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At least 1,243 records · Page 69

THE ARDUOUS JOURNEY TO BLACK HOLE FORMATION IN POTENTIAL GAMMA-RAY BURST PROGENITORS

We present a quantitative study on the properties at death of fast-rotating massive stars evolved at low-metallicity-objects that are proposed as likely progenitors of long-duration {gamma}-ray bursts (LGRBs). We perform one-dimensional+rotation stellar-collapse simulations on the progenitor models of Woosley and Heger, and critically assess their potential for the formation of a black hole and a Keplerian disk (namely, a collapsar) or a proto-magnetar. We note that theoretical uncertainties in the treatment of magnetic fields and the approximate handling of rotation compromise the accuracy of stellar-evolution models. We find that only the fastest rotating progenitors achieve sufficient compactness for black hole formation while the bulk of models possess a core density structure typical of garden-variety core-collapse supernova (SN) progenitors evolved without rotation and at solar metallicity. Of the models that do have sufficient compactness for black hole formation, most of them also retain a large amount of angular momentum in the core, making them prone to a magneto-rotational explosion, therefore preferentially leaving behind a proto-magnetar. A large progenitor angular-momentum budget is often the sole criterion invoked in the community today to assess the suitability for producing a collapsar. This simplification ignores equally important considerations such as the core compactness, which conditions black hole formation, the core angular momentum, which may foster a magneto-rotational explosion preventing black hole formation, or the metallicity and the residual envelope mass which must be compatible with inferences from observed LGRB/SNe. Our study suggests that black hole formation is non-trivial, that there is room for accommodating both collapsars and proto-magnetars as LGRB progenitors, although proto-magnetars seem much more easily produced by current stellar-evolutionary models.

79 ASTRONOMY AND ASTROPHYSICS↗

ALMA reveals the molecular medium fueling the nearest nuclear starburst

We use ALMA observations to derive mass, length, and time scales associated with NGC 253's nuclear starburst. This region forms ∼2 M {sub ☉} yr{sup –1} of stars and resembles other starbursts in ratios of gas, dense gas, and star formation tracers, with star formation consuming the gas reservoir at a normalized rate 10 times higher than in normal galaxy disks. We present new ∼35 pc resolution observations of bulk gas tracers (CO), high critical density transitions (HCN, HCO{sup +}, and CS), and their isotopologues. The starburst is fueled by a highly inclined distribution of dense gas with vertical extent <100 pc and radius ∼250 pc. Within this region, we identify 10 starburst giant molecular clouds (GMCs) that appear as both peaks in the dense gas tracer cubes and the HCN-to-CO ratio map. These are massive (∼10{sup 7} M {sub ☉}) structures with sizes (∼30 pc) similar to GMCs in other systems, but compared to GMCs in normal galaxy disks, they have high line widths (σ ∼ 20-40 km s{sup –1}, Mach number M∼90) and high surface and volume densities (Σ{sub mol} ∼ 6000 M {sub ☉} pc{sup –2}, n {sub H2} ∼ 2000 cm{sup –3}). The self gravity from such high densities can explain the high line widths and the short free fall time τ{sub ff} ∼ 0.7 Myr in the clouds helps explain the more efficient star formation in NGC 253. Though the high inclination obscures the geometry somewhat, we show that simple models suggest a compact, clumpy region of high gas density embedded in a more extended, non-axisymmetric, bar-like distribution. Over the starburst, the surface density still exceeds that of a typical disk galaxy GMC and, as in the clouds, timescales in the disk as a whole are short compared to those in normal galaxy disks. The orbital time (∼10 Myr), disk free fall time (≲ 3 Myr), and disk crossing time (≲ 3 Myr) are each an order of magnitude shorter than in a normal galaxy disk. Finally, the CO-to-H{sub 2} conversion factor implied by our cloud calculations is approximately Galactic, contrasting with results showing a low value for the whole starburst region. The contrast provides resolved support for the idea of mixed molecular ISM phases in starburst galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

