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At least 1,243 records · Page 69

Screening materials for toxicity of pyrolysis gases

The USF-NASA toxicity screening test method is primarily intended to indicate which materials are more toxic under specific test conditions, and not necessarily to explain why they are more toxic. Analysis of the test data obtained, however, in the light of the experience accumulated, can provide some insight into the mechanisms of toxicity and the importance of specific toxicants. The use of free-field movement offers both advantages and disadvantages relative to other behavioral paradigms, and the use of Swiss Webster mice offers both advantages and disadvantages relative to other species and strains.

Hilado, C. J.↗

Evidence for Phanerozoic reactivation of the Najd Fault System in AVHRR, TM, and SPOT images of central Arabia

SPOT stereoscopic and TM multispectral images support evidence in AVHRR thermal-IR images of a major unmapped shear zone in Phanerozoic cover rocks southeast of the ancient Najd Fault System in the Arabian Shield. This shear zone and faults of the Najd share a common alignment, orientation, and sinistral sense of movement. These similarities suggest a 200-km extension of the Najd Fault System and reactivation since it formed in the late Precambrian. Topographic and lithologic features in the TM and SPOT data along one of three faults inferred from the AVHRR data indicate sinistral offsets up to 2.5 km, en echelon folds and secondary faults like those predicted by models of left-lateral strike-slip faulting. The age of the affected outcrops indicates reactivation of Najd faults in the Cretaceous, judging from TM and SPOT data or in the Tertiary, based on AVHRR data. The total length of the system visible at the surface measures 1300 km. If the Najd Fault System is extrapolated beneath sands of the Empty Quarter to faults of a similar trend in South Yemen, the shear zone would span the Arabian Plate. Furthermore, if extensions into the Arabian Sea bed and into Egypt proposed by others are considered, it would exceed 3000 km.

Andre, Constance G.↗

Transformation of two and three-dimensional regions by elliptic systems

Several reports are attached to this document which contain the results of our research at the end of this contract period. Three of the reports deal with our work on generating surface grids. One is a preprint of a paper which will appear in the journal Applied Mathematics and Computation. Another is the abstract from a dissertation which has been prepared by Ahmed Khamayseh, a graduate student who has been supported by this grant for the last two years. The last report on surface grids is the extended abstract of a paper to be presented at the 14th IMACS World Congress in July. This report contains results on conformal mappings of surfaces, which are closely related to elliptic methods for surface grid generation. A preliminary report is included on new methods for dealing with block interfaces in multiblock grid systems. The development work is complete and the methods will eventually be incorporated into the National Grid Project (NGP) grid generation code. Thus, the attached report contains only a simple grid system which was used to test the algorithms to prove that the concepts are sound. These developments will greatly aid grid control when using elliptic systems and prevent unwanted grid movement. The last report is a brief summary of some timings that were obtained when the multiblock grid generation code was run on the Intel IPSC/860 hypercube. Since most of the data in a grid code is local to a particular block, only a small fraction of the total data must be passed between processors. The data is also distributed among the processors so that the total size of the grid can be increase along with the number of processors. This work is only in a preliminary stage. However, one of the ERC graduate students has taken an interest in the project and is presently extending these results as a part of his master's thesis.

Mastin, C. Wayne↗

Hydrodynamically induced fluid transfer and non-convective double-diffusion in microgravity sliding solvent diffusion cells

Microgravity can provide a diffusion-dominated environment for double-diffusion and diffusion-reaction experiments otherwise disrupted by buoyant convection or sedimentation. In sliding solvent diffusion cells, a diffusion interface between two liquid columns is achieved by aligning two offset sliding wells. Fluid in contact with the sliding lid of the cavities is subjected to an applied shear stress. The momentum change by the start/stop action of the well creates an additional hydrodynamical force. In microgravity, these viscous and inertial forces are sufficiently large to deform the diffusion interface and induce hydrodynamic transfer between the wells. A series of KC-135 parabolic flight experiments were conducted to characterize these effects and establish baseline data for microgravity diffusion experiments. Flow visualizations show the diffusion interface to be deformed in a sinusoidal fashion following well alignment. After the wells were separated again in a second sliding movement, the total induced liquid transfer was determined and normalized by the well aspect ratio. The normalized transfer decreased linearly with Reynolds number from 3.3 to 4.0% (w/v) for Re = 0.4 (Stokes flow) to a minimum of 1.0% for Re = 23 to 30. Reynolds numbers that provide minimum induced transfers are characterized by an interface that is highly deformed and unsuitable for diffusion measurements. Flat diffusion interfaces acceptable for diffusion measurements are obtained with Reynolds numbers on the order of 7 to 10. Microgravity experiments aboard a sounding rocket flight verified counterdiffusion of different solutes to be diffusion dominated. Ground control experiments showed enhanced mixing by double-diffusive convection. Careful selection of experimental parameters improves initial conditions and minimizes induced transfer rates.

