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All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Solar radiation on Mars: Update 1991

Detailed information on solar radiation characteristics on Mars are necessary for effective design of future planned solar energy systems operating on the surface of Mars. A procedure and solar radiation related data are presented from which the daily variation of the global, direct beam and diffuse insolation on Mars are calculated. Given the optical depth of the Mars atmosphere, the global radiation is calculated from the normalized net flux function based on multiple wavelength and multiple scattering of the solar radiation. The direct beam was derived from the optical depth using Beer's law, and the diffuse component was obtained from the difference of the global and the direct beam radiation. The optical depths of the Mars atmosphere were derived from images taken of the Sun with a special diode on the cameras used on the two Viking Landers.

Appelbaum, Joseph↗
DOE OSTI2018

Following the Morphological Disruption by an Electrolyte of a Buried Interface

A challenge of broad interest in both materials science and biology is the study of interfaces that are buried within a structure, particularly multilayer structures. Despite the enormous costs of corrosion and many decades of corrosion research, details of the mechanisms of various sorts of corrosion are still not clear, in part due to the difficulty in interrogating the interface between the corroding metal and an organic coating, which is typically used to mitigate corrosion. Generally, the performance of such coatings is evaluated by visual inspection after exposure or by modeling impedance data, which is a process not straightforwardly connected to physical interface structures. "Rocking-curve" X-ray scattering measurements provide a means of probing such interfaces due to the ability of X-rays to penetrate materials. Here, variations in the morphology of an interface between a protective coating and a metal substrate due to exposure to an electrolyte are derived from analysis of rocking-curve data in conjunction with atomic force microscopy imaging of the outer coating surface. The interfaces of cross-linked epoxy coatings with aluminum are irreversibly changed after 12 h of contact between the electrolyte solution and the face of the coating. The character of this change varies with the molecule used to cross-link the coating. Since X-ray off-specular scattering is sensitive to changes on the nanometer scale, it is also able to register interface degradation on time scales shorter than those probed by many other techniques, potentially expediting the evaluation of coatings for protection against degradation of the interface.

36 MATERIALS SCIENCE↗
DOE OSTI2016

A CAREFULLY CHARACTERIZED AND TRACKED TRANS-NEPTUNIAN SURVEY: THE SIZE DISTRIBUTION OF THE PLUTINOS AND THE NUMBER OF NEPTUNIAN TROJANS

The trans-Neptunian objects (TNOs) preserve evidence of planet building processes in their orbital and size distributions. While all populations show steep size distributions for large objects, a relative deficit of Neptunian trojans and scattering objects with diameters of D < 100 km has been detected. We investigated this deficit with a 32 square degree survey, in which we detected 77 TNOs that are brighter than a limiting r-band magnitude of 24.6. Our plutino sample (18 objects in 3:2 mean-motion resonance with Neptune) shows a deficit of D < 100 km objects, rejecting a single power-law size distribution at >99% confidence. Combining our survey with the Canada–France Ecliptic Plane Survey, we perform a detailed analysis of the allowable parameters for the plutino size distribution, including knees and divots. We surmise the existence of 9000 ± 3000 plutinos with an absolute magnitude of H {sub r} ≤ 8.66 and 37000{sub −10000}{sup +12000} with H {sub r} ≤ 10.0 (95% confidence). Our survey also discovered one temporary Uranian trojan, one temporary Neptunian trojan, and one stable Neptunian trojan, for which we estimate populations of 110{sub −100}{sup +500}, 210{sub −200}{sup +900}, and 150{sub −140}{sup +600} with H {sub r} ≤ 10.0, respectively. All three populations are thus less numerous than the main belt asteroids (592 asteroids with H {sub r} ≤ 10.0). With such population sizes, the temporary Neptunian trojans cannot be previously stable trojans diffusing out of the resonance now; they must be recently captured Centaurs or scattering objects. As the bias against the detection of objects grows with larger semimajor axes, our discovery of three 3:1 resonators and one 4:1 resonator adds to the growing evidence that the high-order resonances are far more populated than is typically predicted.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1974

