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At least 1,243 records · Page 69

Fluidized-bed reactor modeling for production of silicon by silane pyrolysis

An ideal backmixed reactor model (CSTR) and a fluidized bed bubbling reactor model (FBBR) were developed for silane pyrolysis. Silane decomposition is assumed to occur via two pathways: homogeneous decomposition and heterogeneous chemical vapor deposition (CVD). Both models account for homogeneous and heterogeneous silane decomposition, homogeneous nucleation, coagulation and growth by diffusion of fines, scavenging of fines by large particles, elutriation of fines and CVD growth of large seed particles. At present the models do not account for attrition. The preliminary comparison of the model predictions with experimental results shows reasonable agreement. The CSTR model with no adjustable parameter yields a lower bound on fines formed and upper estimate on production rates. The FBBR model overpredicts the formation of fines but could be matched to experimental data by adjusting the unkown jet emulsion exchange efficients. The models clearly indicate that in order to suppress the formation of fines (smoke) good gas-solid contacting in the grid region must be achieved and the formation of the bubbles suppressed.

Dudukovic, M. P.↗

Numerical analysis of confined recirculating gas-solid turbulent flows

Particle dispersion in confined recirculating turbulent flows has been investigated numerically. The present computational scheme utilizes Eulerian forms of the governing equations and allows two-way coupling between gas and solid phases. A recently developed two-phase closure model based on the multiple-scale turbulence model was used for the estimation of turbulent viscosities and diffusivities. For the particle size and loading considered in this study, the effect of particulate phase on the conveying gas is small, the nonequilibrium between the two phases is significant. Effects of recirculation, expanded chamber size and secondary annular jet momentum on the particle mixing rate are also investigated. In general, the present numerical results are in reasonably good agreement with the available experimental data.

Chen, C. P.↗

Modified reaction mechanism of aerated n-dodecane liquid flowing over heated metal tubes

The degradation mechanism of the n-dodecane was studied using a modified jet fuel thermal oxidation tester containing a sample withdrawal system as a reaction vessel. The reaction products were identified using gas chromatography and mass spectorometry. The soluble products were found to consist mainly of C5-C10 n-alkanes and 1-alkenes, C7-C10 aldehydes, tetrahydrofuran derivatives, dodecanol and dodecanone isomers, dodecyl hydroperoxide (ROOH) decomposition products, and C24 alkane isomers. The data from the experiments agreed with those of Hazlett et al. (1977). It was found that alkyl peroxide radical reactions dominate in the autooxidation temperature regime (at T not above 300 C); the dominant path is for the alkyl peroxyl radical to react bimolecularly with fuel to yield primarily alkyl hydroperoxides. The alkyl peroxide radical also undergoes self-termination and unimolecular isomerization and decomposition reactions, to yield smaller amounts of C12 alcohol plus ketone products and tetrahydrofuran derivatives, respectively.

Reddy, K. T.↗

Analysis, Verification, and Application of Equations and Procedures for Design of Exhaust-pipe Shrouds

Investigations were made to develop a simplified method for designing exhaust-pipe shrouds to provide desired or maximum cooling of exhaust installations. Analysis of heat exchange and pressure drop of an adequate exhaust-pipe shroud system requires equations for predicting design temperatures and pressure drop on cooling air side of system. Present experiments derive such equations for usual straight annular exhaust-pipe shroud systems for both parallel flow and counter flow. Equations and methods presented are believed to be applicable under certain conditions to the design of shrouds for tail pipes of jet engines.

