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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,243 records · Page 69

Mesoporous optically clear heat insulators for sustainable building envelopes

Mesoporous materials exhibit highly controlled nanoscale structures, often templated by liquid crystalline assemblies of surfactants, with emergent and often designable physical properties. However, scaling their fabrication to be suitable for uses like envelopes of buildings is challenging. Here we describe fabrication of flexible square-meter-sized films and multi-centimeter-thick slabs made of three-dimensional spatial graphs of mesopore tubes having all structural features under 50 nanometers. Solution-based kinetic fabrication process templates growing networks of cylindrical surfactant micelles with thin tubes of polysiloxane forming gel networks and, upon replacing surfactants and solvents with air, yields lightweight materials with >99% visible-range optical transparency and ~10 mW K-1m-1 thermal conductivity. Such predesigned metamaterials enable transparent thermal barriers for wall-grade insulated glass units, square-meter window retrofits and unconcentrated solar thermal energy harnessing.

14 SOLAR ENERGY↗

A Miniaturized Seismometer for Subsurface Probing on Mars

Seismology is one of the most powerful tools for investigating the subsurface structure of a planet. The mechanical structure information derived from seismic measurements is complementary to other methods of probing the subsurface (such as gravity and electromagnetics), both in terms of spatial and depth resolution and the relevant types of material properties being sensed. In the near-surface, the propagation of seismic waves is especially sensitive to density and degree of compaction. In addition, interfaces between layer with contrasting properties can be relatively easily delineated. The subsurface of Mars provides an obvious target for seismic investigations. Searching for the presence of water is among the highest priority goals of the Mars Exploration Program, but there are many other important science questions that could be addressed by a seismic profile of the upper layers of the crust. We have developed an extremely small, lightweight, low-power seismometer for planetary applications which is ideally suited for use on Mars. This instrument has previously been proposed and selected for use on a comet (on the Rosetta Lander, subsequently deselected for programmatic reasons) and Mars (on the NetLander mission, with an emphasis on global structure determination).

Banerdt, W. B.↗

An Octacarboxylate-Linked Sodium Metal–Organic Framework with High Porosity

Alkali metal-based metal-organic frameworks (MOFs) with permanent porosity are scarce because of their high tendency to coordinate with solvents such as water. However, these MOFs are lightweight and bear gravimetric benefits for gas adsorption related applications. In this paper, we present the successful construction of a microporous MOF, designated as HIAM-111, built solely on sodium ions using an octacarboxylate linker. The structure of HIAM-111 is based on 8-connected Na4 clusters and exhibits a novel topology with an underlying 3 2 ,4 2 ,8-c net. Remarkably, HAM-111 possesses a robust and highly porous framework, with a BET surface area of 1561 m 2 /g, significantly surpassing that of the previously reported Na-MOFs. Further investigations demonstrate that HIAM-111 is capable of separating C 2 H 2 /CO 2 and purifying C 2 H 4 directly from C 2 H 4 /C 2 H 2 /C 2 H 6 with high adsorption capacities. The current work may shed light on the rational design of robust and porous MOFs based on alkali metals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advanced technology lightweight fuel cell program

The potential of the alkaline electrolyte fuel cell as the power source in a multi hundred kilowatt orbital energy storage system was studied. The total system weight of an electrolysis cell energy storage system was determined. The tests demonstrated: (1) the performance stability of a platinum on carbon anode catalyst configuration after 5000 hours of testing has no loss in performance; (2) capability of the alkaline fuel cell to operate to a cyclical load profile; (3) suitability of a lightweight graphite electrolyte reservoir plate for use in the alkaline fuel cell; (4) long life potential of a hybrid polysulfone cell edge frame construction; and (5) long term stability of a fiber reinforced potassium titanate matrix structure. The power section tested operates with passive water removal eliminating the requirement for a dynamic hydrogen pump water separator thereby allowing a powerplant design with reduced weight, lower parasite power, and a potential for high reliability and extended endurance. It is concluded that two perovskites are unsuitable for use as a catalyst or as a catalyst support at the cathode of an alkaline fuel cell.