Pioneer 10 ultraviolet photometer observations at Jupiter encounter

A two-channel extreme ultraviolet photometer on Pioneer 10 was used to investigate hydrogen and helium emissions from the atmosphere of Jupiter and emissions associated with the Galilean satellites. The hydrogen Lyman alpha signal observed from Jupiter corresponded to 400 R in brightness. By using the results of Wallace and Hunten (1973), the eddy diffusion coefficient is found to be K = 3 x 10 to the (8 plus or minus 1) power. The He I 584-A emission rate was found to be 5.1 R. The radiative transfer problem for the resonantly scattered He I emissions was investigated in the coherent approximation. With these results, the observed brightness, and the derived eddy diffusion coefficient the He/H2 ratio in the mixing region of the atmosphere was found to be equal to 0.18 minus 0.12 or plus 0.46. Emissions attributed to H I Lyman alpha were found at the orbital radius of Io and appear to be due to resonance scattering by a toroidal cloud of H in orbit around Jupiter.

Carlson, R. W.↗
NASA NTRS1979

Observations of the diffuse interstellar EUV radiation field

Results are reported for observations and a preliminary theoretical analysis of the diffuse interstellar EUV radiation field exhibiting positive measurable fluxes in the wavelength range from 912 to 1150 A. The observations were made with the UV spectrometers on the two Voyager spacecraft, and a spectral half-width of 30 A was obtained. The procedures used in the analysis are described in detail, particularly those relating to the elimination of thermal and cosmic-ray noise, internal instrumental scattering from bright lines, and possible contributions from direct starlight. Measurements in several directions reveal diffuse intensities at 975 A ranging from a maximum of about 10 to the -7th erg/sq cm per (sec sr A) near the galactic plane to an upper limit of 10 to the -8th erg/sq cm per (sec sr A). A comparison of the present measurements with various theoretical predictions and previous measurements indicates reasonable agreement with some theoretical predictions of the interstellar EUV intensity.

Sandel, B. R.↗
DOE OSTI2017

NUMERICAL INTEGRAL OF RESISTANCE COEFFICIENTS IN DIFFUSION

The resistance coefficients in the screened Coulomb potential of stellar plasma are evaluated to high accuracy. I have analyzed the possible singularities in the integral of scattering angle. There are possible singularities in the case of an attractive potential. This may result in a problem for the numerical integral. In order to avoid the problem, I have used a proper scheme, e.g., splitting into many subintervals where the width of each subinterval is determined by the variation of the integrand, to calculate the scattering angle. The collision integrals are calculated by using Romberg’s method, therefore the accuracy is high (i.e., ∼10{sup −12}). The results of collision integrals and their derivatives for −7 ≤ ψ ≤ 5 are listed. By using Hermite polynomial interpolation from those data, the collision integrals can be obtained with an accuracy of 10{sup −10}. For very weakly coupled plasma ( ψ ≥ 4.5), analytical fittings for collision integrals are available with an accuracy of 10{sup −11}. I have compared the final results of resistance coefficients with other works and found that, for a repulsive potential, the results are basically the same as others’; for an attractive potential, the results in cases of intermediate and strong coupling show significant differences. The resulting resistance coefficients are tested in the solar model. Comparing with the widely used models of Cox et al. and Thoul et al., the resistance coefficients in the screened Coulomb potential lead to a slightly weaker effect in the solar model, which is contrary to the expectation of attempts to solve the solar abundance problem.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Water sub-diffusion in membranes for fuel cells

We investigate the dynamics of water confined in soft ionic nano-assemblies, an issue critical for a general understanding of the multi-scale structure-function interplay in advanced materials. We focus in particular on hydrated perfluoro-sulfonic acid compounds employed as electrolytes in fuel cells. These materials form phase-separated morphologies that show outstanding proton-conducting properties, directly related to the state and dynamics of the absorbed water. We have quantified water motion and ion transport by combining Quasi Elastic Neutron Scattering, Pulsed Field Gradient Nuclear Magnetic Resonance, and Molecular Dynamics computer simulation. Effective water and ion diffusion coefficients have been determined together with their variation upon hydration at the relevant atomic, nanoscopic and macroscopic scales, providing a complete picture of transport. We demonstrate that confinement at the nanoscale and direct interaction with the charged interfaces produce anomalous sub-diffusion, due to a heterogeneous space-dependent dynamics within the ionic nanochannels. This is irrespective of the details of the chemistry of the hydrophobic confining matrix, confirming the statistical significance of our conclusions. Our findings turn out to indicate interesting connections and possibilities of crossfertilization with other domains, including biophysics. They also establish fruitful correspondences with advanced topics in statistical mechanics, resulting in new possibilities for the analysis of Neutron scattering data.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Study of Protein Dynamics via Neutron Spin Echo Spectroscopy

