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At least 1,243 records · Page 69

At least some errors are randomly generated (Freud was wrong)

An experiment was carried out to expose something about human error generating mechanisms. In the context of the experiment, an error was made when a subject pressed the wrong key on a computer keyboard or pressed no key at all in the time allotted. These might be considered, respectively, errors of substitution and errors of omission. Each of seven subjects saw a sequence of three digital numbers, made an easily learned binary judgement about each, and was to press the appropriate one of two keys. Each session consisted of 1,000 presentations of randomly permuted, fixed numbers broken into 10 blocks of 100. One of two keys should have been pressed within one second of the onset of each stimulus. These data were subjected to statistical analyses in order to probe the nature of the error generating mechanisms. Goodness of fit tests for a Poisson distribution for the number of errors per 50 trial interval and for an exponential distribution of the length of the intervals between errors were carried out. There is evidence for an endogenous mechanism that may best be described as a random error generator. Furthermore, an item analysis of the number of errors produced per stimulus suggests the existence of a second mechanism operating on task driven factors producing exogenous errors. Some errors, at least, are the result of constant probability generating mechanisms with error rate idiosyncratically determined for each subject.

Sellen, A. J.↗

An Fe XXVI Absorption Line in the Persistent Spectrum of the Dipping Low Mass X-ray Binary 1A 1744-361

We report on Chandra X-ray Observatory (CXO) High-Energy Transmission Grating (HETG) spectra of the dipping Low Mass X-ray Binary (LMXB) 1A 1744-361 during its July 2008 outburst. We find that its persistent emission is well modeled by a blackbody (kT approx. 1.0 keV) plus power-law (Gamma approx. 1.7) with an absorption edge at 7.6 keV. In the residuals of the combined spectrum we find a significant absorption line at 6.961+/-0.002 keV, consistent with the Fe XXVI (hydrogen-like Fe) 2 - 1 transition. We place an upper limit on the velocity of a redshifted flow of v < 221 km/s. We find an equivalent width for the line of 27+2/-3 eV, from which we determine a column density of 7+/-1 x 10(exp 17)/sq cm via a curve-of-growth analysis. Using XSTAR simulations, we place a lower limit on the ionization parameter of > 10(exp 3.6) erg cm/s. The properties of this line are consistent with those observed in other dipping LMXBs. Using Rossi X-ray Timing Explorer (RXTE) data accumulated during this latest outburst we present an updated color-color diagram which clearly shows that IA 1744-361 is an "atoll" source. Finally, using additional dips found in the RXTE and CXO data we provide an updated orbital period estimate of 52+/-5 minutes.

Gavriil, Fotis P.↗

Radio Follow-up of a Candidate γ-Ray Transient in the Sky Localization Area of GW170608

After the identification of a candidate γ-ray transient in the error region of the binary black hole (BBH) merger GW150914 by the Fermi satellite, the question of whether BBH mergers can be associated with electromagnetic counterparts remains highly debated. Here, we present radio follow-up observations of GW170608, a BBH merger that occurred during the second observing run (O2) of the Advanced Laser Interferometer Gravitational-wave Observatory (LIGO). Our radio follow-up focused on a specific field contained in the GW170608 sky localization area, where a candidate high-energy transient was detected by the Fermi Large Area Telescope (LAT). We make use of data collected at 1.4 GHz with the Karl G. Jansky Very Large Array (VLA), as well as with the VLA Lowband Ionosphere and Transient Experiment (VLITE). Our analysis is sensitive to potential radio afterglows with luminosity densities L(1.4GHz) ≳ 6 x 10^(28) erg/sHz. In the most optimistic theoretical models, ≈20% of BBH events occurring in massive hosts could be associated with outflows as radio luminous as this. Although we find no evidence for the presence of a radio counterpart associated with the LAT candidate in the GW170608 error region, our analysis demonstrates the feasibility of future radio follow-up observations of well-localized BBHs. Comparing our radio upper limits with theoretical expectations for the radio afterglows potentially associated with jets launched in BBH mergers, we find that for jets of energy ≈10^(49) erg seen on-axis, only jet angles θ(jet)≳40° are compatible with the observations.

