon results in a back transition into the asymmetric divertor regimes suggesting a need for control of both main ion and impurity seeding levels to achieve a desired divertor state.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2021

Time-dependent density functional theory applied to average atom opacity

We focus on studying the opacity of iron, chromium, and nickel plasmas at conditions relevant to experiments carried out at Sandia National Laboratories. In this work, we calculate the photoabsorption cross sections and subsequent opacity for plasmas using linear-response time-dependent density functional theory (TD-DFT). Our results indicate that the physics of channel mixing accounted for in linear-response TD-DFT leads to an increase in the opacity in the bound-free quasicontinuum, where the Sandia experiments indicate that models underpredict iron opacity. However, the increase seen in our calculations is only in the range of 5%–10%. Further, we do not see any change in this trend for chromium and nickel. This behavior indicates that channel mixing effects do not explain the trends in opacity observed in the Sandia experiments.

74 ATOMIC AND MOLECULAR PHYSICS↗

DOE OSTI2020

Tritium Pressure Enhancement on the TPBAR Cladding by Physical Processes at the Getter

Tritium for the U.S. nuclear weapon stockpile is produced in tritium producing burnable absorber rods (TPBARs) inserted into Tennessee Valley Authoritys (TVA) light-water nuclear reactors. The rods are stainless steel tubes with a permeation barrier coating and internal components that generate and contain the tritium. The TPBAR incorporates a Ni-plated Zircoloy getter tube to capture tritium and prevent it from reaching the rod cladding and permeating into the environment. Under the conventional view of getter behavior, the tritium pressure outside the getter tube is expected to be limited to the equilibrium vapor pressure of Zr hydride at the temperature of the rod as long as the total hydrogen concentration remains below the capacity of the hydride. Since the tritium pressure is higher within the rod core, this behavior relies on the thin getters ability to hold off a differential tritium pressure. The effective tritium pressure on the cladding can also be enhanced by isotope exchange. Hydrogen ingress through the cladding from the reactor coolant creates a hydrogen pressure on the outer surface of the getter that can exchange with tritium, allowing the tritium partial pressure to increase toward this hydrogen gettering pressure. The goal of this work was to use laboratory-scale experiments to examine these mechanisms and create a model of getter behavior that describes tritium transport within the TPBAR. A third mechanism wherein the concentration at the outer surface of the getter is increased by the temperature gradient within the getter tube wall (the Soret effect) is not experimentally tested but is captured in the model. While not conclusively demonstrated by the experiments due to low pressure, high temperature, and small gap volume conditions, the model shows that when combined, the three mechanisms can explain both the magnitude and time dependence of the tritium release observed for reactor fuel assemblies with TPBARs. The model also shows how various modifications of the TPBAR design can reduce this tritium release into the environment.

07 ISOTOPE AND RADIATION SOURCES↗

NASA NTRS1978

Interpolation and Extrapolation of Creep Rupture Data by the Minimum Commitment Method. Part 3: Analysis of Multiheats

The Minimum Commitment Method was applied to two sets of data for which multiple heat information was available. For one alloy, a 304 stainless steel studied in Japan, data on nine well characterized heats were used, while for a proprietary low alloy carbon steel studied in the United Kingdom data were available on seven heats - in many cases to very long rupture times. For this preliminary study no instability factors were used. It was discovered that heat-to-heat variations would be accounted for by introducing heat identifiers in the form A + B log sigma where sigma is the stress and the constants A and B depend only on the heat. With these identifiers all the data could be collapsed onto a single master curve, even though there was considerable scatter among heats. Using these identifiers together with the average behavior of all heats made possible the determination of an accurate constitutive equation for each individual heat. Two basic approaches are discussed for applying the results of the analysis.

Manson, S. S.↗

NASA NTRS1992

Issues in knowledge representation to support maintainability: A case study in scientific data preparation

Scientific data preparation is the process of extracting usable scientific data from raw instrument data. This task involves noise detection (and subsequent noise classification and flagging or removal), extracting data from compressed forms, and construction of derivative or aggregate data (e.g. spectral densities or running averages). A software system called PIPE provides intelligent assistance to users developing scientific data preparation plans using a programming language called Master Plumber. PIPE provides this assistance capability by using a process description to create a dependency model of the scientific data preparation plan. This dependency model can then be used to verify syntactic and semantic constraints on processing steps to perform limited plan validation. PIPE also provides capabilities for using this model to assist in debugging faulty data preparation plans. In this case, the process model is used to focus the developer's attention upon those processing steps and data elements that were used in computing the faulty output values. Finally, the dependency model of a plan can be used to perform plan optimization and runtime estimation. These capabilities allow scientists to spend less time developing data preparation procedures and more time on scientific analysis tasks. Because the scientific data processing modules (called fittings) evolve to match scientists' needs, issues regarding maintainability are of prime importance in PIPE. This paper describes the PIPE system and describes how issues in maintainability affected the knowledge representation used in PIPE to capture knowledge about the behavior of fittings.