Most human body proteins' activity and functionality are related to configurational changes of entire subdomains within the protein crystal structure. The crystal structures build the basis for any calculation that describes the structure or dynamics of a protein, most of the time with strong geometrical restrictions. However, these restrictions from the crystal structure are not present in the solution. The structure of the proteins in the solution may differ from the crystal due to rearrangements of loops or subdomains on the pico to nanosecond time scale (i.e., the internal protein dynamics time regime). This study describes how slow motions on timescales of several tens of nanoseconds can be accessed using neutron scattering. In particular, the dynamical characterization of two major human proteins, an intrinsically disordered protein that lacks a well-defined secondary structure and a classical antibody protein, is addressed by neutron spin echo spectroscopy (NSE) combined with a wide range of laboratory characterization methods. Further insights into protein domain dynamics were achieved using mathematical modeling to describe the experimental neutron data and determine the crossover between combined diffusive and internal protein motions. The extraction of the internal dynamic contribution to the intermediate scattering function obtained from NSE, including the timescale of the various movements, allows further vision into the mechanical properties of single proteins and the softness of proteins in their nearly natural environment in the crowded protein solution.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

Extended linear-in- T resistivity due to electron-phason scattering in moiré superlattices

Due to its incommensurate nature, moiré superlattices host not only acoustic phonons but also another type of soft collective modes called phasons. Here, we investigate the impact of electron-phason scattering on the transport properties of moiré systems. We show that the resistivity can scale linearly with temperature down to temperatures much lower than the Bloch-Grüneisen scale defined by electron kinematics on the Fermi surface. This result stems from the friction between layers, which transfers phason spectral weight to a broad diffusive low-energy peak in the mechanical response of the system. As a result, phason scattering becomes a very efficient channel for entropy production at low temperatures. We also consider the contributions of phasons to thermodynamic properties at low temperatures and find a “metallic-like” linear-in-T behavior for the specific heat, despite the fact that this behavior is due to mechanical and not electronic degrees of freedom. Finally, we discuss the implications of this finding to reports of linear-in-T resistivity in the phase diagram of twisted bilayer graphene.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Analytical model of diffuse reflectance spectrum of skin tissue

We have derived simple analytical expressions that enable highly accurate calculation of diffusely reflected light signals of skin in the spectral range from 450 to 800 nm at a distance from the region of delivery of exciting radiation. The expressions, taking into account the dependence of the detected signals on the refractive index, transport scattering coefficient, absorption coefficient and anisotropy factor of the medium, have been obtained in the approximation of a two-layer medium model (epidermis and dermis) for the same parameters of light scattering but different absorption coefficients of layers. Numerical experiments on the retrieval of the skin biophysical parameters from the diffuse reflectance spectra simulated by the Monte Carlo method show that commercially available fibre-optic spectrophotometers with a fixed distance between the radiation source and detector can reliably determine the concentration of bilirubin, oxy- and deoxyhaemoglobin in the dermis tissues and the tissue structure parameter characterising the size of its effective scatterers. We present the examples of quantitative analysis of the experimental data, confirming the correctness of estimates of biophysical parameters of skin using the obtained analytical expressions. (biophotonics)

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2016

Anion exchange membranes composed of a poly(2,6-dimethyl-1,4-phenylene oxide) random copolymer functionalized with a bulky phosphonium cation

