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All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

Assessment of the Performance of the Atmospheric Correction Algorithm MAJA for Sentinel-2 Surface Reflectance Estimates

The correction of atmospheric effects on optical remote sensing products is an essential component of Analysis Ready Data (ARD) production lines. The MAJA processor aims at providing accurate time series of surface reflectances over land for satellite missions, such as Sentinel-2, Venμs, and Landsat 8. The Centre d’Études Spatiales de la Biosphère (CESBIO) and the Centre National d’Études Spatiales (CNES) share a common effort to maintain, validate, and improve the MAJA processor, using state-of-the-art ground measurement sites, and participating in processor inter-comparisons, such as the Atmospheric Correction Intercomparison Exercise (ACIX). While contributing to the second ACIX-II Land validation exercise, it was found that the candidate MAJA dataset could not adequately be compared to the main reference dataset. MAJA reflectances were corrected for adjacency and topography effects while the reference dataset was not, excluding MAJA from a part of the performance metrics of the exercise. The first part of the following study aims at providing complementary performance assessment to ACIX-II by reprocessing MAJA surface reflectances without adjacency nor topographic correction, allowing for an un-biased full resolution comparison with the reference Sentinel-2 dataset. The second part of the study consists of validating MAJA against surface reflectance measurements time series of up to five years acquired at three automated stations. Both approaches provide extensive insights on the quality of MAJA Sentinel-2 Level 2 products.

ROSAS↗
NASA NTRS2023

The 50-Year Landsat Collection 2 Archive

The Landsat global consolidated data archive now exceeds 50 years. In recognition of the need for consistently processed data across the Landsat satellite series, the U.S. Geological Survey (USGS) initiated collection-based processing of the entire archive that was processed as Collection 1 in 2016. In preparation for the data from the now successfully launched Landsat 9, the USGS reprocessed the Landsat archive as Collection 2 in 2020. This paper describes the rationale for, and the contents and advancements provided by Collection 2, and highlights the differences between the Collection 1 and Collection 2 products. Notably, the Collection 2 products have improved geolocation and, for the first time, the USGS provides a global inventory of Level 2 surface reflectance and surface temperature products. Also for the first time, the USGS used a commercial cloud computing architecture to efficiently process the archive and enable direct cloud access of the Landsat products. The paper concludes with discussion of likely improvements expected in Collection 3 in preparation for the Landsat Next mission that is planned for launch in the early 2030s.

Christopher J Crawford↗
NASA NTRS2024

The CARMENES Search for Exoplanets Around M Dwarfs: Revisiting the GJ 581 Multi-Planetary System With New Doppler Measurements From CARMENES, HARPS, and HIRES

Context.GJ 581 is a nearby M dwarf known to host a packed multiple planet system composed of two super-Earths and a Neptune-mass planet. We present new orbital analyses of the GJ 581 system, utilizing recent radial velocity (RV) data obtained from the CARMENES spectrograph combined with newly reprocessed archival data from the HARPS and HIRES spectrographs. Aims.Our aim was to analyze the post-discovery spectroscopic data of GJ 581, which were obtained with CARMENES. In addition, we used publicly available HIRES and HARPS spectroscopic data to seek evidence of the known and disputed exoplanets in this system. We aimed to investigate the stellar activity of GJ 581 and update the planetary system’s orbital parameters using state-of-the-art numerical models and techniques. Methods.We performed a periodogram analysis of the available precise CARMENES, HIRES, and HARPS RVs and of stellar activity indicators. We conducted detailed orbital analyses by testing various orbital configurations consistent with the RV data. We studied the posterior probability distribution of the parameters fit to the data and we explored the long-term stability and overall orbital dynamics of the GJ 581 system. Results. We refined the orbital parameters of the GJ 581 system using the most precise and complete set of Doppler data available. Consistent with the existing literature, our analysis confirms that the system is unequivocally composed of only three planets detectable in the present data, dismissing the putative planet GJ 581 d as an artifact of stellar activity. Our N-body fit reveals that the system’s inclination is i=47.0+14.6−13.0deg, which implies that the planets could be up to 30% more massive than their previously reported minimum masses. Furthermore, we report that the GJ 581 system exhibits long-term stability, as indicated by the posterior probability distribution, characterized by secular dynamical interactions without the involvement of mean motion resonances.