Chien, Steve↗

NASA NTRS1997

Light-Induced Alterations in Striatal Neurochemical Profiles

Much of our present knowledge regarding circadian rhythms and biological activity during space flight has been derived from those missions orbiting the Earth. During space missions, astronauts can become exposed to bright/dark cycles that vary considerably from those that entrain the mammalian biological timing system to the 24-hour cycle found on Earth. As a spacecraft orbits the Earth, the duration of the light/dark period experienced becomes a function of the time it takes to circumnavigate the planet which in turn depends upon the altitude of the craft. Orbiting the Earth at an altitude of 200-800 km provides a light/dark cycle lasting between 80 and 140 minutes, whereas a voyage to the moon or even another planet would provide a light condition of constant light. Currently, little is known regarding the effects of altered light/dark cycles on neurochemical levels within the central nervous system (CNS). Many biochemical, physiological and behavioral phenomena are under circadian control, governed primarily by the hypothalamic suprachiasmatic nucleus. As such, these phenomena are subject to influence by the environmental light/dark cycle. Circadian variations in locomotor and behavioral activities have been correlated to both the environmental light/dark cycle and to dopamine (DA) levels within the CNS. It has been postulated by Martin-Iverson et al. that DA's role in the control of motor activity is subject to modulation by circadian rhythms (CR), environmental lighting and excitatory amino acids (EAAs). In addition, DA and EAA receptor regulated pathways are involved in both the photic entrainment of CR and the control of motor activity. The cellular mechanisms by which DA and EAA-receptor ligands execute these functions, is still unclear. In order to help elucidate these mechanisms, we set out to determine the effects of altered environmental light/dark cycles on CNS neurotransmitter levels. In this study, we focused on the striatum, a region of the brain that receives a number of dopaminergic and glutamatergic input and is known to be involved in the modulation of locomotor and behavioral responses.

Sroufe, Angela E.↗

NASA NTRS2007

Gravity-Dependent Combustion and Fluids Research - From Drop Towers to Aircraft to the ISS

Driven by the need for knowledge related to the low-gravity environment behavior of fluids in liquid fuels management, thermal control systems and fire safety for spacecraft, NASA embarked on a decades long research program to understand, accommodate and utilize the relevant phenomena. Beginning in the 1950s, and continuing through to today, drop towers and aircraft were used to conduct an ever broadening and increasingly sophisticated suite of experiments designed to elucidate the underlying gravity-dependent physics that drive these processes. But the drop towers and aircraft afford only short time periods of continuous low gravity. Some of the earliest rocket test flights and manned space missions hosted longer duration experiments. The relatively longer duration low-g times available on the space shuttle during the 1980s and 1990s enabled many specialized experiments that provided unique data for a wide range of science and engineering disciplines. Indeed, a number of STS-based Spacelab missions were dedicated solely to basic and applied microgravity research in the biological, life and physical sciences. Between 1980 and 2000, NASA implemented a vigorous Microgravity Science Program wherein combustion science and fluid physics were major components. The current era of space stations from the MIR to the International Space Station have opened up a broad range of opportunities and facilities that are now available to support both applied research for technologies that will help to enable the future exploration missions and for a continuation of the non-exploration basic research that began over fifty years ago. The ISS-based facilities of particular value to the fluid physics and combustion/fire safety communities are the Fluids and Combustion Facility Combustion Integrated Rack and the Fluids Integrated Rack.

Urban, David L.↗

NASA NTRS2019

Psychophysiological Monitoring of Aerospace Crew State

As next-generation space exploration missions necessitate increasingly autonomous systems, there is a critical need to better detect and anticipate crewmember interactions with these systems. The success of present and future autonomous technology in exploration spaceflight is ultimately dependent upon safe and efficient interaction with the human operator. Optimal interaction is particularly important for surface missions during highly coordinated extravehicular activity (EVA), which consists of high physical and cognitive demands with limited ground support. Crew functional state may be affected by a number of variables including workload, stress, and motivation. Real-time assessments of crew state that do not require a crewmember’s time and attention to complete will be especially important to assess operational performance and behavioral health during flight. In response to the need for objective, passive assessment of crew state, the aim of this work is to develop an accurate and precise prediction model of human functional state for surface EVA using multi-modal psychophysiological sensing. The psychophysiological monitoring approach relies on extracting a set of features from physiological signals and using these features to classify an operator’s cognitive state. This work aims to compile a non-invasive sensor suite to collect physiological data in real-time. Training data during cognitive and more complex functional tasks will be used to develop a classifier to discriminate high and low cognitive workload crew states. The classifier will then be tested in an operationally relevant EVA simulation to predict cognitive workload over time. Once a crew state is determined, further research into specific countermeasures, such as decision support systems, would be necessary to optimize the automation and improve crew state and operational performance.

Wusk, Grace C.↗

DOE OSTI2021

Temperature dependence of viscoelastic Poisson’s ratio of cement mortar

Abstract Concrete creep research has focused primarily on uniaxial response. However, biaxially prestressed concrete structures are common, resulting in a multiaxial stress state that can complicate the behavior of a viscoelastic material like concrete. Significant creep strains may be induced in directions transverse to each principle stress due to Poisson’s effect. Past research is unclear regarding the viscoelastic or viscoplastic properties of concrete outside of uniaxial response. It has been reported in separate studies that concrete viscoelastic/viscoplastic Poisson’s ratio (VPR) is an increasing, decreasing and constant function with time, with all reported measurements performed at room temperature. In this paper, the 3D basic creep response of mature cement mortar is examined using a confined compression experiment that allows direct determination of the full stress and infinitesimal strain tensors in a single test, which enables the determination of VPR under a multiaxial stress state. For this purpose, a unique, miniature version of the standardized concrete creep frame is designed that is amenable to placing in climate chambers and temperature ovens. The experimental results indicate that the VPR of sealed, mature cement mortar is nearly constant and equal to the elastic at room temperature, while the VPR gradually increases with time when measured at 60 °C.

Construction & Building Technology↗