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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,243 records · Page 69
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

First measurement of the asymmetry and the Gerasimov-Drell-Hearn integrand from the 3 $\vec{H}$e ($\vec{γ},p$) 2 H reaction at an incident photon energy of 29 MeV

The first measurement of the 3 $\vec{H}$e ($\vec{γ},p$) 2 H process was performed at the High Intensity γ-ray Source ( HIγS ) facility at Triangle Universities Nuclear Laboratory using a circularly polarized, monoenergetic γ -ray beam and a longitudinally polarized 3 He target. The spin-dependent asymmetry and the contribution from the two-body photodisintegration to the 3 He Gerasimov-Drell-Hearn integrand are extracted and compared with state-of-the-art three-nucleon system calculations at the incident photon energy of 29 MeV. The data are in general agreement with the various theoretical predictions based on the Siegert theorem or on explicit inclusion of meson-exchange currents.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

Mirror nucleon removal reactions in p-shell nuclei

Nucleon removal reactions have been shown to be an effective tool for studying the single particle structure of nuclei. This work continues efforts to experimentally probe and benchmark the reaction and structure models used to calculate the removal reaction cross sections when using microscopic nuclear structure inputs. Here, three different single nucleon removal reactions were performed, from p -shell nuclei with masses A = 7, 9, and 10. The residual nuclei from the reactions were detected in coincidence with γ rays to determine partial cross sections to individual final states. The eikonal direct-reaction model is combined with overlap functions and residual nucleus densities from microscopic, variational Monte Carlo calculations to provide consistent nuclear structure input to the partial cross section calculations. Comparisons of measured and calculated cross sections, including for mirror reactions, are presented. The analysis of the partial cross sections leading to the ground states shows a similar behavior to the one observed from analyses of inclusive cross sections using shell model nuclear structure input: the theoretical description of the removal process is in better agreement with the data when removing weakly bound nucleons, than when removing well-bound ones. The two mirror reaction pairs presented here show consistent results between the respective members of the pairs. The results obtained for the population of the excited states, however, show a systematically different trend that appears connected to the structure part of the calculation. Additional cases are needed to better understand the respective roles of structure and dynamical effects in the deviations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

Core of 25 F studied by the 25 F(–p) proton-removal reaction

The 9 Be( 25 F(5/2 + ), 24 O)X proton-removal reaction was studied at the NSCL using the S800 spectrometer. The experimental spectroscopic factor for the ground-state to ground-state transition indicates a substantial depletion of the proton d 5/2 strength compared to shell-model expectations, similar to the findings of an inverse-kinematics (p,2p) measurement performed at RIBF. The 25 F to 24 O ground-states overlap is considerably less than anticipated if the core nucleons behaved as rigid, doubly-magic 24 O within 25 F. We interpret the new results within the framework of the Particle-Vibration Coupling (PVC) model, of a d 5/2 proton coupled to a quadrupole phonon of an effective core. This approach provides a good description of the experimental data, requiring an effective 24 O* core with a phonon energy of ℏω 2 = 3.2 MeV and a B(E2) ≈ 2.7 W.u. – softer and more collective than a bare 24 O. Here, both the Nilsson deformed mean field and the PVC models appear to capture the properties of the effective core of 25 F, suggesting that the additional proton polarizes 24 O in such a way that it becomes either slightly deformed or a quadrupole vibrator.

20 ≤ A ≤ 38↗
DOE OSTI2022

Search for proton decay via p → μ + K 0 in 0.37 megaton-years exposure of Super-Kamiokande

We searched for proton decay via p → μ + K 0 in 0.37 Mton · years of data collected between 1996 and 2018 from the Super-Kamiokande water Cherenkov experiment. The selection criteria were defined separately for K$^0_S$ and K$^0_L$ channels. No significant event excess has been observed. As a result of this analysis, which extends the previous search by an additional 0.2 Mton · years of exposure and uses an improved event reconstruction, we set a lower limit of 3.6 × 10 33 years on the proton lifetime.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Materials Data on P(HO)3 by Materials Project

H3PO3 crystallizes in the monoclinic P2_1 space group. The structure is one-dimensional and consists of six phosphorous acid molecules and one H3PO3 ribbon oriented in the (0, 1, 0) direction. In the H3PO3 ribbon, P5+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of P–O bond distances ranging from 1.62–1.66 Å. There are three inequivalent H+0.33+ sites. In the first H+0.33+ site, H+0.33+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the second H+0.33+ site, H+0.33+ is bonded in a single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.70 Å) H–O bond length. In the third H+0.33+ site, H+0.33+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one P5+ and one H+0.33+ atom. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one P5+ and one H+0.33+ atom. In the third O2- site, O2- is bonded in a 2-coordinate geometry to one P5+ and two H+0.33+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on P(H2I)2 by Materials Project

P(H2)2(I)2 crystallizes in the tetragonal P4/nmm space group. The structure is zero-dimensional and consists of sixteen hydrogen molecules, four iodine molecules, and four phosphine molecules.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on P(NO2)2 by Materials Project