HEAT EXCHANGERS, SHROUDED↗

(abstract) A Test of the Theoretical Models of Bipolar Outflows: The Bipolar Outflow in Mon R2

We report some results of a study of the massive bipolar outflow in the central region of the relatively nearby giant molecular cloud Monoceros R2. We make a quantative comparison of our results with the Shu et al. outflow model which incorporates a radially directed wind sweeping up the ambient material into a shell. We find that this simple model naturally explains the shape of this thin shell. Although Shu's model in its simplest form predicts with reasonable parameters too much mass at very small polar angles, as previously pointed out by Masson and Chernin, it provides a reasonable good fit to the mass distribution at larger polar angles. It is possible that this discrepancy is due to inhomogeneities of the ambient molecular gas which is not considered by the model. We also discuss the constraints imposed by these results on recent jet-driven outflow models.

bipolar outflows giant molecular cloud Monoceros R↗

VLA Ammonia Observations of IRAS 16253-2429: A Very Young and Low Mass Protostellar System

IRAS l6253-2429. the source of the Wasp-Waist Nebula seen in Spitzer IRAC images, is an isolated very low luminosity ("VeLLO") Class 0 protostar in the nearby rho Ophiuchi cloud. We present VLA ammonia mapping observations of the dense gas envelope feeding the central core accreting system. We find a flattened envelope perpendicular to the outflow axis, and gas cavities that appear to cradle the outflow lobes as though carved out by the flow and associated (apparently precessing) jet. Based on the NH3 (1,1) and (2,2) emission distribution, we derive the mass, velocity fields and temperature distribution for the envelope. We discuss the combined evidence for this source as possibly one of the youngest and lowest mass sources in formation yet known.

Wiseman, Jennifer J.↗

Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/Hartley-2

We report measurements of eight primary volatiles (H2O, HCN, CH4, C2H6, CH3OH, C2H2, H2CO, and NH3) and two product species (OH and NH2) in comet lO3P/Hartley-2 using high dispersion infrared spectroscopy. We quantified the long- and short-term behavior of volatile release over a three-month interval that encompassed the comet's close approach to Earth, its perihelion passage, and flyby of the comet by the Deep Impact spacecraft during the EPOXI mission. We present production rates for individual species, their mixing ratios relative to water, and their spatial distributions in the coma on multiple dates. The production rates for water, ethane, HCN, and methanol vary in a manner consistent with independent measures of nucleus rotation, but mixing ratios for HCN, C2H6, & CH3OH are independent of rotational phase. Our results demonstrate that the ensemble average composition of gas released from the nucleus is well defined, and relatively constant over the three-month interval (September 18 through December 1,7). If individual vents vary in composition, enough diverse vents must be active simultaneously to approximate (in sum) the bulk composition of the nucleus. The released primary volatiles exhibit diverse spatial properties which favor the presence of separate polar and apolar ice phases in the nucleus, establish dust and gas release from icy clumps, and from the nucleus, and provide insights into the driver for the cyanogen (CN) polar jet. The spatial distributions of C2H6 & HCN along the near-polar jet (UT 19.5 October) and nearly orthogonal to it (UT 22.5 October) are discussed relative to the origin of CN. The ortho-para ratio (OPR) of water was 2.85 +/- 0.20; the lower bound (2.65) defines T(sub spin) > 32 K. These values are consistent with results returned from ISO in 1997 .

Mumma, M. J.↗

Extremely Low Mass: The Circumstellar Envelope of a Potential Proto-Brown Dwarf

What is the environment for planet formation around extremely low mass stars? Is the environment around brown dwarfs and extremely low mass stars conducive and sufficiently massive for planet production? The determining conditions may be set very early in the process of the host object's formation. IRAS 16253-2429, the source of the Wasp-Waist Nebula seen in Spitzer IRAC images, is an isolated, very low luminosity ("VeLLO") Class 0 protostar in the nearby rho Ophiuchi cloud. We present VLA ammonia mapping observations of the dense gas envelope feeding the central core accreting system. We find a flattened envelope perpendicular to the outflow axis, and gas cavities that appear to cradle the outflow lobes as though carved out by the flow and associated (apparently precessing) jet, indicating environmental disruption. Based on the NH3 (1,1) and (2,2) emission distribution, we derive the mass, velocity fields and temperature distribution for the envelope. We discuss the combined evidence for this source to be one of the youngest and lowest mass sources in formation yet known, and discuss the ramifications for planet formation potential in this extremely low mass system.

