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NASA NTRS2004

Education, Technology, and Media: A Peak into My Summer Internship at NASA Glenn Research Center in Cleveland, Ohio

My name is James Moon and I am a senor at Tennessee State University where my major is Aeronautical and Industrial Technology with a concentration in industrial electronics. I am currently serving my internship in the Engineering and Technical Services Directorate at the Glenn Research Center (GRC). The Engineering and Technical Service Directorate provides the services and infrastructure for the Glenn Research Center to take research concepts to reality. They provide a full range of integrated services including engineering, advanced prototyping and testing, facility management, and information technology for NASA, industry, and academia. Engineering and Technical Services contains the core knowledge in Information Technology (IT). This includes data systems and analysis, inter and intranet based systems design and data security. Including the design and development of embedded real-time sohare applications for flight and supporting ground systems, Engineering and Technical Services provide a wide range of IT services and products specific to the Glenn Research Center research and engineering community.

Moon, James↗

NASA NTRS2007

Lessons Learned from Seven Space Shuttle Missions

Much can be learned from well-written descriptions of the technical and organizational factors that lead to an accident. Subsequent analysis by third parties of investigation reports and associated evidence collected during the investigations can lead to additional insight. Much can also be learned from documented close calls that do not result in loss of life or a spacecraft, such as the Mars Exploration Rover Spirit software anomaly, the SOHO mission interruption, and the NEAR burn anomaly. Seven space shuttle incidents fall into the latter category: Rendezvous Target Failure On STS-41B; Rendezvous Radar Anomaly and Trajectory Dispersion-STS-32 ;Rendezvous Lambert Targeting Anomaly-STS-49; Rendezvous Lambert Targeting Anomaly-STS-51; Zero Doppler Steering Maneuver Anomaly-STS-59; Excessive Propellant Consumption During Rendezvous-STS-69; Global Positioning System Receiver and Associated Shuttle Flight Software Anomalies-STS-91 Procedural work-arounds or software changes prevented them from threatening mission success. Extensive investigations, which included the independent recreation of the anomalies by multiple Shuttle Program organizations, were the key to determining the cause, accurately assessing risk, and identifying software and software process improvements. Lessons learned from these incidents not only validated long-standing operational best practices, but serve to promote discussion and mentoring among Program personnel and are applicable to future space flight programs.

Goodman, John↗

NASA NTRS2013

Microbiological Sampling Methods and Sanitation of Edible Plants Grown on ISS

Pathogenic microbes on the surfaces of salad crops and growth chambers pose a threat to the health of crew on International Space Station. For astronauts to safely consume spacegrown vegetables produced in NASA's new vegetable production unit, VEGGIE, three technical challenges must be overcome: real-time sampling, microbiological analysis, and sanitation. Raphanus sativus cultivar Cherry Bomb II and Latuca sativa cultivar Outredgeous, two saled crops to be grown in VEGGIE, were inoculated with Salmonella enterica serovar Typhimurium (S. Typhimurium), a bacterium known to cause food-borne illness~ Tape- and swab-based sampling techniques were optimized for use in microgravity and assessed for effectiveness in recovery of bacteria from crop surfaces: Rapid pathogen detection and molecular analyses were performed via quantitative real-time polymerase chain reactiop using LightCycler® 480 and RAZOR® EX, a scaled-down instrument that is undergoing evaluation and testing for future flight hardware. These methods were compared with conventional, culture-based methods for the recovery of S. Typhimurium colonies. A sterile wipe saturated with a citric acid-based, food-grade sanitizer was applied to two different surface materials used in VEGGIE flight hardware that had been contaminated with the bacterium Pseudomonas aeruginosa,. another known human pathogen. To sanitize surfaces, wipes were saturated with either the sanitizer or sterile deionized water and applied to each surface. Colony forming units of P. aeruginosa grown on tryptic soy agar plates were enumerated from surface samples after sanitization treatments. Depending on the VEGGIE hardware material, 2- to 4.5-log10 reductions in colony-forming units were observed after sanitization. The difference in recovery of S. Typhimurium between tape- and swab- based sampling techniques was insignificant. RAZOR® EX rapidly detected S. Typhimurium present in both raw culture and extracted DNA samples.