Kyle Artkop↗

Search for Lensing Signatures in the Gravitational-Wave Observations from the First Half of LIGO–Virgo's Third Observing Run

We search for signatures of gravitational lensing in the gravitational-wave signals from compact binary coalescences detected by Advanced Laser Interferometer Gravitational-wave Observatory (LIGO) and Advanced Virgo during O3a, the first half of their third observing run. We study: (1) the expected rate of lensing at current detector sensitivity and the implications of a non-observation of strong lensing or a stochastic gravitational-wave background on the merger-rate density at high redshift; (2) how the interpretation of individual high-mass events would change if they were found to be lensed; (3) the possibility of multiple images due to strong lensing by galaxies or galaxy clusters; and (4) possible wave-optics effects due to point-mass microlenses. Several pairs of signals in the multiple-image analysis show similar parameters and, in this sense, are nominally consistent with the strong lensing hypothesis. However, taking into account population priors, selection effects, and the prior odds against lensing, these events do not provide sufficient evidence for lensing. Overall, we find no compelling evidence for lensing in the observed gravitational-wave signals from any of these analyses.

R. Abbott↗

Numerical Analysis of Fuel Effects on Advanced Compression Ignition Using a Cooperative Fuel Research Engine Computational Fluid Dynamics Model

Growing environmental concerns and demand for a better fuel economy are driving forces that motivate the research for more advanced engines. Multi-mode combustion strategies have gained attention for their potential to provide high thermal efficiency and low emissions for light-duty applications. These strategies target optimizing the engine performance by correlating different combustion modes to load operating conditions. The extension from boosted spark ignition (SI) mode at high loads to advanced compression ignition (ACI) mode at low loads can be achieved by increasing the compression ratio and utilizing intake air heating. Further, in order to enable an accurate control of intake charge condition for ACI mode and rapid mode-switches, it is essential to gain fundamental insights into the autoignition process. Within the scope of ACI, homogeneous charge compression ignition (HCCI) mode is of significant interest. It is known for its potential benefits, operation at low fuel consumption, low NOx, and particulate matter (PM) emissions. In the present work, a virtual Cooperative Fuel Research (CFR) engine model is used to analyze fuel effects on ACI combustion. In particular, the effect of fuel octane sensitivity (S) (at constant Research Octane Number (RON)) on autoignition propensity is assessed under beyond-RON (BRON) and beyond-MON (BMON) ACI conditions. The three-dimensional CFR engine computational fluid dynamics (CFD) model employs a finite-rate chemistry approach with a multi-zone binning strategy to capture autoignition. Two binary blends with Research Octane Number (RON) of 90 are chosen for this study: primary reference fuel (PRF) with S = 0 and toluene–heptane (TH) blend with S = 10.8, representing paraffinic and aromatic gasoline surrogates. Reduced mechanisms for these blends are generated from a detailed gasoline surrogate kinetic mechanism. Simulation results with the reduced mechanisms are validated against experimental data from an in-house CFR engine, with respect to in-cylinder pressure, heat release rate, and combustion phasing. Thereafter, the sensitivity of combustion behavior to ACI operating condition (BRON versus BMON), air-fuel ratio (λ = 2 and 3), and engine speed (600 and 900 rpm) is analyzed for both fuels. It is shown that the sensitivity of a fuel’s autoignition characteristics to λ and engine speed significantly differs at BRON and BMON conditions. Moreover, this sensitivity is found to vary among fuels, despite the same RON. It is also observed that the presence of low-temperature heat release (LTHR) under BRON condition leads to more sequential autoignition and longer combustion duration than BMON condition. Finally, the study indicates that the octane index (OI) fails to capture the trend in the variation of autoignition propensity with S under the BMON condition.

