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At least 1,243 records · Page 69
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NASA NTRS1991

Diffusion of water in rhyolitic glasses

The process of water diffusion in 11 natural rhyolitic glasses was considered using the results of measurements by FTIR spectroscopy of concentration profiles of both H2O and OH at different temperatures. The diffusion coefficients of H2O and OH, D(H2O) and D(OH), respectively, were calculated from concentration profiles. Results indicate that, at 400-530 C, the value of D(OH) is negligible compared to that of D(H2O), and that OH does not contribute significantly to the diffusion of total water even at water concentrations as low as 0.2 percent, which is minute compared to that of OH. In the activation energy vs radius plot, the D(H2O) followed the same trend as that of noble gases.

Zhang, Youxue↗
NASA NTRS1990

Solubility and diffusion of hydrogen in IN-100 and Waspaloy

The solubility of hydrogen, at a fixed hydrogen pressure, was measured in two different heat treatment conditions in both IN-100 and Waspaloy by equilibrium and analysis. The diffusion coefficients were determined by measuring the rate of hydrogen evolution in a vacuum. Hydrogen evolution appeared to be a diffusion-controlled process in all cases. For hydrogen diffusion in Waspaloy, Delta H was 38.5 kJ and D0 was 2.6 x 10 to the -7th sq/s. For IN-100, Delta H was 68.2 kJ and D0 was 59 x 10 to the -7th sq/s. The values for Waspaloy are close to those for pure nickel. The values for IN-100 are more similar to high nickel alloys that show trapping or surface layer impedance.

Khan, A. S.↗
NASA NTRS1991

Finite-element analysis of turbulent flow in annular exhaust diffusers of gas turbine engines

A modified version of the Petrov-Galerkin weighted residual method coupled with a biquadratic finite element of the Lagrangian type was used to develop a finite-element model of the turbulent flow field in the annular exhaust diffuser of a gas turbine engine. The swirling flow field was analyzed with emphasis on the diffuser off-design operation. A comparison of the numerical results with experimental data shows that the model is applicable to moderately separating flows of the kind that are typically associated with the off-design performance of diffusing passages in gas turbines.

Baskharone, E. A.↗
NASA NTRS1991

The interstellar C-H stretching band near 3.4 microns - Constraints on the composition of organic material in the diffuse interstellar medium

The composition and history of dust in the diffuse ISM was studied using 3600-2700/cm absorption spectra of objects which have widely varying amounts of visual extinctions along different lines of sight. The 3300/cm and 2950/cm features are attributed to O-H and C-H stretching vibrations, respectively. The O-H feature in OH 32.8-0.3 is suggestive of circumstellar water ice and is probably not due to material in the diffuse ISM. The features in the 3100-2700/cm region are attributed either to C-H vibrations or to M stars. The spectra of the latter show a series of narrow features in this region that are identified with photospheric OH. Objects in which these bands are seen include OH 01-477, T629-5, and the Galactic center source IRS 7. The C-H stretch feature of diffuse ISM dust has subpeaks which fall within 5/cm of C-H stretching vibrations in the -CH2- and -CH3 groups of saturated aliphatic hydrocarbons.

Sandford, S. A.↗
NASA NTRS1991

Charge collected by diffusion from an ion track under mixed boundary conditions

Charge-carrier diffusion from an ion track in a silicon substrate at least a few hundred microns thick is analyzed. The substrate upper surface is treated as reflective except for a small section, intended to represent a reverse-biased junction, which is treated as a sink. Total charge collected by the sink is calculated by assuming transport to be governed by an ambipolar diffusion equation with temporally constant and spatially uniform carrier lifetime and diffusion coefficient. Present results apply to a normally incident track but could easily be generalized to arbitrary track direction. The collected charge is found to depend on track length and on the electrostatic capacitance, rather than the area, of the sink. Theoretical predictions are compared to the results of a numerical simulation called the Poisson and Continuity Equation Solver (PISCES) for three cases and are found to agree within a factor of two in the worst case.

Edmonds, Larry D.↗
NASA NTRS1991

Plasma diffusion at the magnetopause - The case of lower hybrid drift waves

The diffusion expected from the quasi-linear theory of the lower hybrid drift instability at the earth's magnetopause is recalculated. The resulting diffusion coefficient is marginally large enough to explain the thickness of the boundary layer under quiet conditions, based on observational upper limits for the wave intensities. Thus, one possible model for the boundary layer could involve equilibrium between the diffusion arising from lower hybrid waves and various loss processes.

Treumann, R. A.↗
NASA NTRS1991

Oxygen tracer diffusion in single-crystal alumina

Oxygen tracer diffusion coefficients are determined in single-crystal alumina samples with differing dopant levels using the gas-exchange technique. The diffusion direction is parallel to the c-axis and the ambient PO2 is 1 atm (100,000 Pa) for all experiments except a single run with a low PO2, approximately 10 to the -15th atm (10 to the -10th Pa) produced by a CO/CO2 mixture. The diffusion is insensitive to both impurities and ambient PO2. The insensitivities are discussed in terms of point-defect clustering. Prior tracer studies are compared and discussed.