Constraints on dissipative unified dark matter

Modern cosmology suggests that the Universe contains two dark components — dark matter and dark energy — both unkown in laboratory physics and both lacking direct evidence. Alternatively, a unified dark sector, described by a single fluid, has been proposed. Dissipation is a common phenomenon in nature and it thus seems natural to consider models dominated by a viscous dark fluid. We focus on the study of bulk viscosity, as isotropy and homogeneity at large scales implies the suppression of shear viscosity, heat flow and diffusion. The generic ansatz ξ∝ρ{sup ν} for the coefficient of bulk viscosity (ρ denotes the mass/energy density), which for ν = −1/2 mimics the ΛCDM background evolution, offers excellent fits to supernova and H(z) data. We show that viscous dark fluids suffer from large contributions to the integrated Sachs-Wolfe effect (generalising a previous study by Li and Barrow) and a suppression of structure growth at small-scales (as seen from a generalized Meszaros equation). Based on recent observations, we conclude that viscous dark fluid models (with ξ∝ρ{sup ν} and neglecting baryons) are strongly challenged.

79 ASTRONOMY AND ASTROPHYSICS↗

Nonthermal Site Occupation at the Donor-Acceptor Interface of Organic Solar Cells

Here, we investigate the nature of occupation and relaxation within the charge transfer density of states (CT DOS) for bulk heterojunction organic solar cells consisting of the donor boron subphthalocyanine chloride and the acceptor C 60 . We observe relaxation of geminate CT states on a sub-ns timescale via an approximately 70-meV dynamic redshift in their photoluminescence, whereas free carrier relaxation at longer times leads to the formation of nongeminate CT states at even lower energy. In steady state, we find that thermalization within the DOS is incomplete, resulting in a Boltzmann-like CT state distribution characterized by an effective temperature above that of the ambient. These findings confirm that electron and hole populations can be far from equilibrium in organic solar cells and may prompt a reassessment of analyses that assume the same temperature for their charge-carrier distributions in the dark and under illumination.

14 SOLAR ENERGY↗

Gapless surface electronic structure of $1T–$$\mathrm{TiSe_2}$ in the distorted phase

Here, low temperature, high resolution angle resolved photoemission experiments performed on bulk $1T–$$\mathrm{TiSe_2}$ samples display conspicuous band folding as the only prominent signature of the periodic lattice distortion. The presence of a bulk electronic gap supporting a charge density wave phase is not confirmed in light of the new data. These observations cast serious doubts on the common belief of an electronic instability as the likely origin for the observed structural transition in $\mathrm{TiSe_2}$.

36 MATERIALS SCIENCE↗

Electron Paramagentic Resonance Investigation of Mechanism of Light- and Elevated-Temperature-Induced Degradation in Ga-doped Cz Si

We report on the electron paramagnetic resonance (EPR) spectra recorded at 6 K for Ga-doped Czochralski (Cz) Si in the initial stages of light- and elevated-temperature-induced degradation (LeTID). We show that the narrow-range EPR spectrum depends on the duration of simultaneous heat and light exposure. After prolonged LeTID, the EPR intensity increases at ~334 mT. The EPR signature at ~334 mT is characteristic of Si dangling bonds, and the increase in the dangling bond density can be attributed to the bulk and not the surface. Additionally, we show that the inverse of the minority carrier lifetime in Ga-doped Cz Si samples, measured by quasi-steady-state photoconductance (QSSPC) decay, correlates with the increase in the intensity of the Si dangling bond signal measured by EPR. Based on these observations, we put forth a hypothesis connecting H to LeTID and the corresponding defect structure.