33 ADVANCED PROPULSION SYSTEMS↗

Hardware-accelerated inference for real-time gravitational-wave astronomy

The field of transient astronomy has seen a revolution with the first gravitational-wave detections and the arrival of multi-messenger observations they enabled. Transformed by the first detection of binary black hole and binary neutron star mergers, computational demands in gravitational-wave astronomy are expected to grow by at least a factor of two over the next five years as the global network of kilometer-scale interferometers are brought to design sensitivity. With the increase in detector sensitivity, real-time delivery of gravitational-wave alerts will become increasingly important as an enabler of multi-messenger followup. In this work, we report a novel implementation and deployment of deep learning inference for real-time gravitational-wave data denoising and astrophysical source identification. This is accomplished using a generic Inference-as-a-Service model that is capable of adapting to the future needs of gravitational-wave data analysis. Overall, our implementation allows seamless incorporation of hardware accelerators and also enables the use of commercial or private (dedicated) as-a-service computing. Based on our results, we propose a paradigm shift in low-latency and offline computing in gravitational-wave astronomy. Such a shift can address key challenges in peak-usage, scalability and reliability, and provide a data analysis platform particularly optimized for deep learning applications. The achieved sub-millisecond scale latency will also be relevant for any machine learning-based real-time control systems that may be invoked in the operation of near-future and next generation ground-based laser interferometers, as well as the front-end collection, distribution and processing of data from such instruments.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Observations of grain-boundary phase transformations in an elemental metal

The theory of grain boundary (the interface between crystallites, GB) structure has a long history 1 and the concept of GBs undergoing phase transformations was proposed 50 years ago 2,3 . The underlying assumption was that multiple stable and metastable states exist for different GB orientations 4,5,6 . The terminology ‘complexion’ was recently proposed to distinguish between interfacial states that differ in any equilibrium thermodynamic property 7 . Different types of complexion and transitions between complexions have been characterized, mostly in binary or multicomponent systems 8,9,10,11,12,13,14,15,16,17,18,19 . Simulations have provided insight into the phase behaviour of interfaces and shown that GB transitions can occur in many material systems 20,21,22,23,24 . However, the direct experimental observation and transformation kinetics of GBs in an elemental metal have remained elusive. In this work we demonstrate atomic-scale GB phase coexistence and transformations at symmetric and asymmetric $[11\bar{1}]$ tilt GBs in elemental copper. Atomic-resolution imaging reveals the coexistence of two different structures at Σ19b GBs (where Σ19 is the density of coincident sites and b is a GB variant), in agreement with evolutionary GB structure search and clustering analysis 21,25,26 . We also use finite-temperature molecular dynamics simulations to explore the coexistence and transformation kinetics of these GB phases. Our results demonstrate how GB phases can be kinetically trapped, enabling atomic-scale room-temperature observations. Our work paves the way for atomic-scale in situ studies of metallic GB phase transformations, which were previously detected only indirectly 9,15,27,28,29 , through their influence on abnormal grain growth, non-Arrhenius-type diffusion or liquid metal embrittlement.

36 MATERIALS SCIENCE↗

High Energy Observations of X-Ray Binaries and Gamma-Ray Blazars

The report discusses the CGRO observation of X-ray binary systems and studies of gamma-ray blasars. Numerous authors have suggested mechanisms for particle acceleration within X-Ray Binary (XRB) systems. Among the acceleration mechanisms that have been applied are pulsar acceleration, shock acceleration at an accretion shock front, shock acceleration at a pulsar wind termination shock, plasma turbulence excited by the accretion flow, and a number of electrodynamic mechanisms. There are therefore many mechanisms which are capable of generating very energetic particles in the XRB environment. If the reports of TeV/PeV gamma-ray generation in XRBs are correct, then one can show that the accelerated particles must be hadrons and that the most likely gamma-ray production mechanism is the decay of collisionally-produced (or photoproduced) neutral pions. At these ultra-high energies, the emission is so strongly beamed that the target conditions are constrained by the requirement that the column depth be large enough to efficiently generate gamma-rays, but not so large that the gamma-rays are absorbed. These constraints naturally lead to models that explain the periodic, narrow duty-cycle pulses observed at TeV/PeV energies as arising from interactions with, either, the atmosphere of the binary companion, an accretion column, or an accretion disk. The production of these TeV/PeV gamma-rays by the decay of pions from "leading isobars" must also be accompanied by a more isotropic emission component in the EGRET energy band from the decay of slower pions (i.e. the "pionization" component). Since the attenuation of 35 MeV-1 GeV photons by photon-photon pair production is not likely to be significant in most XRBs, the TeV/PeV reports therefore strongly suggest sporadic emission in the EGRET energy band. One of the key unresolved issues for understanding AGN is the relationship between XBLs and RBLs.To test the "reunification" hypothesis, authors conducted a multiwavelength campaign during Cycle 7 of the CGRO observing program. The analysis of the cycle 4 through cycle 6 CGRO measurements was completed. Two previously unknown EGRET sources was discovered.