Cawley, James D.↗
NASA NTRS1991

Influence of mass diffusion on the stability of thermophoretic growth of a solid from the vapor phase

The stability of solid planar growth from a binary vapor phase with a condensing species dilute in a carrier gas is examined when the ratio of depositing to carrier species molecular mass is large and the main diffusive transport mechanism is thermal diffusion. It is shown that a deformation of the solid-gas interface induces a deformation of the gas phase isotherms that increases the thermal gradients and thereby the local mass deposition rate at the crests and reduces them at the valleys. The initial surface deformation is enhanced by the modified deposition rates in the absence of appreciable Fick/Brownian diffusion and interfacial energy effects.

Castillo, J. L.↗
NASA NTRS1992

GRIS observations of the galactic center and the gamma ray galactic diffuse continuum

On two flights in 1988, the Gamma-Ray Imaging Spectrometer (GRIS) discovered the galactic center in a high state (greater than 1 x 10(exp -3) ph/(sq cm sec)) of positron annihilation line emission (511 keV) after nearly a decade of failed attempts to confirm the exciting early results of balloon and satellite instruments. These two flights represented the first flights of a new generation of high resolution germanium spectrometers designed to achieve significantly greater sensitivity for astrophysical observations. During the fall flight, an observation of the galactic plane at 335 degrees longitude was also performed. This observation showed a very low level of 511 keV emission (2 +/- 1 x 10(exp -4) ph/(sq cm sec)), confirming the galactic center origin of the line, and a high level of hard x-ray and gamma-ray continuum emission (1 x 10(exp -4) ph/(sq cm sec keV) at 100 keV), which we attribute to galactic diffuse emission. Improved fits to the spectrum of the galactic center are presented with the proposed diffuse component subtracted. We conclude that our galactic center continuum spectrum is consistent with the sum of the 1E1740.7-2942 spectrum observed by SIGMA/GRANAT and our 1 = 335 degree galactic plane spectrum. The predicted diffuse flux should be easily measurable by the Oriented Scintillation Spectrometer Experiment (OSSE) experiment on the Gamma Ray Observatory (GRO).

Tueller, J.↗
NASA NTRS1991

The evolution of the diffuse cosmic ultraviolet background constrained by the Hubble Space Telescope observations of 3C 273

Results are presented of recent HST UV spectroscopy of 3C 273, which revealed more low-redshift Lyman-alpha absorption lines (IGM clouds) than expected from the extrapolation from high-redshift (not less than 1.6) observations. It is shown on the basis of the standard pressure confined cloud model of the Lyman-alpha forest that this result indicates a sharp drop in the diffuse cosmic UV background from 2 to 0 redshift. It is predicted that the H I optical depth will drop slowly or perhaps even increase with decreasing redshift at less than 2 redshift. The implied constraints on the density and pressure of the diffuse IGM at 0 redshift are also derived. The inferred evolution of the diffuse UV flux bears a striking resemblance to the most recent direct determinations of the volume emissivity of the quasar population.

Ikeuchi, Satoru↗
NASA NTRS1990

Thermal diffusivity measurements on composite porosity samples

A phase lag technique is used to make quantitative measurements of diffusivity in composite porosity samples. Changes in through-ply diffusivity in a graphite composite due to varying porosity levels are examined. The relationship between the amount of porosity and the change in diffusivity is analyzed using an electrical analog for modeling heat flow in the composite.

Zalameda, Joseph N.↗
NASA NTRS1991

Quasi-linear pitch angle and energy diffusion of pickup ions near Comet Halley

The process of ion pickup in the environment of Halley's comet is studied in order to see if velocity diffusion driven by the observed level of turbulence can explain the observed development of the implanted ion distribution. The theoretical description used is based on a quasi-linear approach and considers the implantation and transport of cometary ions along solar wind flow lines. To make such a study requires some way of extrapolating the measurements on the Giotto trajectory into the upstream region; models for mass loading and turbulence are used. A simplified kinetic equation describing the source, convection, and quasi-linear velocity diffusion of the heavy cometary ions is solved numerically along flow lines parallel to the sun-comet line. Full two-dimensional (pitch angle and velocity) distributions are obtained at positions along the Giotto trajectory, which are compared with measurements. This study finds that quasi-linear theory, with the empirical model for the observed turbulence level, produces the right order of pitch angle diffusion.