Parrish, Charles H. II↗

NASA NTRS2015

Defining Operational Space Suit Requirements for Commercial Orbital Spaceflight

As the commercial spaceflight industry transitions from suborbital brevity to orbital outposts, spacewalking will become a major consideration for tourists, scientists, and hardware providers. The challenge exists to develop a space suit designed for the orbital commercial spaceflight industry. The unique needs and requirements of this industry will drive space suit designs and costs that are unlike any existing product. Commercial space tourists will pay for the experience of a lifetime, while scientists may not be able to rely on robotics for all operations and external hardware repairs. This study was aimed at defining space suit operational and functional needs across the spectrum of spacewalk elements, identifying technical design drivers and establishing appropriate options. Recommendations from the analysis are offered for consideration

Alpert, Brian K.↗

NASA NTRS2019

eddy Users Manual

eddy is a collection of tools - nonlinear solvers, meshing, post-processing, visualization, optimization, etc. - for performing scale-resolving simulations of multi-physics applications. The framework is designed to enable advanced R&D on a variety of topics by leveraging a mature capability for scale resolving simulations, and simultaneously be an appropriate tool for application analysis and support. Currently, eddy is at a relatively low technical readiness level (TRL), and users and developers should maintain appropriate expectations. The technical details behind eddy are outlined in several publications which can be consulted for more information [1–10]. The solvers are built around an unstructured high-order capability, and heavily utilize the tensor product sum-factorization approach for efficiency. The unsteady formulation utilizes a fully implicit space-time approach with a matrix-free Newton- Krylov method. A primitive steady-state solver is available for testing purposes, but is not expected to converge for all but simple verification cases. The Navier-Stokes fluid solvers do not support either RANS or hybrid-RANS capability, only LES and wall-modeled LES approaches. All of the solvers within eddy support three modes of operation: a primal solve of the full nonlinear problem, and two linearization approaches of the primal solve - the ad joint and the tangent solution. Details on how to select and use these three modes are outlined in Sec. 3.

Murman, Scott M.↗

DOE OSTI2018

APPLICATION OF THE FAVOR-OCI FRACTURE MECHANICS COMPUTER PROGRAM TO ASME CODE SECTION XI, IWB-3610 FLAW ACCEPTANCE CRITERIA EVALUATIONS

This paper presents an overview of added features in a new version of the FAVOR (Fracture Analysis of Vessels Oak Ridge) computer code called FAVOR-OCI. The original FAVOR code was developed at the US Department of Energy’s Oak Ridge National Laboratory (ORNL) under the sponsorship of the US Nuclear Regulatory Commission (NRC). FAVOR is applied by US and international nuclear power industries to perform deterministic and probabilistic fracture mechanics analyses of commercial nuclear reactor pressure vessels (RPVs). Appli-cations of FAVOR are focused on insuring that the structural integrity of aging, and increasingly embrittled, RPVs is main-tained throughout their licensed service life. Based on the final ORNL release of FAVOR, v16.1, FAVOR-OCI extends existing deterministic features of FAVOR while preserving all prev-iously-existing probabilistic capabilities of FAVOR.The objective of this paper is to describe new deterministic features in FAVOR-OCI that can be applied to analytical evaluations of planar flaws. These evaluations are consistent with the acceptance criteria of ASME Code, Section XI, Article IWB-3610, including Subarticles IWB-3611 (acceptance based on flaw size) and IWB-3612 (acceptance based on applied stress intensity factor). The linear elastic fracture mechanics (LEFM) capabilities of FAVOR-OCI also incorporate the analytical procedures presented in the Nonmandatory Appendix A, Analysis of Flaws, Article A-3000, Method of KI Determination, for both surface and subsurface (embedded) flaws.The paper describes a computational methodology for determining critical values of fracture-related parameters that satisfy ASME Code Section XI acceptance criteria for flaws exposed to multiple thermal-hydraulic transients. These com-pute-intensive analyses can be carried out with a single execution of FAVOR-OCI. The new methodology determines critical values by solving for either the point of tangency or point of intersection between applied KI versus time histories and a user-selected fracture toughness material property (e.g., ASME KIc, FAVOR Weibull KIc, or Master Curve Weibull KJc) for surface or subsurface flaws. Situations where warm prestress conditions apply can also be addressed. The paper highlights a need for this new capability via applications to a recent independent review of safety cases for RPVs in two Belgian nuclear power plants (NPPs). That review required ASME Section XI assessments of several thousand embedded, quasi-laminar flaws in the wall of each RPV. Analysis results provided by the new capability contributed to the technical bases compiled from several sources by the Belgian nuclear regulatory agency (FANC) and eventually used by FANC to justify the restart of these NPPs.