A random copolymer, tris(2,4,6-trimethoxyphenyl) phosphonium functionalized poly(2,6-dimethyl-1,4-phenylene oxide) (PPO-TPQP) was cast from three different solvents: dimethyl sulfoxide (DMSO), ethyl lactate, or a 41:59 vol% mixture of DMSO and ethyl lactate. Solvents were selected via analysis of the Hansen solubility parameters to vary the phase separation of the polymer in the films. An optimized mixture of DMSO and ethyl lactate chosen for film fabrication and this film was contrasted with films cast from the neat constituent solvents. Atomic force microscopy identified domains from nanometer to tens of nanometer sizes, while the light microscopy showed features on the order of micron. SAXS revealed a cation scattering peak with a d-spacing from 7 to 15 A. Trends in conductivity and water diffusion for the membranes vary depending on the solvent from which they are cast. The mixed solvent cast membrane shows a linear Arrhenius behavior indicating fully dissociated cationic/anionic groups, and has the highest bromide conductivity of 3 mS/cm at 95% RH, 90 degrees C. The ethyl lactate cast membrane shows a linear Arrhenius relation in conductivity, but a Vogel-Tamman-Fulcher behavior in its water self-diffusion. While water increases bromide dissociation, water and bromide transport in these films seems to be decoupled. This is particularly true for the film cast from ethyl lactate.

Liu, Ye↗
NASA NTRS2013

Some New Lidar Equations for Laser Pulses Scattered Back from Optically Thick Media Such as Clouds, Dense Aerosol Plumes, Sea Ice, Snow, and Turbid Coastal Waters

I survey the theoretical foundations of the slowly-but-surely emerging field of multiple scattering lidar, which has already found applications in atmospheric and cryospheric optics that I also discuss. In multiple scattering lidar, returned pulses are stretched far beyond recognition, and there is no longer a one-to-one connection between range and return-trip timing. Moreover, one can exploit the radial profile of the diffuse radiance field excited by the laser source that, by its very nature, is highly concentrated in space and collimated in direction. One needs, however, a new class of lidar equations to explore this new phenomenology. A very useful set is derived from radiative diffusion theory, which is found at the opposite asymptotic limit of radiative transfer theory than the conventional (single-scattering) limit used to derive the standard lidar equation. In particular, one can use it to show that, even if the simple time-of-flight-to-range connection is irretrievably lost, multiply-scattered lidar light can be used to restore a unique profiling capability with coarser resolution but much deeper penetration into a wide variety of optical thick media in nature. Several new applications are proposed, including a laser bathymetry technique that should work for highly turbid coastal waters.

turbid water↗
DOE OSTI2014

Relativistic electron precipitation events driven by electromagnetic ion-cyclotron waves

We adopt a canonical approach to describe the stochastic motion of relativistic belt electrons and their scattering into the loss cone by nonlinear EMIC waves. The estimated rate of scattering is sufficient to account for the rate and intensity of bursty electron precipitation. This interaction is shown to result in particle scattering into the loss cone, forming ∼10 s microbursts of precipitating electrons. These dynamics can account for the statistical correlations between processes of energization, pitch angle scattering, and relativistic electron precipitation events, that are manifested on large temporal scales of the order of the diffusion time ∼tens of minutes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Elastic scattering by hot electrons and apparent lifetime of longitudinal optical phonons in gallium nitride

Longitudinal optical (LO) phonons in GaN generated in the channel of high electron mobility transistors (HEMT) are shown to undergo nearly elastic scattering via collisions with hot electrons. The net result of these collisions is the diffusion of LO phonons in the Brillouin zone causing reduction of phonon and electron temperatures. This previously unexplored diffusion mechanism explicates how an increase in electron density causes reduction of the apparent lifetime of LO phonons, obtained from the time resolved Raman studies and microwave noise measurements, while the actual decay rate of the LO phonons remains unaffected by the carrier density. Therefore, the saturation velocity in GaN HEMT steadily declines with increased carrier density, in a qualitative agreement with experimental results.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Insights into the Water Transport Mechanism in Polymeric Membranes from Neutron Scattering

Polymeric membranes are ubiquitous in transport applications including gas separation, water desalination, solid-state batteries, and fuel cells. The transport mechanism in certain classes of membranes is well understood. It is generally believed that polymeric membranes used in gas separation follow the solution-diffusion model. However, the transport mechanism in other membranes such as the ones used in water desalination is less clear as both the solution-diffusion and hydrodynamic models have been proposed. In this contribution, we study the structure as well as the water and polymer dynamics of several polymeric membranes using small-angle and quasi-elastic neutron scattering. We demonstrate that on the scale of a few nanometers, water appears to diffuse through a desalination membrane at a rate comparable to bulk water, while water diffuses at a rate that is a factor of 2 slower in an anion-exchange membrane. These results illustrate the importance of studying both the structure and dynamics of membrane materials and have important implications in understanding the transport mechanisms that differentiate the different types of polymeric membranes.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Simultaneous in Situ X-ray Scattering and Infrared Imaging of Polymer Extrusion in Additive Manufacturing