Vestrand, W. Thomas↗

Atomic and Electronic Structure in MgO–SiO 2

Understanding disordered structure is difficult due to insufficient information in experimental data. Here, we overcome this issue by using a combination of diffraction and simulation to investigate oxygen packing and network topology in glassy (g-) and liquid (l-) MgO–SiO 2 based on a comparison with the crystalline topology. We find that packing of oxygen atoms in Mg 2 SiO 4 is larger than that in MgSiO 3 , and that of the glasses is larger than that of the liquids. Moreover, topological analysis suggests that topological similarity between crystalline (c)- and g-(l-) Mg 2 SiO 4 is the signature of low glass-forming ability (GFA), and high GFA g-(l-) MgSiO 3 shows a unique glass topology, which is different from c-MgSiO 3 . We also find that the lowest unoccupied molecular orbital (LUMO) is a free electron-like state at a void site of magnesium atom arising from decreased oxygen coordination, which is far away from crystalline oxides in which LUMO is occupied by oxygen’s 3s orbital state in g- and l-MgO–SiO 2 , suggesting that electronic structure does not play an important role to determine GFA. We finally concluded the GFA of MgO–SiO 2 binary is dominated by the atomic structure in terms of network topology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the inconsistency of [C/Fe] abundances and the fractions of carbon-enhanced metal-poor stars among various stellar surveys

Carbon-enhanced metal-poor (CEMP) stars are a unique resource for Galactic archaeology because they probe the properties of the First Stars, early chemical evolution, and binary interactions at very low metallicity. Comparing the fractions and properties of CEMP stars in different Galactic environments can provide us with unique insights into the formation and evolution of the Milky Way halo and its building blocks. In this work, we investigate whether directly comparing fractions of CEMP stars from different literature samples of very metal-poor [Fe/H] < -2.0 stars is valid. We compiled published CEMP fractions and samples of Galactic halo stars from the past 25 years, and find that they are not all consistent with each other. Focusing on giant stars, we find significant differences between various surveys when comparing their trends of [Fe/H] versus [C/Fe] and their distributions of CEMP stars. To test the role of the analysis pipelines for low-resolution spectroscopic samples, we re-analysed giant stars from various surveys with the sspp and ferre pipelines. We found systematic differences in [C/Fe] of ~0.1-0.4 dex, partly independent of degeneracies with the stellar atmospheric parameters. These systematics are likely due to the different pipeline approaches, different assumptions in the employed synthetic grids, and/or the comparison of different evolutionary phases. We conclude that current biases in (the analysis of) very metal-poor samples limit the conclusions one can draw from comparing different surveys. We provide some recommendations and suggestions that will hopefully aid the community to unlock the full potential of CEMP stars for Galactic archaeology.