Dickson, Terry L.↗

DOE OSTI2021

Annual Summary Report for the Remote-Handled Low-Level Waste Disposal Facility—FY 2020

This Fiscal Year (FY) 2020 annual summary report documents the continued adequacy of the performance assessment (PA), the composite analysis (CA) and associated operating disposal-authorization statement (ODAS) technical basis documents for the Remote Handled (RH) Low-Level Waste (LLW) Disposal Facility at Idaho National Laboratory. Annual review of the adequacy of the PA and CA for the RHLLW Disposal Facility ensures that conclusions of the analyses remain valid in accordance with requirements of Department of Energy (DOE) Order 435.1 Change 1, “Radioactive Waste Management.” In FY 2020, no significant operational changes or other activities occurred that would cause deviation from the assumptions in the PA and CA pertaining to disposal geometry, verification of waste characteristics, tracking disposal inventories against total limits, facility closure design, or institutional controls. Fifteen total waste-canister shipments were received at the RHLLW Disposal Facility, and 15 total waste canisters were emplaced.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

Fiscal Year 2020 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites at the Nevada National Security Site, Nye County, Nevada

U.S. Department of Energy Standard DOE-STD-5002-2017, “Disposal Authorization Statement and Tank Closure Documentation,” requires preparation of an Annual Summary Report comparing low-level radioactive waste disposal facilities operations with the Disposal Authorization Statement (DAS) and its supporting technical documents including the performance assessment (PA) and the composite analysis (CA). The fiscal year (FY) 2020 Annual Summary Report for the Area 3 and Area 5 Radioactive Waste Management Sites (RWMSs) was prepared by reviewing planned and discovered changes, waste receipts, monitoring results, research and development (R&D) results, and the status of DAS conditions and issues to assess the validity of the DASs, PAs, and CAs.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Industrial Load Flexibility, the U.S. Power Grid and Ammonia

A variable renewable power grid is a new technological regime that involves real time harvesting and low-cost availability of energy resources coupled with storage to meet additional needs. Decarbonization through electrification of end uses formerly met by combustion processes will be a concurrent trend. Taken together, these two changes may make flexibility on the demand side more valuable to the grid and to industrial users. Industry accounted for 26% of US power demand in 2021. Traditionally, industrial processes for producing ammonia and other basic materials have been optimized for a system based on fossil resources, where energy can be called upon according to needs. Large capital expenditures as well as safety considerations have favored plants running at steady state at close to their maximum capacity. It is possible, however, that the renewable energy transition will offer opportunities to sectors that can operate in a more flexible manner. Innovations that make use of flexibility to enhance their business model to move forward, individuals and groups active in their development, use and regulation, together with institutions and infrastructures, can be considered as a technological innovation system (TIS). Beyond economic and technical factors on their own, the TIS is an important analysis framework for studying the development and diffusion of technologies. This work attempts to map the TIS of flexible industrial loads and their interaction with electric power in the US, with a particular focus on ammonia as a case study. We have conducted interviews with stakeholders involved in ammonia projects, working in system operators, trade groups, regulators and utilities. We assess to what extent a technological innovation system is functioning and document characteristics that allow industries to operate flexibly.