PO3NNO crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four PO3N clusters. In each PO3N cluster, P5+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of P–O bond distances ranging from 1.46–1.65 Å. N+1.50+ is bonded in a single-bond geometry to one O2- atom. The N–O bond length is 1.33 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one P5+ and one N+1.50+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one P5+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one P5+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on P(HO)3 by Materials Project

H3PO3 crystallizes in the monoclinic P2_1 space group. The structure is one-dimensional and consists of four phosphorous acid molecules and two H3PO3 ribbons oriented in the (0, 1, 0) direction. In each H3PO3 ribbon, P5+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There is one shorter (1.61 Å) and two longer (1.64 Å) P–O bond length. There are three inequivalent H+0.33+ sites. In the first H+0.33+ site, H+0.33+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the second H+0.33+ site, H+0.33+ is bonded in a distorted single-bond geometry to two O2- atoms. There is one shorter (1.00 Å) and one longer (1.70 Å) H–O bond length. In the third H+0.33+ site, H+0.33+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.01 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one P5+ and one H+0.33+ atom. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one P5+ and one H+0.33+ atom. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to one P5+ and two H+0.33+ atoms.

36 MATERIALS SCIENCE↗
NASA NTRS1985

The 4He(p,d)3He reaction at 200 and 400 MeV

The distorted wave calculations are compared with the He-4(p,d) cross section. At all four energies the theoretical description of the data is relatively poor. While the general magnitude of the cross sections is not in bad agreement, the detailed slopes of the theoretical angular distributions miss the shapes of the experimental data in a rather fundamental way.

Alons, P. W. F.↗
NASA NTRS1986

Measurements of n-p correlations in the reaction of relativistic neon with uranium

We report a preliminary measurement of coincident neutron-proton pairs emitted at 45 degrees in the interaction of 400, 530, and 650 MeV/A neon beams incident on uranium. Charged particles were identified by time of flight and momentum, as determined in a magnetic spectrometer. Neutral particles were detected using a thick plastic scintillator, and their time of flight was measured between an entrance scintillator, triggered by a charged particle, and the neutron detector. The scatter plots and contour plots of neutron momentum vs. proton momentum appear to show a slight correlation ridge above an uncorrelated background. The projections of this plane on the n-p momentum difference axis are essentially flat, showing a one standard deviation enhancement for each of the three beams energies. At each beam energy, the calculated momentum correlation function for the neutron-proton pairs is enhanced near zero neutron-proton momentum difference by approximately one standard deviation over the expected value for no correlation. This enhancement is expected to occur as a consequence of the attractive final state interaction between the neutron and proton (i.e., virtual or "singlet" deuterons). The implications of these measurements are discussed.

NASA Program Space Medicine↗
DOE OSTI2020

Fermi Level Engineering of Passivation and Electron Transport Materials for p-Type CuBi 2 O 4 Employing a High-Throughput Methodology

Metal oxide semiconductors are promising for solar photochemistry if the issues of excessive charge carrier recombination and material degradation can be resolved, which are both influenced by surface quality and interface chemistry. Coating the semiconductor with an overlayer to passivate surface states is a common remedial strategy but is less desirable than application of a functional coating that can improve carrier extraction and reduce recombination while mitigating corrosion. Here, a data-driven materials science approach utilizing high-throughput methodologies, including inkjet printing and scanning droplet electrochemical cell measurements, is used to create and evaluate multi-element coating libraries to discover new classes of candidate passivation and electron-selective contact materials for p-type CuBi 2 O 4 . The optimized overlayer (Cu 1.5 TiO z ) improves the onset potential by 110 mV, the photocurrent by 2.8×, and the absorbed photon-to-current efficiency by 15.5% compared to non-coated photoelectrodes. It is shown that these enhancements are related to reduced surface recombination through passivation of surface defect states as well as improved carrier extraction efficiency through Fermi level engineering. This work presents a generalizable, high-throughput method to design and optimize passivation materials for a variety of semiconductors, providing a powerful platform for development of high-performance photoelectrodes for incorporation into solar-fuel generation systems.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Suppressing Charged Cation Antisites via Se Vapor Annealing Enables p-Type Dopability in AgBiSe 2 –SnSe Thermoelectrics

Cation disordering is commonly found in multinary cubic compounds, but its effect on electronic properties has been neglected because of difficulties in determining the ordered structure and defect energetics. An absence of rational understanding of the point defects present has led to poor reproducibility and uncontrolled conduction type. AgBiSe 2 is a representative compound that suffers from poor reproducibility of thermoelectric properties, while the origins of its intrinsic n-type conductivity remain speculative. Here, it is demonstrated that cation disordering is facilitated by Bi Ag charged antisite defects in cubic AgBiSe 2 which also act as a principal donor defect that greatly controls the electronic properties. Using density functional theory calculations and in situ Raman spectroscopy, how saturation annealing with selenium vapor can stabilize p-type conductivity in cubic AgBiSe 2 alloyed with SnSe at high temperatures is elucidated. With stable and controlled hole concentration, a peak is observed in the weighted mobility and the density-of-states effective mass in AgBiSnSe 3 , implying an increased valley degeneracy in this system. These findings corroborate the importance of considering the defect energetics for exploring the dopability of ternary thermoelectric chalcogenides and engineering electronic bands by controlling self-doping.