Wiseman, Jennifer↗

The Quest for an OCO (Orbiting Carbon Observatory) Re-Flight

The objective of the OCO (Orbiting Carbon Observatory) mission was to make the first space-based measurements of atmospheric carbon dioxide with the accuracy needed to quantify sources and sinks of this important greenhouse gas. Unfortunately, the observatory was lost as a result of a launch vehicle failure on 24 February 2009. The JPL (Jet Propulsion Laboratory) was directed to assess the options for the re-flight of the OCO instrument and recovery of the carbon-related measurement, and to understand and quantitatively assess the cost, schedule, and technical and programmatic risks of the identified options. The two most likely solutions were (1) a shared platform with the TIRS (Thermal Infrared Sensor) instrument and (2) a dedicated OSC (Orbital Sciences Corporation) LEOStar-2 spacecraft bus similar to that utilized for the original OCO mission. A joint OCO-TIRS mission study was commissioned and two specific options were examined. However, each presented technical challenges that would drive cost. It was determined that the best option was to rebuild the OCO observatory to the extent possible including another LEOStar-2 spacecraft bus. This lowest risk approach leverages the original OCO design and provides the shortest path to launch, which is targeted for no later than the February 2013 timeframe.

carbon↗

A Review of Distributed Electric Propulsion Concepts for Air Vehicle Technology

The continuous, yet incremental performance gains in high-efficiency gas turbine engines over the last eight decades has enabled passengers to travel long distances at high speeds. Modern commercial jet transports are so common that most passengers traveling by air today take the innovative developments of jet engine technologies for granted. However, the ever-increasing demands for travel in the 21st century has also brought an increased awareness of the energy and environmental concerns associated with aviation. Due to the forecasted limited supply of petroleum-based fuel sources and the global warming potential associated with emissions of traditional aircraft propulsion systems, the need for environmentally-responsible solutions in aircraft technology has been recognized as a priority in the development of future aircraft configurations.

Hyun Dae Kim↗

Bursting Bubbles from Combustion of Thermoplastic Materials in Microgravity

Many thermoplastic materials in common use for a wide range of applications, including spacecraft, develop bubbles internally as they burn due to chemical reactions taking place within the bulk. These bubbles grow and migrate until they burst at the surface, forceably ejecting volatile gases and, occasionally, molten fuel. In experiments in normal gravity, Kashiwagi and Ohlemiller observed vapor jets extending a few centimeters from the surface of a radiatively heated polymethylmethacrylate (PMMA) sample, with some molten material ejected into the gas phase. These physical phenomena complicated the combustion process considerably. In addition to the non-steady release of volatiles, the depth of the surface layer affected by oxygen was increased, attributed to the roughening of the surface by bursting events. The ejection of burning droplets in random directions presents a potential fire hazard unique to microgravity. In microgravity combustion experiments on nylon Velcro fasteners and on polyethylene wire insulation, the presence of bursting fuel vapor bubbles was associated with the ejection of small particles of molten fuel as well as pulsations of the flame. For the nylon fasteners, particle velocities were higher than 30 cm/sec. The droplets burned robustly until all fuel was consumed, demonstrating the potential for the spread of fire in random directions over an extended distance. The sequence of events for a bursting bubble has been photographed by Newitt et al.. As the bubble reaches the fluid surface, the outer surface forms a dome while the internal bubble pressure maintains a depression at the inner interface. Liquid drains from the dome until it breaks into a cloud of droplets on the order of a few microns in size. The bubble gases are released rapidly, generating vortices in the quiescent surroundings and transporting the tiny droplets. The depression left by the escaping gases collapses into a central jet, which rises with a high velocity and may break up, releasing one or more relatively large drops (on the order of a millimeter in these experiments). A better understanding of bubble development and bursting processes, the effects of bursting behavior on burning rate of the bulk material, and the circumstances under which large droplets are expelled, as well as their trajectories, sizes, and burning rates, is sought through computer modeling compared with experiment.