ammonia↗

DOE OSTI2024

Presentation on the INL Remote-Handled Low-Level Waste Disposal Facility FY-2023 Annual Summary Report

The abstract below is from the report INL/RPT-24-76103. The powerpoint presentation contains information taken from the report. This Fiscal Year (FY) 2023 annual summary report (ASR) documents the continued adequacy of the performance assessment (PA), the composite analysis (CA) and associated operating disposal-authorization statement (ODAS) technical basis documents for the Remote Handled (RH) Low-Level Waste (LLW) Disposal Facility at Idaho National Laboratory. Annual review of the adequacy of the PA and CA for the RHLLW Disposal Facility ensures that conclusions of the analyses remain valid in accordance with requirements of Department of Energy (DOE) Order 435.1, “Radioactive Waste Management.” In FY 2023, no significant operational changes or other activities occurred that would cause deviation from the assumptions in the PA and CA pertaining to disposal geometry, verification of waste characteristics, tracking disposal inventories against total limits, facility closure design, or institutional controls. Sixteen total waste-canister shipments were received at the RHLLW Disposal Facility, and 15 total waste canisters were emplaced.

12 - MGMT OF RADIOACTIVE AND NON-RADIOACTIVE WASTE↗

DOE OSTI1996

Nuclear Safety [Vol. 37, No. 2, April-June 1996]

Nuclear Safety is a journal that covers significant issues in the field of nuclear safety. Its primary scope is safety in the design, construction, operation, and decommissioning of nuclear power reactors worldwide and the research and analysis activities that promote this goal, but it also encompasses the safety aspects of the entire nuclear fuel cycle, including fuel fabrication, spent-fuel processing and handling, and nuclear waste disposal, the handling of fissionable materials and radioisotopes, and the environmental effects of all these activities. Table of Contents for this issue follows. GENERAL SAFETY CONSIDERATIONS: 97 The Nuclear Community and the Public: Cognitive and Cultural Influences on Thinking About Nuclear Risk, M. A. Meyer; 109 Twenty-Third Water Reactor Safety Information Meeting, D. A. Copinger; ACCIDENT ANALYSIS: 126 Analysis of a PWR LBLOCA Without SCRAM, Trevor N. Tyler, Rafael Macian-Juan and John H. Mahaffy; DESIGN FEATURES: 139 Vulnerability of Multiple-Barrier Systems, N. C. Lind; ENVIRONMENTAL EFFECTS: 149 A Study of Wet Catalytic Oxidation of Radioactive Spent Ion Exchange Resin by Hydrogen Peroxide, Xingchao Jian, Tianbao Wu, and Guichun Yun; 157 A Comparison Study and Resolution of Differences Between Emergency Response and Safety Analysis Codes Used at the Savannah River Site, A. A. Simpkins; OPERATING EXPERIENCES: 164 Reactor Shutdown Experience, Compiled by J. W. Cletcher; RECENT DEVELOPMENTS: 167 Reports, Standards, and Safety Guides, D. S. Queener; 172 Proposed Rule Changes as of Dec. 31,1995; ANNOUNCEMENTS: 178 American Nuclear Society 1997 Annual Meeting; 178 American Nuclear Society Nuclear Criticality and Safety Division Topical Meeting; 176 The Authors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2019

H2@Scale Analysis

The 'H2@Scale' concept focuses on the opportunity for hydrogen to be an energy intermediate like electricity that supports both production opportunities and demand applications. Hydrogen is complementary to electricity because of its inherent capability to be stored. It can also be produced easily from electricity and is fungible with a variety of applications. This presentation summarizes the H2@Scale analysis efforts performed during the latter half of 2018 and the first quarter of 2019. We analyzed the technical and economic potential for hydrogen. Our preliminary estimate of the maximum market size for hydrogen is 166 million metric tons (MMT) annually. The analysis shows sufficient wind and solar resources to meet that demand. Five economic potential scenarios are also presented. Their market sizes, prices, sources, and applications are estimated through development of national supply and demand curves and using them to estimate market equilibria. The resulting market size ranges from 14 MMT/yr to 48 MMT/yr. Analysis is underway to identify the lowest-cost delivery and storage options for those four scenarios. Additional proposed work focuses on developing regional fidelity and understanding potential opportunities for a transition from today's hydrogen market to one with H2@Scale.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