Satellites↗
NASA NTRSDate not supplied

Integrated Multi-Satellite Retrievals for GPM (IMERG)

The Integrated Multi-satellitE Retrievals for GPM (IMERG) product from the U.S. Science Team of the NASA-JAXA Global Precipitation Measurement (GPM) mission provides global satellite precipitation estimates for a wide range of scientific research and societal applications. By adopting a constellation approach using low-Earth orbit passive microwave and geosynchronous-orbit infrared observations from domestic and international partners, IMERG is able to achieve a high resolution of 0.1° every half-hour globally, with three Runs to cater to applications with different latency requirements. With the completion of the reprocessing of the latest version, IMERG V07 now provides improved global satellite precipitation estimates for a period of more than 20 years. This presentation summarizes background on retrievals, the IMERG algorithm, and access to the data. As well, it showcases select results from the data, which might give participants ideas about how they can analyze the data themselves. The presentation ends with a prospectus for the timeline for the upcoming Version 08 and provides a list of references.

IMERG↗
NASA NTRSDate not supplied

Explore Information Content Efficiently from Current and Future Hyperspectral Satellite Missions using a Spectral Fingerprinting Method

Hyperspectral remote sensors from current and future missions provide measurements of the Top of Atmosphere (TOA) radiance or reflectance spectra with high information content. For example, the Atmospheric Infrared Sounder (AIRS), together with the Cross-track Infrared Sounder (CrIS), and the Infrared Atmospheric Sounding Interferometer (IASI) have provided more than 20 years radiance measurements with thousands of spectral channels. These measurements will be continued for the next two decades with the same or more advanced hyperspectral sensors. The upcoming missions such as NASA’s CLARREO Pathfinder (CPF) and ESA’s TRUTHS will provide unprecedented accurate TOA hyperspectral radiance measurements in solar spectral region. Traditional ways to derive Climate Data Records (CDRs) from these measurements are performing spatial and temporal averages of the retrieved Level-2 products. However, it is a time-consuming process to generate decades of Level-2 data from Level-1 data. Furthermore, the differences in Level-2 algorithms used for different satellite sensors will introduce errors in derived CDRs. In this presentation, we will describe a spectral fingerprinting method to generate high-quality CDRs directly from spatiotemporally averaged Level-1 data. By using consistent radiative kernels which contain the spectral information of various atmospheric and surface CDRs, we can reduce the errors due to algorithm inconsistency. Additionally, the spectral fingerprinting method reduces the time needed to generate CDRs by more than three orders of magnitude. This makes it easy to reprocess CDRs once the Level-1 data from different satellites have been improved via either re-calibrations or inter-satellite calibrations. We will present results of applying spectral fingerprinting method to 20-years of AIRS and CrIS data. The resulting CDRs include: 1) vertical profiles of atmospheric temperature and water vapor, 2) cloud properties such as optical depth, effective size, and height, 3) vertical profiles or column amounts for atmospheric trace gases such as O3 and CO, and 4) surface emissivity spectra and skin temperatures. These CDRs will be publicly available at NASA GES DISC in late 2024. The same fingerprinting method is planned to be applied to future CPF and TRUTHS data for solar spectral region.

hyperspectral remote sensing↗
NASA NTRS2024

Stellar Occultation Observations to Constrain the Stratosphere of Uranus for Aerocapture