79 ASTRONOMY AND ASTROPHYSICS↗

X-Ray Properties of Optically Variable Low-mass AGN Candidates

We present an X-ray analysis of 14 nearby (z < 0.044) active galactic nuclei (AGNs) in low-mass galaxies (M* ≲ 5 × 10 9 M ⊙ ) selected based on their optical variability. Comparing and contrasting different AGN selection techniques in low-mass galaxies is essential for obtaining an accurate estimate of the active fraction in this regime. We use both new and archival observations from the Chandra X-ray Observatory to search for X-ray point sources consistent with AGNs. Four objects have detected nuclear X-ray emission with luminosities ranging from L 0.5-7 ≈ 3 × 10 40 to 9 × 10 42 erg s -1 with two more marginal detections. All of the detected galaxies have luminosities exceeding those anticipated from X-ray binaries, and all sources are nuclear, suggesting the X-ray emission in most sources is due to an AGN. These observations demonstrate the success of variability at identifying AGNs in low-mass galaxies. We also explore emission-line diagnostics and discuss the differences in the results of these methods for AGN selection, in particular regarding low-mass and low-metallicity systems.

79 ASTRONOMY AND ASTROPHYSICS↗

Corrosion of Zinc Cold Spray Coatings in a Wet Sweet and Sour Gas Environment

Internal corrosion is a problem for steel pipelines transporting natural gas or CO 2 containing water and partial pressures of H 2 S higher than 0.3 kPa (0.05 psi). This work aims to mitigate internal corrosion in steel pipelines transporting natural gas containing H 2 S using cold spray coatings. Two types of the cold spray binary metallic coatings (zinc chromium [ZnCr]. zinc niobium [ZnNb]) were studied using electrochemical techniques: potentiodynamic polarization, linear polarization resistance, and electrochemical impedance spectroscopy. The corrosion resistance of cold spray coatings (ZnCr, ZnNb) was evaluated in an environment containing 4 bar CO 2 pressure, simulating the partial pressures found in gas transmission lines over a solution of 3.5 wt% NaCl heated to 40°C. A concentration of 0.003 M Na 2 S 2 O 3 ·5H 2 O, corresponding to H 2 S partial pressures around 0.079 bar (1.146 psi), was used to simulate sour conditions. Postcorrosion surface characterization was performed using a scanning electron microscope (SEM) equipped with an energy-dispersive x-ray spectroscope (EDS) and x-ray diffraction analysis. The data showed that the presence of 0.003 M Na 2 S 2 O 3 ·5H 2 O shifted the corrosion potential to more anodic values and decreased the corrosion current density. Both coatings showed similar behavior after 1 h of exposure in the CO 2 /H 2 S environment, indicating that similar electrochemical reactions were occurring on ZnNb and ZnCr. SEM images and EDS surface analyses for specimens showed a significant change in the surface chemical composition of carbon steel coated with ZnNb and ZnCr after 24 h of immersion. In the presence of thiosulfate (under sour conditions), the formation of corrosion product layers (ZnCO 3 and ZnS) on top of ZnNb and ZnCr coatings increased their corrosion resistance, which helped to reduce their corrosion by a factor of 2. Under a sweet environment, the corrosion rates for steel coated with cold spray coatings after 14 d of exposure are lower than that for galvanized steel by a factor of 5 due to the ZnCO 3 layer formed on top of the coatings. The ZnCO 3 layer formed on the steel surface acts as a physical barrier against corrosion by blocking the diffusion of corrosive species to the surface. No localized attack was observed. ZnCr Cold spray coating with defect showed promising corrosion protection against CO 2 corrosion (sweet corrosion) after 14 d of exposure to a CO 2 environment. Here, the scratch on the coating simulated damage created in service, and it was deep enough to expose the substrate material (steel). The formation of zinc oxide (ZnO) and zinc carbonate (ZnCO 3 ) on the scratch confirmed the cathodic protection of the steel by ZnCr and ZnNb coatings.