NASA NTRS1999

Remembering Apollo 11: The 30th Anniversary Data Archive CD-ROM

On July 20, 1969, the human race accomplished its single greatest technological achievement of all time when a human first set foot on another celestial body. Six hours after landing at 4:17 p.m. Eastern Standard Time (with less than thirty seconds of fuel remaining), Neil A. Armstrong took the "small step" into our greater future when he stepped off the Lunar Module, named Eagle, onto the surface of the Moon, from which he could look up and see Earth in the heavens as no one had done before him. He was shortly joined by Edwin "Buzz" Aldrin, and the two astronauts spent twenty-one hours on the lunar surface and returned forty-six pounds of lunar rocks. After their historic walks on the Moon, they successfully docked with Michael Collins, patiently orbiting the cold but no longer lifeless Moon alone in the Command module Columbia. This CR-ROM is intended as a collection of hard to find technical data and other interesting information about the Apollo 11 mission, as well as the apollo program in general. It includes basic overviews, such as a retrospective analysis, an annotated bibliography, and history of the lunar-orbit rendezvous concept. It also contains technical data, such as mission operations reports, press kits, and news references for all of the Apollo missions, the Apollo spacecraft, and the Saturn V launch vehicle. Rounding out this CD-ROM are extensive histories of the lunar Orbiter program (the robotic predecessor to Apollo, biographies of the Apollo astronauts and other key individuals, and interesting audio-visual materials, such as video and audio clips, photo galleries, and blueprint-like diagrams of the Apollo spacecraft.

Edgar M Cortright↗

DOE OSTI2021

Supply Chain Sustainability Analysis of Renewable Hydrocarbon Fuels via Indirect Liquefaction, Ex Situ Catalytic Fast Pyrolysis, Hydrothermal Liquefaction, Combined Algal Processing, and Biochemical Conversion: Update of the 2020 State-of-Technology Cases

The Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) aims to develop and deploy technologies to transform renewable biomass resources into commercially viable, high-performance biofuels, bioproducts, and biopower through public and private partnerships (U.S. Department of Energy, 2016). BETO and its national laboratory teams conduct in-depth techno-economic assessments (TEA) of biomass feedstock supply and logistics and conversion technologies to produce biofuels. There are two general types of TEAs: A design case outlines a target case (future projection) for a particular biofuel pathway. It enables identification of data gaps and research and development needs and provides goals and benchmarks against which technology progress is assessed. A state of technology (SOT) analysis assesses progress within and across relevant technology areas based on actual results at current experimental scales relative to technical targets and cost goals from design cases, and includes technical, economic, and environmental criteria as available. In addition to developing a TEA for a pathway of interest, BETO also performs a supply chain sustainability analysis (SCSA). The SCSA takes the life-cycle analysis approach that BETO has been supporting for about 20 years. It enables BETO to identify energy consumption, environmental, and sustainability issues that may be associated with biofuel production. Approaches to mitigate these issues can then be developed. Additionally, the SCSA allows for comparison of energy and environmental impacts across biofuel pathways in BETO’s research and development portfolio. This technical report describes the SCSAs for the production of renewable hydrocarbon transportation fuels via a range of conversion technologies in the 2020 SOTs: (1) renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of woody lignocellulosic biomass (note that the IDL pathway in this SCSA represents the syngas conversion design [Harris et al. 2021]); (2) renewable gasoline (RG) and diesel (RD) blendstocks via ex situ catalytic fast pyrolysis of woody lignocellulosic biomass [Abhijit et al. 2021]; (3) RD via hydrothermal liquefaction (HTL) of wet sludge from a wastewater treatment plant; (4) renewable hydrocarbon fuels via biochemical conversion of herbaceous lignocellulosic biomass (Davis et al. 2021; Lin et al. 2021); (5) renewable diesel via HTL of a blend of algae (Davis and Klein, 2021) and woody biomass (Hartley et al. 2020); and (6) renewable diesel via combined algae processing (CAP) (Wiatrowski and Davis, 2021). This technical report focuses on the environmental performance of these six biofuel production pathways in their 2020 SOT cases. The results of these renewable hydrocarbon fuel pathways in these SCSA analyses update those for the respective 2019 SOT cases (Cai et al. 2020). They also provide an opportunity to examine the impact of technology improvements in both biomass feedstock production and biofuel production that have been achieved in 2020 SOTs on the sustainability performance of these renewable transportation fuels. The SCSA results also reflect updates to Argonne National Laboratory’s Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET®) model, which was released in October 2020 (Wang et al. 2020). These GREET updates include the production of natural gas, electricity, and petroleum-based fuels that can influence biofuels’ supply chain greenhouse gas (GHG) (CO 2 , CH 4 , and N 2 O) emissions, water consumption, and air pollutant emissions. GHG emissions, water consumption, and nitrogen oxides (NO x ) emissions are the main sustainability metrics assessed in this analysis. In this analysis, we define water consumption as the amount of water withdrawn from a freshwater source that is not returned (or returnable) to a freshwater source at the same level of quality. Life-cycle fossil energy consumption and net energy balance, which is the life-cycle fossil energy consumption deducted from the renewable biofuel energy produced, are also assessed.