Background on Uranus: Voyager 2 (V2) UV stellar and solar occultations at Uranus detected a warm stratosphere and extremely hot thermosphere [1, 2], far in excess of solar irradiance [3, 4] and internal heating [5, 6]. New theories to explain similar heating at Jupiter [7] and Saturn [8] cannot be tested at Uranus due to a dearth of reliable measurements. In [9, 10], we reprocessed 26 archival Earth-based stellar occultations by Uranus (1977-1996), finding stratospheric temperatures (~200 K) warmer than the original (~100 K), but in stark tension with V2 (~300-500 K). In [10], we built a physics-based, 1-D atmospheric model (see Fig 1) that finds a nearly isothermal stratosphere and a dynamic heat sink in the lower thermosphere. Aerocapture: Aerocapture is spacecraft maneuver that uses a single deep dip to enter orbit. It could decrease cruise time and launch mass for a Uranus mission, but the greatest impediment is uncertain stratospheric densities of Uranus [11]. Aims: 1) Observe and process many high S/N Uranus stellar occultations in the next decade; 2) constrain stratospheric densities for aerocapture; 3) better understand the energy balance; 4) determine stratospheric changes since 1996. Upcoming Occultations: We will present our observing plan for the 2025 April Uranus occultation (K mag 8) and discuss the best-in-a-century 2031 event (K mag 4). We will discuss other events in the early 2030s [12] [13], predicted constraints on density, and simulations of aerocapture for UOP. We will discuss the Shadow Chaser, a small satellite concept for observing occultations from Earth orbit [12]. Conclusions: New stellar occultations can vastly improve profiles of the stratosphere of Uranus; this is critical for understanding energy circulation and constraining densities for using aerocapture on UOP. References: [1] Herbert, F. et al. (1987). JGR. [2] Stevens, M. et al. (1993). Icarus. [3] Marley, M. & McKay, C. (1999). Icarus, [4] Li, C. et al. (2018). JQRST. [5] Pearl, J. et al. (1990). Icarus. [6] Melin, H (2020). Nat Astron. [7] O’Donoghue, J. et al. (2021) Nature. [8] Mueller-Wodarg, I. et al. (2019) GRL. [9] Saunders, W. et al. (2023). PSJ. [10] Saunders, W. et al. (2024). PSJ. [11] Report of the Aerocapture Demonstration Relevance Assessment Team (2023). [12] Saunders, W. et al. (2022). P&SS. [13] French, R. & Souami, D. (2023) PSJ.

William Saunders↗
NASA NTRS2026

Application of Energy-efficient Electromagnetic Melt-Processing for the Upcycling of Recycled Polyphenylene Sulfide into Multifunctional Segregated Nanocomposites

Polyphenylene sulfide (PPS) is widely used in structural and functional composites because of its thermal stability, chemical resistance, and mechanical strength. As circular manufacturing becomes increasingly important, extending the service life of recycled PPS (rPPS) is essential. However, conventional high-temperature reprocessing accelerates thermo-oxidative degradation, reducing recycled composite performance. This study proposes a rapid and potentially energy-saving upcycling strategy for rPPS using electromagnetic (EM) melt-processing to form segregated carbon nanotube (CNT) networks and produce EM-responsive nanocomposites. The aim was to determine whether CNT-assisted EM heating could reduce polymer degradation while improving multifunctional properties at ultralow filler loadings. rPPS micropellets were coated with CNTs by ball milling to create conductive shells, then compacted into green bodies (GBs) and selectively melted by rapid EM irradiation. Structural, electrical, mechanical, rheological, and electromagnetic interference (EMI) shielding properties were evaluated. Electrical percolation occurred at an ultralow CNT loading of 0.08 wt%, with conductivity reaching (1.24 ± 0.74) × 10 -5 S⋅m -1 at 0.1 wt%. At this concentration, tensile strength and modulus increased by 72% and 99%, respectively. At ~ 0.7 mm thickness, X-band EMI shielding effectiveness reached 6 dB for GBs and 3 dB after EM processing. This shows that EM melt-processing upcycles rPPS into high-performance multifunctional nanocomposites with minimum thermal degradation.

recycled↗
DOE OSTI2017

Room temperature electrodeposition of actinides from ionic solutions

Uranic and transuranic metals and metal oxides are first dissolved in ozone compositions. The resulting solution in ozone can be further dissolved in ionic liquids to form a second solution. The metals in the second solution are then electrochemically deposited from the second solutions as room temperature ionic liquid (RTIL), tri-methyl-n-butyl ammonium n-bis(trifluoromethansulfonylimide) [Me.sub.3N.sup.nBu][TFSI] providing an alternative non-aqueous system for the extraction and reclamation of actinides from reprocessed fuel materials. Deposition of U metal is achieved using TFSI complexes of U(III) and U(IV) containing the anion common to the RTIL. TFSI complexes of uranium were produced to ensure solubility of the species in the ionic liquid. The methods provide a first measure of the thermodynamic properties of U metal deposition using Uranium complexes with different oxidation states from RTIL solution at room temperature.