Pollmann, Konrad W.↗

ITOS to EDGE "Bridge" Software for Morpheus Lunar/Martian Vehicle

My project Involved Improving upon existing software and writing new software for the Project Morpheus Team. Specifically, I created and updated Integrated Test and Operations Systems (ITOS) user Interfaces for on-board Interaction with the vehicle during archive playback as well as live streaming data. These Interfaces are an integral part of the testing and operations for the Morpheus vehicle providing any and all information from the vehicle to evaluate instruments and insure coherence and control of the vehicle during Morpheus missions. I also created a "bridge" program for Interfacing "live" telemetry data with the Engineering DOUG Graphics Engine (EDGE) software for a graphical (standalone or VR dome) view of live Morpheus nights or archive replays, providing graphical representation of vehicle night and movement during subsequent tests and in real missions.

Hirsh, Robert↗

Application of Advanced Earth Observations and Model Simulations to Improve Air Quality Monitoring in the Hindu-Kush-Himalayan Region

Air pollution is a serious environmental health concern in the Hindu Kush Himalayan (HKH) region of south-central Asia, as rapid industrialization and population growth have led to increased anthropogenic emissions from transportation, residential, industrial, energy, and biomass burning sources. Natural emissions from dust and forest fires are additional sources of air pollutants that can exacerbate air quality in the region. The combination of the complex pollutant mixtures and atmospherically stable weather conditions during the winter monsoon can visibility reductions and hazardous air quality from persistent haze episodes. The Kathmandu Valley is especially vulnerable to extreme haze issues due to the surrounding mountains that restrict air movement and retains pollutants in the atmosphere. This study uses state-of-the-art satellite observations and modeling capabilities in conjunction with ground-based networks to provide a comprehensive data toolkit for advancing air quality monitoring and forecasting decisions in the HKH region. The toolkit includes new generation satellite observations from the TROPOspheric Monitoring Instrument (TROPOMI), Geostationary Environment Monitoring Spectrometer (GEMS), and Advanced Meteorological Imager, which provide high spatiotemporal information on NO2, HCHO, SO2, O3, and aerosol optical depth (AOD). Particulate matter with diameters less than 2.5 micrometers (PM2.5) are derived from the satellite-retrieved AOD using ground-based observations and forecast model data. The satellite observations are also used to initialize and constrain forecast model systems designed for the HKH region. This talk will highlight the performance of the air quality toolkit for enhancing decision-making processes during exceptional air quality events in the region. Note: Presentation includes additional attachment of full presentation with sound and animation (best when viewed as slide show) with runtime of 15 min 32 secs

Aaron Naeger↗

Lab Scale Demonstration of Pipeline Third-Party Damage Classification Using Convolutional Neural Networks

This research aims to propose a simple experiment for third party damage classification problem by generating a dataset of third-party damage events on a laboratory scale utilizing single mode-multi mode-single mode (SMS) fiber acoustic sensor. The sound samples representative of various third-party activities, such as vehicle movements, excavation, and digging, were sourced from open-source databases. These samples were then played through a speaker in proximity to an SMS sensor, and the resultant fiber acoustic vibration data were recorded for each event. This process yielded a collection of 200 samples across 13 distinct third-party events. Convolutional Neural Networks (CNNs) were employed to classify these samples into their respective categories, and an accuracy exceeding 97% was obtained from our results.

Bukka, Sandeep Reddy↗

Lab-Scale Demonstration of Pipeline Third-Party Damage Classification Using Convolutional Neural Networks

This research aims to mitigate the challenges of field tests for classification of third-party damages by generating a dataset of third-party damage events on a laboratory scale utilizing single mode-multi mode-single mode (SMS) fiber acoustic sensor. The sound samples representative of various third-party activities, such as vehicle movements, excavation, and digging, were sourced from open-source databases. These samples were then played through a speaker in proximity to an SMS sensor, and the resultant fiber acoustic vibration data were recorded for each event. This process yielded a collection of 200 samples across 13 distinct third-party events. Convolutional Neural Networks (CNNs) were employed to classify these samples into their respective categories, and an accuracy exceeding 97% was obtained from our results.