Butler, K. B.↗

Assessment of Turbulent Combustion Models for Simulating Prechamber Ignition in a Natural Gas Engine

Lean combustion is a promising strategy to increase thermal efficiency in an internal combustion engine, by exploiting a favorable specific heat ratio of the fresh mixture while simultaneously suppressing the heat losses to the cylinder wall. However, unstable ignition and slow flame propagation at fuel-lean conditions lead to large cycle-to-cycle variability and limit the high-efficiency engine operating range. Prechamber ignition is considered an effective concept to extend the lean operating limit, by providing spatially distributed ignition with multiple turbulent flame-jets and enabling a faster combustion rate compared to the conventional spark ignition approach. From a numerical modeling standpoint to date science base and available simulation tools are inadequate to properly understand and predict the combustion processes in prechamber ignited engines. In this paper, conceptually different Reynolds-averaged Navier–Stokes (RANS) combustion models widely adopted in the engine modeling community are used to simulate the ignition and combustion processes in a medium-duty natural gas engine with a prechamber spark-ignition system. Here, a flamelet-based turbulent combustion model, i.e., G-equation, and a multizone well-stirred reactor model are employed for this modeling study. Simulation results are compared with experimental data in terms of in-cylinder pressure and heat release rate. Finally, the analysis of the performance of the two models is carried out to highlight the strengths and limitations of the two evaluated approaches.

42 ENGINEERING↗

Effect of Intense Sound Waves on a Stationary Gas Flame

Intense sound waves with a resonant frequency of 5000 cycles per second were imposed on a stationary propane-air flame issuing from a nozzle. In addition to a slight increase of the flame velocity, a fundamental change both in the shape of the burning zone and in the flow pattern could be observed. An attempt is made to explain the origin of the variations in the flame configuration on the basis of transition at the nozzle from jet flow to potential flow.

FLAME PROPAGATION - EFFECT OF SOUND WAVES↗

The relationship of satellite-inferred stratospheric aerosol extinction to the position of the 50-mb north polar jet stream

The relationship between stratospheric aerosols and the location of the north polar night stratospheric jet stream was investigated for selected periods of four successive winters (1979-1982), using measurements from SAM II (Stratospheric Aerosol Measurement II) and SAGE I (Stratospheric Aerosol and Gas Experiment I) satellite-borne sun photometers and corresponding meteorological observations. Each period investigated included a polar stratospheric warming during which major dynamic meteorological changes are known to have perturbed the structure of the polar vortex. The analysis of variations in aerosol extinction mixing ratio patterns among winters and during major stratospheric warming events within separate winters showed a well-defined positive gradient in extinction mixing ratio and temperature across the jet stream from the cyclonic side to the anticyclonic side at altitudes between 20 and 30 km during each winter period. Estimates of extinction mixing ratio profiles measured near the center of the polar vortex suggest that a gradual subsidence took place within the polar vortex during at least three of the four winter periods.

Livingston, John M.↗

Turning a liability into an asset: creating liquid transportation fuels from CO2, natural gas, or RNG

GTI will be discussing our Cool GTL process, a new low cost versatile integrated modular process which can convert CO2, methane, ethane, and biogas, to gasoline jet and diesel with no wax intermediate product. We have tested Cool GTL at small scale and are beginning tests at larger 2 gallon/day scale for biogas conversion ( with DOE funding). Our ultimate goal is to have several commercial deployments of Cool GTL in a variety of applications running in 5 years. Most exciting is the fact that Cool GTL can totally eliminate Global Warming and produce all the worlds transportation fuel by conversion of the excess CO2 currently in the air to liquid transportation fuels, leading to a modern revolution in the way transportation fuels are produced.