36 MATERIALS SCIENCE↗
DOE OSTI2017

CeLAND: search for a 4th light neutrino state with a 3 PBq 144 Ce- 144 Pr electron antineutrino generator in KamLAND

The reactor neutrino and gallium anomalies can be tested with a 3-4 PBq (75-100 kCi scale) 144 Ce- 144 Pr antineutrino beta-source deployed at the center or next to a large low-background liquid scintillator detector. The antineutrino generator will be produced by the Russian reprocessing plant PA Mayak as early as 2014, transported to Japan, and deployed in the Kamioka Liquid Scintillator Anti-Neutrino Detector (KamLAND) as early as 2015. KamLAND's 13 m diameter target volume provides a suitable environment to measure the energy and position dependence of the detected neutrino flux. A characteristic oscillation pattern would be visible for a baseline of about 10 m or less, providing a very clean signal of neutrino disappearance into a yet-unknown, sterile neutrino state. This will provide a comprehensive test of the electron dissaperance neutrino anomalies and could lead to the discovery of a 4th neutrino state for Δm$2\atop{new}$ ≳ 0.1 eV 2 and sin 2 (2θ new ) > 0.05.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2017

Spent Nuclear Fuel Canister Capacity: Have the Limits Been Reached?

The commercial US nuclear utilities have been transferring spent nuclear fuel (SNF) from spent fuel pools (SFPs) to dry storage systems since 1986. SFPs were initially constructed for temporary storage, but without SNF reprocessing options in the United States and with no final disposal pathway yet available,SFPs started to reach capacity. Hence, to allow continued operation of the nation’s commercial nuclearreactor fleet, utilities started transferring SNF from SFPs (wet storage) to dry storage. Dry storage systems have evolved from storage-only systems first loaded in 1986 to the high-capacity dual-purpose storage and transport canisters used today. A question has arisen as to whether maximum canister capacity has been reached at the current capacity of ~50 kW heat load for storage, with 37-assembly pressurized water reactor and 89-assembly boiling water reactor canisters. This paper presents a holistic overview of commercial US SNF management practices over the years, the current SFP status in terms of filled (occupied) and empty (available) locations, the expected future reactor discharges, and the decay heat load distribution of SFP inventories as of June 2013. Finally, the paper makes a case that further increase in dry storage system capacity both in terms of number of assemblies and decay heat (1) is not needed, and (2) may not be practical from the cost-benefit perspective. b

Banerjee, Kaushik↗
DOE OSTI2017

Pyroprocessing Monitoring Technology Development at Idaho National Laboratory

The Idaho National Laboratory (INL), with support from the U.S. Department of Energy, Office of Nuclear Energy, Nuclear Technology Research and Development program, has been developing advanced instrumentation and approaches for enhancing the effectiveness of nuclear material control and accounting for future reprocessing facilities with particular emphasis on pyroprocessing. Advanced modeling capabilities augment new instrumentation development, predict material flows, integrate process monitoring data, and assess overall system effectiveness of the safeguards and security system. In this paper we provide a brief overview of the Safeguards and Security by Design approach being pursued under the program and details of advanced process monitoring instrumentation under development at the INL, which includes a triple bubbler system for on-line monitoring of level and density of molten salt, sensors for monitoring actinide concentrations in molten salt, and thermal-couple instrumentation for near real time determination of Pu content in U/TRU ingots. Laboratory and field testing data will be presented, as well as integration of these sensors into a concept for utilization of process monitoring information in concert with traditional nuclear material accountancy data.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗
DOE OSTI2018

