Laboratory measurements of electromagnetic properties of atmospheric gases at millimeter wavelengths.
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Several models for the atmosphere of Titan have been investigated, taking into account various combinations of neon and argon. The investigation shows that the addition of large amounts of Ne and/or Ar will substantially reduce the hydrogen abundance required for a given greenhouse effect. The fact that a large amount of neon should be present if the atmosphere is a relic of the solar nebula is an especially attractive feature of the models, because it is hard to justify appropriate abundances of other enhancing agents.
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A molecular beam time-of-flight technique is studied as a means of determining surface stay times for physical adsorption. The experimental approach consists of pulsing a molecular beam, allowing the pulse to strike an adsorbing surface and detecting the molecular pulse after it has subsequently desorbed. The technique is also found to be useful for general studies of adsorption under nonequilibrium conditions including the study of adsorbate-adsorbate interactions. The shape of the detected pulse is analyzed in detail for a first-order desorption process. For mean stay times, tau, less than the mean molecular transit times involved, the peak of the detected pulse is delayed by an amount approximately equal to tau. For tau much greater than these transit times, the detected pulse should decay as exp(-t/tau). However, for stay times of the order of the transit times, both the molecular speed distributions and the incident pulse duration time must be taken into account.
Equilibrium thermodynamic properties and species concentrations for carbon dioxide are tabulated for moving, standing, and reflected shock waves. Initial pressures range from 6.665 to 6665 N/sq m (0.05 to 50.0 torr), and temperatures from 2,000 to over 80,000K. In this study, 20 molecular and atomic species were considered.
Two areas of research are briefly summarized. The first is concerned with calculating the conductivity of a slightly ionized gas. A method is proposed which involves an expansion of the Boltzmann collision operator (of the electron distribution function, involving the neutral gas-electron interactions) in powers of the electron-gas mass ratio. The second area of investigation focuses on the problem of a radio wave propagating through the interplanetary medium, taking account of the decreasing plasma density with distance from the sun.
A fluidic oscillator was investigated for use in measuring fuel-air ratios in hydrocarbon combustion processes. The oscillator was operated with dry exhaust gas from an experimental combustor burning ASTM A-1 fuel. Tests were conducted with fuel-air ratios between 0.015 and 0.031. Fuel-air ratios determined by oscillator frequency were within 0.001 of the values computed from separate flow measurements of the air and fuel.
The surface chemistry of Apollo 17 lunar fines samples 74220 (the orange soil) and 74241 (the gray control soil) has been studied by measuring the adsorption of nitrogen, argon, and oxygen (all at 77 K) and also water vapor (at 20 or 22 C). In agreement with results for samples from other missions, both samples had low initial specific surface areas, consisted of nonporous particles, and were attacked by water vapor at high relative pressure to give an increased specific surface area and create a pore system which gave rise to a capillary condensation hysteresis loop in the adsorption isotherms. In contrast to previous samples, both of the Apollo 17 soils were partially hydrophobic in their initial interaction with water vapor (both samples were completely hydrophilic after the reaction with water). The results are consistent with formation at high temperatures without subsequent exposure to significant amounts of water.
Experiments using simulated solar radiation in a chamber, with a controlled atmospheric pressure near 1 atmosphere, were conducted to evaluate O3 production. The effects of CO and H2O were analyzed to determine if the CO and H2O addition could reduce NO destruction of O3. The results show that NO is destroyed while destroying O3.
Quantitative efforts to assess the surface properties of lunar fines, particularly water induced porosity are discussed. Data show that: (1) changes induced in lunar fines are not visible in high energy electron micrographs, (2) scanning micrographs show no change in particle size distribution as a result of reaction with water, (3) water induced changes are internal to the particles themselves, (4) normal laboratory atmosphere blocks alteration reaction with water, and (5) surface properties of mature lunar soils appear to be almost independent of chemical composition and mineralogy, but there are some variations in their reactivity toward water.
The refractive index change in a collisionless gas is evaluated from the Stark shifts of the rotational energy levels that arise from the polarizability anisotropy. For the limit of an extremely short-duration excitation, a multilevel coherent effect resulted in delayed refractive index bursts. Both stationary and transient responses of this birefringence to an optical field were considered for symmetric top molecules, with particular emphasis on the special case of linear molecules.
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Surface properties of lunar fines samples from the Apollo 12, 14, and 16 missions have been investigated by studying the adsorption of nitrogen, argon, oxygen, carbon monoxide (all at 77 K), and water vapor (at 20 or 22 C) on the samples. Initially the samples were all nonporous and had a uniformly low specific surface area (0.3 to 0.6 sq m/g). Water interacts strongly with the surface of lunar fines, chemisorbing at low pressures followed by a massive adsorption at high pressures. Nitrogen adsorption measurements after the interaction with water showed that the surface properties had undergone a severe alteration as a result of the attack by water vapor. This alteration consisted of a marked increase in the specific surface area and the creation of a pore system. The results are interpreted on the basis of a penetration of water into the damage tracks.
The Raman scattering technique has been applied to investigate the effects of fluid undercutting in a simulation of the fluid-piston concept for wind-tunnel design. Measurements of the structure of the driver-driven gas interface and of the effect of undercutting on test duration were performed. Tests were conducted over a Froude number range of 0.0021 to 0.526 at driver-to-driven gas density ratios of 1.103 and 1.573. The effects of inlet design, test-channel inclination angle, and pretest pressurization were also examined. The results are compared with shadowgraph and pressure measurements to illustrate the characteristics of the Raman technique and to explain the discrepancy between the shadowgraph and pressure results.