36 MATERIALS SCIENCE↗
DOE OSTI2022

The 40 Ar(d,p) 41 Ar cross section between 3–7 MeV

To determine the safety of using argon as a deuteron beam stopping material, the 40 Ar(d,p) 41 Ar cross section was measured at average deuteron energies of 3.6 MeV, 5.5 MeV, and 7.0 MeV using an activation method. A 16-MeV deuteron beam produced by Lawrence Berkeley National Laboratory’s 88-Inch Cyclotron was degraded to each energy by nickel foils and the front wall of an aluminum gas chamber. The reduced-energy deuterons were used to activate a sample of nat Ar gas. After each irradiation, the gas chamber’s 41 Ar activation was measured with a high-purity germanium detector. The cross sections measured were larger than a previous measurement by ~40%.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

TexAT detector upgrade for 14 O($α$, $p$) 17 F cross section measurement

A direct cross-section measurement of the 14 O($α$, $p$) 17 F reaction is important to understand the light curves of x-ray bursts. The measurement will be performed using the Texas Active Target TPC version 2 (TexAT_v2). The TexAT_v2 aims at measuring lower energy protons from the reaction than the original TexAT. Newly developed silicon and CsI(Tl) detector arrays are added at the left, right and bottom of a modified field cage to increase its detection efficiency. Furthermore, this paper describes the overall specifications and two commissioning experiments performed at Texas A&M University.

14O(α, p)17F↗
DOE OSTI2025

Signature of 0 + excited state and shape coexistence in 94 Kr through 93 Kr(d,p) 94 Kr reaction

A measurement of the excitation spectrum of 94 Kr via one-neutron transfer to the ground state of 93 Kr using the 93 Kr(d,p) 94 Kr reaction at 8A MeV, observing the outgoing protons, performed with the IRIS facility at TRIUMF is reported. Two states in 94 Kr, at 1.50±0.14 MeV and 2.20±0.14 MeV, were observed. An adiabatic-wave approximation analysis of the differential cross sections leads us to identify the lower energy state as being populated with neutron transfer to the 3 s1/2 orbital. This leads to the first observation of the lowest 0 + excited state in 94 Kr, hence signaling shape co-existence. Theoretical calculations performed within the in-medium similarity renormalization group framework are presented that also show the existence of a low-energy 0 + state, aligning qualitatively with the observation.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2022

Potential-induced degradation of Cu(In,Ga)Se 2 can occur by shunting the front i-ZnO and by damaging the p-n junction

In this work we test field-relevant potential-induced degradation (PID) behavior by encapsulating laboratory Cu(In,Ga)Se 2 (CIGS) solar cells and applying +1000 V uniformly on the face of the front glass. In this configuration, we find that K-rich borosilicate glass reduces the extent of PID relative to Na-rich soda-lime glass. We also find that the standard testing protocol of stressing cells at short-circuit leads to faster PID than stressing cells at open-circuit. We characterize two types of CIGS PID: The first, front shunting PID, is driven by front-glass stress and occurs when alkali metal cations accumulate in the i-ZnO buffer, where they increase shunt conductance to reduce fill factor. The second, p-n junction PID, results from back-glass stress as alkali metal cations pile up near the CIGS surface/CdS buffer, where they reduce charge carrier concentration, open-circuit voltage, and fill factor to degrade efficiency ~160 times faster than front shunting PID.

14 SOLAR ENERGY↗
DOE OSTI2024

Photo-Crosslinkable Naphthalene Diimide Polymer for Solution-Processed n – i – p Perovskite Solar Cells

We copolymerize a norbornene monomer bearing a pendant naphthalene diimide with a norbornene bearing a cinnamate pendant moiety to synthesize a crosslinkable electron-transporting polymer and study its use in solution-processed n–i–p perovskite solar cells. The crosslinked material exhibits over 90% transparency in the visible region and higher thermal stability (>300 °C) and lower surface energy than the corresponding homopolymer of the naphthalene diimide functionalized norbornene. Coating an ITO surface with the photo-crosslinked copolymer yields a slightly lower work function than homopolymer-coated ITO. We show that the morphologies of the perovskite films deposited on both polymers are similar (~300 nm features) based upon scanning electron microscopy. Our solar-cell device results show that the crosslinked naphthalene diimide polymer gives a higher open-circuit voltage (1.08 vs 1.05 V), fill factor (average 64.43 vs 58.77%), and stabilized power conversion efficiency (12.28 vs 10.33%) compared to its non-crosslinked homopolymer counterpart, as well as reduced hysteresis. As a result, we attribute the improved performance to decreased work function, reduced nonradiative recombination, and higher shunt resistance.

14 SOLAR ENERGY↗