36 MATERIALS SCIENCE↗

Search for Hard X-Ray Emission from Aquila X-1: High Energy Emission from Gamma-ray Radio Star 2CG 135+1/LSI 61 305

Several investigations supported by these CCRO grant were completed or are close to completion. The study of EGRET data for the unidentified source 2CG 135+01 was very fruitful. We discovered transient gamma-ray emission by combining several data obtained since 1994 through 1997. It is the first time that time variable emission is established for this enigmatic source, and clearly an interpretation in terms of an isolated radio pulsar (Geminga-like) is disfavored now. Our preferred model is a Galactic source, probably an energetic pulsar (such as PSR129-63) in a binary system producing gamma-rays because of pulsar wind/mass outflow interaction. We also accumulated may data concerning the radio source LSI 61 303, the possible counterpart of 2CG 135+01. We show that a possible anti-correlation between radio and gamma-ray emission exists. This anticorrelation is evident only in the energy range above 100 MeV, as demonstrated by the lack of it obtained from OSSE data. If confirmed, this anti-correlation would prove to be very important for the interpretation of the hundreds of unidentified gamma-ray sources currently discovered by EGRET near the Galactic plane, and would point to a new class of sources in addition to AGNs and isolated pulsars. We also completed the analysis of several time variable gamma-ray sources near the Galactic plane, with the discussion of evidence for transient emission from 2EG J1813-12 and 2EG J1828+01. We completed several investigations regarding gamma-ray bursts (GRBs), including the study of the brightness distribution for different spectral/duration GRB sub-classes, an investigation of acceleration processes and their consequences for GRB afterglow emission [61, the application of the synchrotron shock model of GRBs to X-ray energies.

Tavani, Marco↗

Probing the Masses of the PSR JO621+1002 Binary System Through Relativistic Apsidal Motion

Orbital, spin and astrometric parameters of the millisecond pulsar PSR J0621+1002 have been determined through six years of timing observations at three radio telescopes. The chief result is a measurement of the rate of periastron advance, omega=0 deg.0116 +/-0 deg.0008/yr. Interpreted as a general relativistic effect, this implies the sum of the pulsar mass, m(1), and the companion mass, m(2), to be M=m(1)+m(2)= 2.81 +/-0.30 solar mass. The Keplerian parameters rule out certain combinations of m(1) and m(2), as does the non-detection of Shapiro delay in the pulse arrival times. These constraints, together with the assumption that the companion is a white dwarf, lead to the maximum likelihood values m(1)=1.69((sup +0.30)(sub -0.30)) solar mass and m(2)=0.98((sup +0.32)(sub -0.12) solar mass (68% confidence). The other major finding is that the pulsar experiences dramatic variability in its dispersion measure (DM), with gradients as steep as 0.013 pc/cu cm/yr. A structure function analysis of the DM variations uncovers spatial fluctuations in the interstellar electron density that cannot be fit to a single power law, unlike the Kolmogorov turbulent spectrum that has been seen in the direction of other pulsars. Other results from the timing analysis include the first measurements of the pulsar's proper motion, mu=3.5+/-0.3 mas/yr, and of its spin-down rate, dP/dt=4.7 x 10(exp -20), which, when corrected for kinematic biases and combined with the pulse period, P=28.8 ms, gives a characteristic age of 1.1 x 10(exp 10) yr and a surface magnetic field strength of 1.2 x 10 (exp 9) G.

Spaver, Eric M.↗

Suppressing Ordering in Equiatomic Fe-Co via Laser Powder Bed Fusion

Neutron and electron diffraction was employed to evaluate the effectiveness of thermal management strategies in suppressing the formation of the equilibrium-ordered B2 (CsCl) phase in equiatomic binary Fe-Co specimens fabricated by laser powder bed fusion additive manufacturing. Specimens with a tensile dogbone geometry were fabricated using various combinations of process parameters (laser power and raster speed) and thermal management strategies (no support struts, struts only in the top gauge section, and struts throughout the gauge section). Diffraction results demonstrate that the rapid solidification during PBF-L effectively minimized B2 formation, with laser power and effective scan velocity having no significant impact on the degree of ordering. Furthermore, the inclusion of support struts in the top grip region had no perceivable impact on ordering, whereas specimens with support struts in the gauge region exhibited no detectable ordering. Results are discussed in the context of thermal finite element analysis predictions.