In situ wide-angle X-ray scattering together with infrared imaging was performed during three-dimensional material extrusion printing and correlated with the development of the crystalline structure and subsequent thermomechanical properties. Identical samples were printed with nozzle motion either along the short axis or the long axis. The short axis mode had higher thermal retention, which resulted in later onset of crystal structure. The longer time spent at temperatures between the glass transition and the melting point produced samples with higher degree of crystallinity but also significantly increased brittleness. The tracer diffusion coefficient D ( T ), together with its temperature dependence, was measured using neutron reflectivity, and the total interdiffusion length between filaments was then calculated using D ( T ) for each temperature point, as determined by the measured thermal profiles. This allowed us to define the time/temperature plane that yielded the minimum diffusion length ΔL that provides mechanical integrity of the printed features ( ΔL less than the radius of gyration of the poly(l-lactide)). The model was probed by printing structures at four nozzle temperatures and measuring the time dependence of the thermal profiles at filaments in the horizontal and vertical positions. In conclusion, the data indicated that the thermal retention was anisotropic, where higher values were obtained in the horizontal plane. Mechanical measurements indicated large differential increases in the torsional strength, corresponding to the direction with increased thermal retention.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Observation of two different fractal structures in nanoparticle, protein and surfactant complexes

Small angle neutron scattering has been carried out from a complex of nanoparticle, protein and surfactant. Although all the components are similarly (anionic) charged, we have observed strong interactions in their complex formation. It is characterized by the coexistence of two different mass fractal structures. The first fractal structure is originated from the protein and surfactant interaction and second from the depletion effect of first fractal structure leading the nanoparticle aggregation. The fractal structure of protein-surfactant complex represents to bead necklace structure of micelle-like clusters of surfactant formed along the unfolded protein chain. Its fractal dimension depends on the surfactant to protein ratio (r) and decreases with the increase in r. However, fractal dimension of nanoparticle aggregates in nanoparticle-protein complex is found to be independent of protein concentration and governed by the diffusion limited aggregation like morphology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Region-of-interest diffuse optical tomography system

Diffuse optical tomography (DOT) using near-infrared light is a promising tool for non-invasive imaging of deep tissue. This technique is capable of quantitative reconstruction of absorption (μ{sub a}) and scattering coefficient (μ{sub s}) inhomogeneities in the tissue. The rationale for reconstructing the optical property map is that the absorption coefficient variation provides diagnostic information about metabolic and disease states of the tissue. The aim of DOT is to reconstruct the internal tissue cross section with good spatial resolution and contrast from noisy measurements non-invasively. We develop a region-of-interest scanning system based on DOT principles. Modulated light is injected into the phantom/tissue through one of the four light emitting diode sources. The light traversing through the tissue gets partially absorbed and scattered multiple times. The intensity and phase of the exiting light are measured using a set of photodetectors. The light transport through a tissue is diffusive in nature and is modeled using radiative transfer equation. However, a simplified model based on diffusion equation (DE) can be used if the system satisfies following conditions: (a) the optical parameter of the inhomogeneity is close to the optical property of the background, and (b) μ{sub s} of the medium is much greater than μ{sub a} (μ{sub s} > > μ{sub a}). The light transport through a highly scattering tissue satisfies both of these conditions. A discrete version of DE based on finite element method is used for solving the inverse problem. The depth of probing light inside the tissue depends on the wavelength of light, absorption, and scattering coefficients of the medium and the separation between the source and detector locations. Extensive simulation studies have been carried out and the results are validated using two sets of experimental measurements. The utility of the system can be further improved by using multiple wavelength light sources. In such a scheme, the spectroscopic variation of absorption coefficient in the tissue can be used to arrive at the oxygenation changes in the tissue.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