09 BIOMASS FUELS↗

NASA NTRS1983

Interactive analysis of a large aperture Earth observations satellite

A system level design and analysis has been conducted on an Earth Observation Satellite (EOS) system using the Interactive Design and Evaluation of Advanced Spacecraft (IDEAS) computer-aided design and analysis program. The IDEAS program consists of about 40 user-friendly technical modules and an interactive graphics display. The reflector support system and feed mast of the EOS spacecraft are constructed with box-truss structural concept, a lattice configuration which can be packaged for delivery in a single Shuttle flight and deployed in orbit. The deployed spacecraft consists of a 120-m by 60-m parabolic focal axis. The spacecraft was modeled for structural, thermal, and control systems analysis and structural elements were designed. On-orbit dynamic and thermal loading analyses were conducted; spacecraft weights and developmental and first unit costs were determined.

Wright, R. L.↗

DOE OSTI2025

Blending Pipeline Analysis Tool for Hydrogen (BlendPATH) Documentation and User Manual

The Blending Pipeline Analysis Tool for Hydrogen (BlendPATH) is a flexible, open-source Python tool designed to provide users with case-by-case analysis capabilities to identify the necessary modifications to repurpose existing natural gas transmission pipeline networks to transport hydrogen as a blend of a user-specified volume fraction of hydrogen or as a pure stream and to estimate the associated capital and operating expenditures resulting from those modifications. This tool is intended to be applied during the initial screening stage of a prospective project when pipeline developers compile transmission pipeline technical documentation and history but prior to performing detailed pipeline inspections. Performing analysis with BlendPATH during this initial screening stage can provide the user with an understanding of promising opportunities and probable economic outcomes of repurposing their pipeline network for hydrogen before proceeding with detailed pipeline materials testing and pipeline inspections. BlendPATH consists of multiple modules to simulate, assess, and modify existing natural gas transmission pipeline network designs to be compatible with hydrogen as a blend or pure stream. The tool employs an open-source gas network hydraulic model to simulate existing, user-specified transmission pipeline networks, and it applies ASME B31.12 to assess the pipe segments within these networks for compatibility with hydrogen and to modify the networks to achieve compatibility where the existing infrastructure is inadequate. Users can specify ASME B31.12 design options for pipeline assessment and can select from multiple methods for pipeline modification. This report details the functionalities of BlendPATH Version 2.0.2 and demonstrates an example of applying BlendPATH to a case study. Potential and intended users of this framework include natural gas pipeline developers and operators and researchers at both public and private institutions. BlendPATH is publicly available at https://github.com/NREL/BlendPATH.