Laser Material Processing↗

Analysis of X-Ray Microradiographs of Al-Au Interface Quench Profile using Modeling of Solidification Including Double-Diffusion and Convection in the Melt

Experimental data on Al-0.8Au horizontal solidification of a 1 mm thick specimen in a BN crucible shows the effect of growth rate on the solidification interface shape. For translation rates below 0.5 micron/s the interface maintains a plain and flat shape. When the translation rate is 3 to 5 micron/s or more, the interface appearance changes to two planar zones, with the zone closer to the bottom having higher inclination. The interface shapes were measured by first quenching in place during growth. X-ray microscopy shows the interface shape within the quenched sample by viewing through the side of the specimen. In order to provide theoretical explanation of the phenomena, numerical modeling was undertaken using finite element code FIDAP. Double diffusion convection in Al-0.8Au melt and crystal-melt interface curvature during directional solidification was analyzed numerically. Actual thermophysical properties of Al-0.8Au including the binary Al-Au phase diagram were used. Although convection in the sample is weak, for the slower translation rate convection and diffusion is sufficient for the redistribution of initial compositional stratification caused by gravity. When translation rate is raised, neither convection nor diffusion can provide proper mixing so that solidification temperatures differ significantly near the bottom within the bulk of the sample. As a result, the solid-liquid interface appears to have two planar zones with different inclination.

Bune, Andris V.↗

Modeling Magnetic Disk Wind State Transitions in Black Hole X-Ray Binaries

We analyze three prototypical black hole X-ray binaries, 4U 1630–472, GRO J1655–40, and H1743–322, in an effort to systematically understand the intrinsic state transition of the observed accretion disk winds between wind-on and wind-off states by utilizing state-of-the-art Chandra/HETGS archival data from multi-epoch observations. We apply our magnetically driven wind models in the context of magnetohydrodynamic(MHD)calculations to constrain(1)their global density slope(p),(2)their density (n17) at the foot point of the inner most launching radius, and(3)the abundances of heavier elements(AFe,S,Si). Incorporating the MHD winds into xstar photoionization calculations in a self-consistent manner, we create a library of synthetic absorption spectra given the observed X-ray continua. Our analysis clearly indicates a characteristic bimodal transition of multi-ion X-ray winds; i.e., the wind density gradient is found to steepen(fro mp∼1.2–1.4 to∼1.4–1.5)while its density normalization declines as the source transitions from the wind-onto the wind-off state. The model implies that the ionized wind remains physically present even in the wind-off state, despite its apparent absence in the observed spectra. Super solar abundances for heavier elements are also favored. Our global multi-ion wind models, taking into account soft X-ray ions as well as Fe K absorbers, show that the internal wind condition plays an important role in wind transitions besides photoionization changes. Simulated XRISM/Resolve and Athena/X-IFU spectra are presented to demonstrate a high fidelity of the multi-ion wind model for a better understanding of these powerful ionized winds in the coming decades

Keigo Fukumura↗

Probing the Chemical Kinetics of Minimalist Functional Group Gasoline Surrogates

We report surrogate mixtures are routinely used for understanding gasoline fuel combustion in engine simulations. The general trend in surrogate formulation has been to increase the number of fuel components in a mixture to better emulate real fuel properties. Recently, a new surrogate design strategy based on functional group analysis of real gasolines was proposed using a minimal number of species [minimalist functional group (MFG)-approach]. MFG surrogates (having just one or two components) could experimentally capture the ignition delay time (IDT), threshold sooting index, and smoke point of different gasoline fuels with hundreds of components. However, other combustion characteristics were not explored, and kinetic modeling of MFG surrogates was not reported. These aspects are addressed in this paper, where the combustion behavior of MFG surrogates for various gasolines was assessed by simulating IDT, jet-stirred reactor oxidation, and premixed laminar flame speeds using chemical kinetic modeling. MFG simulations were compared with experimental data of the real gasolines as well as with the more complex multicomponent (five to nine species) surrogates. This study reveals that binary MFG surrogate mixtures are capable of accurately simulating the combustion behavior of more complex gasoline fuels with hundreds of components.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