Cz Si↗

Fabrication of Nb/Pb structures through ultrashort pulsed laser deposition

This work reports the fabrication of Nb/Pb structures with an application as photocathode devices. The use of relatively low energy densities for the ablation of Nb with ultrashort pulses favors the reduction of droplets during the growth of the film. However, the use of laser fluences in this ablation regime results in a consequent reduction in the average deposition rate. On the other hand, despite the low deposition rate, the films present a superior adherence to the substrate and an excellent coverage of the irregular substrate surface, avoiding the appearance of voids or discontinuities on the film surface. Moreover, the low energy densities used for the ablation favor the growth of nanocrystalline films with a similar crystalline structure to the bulk material. Therefore, the use of low ablation energy densities with ultrashort pulses for the deposition of the Nb thin films allows the growth of very adherent and nanocrystalline films with adequate properties for the fabrication of Nb/Pb structures to be included in superconducting radiofrequency cavities.

42 ENGINEERING↗

Characterization of Electrodeposited Technetium on Gold Foil

The reduction and electrodeposition of TcO{sub 4}{sup -} on a smooth gold foil electrode with an exposed area of 0.25 cm{sup 2} was performed in 1 M H{sub 2}SO{sub 4} supporting electrolyte using bulk electrolysis with a constant current density of 1.0 A/cm{sup 2} at a potential of -2.0 V. Significant hydrogen evolution accompanied the formation of Tc deposits. Tc concentrations consisted of 0.01 M and 2 x 10{sup -3} M and were electrodeposited over various times. Deposited fractions of Tc were characterized by powder x-ray diffraction, x-ray absorption fine structure spectroscopy, and scanning electron microscopy with the capability to measure semiquantitative elemental compositions by energy-dispersive x-ray emission spectroscopy. Results indicate the presence of Tc metal on all samples as the primary electrodeposited constituent for all deposition times and Tc concentrations. Thin films of Tc have been observed followed by the formation of beads that are removable by scratching. After 2000, the quantity of Tc removed from solution and deposited was 0.64 mg Tc per cm{sup 2}. The solution, after electrodeposition, showed characteristic absorbances near 500 nm corresponding to hydrolyzed Tc(IV) produced during deposition of Tc metal. No detectable Tc(IV) was deposited to the cathode.

08 HYDROGEN↗

Upcycling Linear Low-Density Polyethylene Waste into Graphene for High Mass Loading Supercapacitors

Upcycling plastic into advanced carbons, such as graphene and porous carbon, offers attractive options to manage waste streams by converting the plastic into carbon electrode materials for energy storage devices. Linear low density polyethylene (LLDPE) is firstly bulk-oxidized with a facile and scalable method and then carbonized and catalyticlly graphenized into porous graphene materials. The LLDPE derived graphene (LLDPE-G) has a BET specific surface area up to 1800 m2/g and Raman ID/IG ratio of 0.85. When used as electrode material for symmetric supercapacitor, LLDPE-G possesses outstanding specific capacitance and excellent areal capacitance. Moreover, LLDPE-G exhibits exceptional cycling stability with capacitance retention of 95.8% after 100,000 cycles. Last but not least, KCl is recycled and reused over 3 cycles with material quality and electrocapacitive performance of LLDPE-G retained and verified after each cycle.

Gao, Yuan↗

Electronic structure of compressively strained thin film La$_2$PrNi$_2$O$_7$

The discovery of superconductivity in the bulk nickelates under high pressure is a major advance in physics. The recent observation of superconductivity at ambient pressure in compressively strained bilayer nickelate thin films has now enabled direct characterization of the superconducting phase through angle resolved photoemission spectroscopy (ARPES). Here we present an in-situ ARPES study of compressively strained La$_2$PrNi$_2$O$_7$ films grown by oxide molecular beam epitaxy, and the ozone treated counterparts with an onset T$_c$ of 40 K, supplemented with results from pulsed laser deposition films with similar T$_c$. We resolve a systematic strain-driven electronic band shift with respect to that of bulk crystals, in qualitative agreement with density functional theory (DFT) calculations. However, the strongly renormalized flat 3$d_{z2}$ band shifts a factor of 5-10 smaller than anticipated by DFT. Furthermore, it stays ~70 meV below the Fermi level, contradicting the expectation that superconductivity results from the high density of states of this band at the Fermi level. We also observed a non-trivial k$_z$ dispersion of the cuprate-like 3$d_{x2-y2}$ band. Combined with results from both X-ray diffraction and DFT, we suggest that the strained films are under ~5 GPa effective pressure, considerably larger than the naïve expectation from the DFT relaxed structure. Finally, the ~70 meV energy position is intriguingly close to the collective mode coupling more prominently seen in thin films, in the energy range of both oxygen related phonons and the maximum of the spin excitation spectrum.