Safeguards Challenges for Molten Salt Reactors

There are now a wide variety of molten salt reactor (MSR) technologies being proposed or developed that are gaining international interest and momentum toward deployment. There are two sub-categories of this class of reactors - those that are liquid fueled (i.e., the molten salt is both the fuel and the coolant) and those that have solid fuel with the molten salt used as coolant only. The liquid-fueled MSRs present unique challenges to current safeguards approaches. These challenges exist because there are currently no conceptual approaches to applying safeguards to unique, tightly coupled nuclear energy systems with the reactor core, balance of plant, and fuel cycle (everything else including salt processing and material separations) combined in a single facility. The application of safeguards to liquid-fueled MSRs will have to take into consideration several technical factors including: The homogeneous mixture of fuel, coolant, fission products, and actinides (with the attendant extremely high radiation field); Continuous variation in isotopic concentrations in the fuel salt, including removal (passive or active) of fission products, rare earth elements, and noble metals; High operating temperatures of the fuel salt; Online processing where some fraction of the inventory can be removed while the reactor is operational; Unique refueling schemes, including the ability to continuously feed the core with fresh fissile or fertile material; The presence of frozen fuel, potentially requiring a different safeguards process from the liquid fuel; and The presence of fuel outside the vessel. Additionally, If the thorium fuel cycle is employed, there will be additional complications since the resulting radiation signatures will be different from those of the uranium-based fuel cycle. The existing IAEA inspection regimes are based on the uranium-plutonium fuel cycle, item counting for nuclear reactors, and bulk material accountancy for the front and back end of the nuclear fuel cycle. These techniques and associated instrumentation for bulk accountancy have been developed predominantly for enrichment, fuel fabrication, and aqueous reprocessing. However, none of these bulk accountancy measures can be directly applied to liquid-fueled MSRs. This paper will explore some of the possible challenges in applying safeguards to molten salt reactors.

Kovacic, Donald N↗
DOE OSTI2018

Application of a Triple Bubbler Sensor for Determining the Density, Surface Tension, and Depth in Molten Salts

Electrochemical (i.e. pyroprocessing) technology is being widely studied throughout the world as a potential alternative to aqueous reprocessing of spent nuclear fuel (SNF). Central to this process is the electrorefiner (ER), in which the useful uranium in the SNF is electrochemically transported through a molten salt electrolyte to a cathode for later recovery. As part of this process, uranium, plutonium, and other actinides accumulate in the ER salt over time. Material accountancy and safeguards of these special nuclear material buildups in near real-time is a significant challenge due to the elevated processing temperatures, remote operation within a hotcell, and high radiation fields. Analytical techniques outside of the hotcell can be used to provide the SNM concentrations of salt samples from the ER. However, determining the actual mass of these materials in the ER presents a significant challenge because the density and volume within the vessel is largely unknown. The Idaho National Laboratory (INL) has developed a triple bubbler sensor capable of determining the density, surface tension, and depth of a fluid in near real-time. Previous experiments in aqueous media has shown that the sensor is capable of determining the density, surface tension and depth with accuracies on the order of 0.2%. The goal of this current work is to test the sensor in several molten salt media to calibrate and validate the triple bubbler. Experiments have been performed in LiCl-KCl eutectic salt. Calibration factors were 1.0015 and 1.26 for density and surface tension, respectively. With the above calibration factors applied, the depth of the salt in the test vessel was determined to within 0.4%. These results indicate that the triple bubbler sensor has the potential to accurately (less than 1% uncertainty) determine the density, surface, tension, and depth of the ER salt in near real-time. The triple bubbler sensor designed at INL can significantly enhance the material accountancy, safeguards, and process monitoring of the electrochemical processing of SNF.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗
DOE OSTI2018

Thermodynamic Properties of Rare Earth Chlorides in Molten Salts: A Novel Approach to Experimental Electrochemistry of Molten Salts