Martin, R. E.↗

The MESUR Mission

The MESUR mission will place a network of small, robust landers on the Martian surface, making a coordinated set of observations for at least one Martian year. MESUR presents some major challenges for development of instruments, instrument deployment systems, and on board data processing techniques. The instrument payload has not yet been selected, but the straw man payload is (1) a three-axis seismometer; (2) a meteorology package that senses pressure, temperature, wind speed and direction, humidity, and sky brightness; (3) an alphaproton-X-ray spectrometer (APXS); (4) a thermal analysis/evolved gas analysis (TA/EGA) instrument; (5) a descent imager, (6) a panoramic surface imager; (7) an atmospheric structure instrument (ASI) that senses pressure, temperature, and acceleration during descent to the surface; and (8) radio science. Because of the large number of landers to be sent (about 16), all these instruments must be very lightweight. All but the descent imager and the ASI must survive landing loads that may approach 100 g. The meteorology package, seismometer, and surface imager must be able to survive on the surface for at least one Martian year. The seismometer requires deployment off the lander body. The panoramic imager and some components of the meteorology package require deployment above the lander body. The APXS must be placed directly against one or more rocks near the lander, prompting consideration of a micro rover for deployment of this instrument. The TA/EGA requires a system to acquire, contain, and heat a soil sample. Both the imagers and, especially, the seismometer will be capable of producing large volumes of data, and will require use of sophisticated data compression techniques.

Squyres, S. W.↗

A Proposed Role of Aeroelasticity in NASA's New Exploration Vision

On 14 January 2004, NASA received a mandate to return astronauts to the Moon, evolve a sustained presence there, then head out into the solar system to Mars and perhaps beyond. This new space exploration initiative directs NASA to develop human and robotic technologies that can deliver payloads larger than Apollo to the Moon, to Mars, and bring astronauts and samples safely back to Earth at costs much lower than Apollo. These challenges require creative aerospace systems. On proposed technology for safely delivering payloads to the surface of Mars and returning samples to Earth involves deployed flexible and inflatable decelerators for atmospheric entry. Because inflatable decelerators provide the entry vehicle more drag surface area at smaller mass than traditional ablative devices, this class of decelerators can potentially accomodate larger mass payloads. The flexibility of these lightweight aeroshells can pose both vehicle and aeroelastic stability problems if not properly designed for the expected flight regimes. Computational tools need to be developed for modelling the large and nonlinear deformations of these highly flexible structures. Unlike wind tunnel testing, an integrated and efficient aeroelastic analysis tool can explore the entire flight environment. This paper will provide some background on flexible deployable decelerators, survey the current state of technology and outline the proposed development of an aeroelastic analysis and capability.

Bartels, Robert E.↗

In-Vacuum Photogrammetry of a Ten-Meter Square Solar Sail

Solar sailing is a promising, future in-space propulsion method that uses the small force of reflecting sunlight to accelerate a large, reflective membrane without expendable propellants. One of two solar sail configurations under development by NASA is a striped net approach by L'Garde, Inc. This design uses four inflatably deployed, lightweight booms supporting a network of thin strings onto which four quadrants of ultrathin aluminized membranes are attached. The NASA Langley Research Center (LaRC) provided both experimental and analytical support to L'Garde for validating the structural characteristics of this unique, ultralightweight spacecraft concept. One of LaRC's responsibilities was to develop and apply photogrammetric methods to measure sail shape. The deployed shape provides important information for validating the accuracy of finite-element modeling techniques. Photogrammetry is the science and art of calculating 3D coordinates of targets or other distinguishing features on structures using images. A minimum of two camera views of each target is required for 3D determination, but having four or more camera views is preferable for improved reliability and accuracy. Using retroreflective circular targets typically provides the highest measurement accuracy and automation. References 3 and 4 provide details of photogrammetry technology, and reference 5 discusses previous experiences with photogrammetry for measuring gossamer spacecraft structures such as solar sails. This paper discusses the experimental techniques used to measure a L Garde 10-m solar sail test in vacuum with photogrammetry. The test was conducted at the NASA-Glenn Space Power Facility (SPF) located at Plum Brook Station in Sandusky, Ohio. The SPF is the largest vacuum chamber in the United States, measuring 30 m in diameter by 37 m in height. High vacuum levels (10(exp -6) torr) can be maintained inside the chamber, and cold environments (-195 C) are possible using variable-geometry cryogenic cold walls. This test used a vacuum level of approximately 1 torr (sufficient for structural static/dynamic characterization) and instead of using the cryogenic cold walls, used local LN2 cold plates underneath each of the four cold-rigidizable solar sail booms instead.

Pappa, Richard S.↗

Structures, Design and Test: Materials

NASA Marshall has developed a technology that combines a film/adhesive laydown module with fiber placement technology to enable the processing of composite prepreg tow/tape and films, foils, or adhesives on the same placement machine. The deve!opment of this technology grew out of NASA's need for lightweight, permeation-resistant cryogenic propellant tanks.