FOS: Physical sciences↗

The solar envelope

Processes which occur within the region between approximately 2 solar radii and 25 solar radii, which is called the solar envelope and the effect on the solar wind as seen at 1 AU are discussed. In the envelope the wind speed becomes supersonic and super-Alfvenic, the magnetic energy density is larger than the flow energy density, and the magnetic energy density is much larger than the thermal energy density. Large azimuthal gradients in the bulk speed are expected in the envelope, but the stream interactions near the outer edge of the envelope are probably relatively small. Cosmic ray observations suggest the presence of hydromagnetic waves in the envelope. The collisionless damping of such waves could heat protons out to approximately 25 solar radii and thereby cause an increase in V and T sub p consistent with the observed T sub p -V relation. A mechanism which couples protons and electrons would also heat and accelerate the wind. Alfven waves can accelerate the wind in the envelope without necessarily causing heating of protons; the Lorentz force might have a similar effect.

Burlaga, L. F.↗

A shock-induced phase change in orthoclase.

New shock compression data to 340 kb for single-crystal orthoclase (along (001)), demonstrate the onset of a shock-induced phase change at about 115 kb. Along the Hugoniot a mixed-phase region extends to about 300 kb, above which the data are believed to correspond to the properties of a high-pressure phase having the hollandite structure (zero pressure density of 3.84 g/cu cm) reported by Ringwood et al. If the hollandite value for the zero pressure density is used, the zero pressure bulk modulus of this phase is approximately 1.8 plus or minus 0.2 Mb.

Ahrens, T. J.↗

Some important imaging goals for asteroid missions

Very high resolution imaging provides the best means of examining geological processes acting on asteroid surfaces. Imaging also may be important for revealing how asteroids accreted and for obtaining some data on their differentiation history. Imaging from rendezvous together with Doppler tracking is the only way to determine accurate densities and hence place limits on bulk composition.

Veverka, J.↗

The Development and Prevention of Channel Segregation During Alloy Solidification

During alloy solidification, interdendritic microsegregation causes density differences between entrapped liquid and bulk liquid which provides a driving force for convection. One of the consequences of this effect is the formation of long, nearly vertical liquid channels, rich in solute, flowing through the solid-liquid mushy zone somewhat as a river and tributary system. In ingot castings where the heat flow is vertically downwards and the solute less dense than the solute the convective flow is antiparallel with the flow caused by contraction on freezing. Identification of the mechanisms involved in these two problems is discussed. It is known that certain types of bulk liquid movements can inhibit channel development and the mechanism by which they do so are examined.

Hellawell, A.↗

The shock wave equation of state of brucite Mg(OH)2

New shock equation of state (EOS) data on magnesium hydroxide between 12 and 60 GPa is presented. It is found that the brucite EOS data between 12 and 97 GPa can be fit with a single linear U(s) - u(p) relationship: U(s) = 4.76(0.11) + 1.35(0.05)u(p). The third order Birch-Murnaghan equation parameters are K(os) = 51 + or - 4 GPa and K(os)prime = 5.0 + or - 0.4. The first partial release states measured for brucite Mg(OH)2 are reported. Calculated phase boundaries using the EOS data are found to be consistent with the experimental data and indicate that brucite is unlikely to be stable under lower mantle conditions. At high pressure, bulk sound velocities calculated for MgO and Mg(OH)2 are very similar, indicating that the presence of hydrous assemblages in the lower mantle may not produce anomalous bulk seismic velocities. A comparison of densities in brucite and other high-pressure phases under mantle conditions shows that the water content of the lower mantle is between 0 and 3 wt pct.