The thermodynamic and electrochemical properties of rare earth chlorides in molten salt solutions are of interest from the standpoint of both pyrochemical processing of spent nuclear fuel and for the development of Generation IV nuclear reactors. Knowledge of key properties like activity coefficients and phase diagrams will accelerate the development of safe reliable carbon free energy. In this work, three conduits of research have been pursued and reported within the larger theme of minimization of waste in spent fuel reprocessing and associated technology development. The activity coefficient of rare earth chlorides has been investigated using ground breaking theory and experimental approach. Furthermore, an ionic size dependent activity coefficient model is presented. This book also contains research into quaternary phase diagrams for LiCl-KCl-CsCl-RECl3 molten salt systems. This book should prove an excellent introduction to anyone pursuing a career in experimental high temperature electrochemistry and molten salt chemistry.

Bagri, Prashant↗
DOE OSTI2016

IODINE ADSORPTION IN FIXED BED ADSORBER TESTS

I-129 emissions control is needed for used fuel aqueous reprocessing. I-129 capture has been studied for 40 years; Two sorbents tested in recent years – Silver Zeolite (AgZ) and silver-functionalized Aerogel (AGAero). Results show needed iodine adsorption efficiencies are possible, DFs up to10,000. Mass transfer zone (MTZ) depths ~2 in. for I2 and 8 in. for CH3I, but increase over time; deeper sorbent beds needed for efficient CH3I capture. Ag utilization between 10-70% for most test durations; lower for higher NOx. Iodine sorption capacities: ~10 g/100 AgZ and ~20 g/100 g AgAero; lower for high NOx. Nearly all adsorbed I was physisorbed iodine for I2 and CH3I.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2017

A Triple Bubbler System to Measure Density, Surface Tension, and Depth of Electrorefiner Molten Salt

In pyroprocessing of used nuclear fuel (UNF), uranium from the fuel is electrochemically dissolved at the anode and transported through a molten salt electrolyte to the cathode—where it is later recovered for reuse. As part of this process, special nuclear materials (SNM) dissolve into the molten salt electrolyte. Monitoring the mass of these materials, particularly plutonium, is important for material accountability and safeguards of the electrorefiner (ER) used in pyroprocessing. The mass of plutonium in the ER vessel is a function of the volume and density of the salt as well as the plutonium concentration. Measuring these parameters presents challenges due to the high temperature, radiation, and accessibility of the ER within a hotcell. Here, the main motivation for this work was to develop a method capable of measuring the density and depth (volume) of salt under the extreme operating conditions within the ER to enhance the SNM accountability and safeguards of pyroprocessing. In addition, these online measurements would be useful for monitoring level changes associated with removal of electrolyte from the ER and different unit operations associated with electrochemical reprocessing of used nuclear fuel.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2019

Expression of Interest for off-gas system design build

Idaho National Laboratory (INL) and Pacific Northwest National Laboratory (PNNL) are studying a used nuclear fuel reprocessing system that could be used to recycle used nuclear fuel by separating waste fission products from re-useable, valuable uranium that can be used in making new nuclear fuel. This process includes dissolving the mixture of uranium and fission products in a nitric and hydrofluoric acids, then using an organic extraction process to remove and recover the uranium. The waste fission products remain in the acidic aqueous “raffinate” stream.” The fission products in this raffinate waste stream are expected to require stabilization in a vitrified glass waste form for safe disposal. INL and PNNL plan to construct and operate a facility in which to test the performance of the electric melter process that would receive a non-radioactive but chemically similar simulant of this raffinate. This test system will be located at INL in or near Idaho Falls, ID. In the melter, which operates at a temperature of about 1,050 to 1,150oC, the water, nitric acid, and other volatile and semi-volatile materials evolve into an off-gas stream, while the fission products (in this case, non-radioactive simulants of fission products) are melted with glass forming chemicals into a molten glass. Upon cooling, the molten glass provides a durable waste form for long-term disposal. Expressions of interest are requested from companies who would like to receive a request for proposal to design and build this off-gas system. We expect to request proposals and desire to award a contract prior to the end of September 2019.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