Source record↗

A One-Piece Lunar Regolith Bag Garage Prototype

Shelter structures on the moon, even in early phases of exploration, should incorporate lunar materials as much as possible. This Technical Memorandum details the design and construction of a prototype for a one-piece regolith bag unpressurized garage concept and a materials testing program to investigate six candidate fabrics to learn how they might perform in the lunar environment. The conceptualization was that a lightweight fabric form be launched from Earth and landed on the lunar surface to be robotically filled with raw lunar regolith. Regolith bag fabric candidates included: Vectran(TM), Nextel(TM), Gore PTFE Fabric(TM), Zylon(TM), Twaron(TM), and Nomex(TM). Tensile (including post radiation exposure), fold, abrasion, and hypervelocity impact testing were performed under ambient conditions, and also performed under cold and elevated temperatures. In some cases, Johnson Space Center lunar simulant (JSC-1) was used in conjunction with testing. A series of preliminary structures was constructed during final prototype design based on the principles of the classic masonry arch. The prototype was constructed of Kevlar(TM) and filled with vermiculite. The structure is free-standing, but has not yet been load tested. Future plans would be to construct higher fidelity prototypes and to conduct appropriate tests of the structure.

Smithers, G. A.↗

Synergistic enhancement of nanocellulose foam with dual in situ mineralization and crosslinking reaction

Cellulose nanocrystals (CNCs) foams have recently gained research interests because they are renewable, abundant, biodegradable and exhibit high surface area. However, the application of CNCs-based foams is still challenging, which is attributed to its lack of effective entanglements between the CNCs particles, thus lowering foam properties. In this study, a synergistic enhancement strategy was proposed, based on the in situ mineralization with hydroxyapatite (HAP) layer onto the CNCs surface, followed by a chemical crosslinking reaction. The physical and chemical structures of the composites were analyzed with SEM, STEM, XRD, FTIR, and TGA. By controlling the amount of coated HAP and the crosslinker, it is possible to manufacture a series of CNCs-based foams that are lightweight (50–75 mg/cm 3 ), highly porous (~90%) with high water absorption (>1300%) and outstanding mechanical strength properties (as high as 1.37 MPa). Moreover, our study further indicated that these CNCs/HAP materials could increase the proliferation of rat osteoblast cells. The method developed in this study presents a novel approach to design improved networked CNCs foam, which has the potential to be used in thermal-retardant material, wastewater treatment, tissue engineering, and personal care applications.

59 BASIC BIOLOGICAL SCIENCES↗

Waveguide submillimeter mixers

A waveguide Schottky barrier diode mixer, which in preliminary tests has yielded a single sideband receiver noise temperature of 4300 K at 692 GHz, when cooled to 77 K is presented. Further refinements and operation at 20 K should produce a significant improvement in performance. From a system point of view, the very high efficiency of the radiation pattern produced by the conical feedhorn with cylindrical corrector mirror enhances the effective sensitivity by a factor of 1.5 to 2 compared to open-structure corner-reflector systems. A second-harmonic mixer for 557 GHz, also in the fundamental mode rectangular waveguide was developed. When combined with a frequency-tripled Gunn oscillator, this makes an extremely compact and lightweight submillimeter radiometer.

Goldsmith, Paul F.↗

Telescope structures - An evolutionary overview

A development history is presented for telescope structural support materials, design concepts, equatorial and altazimuthal orientational preferences, and mechanical control system structural realizations. In the course of 50 years after Galileo, the basic configurations of all reflecting telescopes was set for the subsequent 300 years: these were the Cassegrain, Gregorian, and Newtonian designs. The challenge of making a lightweight ribbed pyrex glass primary mirror for the 5-m Palomar telescope was met by von Karman's use of finite element analysis. Attention is given to the prospects for a 20-m deployable space-based reflecting telescope.

Meinel, Aden B.↗

Recent Advances in Near-Net-Shape Fabrication of Al-Li Alloy 2195 for Launch Vehicles

Recent applications in launch vehicles use 2195 processed to Super Lightweight Tank specifications. Potential benefits exist by tailoring heat treatment and other processing parameters to the application. Assess the potential benefits and advocate application of Al-Li near-net-shape technologies for other launch vehicle structural components. Work with manufacturing and material producers to optimize Al-Li ingot shape and size for enhanced near-net-shape processing. Examine time dependent properties of 2195 critical for reusable applications.

Wagner, John↗

Lithium-Air Cell Development

Lithium-air (Li-air) primary batteries have a theoretical specific capacity of 11,400 Wh/kg, the highest of any common metal-air system. NASA is developing Li-air technology for a Mobile Oxygen Concentrator for Spacecraft Emergencies, an application which requires an extremely lightweight primary battery that can discharge over 24 hours continuously. Several vendors were funded through the NASA SBIR program to develop Li-air technology to fulfill the requirements of this application. New catalysts and carbon cathode structures were developed to enhance the oxygen reduction reaction and increase surface area to improve cell performance. Techniques to stabilize the lithium metal anode surface were explored. Experimental results for prototype laboratory cells are given. Projections are made for the performance of hypothetical cells constructed from the materials that were developed.