09 BIOMASS FUELS↗

Real-Time Optical Fuel-to-Air Ratio Sensor for Gas Turbine Combustors

The measurement of the temporal distribution of fuel in gas turbine combustors is important in considering pollution, combustion efficiency and combustor dynamics and acoustics. Much of the previous work in measuring fuel distributions in gas turbine combustors has focused on the spatial aspect of the distribution. The temporal aspect however, has often been overlooked, even though it is just as important. In part, this is due to the challenges of applying real-time diagnostic techniques in a high pressure and high temperature environment. A simple and low-cost instrument that non-intrusively measures the real-time fuel-to-air ratio (FAR) in a gas turbine combustor has been developed. The device uses a dual wavelength laser absorption technique to measure the concentration of most hydrocarbon fuels such as jet fuel, methane, propane, etc. The device can be configured to use fiber optics to measure the local FAR inside a high pressure test rig without the need for windows. Alternatively, the device can readily be used in test rigs that have existing windows without modifications. An initial application of this instrument was to obtain time-resolved measurements of the FAR in the premixer of a lean premixed prevaporized (LPP) combustor at inlet air pressures and temperatures as high as 17 atm at 800 K, with liquid JP-8 as the fuel. Results will be presented that quantitatively show the transient nature of the local FAR inside a LPP gas turbine combustor at actual operating conditions. The high speed (kHz) time resolution of this device, combined with a rugged fiber optic delivery system, should enable the realization of a flight capable active-feedback and control system for the abatement of noise and pollutant emissions in the future. Other applications that require an in-situ and time-resolved measurement of fuel vapor concentrations should also find this device to be of use.

Nguyen, Quang-Viet↗

Life-cycle analysis of sustainable aviation fuel production through catalytic hydrothermolysis

Catalytic hydrothermolysis (CH) is a sustainable aviation fuel (SAF) pathway that has been recently approved for use in aircraft fuel production. In alignment with broader sustainable aviation goals, SAF production through CH requires a quantitative assessment of carbon intensity (CI) impacts. In this study, a current-day life-cycle analysis (LCA) was performed on SAF produced via CH to determine the CI. Various oily feedstocks were considered, including vegetable oils (soybean, carinata, camelina and canola) and low-burden oils and greases (corn oil, yellow grease and brown grease). Life-cycle inventory data were collected on all processes within the CH LCA boundary: feedstock cultivation and/or collection, preprocessing, hydrothermal cleanup and CH, biocrude refining, fuel transportation and end use through combustion. Baseline results show that the CH-produced SAF can be generated with CI reductions ranging from 48 to 82% compared with conventional jet fuel. Modest improvements to CI can be achieved through incremental changes to the brown grease CH process, such as relaxing the dewatering specification and implementing renewable natural gas and electricity, which could decrease the CI from 22.9 to 7.9 g CO 2 e/MJ. Total CH fuel production potential was also assessed on the basis of current or near-future feedstock availability and CI. The total biofuel production potential of CH (SAF and renewable fuel co-products) in the US sums to approximately 3487 million gallons per year, with 97% of these volumes having a CI below 50% of that for petroleum jet fuel. The study shows that from an LCA perspective, CH offers a viable SAF pathway that is comparable with existing SAF pathways like hydroprocessed esters and fatty acids.

09 BIOMASS FUELS↗

Heat transfer in gas turbine engines and three-dimensional flows; Proceedings of the Symposium, ASME Winter Annual Meeting, Chicago, IL, Nov. 27-Dec. 2, 1988

The present conference on heat transfer characteristics of gas turbines and three-dimensional flows discusses velocity-temperature fluctuation correlations at the flow stagnation flow of a circular cylinder in turbulent flow, heat transfer across turbulent boundary layers with pressure gradients, the effect of jet grid turbulence on boundary layer heat transfer, and heat transfer characteristics predictions for discrete-hole film cooling. Also discussed are local heat transfer in internally cooled turbine airfoil leading edges, secondary flows in vane cascades and curved ducts, three-dimensional numerical modeling in gas turbine coal combustor design, numerical and experimental results for tube-fin heat exchanger airflow and heating characteristics, and the computation of external hypersonic three-dimensional flow field and heat transfer characteristics.

Elovic, E.↗