Duffy, Thomas S.↗

Ion transport and loss in the earth's quiet ring current. I - Data and standard model

A study of the transport and loss of ions in the earth's quiet time ring current, in which the standard radial diffusion model developed for the high-energy radiation belt particles is compared with the measurements of the lower-energy ring current ions, is presented. The data set provides ionic composition information in an energy range that includes the bulk of the ring current energy density, 1-300 keV/e. Protons are found to dominate the quiet time energy density at all altitudes, peaking near L of about 4 at 60 keV/cu cm, with much smaller contributions from O(+) (1-10 percent), He(+) (1-5 percent), and He(2+) (less than 1 percent). A minimization procedure is used to fit the amplitudes of the standard electric radial diffusion coefficient, yielding 5.8 x 10 exp -11 R(E-squared)/s. Fluctuation ionospheric electric fields are suggested as the source of the additional diffusion detected.

Sheldon, R. B.↗

Electrochemical Characterization of Semiconductor Materials and Structures

For a period covering October 1, 1995 through August 12, 1996, the research group at CSU has conducted theoretical and experimental research on "Electrochemical Characterization of Semiconductor Materials and Structures. " The objective of this investigation was to demonstrate the applicability of electrochemical techniques for characterization of complex device structures based on InP and GaAs, Ge, InGaAs, InSb, InAs and InSb, including: (1) accurate EC-V net majority carrier concentration depth profiling, and (2) surface and bulk structural and electrical type defect densities. Our motivation for this R&D effort was as follows: "Advanced space solar cells and ThermoPhotoVoltaic (TPV) cells are fabricated using a large variety of III-V materials based on InP and GaAs for solar cells and low bandgap materials such as Ge, InGaAs, InAs and InSb for TPV applications. At the present time for complex device structures using these materials, however, there is no simple way to assess the quality of these structures prior to device fabrication. Therefore, process optimization is a very time consuming and a costly endeavor". Completion of this R&D effort would have had unquestionable benefits for space solar cell and TPV cells, since electrochemical characterization of the above cell structures, if properly designed can provide many useful structural and electrical material information virtually at any depth inside various layers and at the interfaces. This, could have been applied for step-by-step process optimization, which could have been used for fabrication of new generation high efficiency, low cost space PV and TPV cells.

Source record↗

Silicon in Mars' Core: A Prediction Based on Mars Model Using Nitrogen and Oxygen Isotopes in SNC Meteorites

Chemical and (oxygen) isotopic compositions of SNC meteorites have been used by a number of workers to infer the nature of precursor materials for the accretion of Mars. The idea that chondritic materials played a key role in the formation of Mars has been the central assumption in these works. Wanke and Dreibus have proposed a mixture of two types of chondritic materials, differing in oxygen fugacity but having CI type bulk chemical composition for the nonvolatile elements, for Mars' precursor. But a number of studies based on high pressure and temperature melting experiments do not favor a CI type bulk planet composition for Mars, as it predicts a bulk planet Fe/Si ratio much higher than that reported from the recent Pathfinder data. Oxygen forms the bulk of Mars (approximately 40% by wt.) and might provide clues to the type of materials that formed Mars. But models based on the oxygen isotopic compositions of SNC meteorites predict three different mixtures of precursor materials for Mars: 90% H + 10% CM, 85% H + 11% CV + 4% CI and 45% EH + 55% H. As each of these models has been shown to be consistent with the bulk geophysical properties (such as mean density, and moment of inertia factor) of Mars, the nature of the material that accreted to form Mars remains ambiguous.

Mohapatra, R. K.↗