Huddleston, D. E.↗
NASA NTRS1990

Steady-state thermal-solutal convection and diffusion in a simulated float zone

Models describing the steady-state thermal diffusion in a pure system, the thermal-solutal diffusion in a binary system, and heat and momentum transverse in a pure system are presented. The geometry of the model is described by a 2D Cartesian coordinate system that is applicable for crystal sheets. The melting, solidifying, and melt/gas interfacial shapes as well as the thermal, flow, and solutal profiles are analytically evaluated as functions of the heat and ambient temperature profiles and material properties. The solution procedure involves a coupled asymptotic/numerical approach which reduces the coupled set of partial differential equations to ordinary type. The results should be applicable in situations where melt flows are not intense enough to change the thermal field in pure systems, or where the physical properties of the melt are such that the convective field is decoupled from the thermal field, the latter being established primarily by diffusion.

Young, G. W.↗
NASA NTRS1991

Thermally driven diffusion of SO2 within the surface of Io

The presence of sulfur dioxide (SO2) on Io, together with the fact that the surface layer of Io has extremely high porosity, suggests the possibility of diffusion of this volatile within the surface, as well as exchange between the surface and an atmosphere. The former possibility is investigated through the development of a surface layer thermal model and subsequent calculations of the thermally driven diffusion flux of SO2 within the layer. The major factors affecting the diffusion process are the temperature and temperature gradient in the surface layer throughout the day, and the porosity and grain size in the surface layer. The results indicate that the net transport of SO2 in the near-surface region is downward into the subsurface, causing near-surface depletion of SO2. Near-surface depletion would result in a layer of reduced thermal inertia overlying the bulk of the surface, consistent with thermal eclipse observations of Io. For the present nominal model with 10-micron grains and a porosity of 85 percent, the peak net diurnal downward flux reaches nearly 0.008 g/sq cm per period.

Meade, Paul E.↗
NASA NTRS1992

Tidal evolution of globular clusters. II - The effects of Galactic tidal field and diffusion

The tidal evolution of globular clusters subject to various degrees of the internal diffusion process is investigated. In cases of negligible diffusion, clusters are found to be tidally truncated to the theoretical tidal radius at perigalacticon. There is no apparent orbital phase dependence of the tidal radius for clusters with eccentric orbits. In clusters with moderately short two-body relaxation time scales, diffusion processes significantly modify the structure of the outer regions in such a way that the limiting radius may be comparable to the tidal radius at apogalacticon. The Galactical tidal torque induces isotropy in the velocity dispersion of the outer regions of the cluster. For relaxed clusters, the velocity dispersion may be isotropic in the core, anisotropic in the envelope and isotropic near the limiting radius. Disk shocking is also very efficient for isotropizing the orbits of stars in the outer cluster regions. Stars with direct orbits are less stable, so that prolonged tidal interaction can lead to apparent retrograde rotation in the outer regions of the cluster.

Oh, K. S.↗
NASA NTRS1991

Measurement and analysis of grain boundary grooving by volume diffusion

Experimental measurements of isothermal grain boundary grooving by volume diffusion are carried out for Sn bicrystals in the Sn-Pb system near the eutectic temperature. The dimensions of the groove increase with a temporal exponent of 1/3, and measurement of the associated rate constant allows the determination of the product of the liquid diffusion coefficient D and the capillarity length Gamma associated with the interfacial free energy of the crystal-melt interface. The small-slope theory of Mullins is generalized to the entire range of dihedral angles by using a boundary integral formulation of the associated free boundary problem, and excellent agreement with experimental groove shapes is obtained. By using the diffusivity measured by Jordon and Hunt, the present measured values of Gamma are found to agree to within 5 percent with the values obtained from experiments by Gunduz and Hunt on grain boundary grooving in a temperature gradient.

Hardy, S. C.↗
NASA NTRS1992

Effective diffusion equation in a random velocity field

The effects are studied of assumed random velocity fields on diffusion in a binary fluid. Random velocity fields can result, for example, from the high-frequency components of residual accelerations onboard spacecraft (often called g-jitter). An effective diffusion equation is derived for an average concentration which includes spatial and temporal correlations induced by the fluctuating velocity fields assumed to be Gaussianly distributed. The resulting equation becomes nonlocal, and if correlations between different components of the velocity field exist, it is also anisotropic. The simple limiting case of short correlation times is discussed and an effective diffusivity is obtained which reflects the enhanced mixing caused by the velocity fields. The results obtained in the limit of short correlation times are valid even if the probability distribution of the velocity field is not Gaussian.

Vinals, Jorge↗
NASA NTRS1992

Ages of globular clusters and helium diffusion

Evolutionary tracks have been calculated with alpha-enhanced compositions which cover the entire globular cluster metallicity range and have constructed isochrones which include the effects of microscopic diffusion of helium. The turnoff magnitudes from the isochrones were combined with the theoretical RR Lyrae magnitudes from Lee to determine the ages of 32 Galactic globular clusters using the magnitude difference between the turnoff and horizontal branch. It is found that including the effects of helium diffusion has a negligible effect on the derived ages of globular clusters. Regardless of the inclusion of helium diffusion, a significant age spread of 5 Gyr among the globular clusters is found. The oldest globular clusters studied here are 17 +/- 2 Gyr old.

Chaboyer, Brian↗