Lithium-air↗

Design Considerations for a Crewed Mars Ascent Vehicle

Exploration architecture studies identified the Mars Ascent Vehicle (MAV) as one of the largest "gear ratio" items in a crewed Mars mission. Because every kilogram of mass ascended from the Martian surface requires seven kilograms or more of ascent propellant, it is desirable for the MAV to be as small and lightweight as possible. Analysis identified four key factors that drive MAV sizing: 1) Number of crew: more crew members require more equipment-and a larger cabin diameter to hold that equipment-with direct implications to structural, thermal, propulsion, and power subsystem mass. 2) Which suit is worn during ascent: Extravehicular Activity (EVA) type suits are physically larger and heavier than Intravehicular Activity (IVA) type suits and because they are less flexible, EVA suits require more elbow-room to maneuver in and out of. An empty EVA suit takes up about as much cabin volume as a crew member. 3) How much time crew spends in the MAV: less than about 12 hours and the MAV can be considered a "taxi" with few provisions for crew comfort. However, if the crew spends more than 12 consecutive hours in the MAV, it begins to look like a Habitat requiring more crew comfort items. 4) How crew get into/out of the MAV: ingress/egress method drives structural mass (for example, EVA hatch vs. pressurized tunnel vs. suit port) as well as consumables mass for lost cabin atmosphere, and has profound impacts on surface element architecture. To minimize MAV cabin mass, the following is recommended: Limit MAV usage to 24 consecutive hours or less; discard EVA suits on the surface and ascend wearing IVA suits; Limit MAV functionality to ascent only, rather than dual-use ascent/habitat functions; and ingress/egress the MAV via a detachable tunnel to another pressurized surface asset.

Rucker, Michelle A.↗

Dynamics and Control of Orbiting Space Structures NASA Advanced Design Program (ADP)

The report summarizes the advanced design program in the mechanical engineering department at Vanderbilt University for the academic years 1994-1995 and 1995-1996. Approximately 100 students participated in the two years of the subject grant funding. The NASA-oriented design projects that were selected included lightweight hydrogen propellant tank for the reusable launch vehicle, a thermal barrier coating test facility, a piezoelectric motor for space antenna control, and a lightweight satellite for automated materials processing. The NASA supported advanced design program (ADP) has been a success and a number of graduates are working in aerospace and are doing design.

Cruse, T. A.↗

Structural Modeling of a Five-Meter Thin Film Inflatable Antenna/Concentrator With Rigidized Support Struts

Dynamic characterization of a non-rigidized thin film inflatable antenna/solar concentrator structure with rigidized composite support struts is described in detail. A two-step finite element modeling approach in MSC/NASTRAN is utilized, consisting of: (1) a nonlinear static pressurization procedure used to obtain the updated stiffness matrix, and (2) a modal "restart" eigen solution that uses the modified stiffness matrix. Unique problems encountered in modeling of this large 5-m lightweight inflatable are identified, including considerable difficulty in obtaining convergence in the nonlinear pressurization solution. It was found that the extremely thin polyimide film material (.001 in or I mil) presents tremendous problems in obtaining a converged solution when internal pressure loading is applied. It was concluded that the ratios of film thickness to other geometric dimensions such as torus cross-sectional and ring diameter and lenticular diameter are the critical parameters for convergence of the pressurization procedure. Comparison of finite element predictions for frequency and mode shapes with experimental results indicated reasonable agreement considering the complexity of the structure, the film-to-air interaction, and the nonlinear material properties of the film. It was also concluded that analysis should be done using different finite element to codes to determine if a more robust and stable solution can be obtained.

Smalley, Kurt B.↗

Lightweight Integrated Optical Sensor for Atmospheric Measurements on Mobile Platforms

The goal of the Phase I program was to develop a novel open path sensor platform technology based on integration of semiconductor waveguides with efficient optoelectronic components on a monolithic platform. The successful Phase I effort resulted in demonstration of a novel optical resonator structure based on semiconductor high contrast gratings (HCGs) that will enable implementation of an ultra-compact, low-power gas sensor suitable for use on mobile platforms. Extensive numerical modeling was performed to design a device optimized for measuring CO2 at a wavelength for which a laser was available for proof of concept. Devices were fabricated and tested to match the target wavelength, angle, and operating temperature. This demonstration is the first implementation of HCGs at the wavelengths of interest and shows the flexibility of the proposed architecture for gas sensing applications. The measured cavity Q was lower than anticipated due to fabrication process challenges. The PSI and UC Berkeley team has identified solutions to these challenges and will produce optimized devices in a Phase II program where a prototype sensor will be fabricated and tested.

54 ENVIRONMENTAL SCIENCES↗