08 HYDROGEN↗

DOE OSTI2017

Regio-Selective Intramolecular Hydrogen/Deuterium Exchange in Gas-Phase Electron Transfer Dissociation

Protein backbone amide hydrogen/deuterium exchange mass spectrometry (HDX-MS) typically utilizes enzymatic digestion after the exchange reaction and before MS analysis to improve data resolution. Gas-phase fragmentation of a peptic fragment prior to MS analysis is a promising technique to further increase the resolution. The biggest technical challenge for this method is elimination of intramolecular hydrogen/deuterium exchange (scrambling) in the gas phase. The scrambling obscures the location of deuterium. Jørgensen’s group pioneered a method to minimize the scrambling in gas-phase electron capture/transfer dissociation. Despite active investigation, the mechanism of hydrogen scrambling is not well-understood. The difficulty stems from the fact that the degree of hydrogen scrambling depends on instruments, various parameters of mass analysis, and peptide analyzed. In most hydrogen scrambling investigations, the hydrogen scrambling is measured by the percentage of scrambling in a whole molecule. This paper demonstrates that the degree of intramolecular hydrogen/deuterium exchange depends on the nature of exchangeable hydrogen sites. The deuterium on Tyr amide of neurotensin (9–13), Arg-Pro-Tyr-Ile-Leu, migrated significantly faster than that on Ile or Leu amides, indicating the loss of deuterium from the original sites is not mere randomization of hydrogen and deuterium but more site-specific phenomena. This more precise approach may help understand the mechanism of intramolecular hydrogen exchange and provide higher confidence for the parameter optimization to eliminate intramolecular hydrogen/deuterium exchange during gas-phase fragmentation. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

NASA NTRSDate not supplied

An Interim Set of TNT Curves for LOX/LNG Explosions

Space launch companies are actively developing, or in some cases have already developed, new vehicles that use large quantities of liquid oxygen (LOX) and liquid natural gas (LNG) propellants. This propellant mixture currently lacks sound/verified LOX/LNG explosive safety standards for use in explosive siting and flight safety analysis. In the U.S., multiple government and commercial organizations have conducted limited testing, or are preparing to conduct tests, intended to provide a sound technical basis for explosive standards applicable to space launch vehicle ground and flight operations. The limited testing and analysis conducted so far indicates the potential to produce extremely energetic explosions due to the miscibility of LOX/LNG (methane), a unique feature relative to previously used propellant mixtures such as hydrogen/oxygen or kerosene/oxygen. MOX is a homogenous mixture of methane and oxygen that is possible because of methane’s 100% miscibility in LOX. Preliminary testing by N2L, Inc. described in this paper shows that it is possible to form MOX with a variety of mixing methods, and that MOX is a sensitive high explosive capable of producing overpressures greater than comparable masses of C-4. The limited amount and quality of large-scale LOX/LNG explosive test data, and the potential formation of high-explosive MOX, create significant unknowns in the determination of hazard areas (cleared of the public) for ground operations (such as a static fire test) and flights of launch vehicles with LOX/LNG propellant. This paper will review the methods used by NASA to develop and validate the LOX/LH2 blast model using large-scale explosive test programs such as Project PYRO, the Hydrogen-Oxygen Vertical Impact (HOVI), and the Large-Scale Hydrogen-Oxygen Explosion (LSHOE) tests. This paper will describe how the same process was used to prepare an interim LOX/LNG blast model that applies to various LV failure scenarios and conservatively accounts for potential MOX formation. This paper also summarizes past and future testing and modeling efforts funded by a consortium of NASA, the US Federal Aviation Administration (FAA), and the US Space Force (USSF). These test programs should be concluded within the next 3 years and are intended to provide empirical data for model verification and validation.

Liquid Oxygen↗