Bukka, Sandeep Reddy↗

Exploring dynamic surface processes during silicate mineral (wollastonite) dissolution with liquid cell

Most liquid cell transmission electron microscopy (LC TEM) studies focus on nanoparticles or nanowires, in large part because the preparation and study of materials in this size range is straightforward. By contrast, this is not true for samples in the micrometre size range, in large part because of the difficulties associated with sample preparation starting from a ‘bulk’ material. There are also many advantages inherent to the study of micrometre-sized samples compared to their nanometre-sized counterparts. Here, we present a liquid cell transmission electron study that employed an innovative sample preparation technique using focused ion beam (FIB) milling to fabricate micrometre-sized electron transparent lamellae that were then welded to the liquid cell substrate. This technique, for which we have described in detail all of the fabrication steps, allows for samples having dimensions of several square micrometres to be observed by TEM in situ in a liquid. We applied this technique to test whether we could observe and measure in situ dissolution of a crystalline material called wollastonite, a calcium silicate mineral. More specifically, this study was used to observe and record surface dynamics associated with step and terrace edge movement, which are ultimately linked to the overall rate of dissolution. The wollastonite lamella underwent chemical reactions in pure deionized water at ambient temperature in a liquid cell with a 5-math formulam-spacer thickness. The movement of surface steps and terraces was measured periodically over a period of almost 5 h. Quite unexpectedly, the one-dimensional rates of retreat of these surface features were not constant, but changed over time. In addition, there were noticeable quantitative differences in retreat rates as a function crystallographic orientation, indicating that surface retreat is anisotropic. Several bulk rates of dissolution were also determined (1.6–4.2 • 10 -7 mol m -2 s -1 ) using the rates of retreat of representative terraces and steps, and were found to be within one order of magnitude of dissolution rates in the literature based on aqueous chemistry data.

36 MATERIALS SCIENCE↗

GRACE Follow-On Early In-Flight Challenges

The Gravity Recovery and Climate Experiment (GRACE) Follow-On Mission is a successor to the highly successful GRACE Mission, which operated from 2002-2017. It is a partnership between the National Aeronautics and Space Administration (NASA) and the German Research Center for Geosciences, GeoForschungsZentrum Potsdam (GFZ). Under this partnership, the United States provides the project management, satellites and instruments, Germany provides the launch and mission operations. The partners share responsibilities for producing science data products. GRACE Follow-On, like its predecessor GRACE, consists of twin satellites which fly in a tandem formation at a near polar orbit separated by about 200 km along track. The mission continues the work of GRACE by tracking the movement of water, observing changes in ice sheets and sea level to provide a unique view of Earth’s changing climate. The satellites were launched May 22, 2018 from Vandenberg Air Force Base, in California, on a SpaceX Falcon 9 Rocket. Launch and Early Operations (LEOP) were completed within the first week and on-orbit commissioning proceeded for the next 8 months. The GRACE Follow-On mission is designed to last five years. The mission operations team has had to address several technical challenges early into the planned five-year mission life. The commissioning period was extended by 5 months to successfully address these issues, making it possible for the mission to meet key requirements for delivery and quality of the science data products. This paper will address the challenges faced by GRACE Follow-On and the actions taken by the mission operations team to continue to safely operate the mission.

Witkowski, M.M.↗

Experimental Study of Convective Heating on the Back Face and Payload of a Hypersonic Inflatable Aerodynamic Decelerator (HIAD) Aeroshell

A wind tunnel test program has been conducted to define convective heating environments on the back-face of a Hypersonic Inflatable Aerodynamic Decelerator aeroshell. Wind tunnel testing was conducted at Mach 6 and Mach 10 at unit Reynolds numbers from 0.5×10(exp 6)/ft to 3.9×10(exp 6)/ft on a 6.3088 in diameter aeroshell model. Global heating data were obtained through phosphor thermography on the aeroshell back face, as well as on the payload and the aeroshell front face. For all test conditions, laminar flow was produced on the aeroshell front face, while the separated wake shear layer and aeroshell back-face boundary layer were transitional or turbulent. Along the leeward centerline of the aeroshell back face and payload centerbody, heating levels increased with both free stream Reynolds number and angle of attack. The Reynolds number dependency was due to increasing strength of wake turbulence with Reynolds number. The angle-of-attack dependency was due to movement of the wake-vortex reattachment point on the aeroshell back face. The maximum heating levels on the aeroshell back face and payload were approximately 5% to 6%, respectively, of the aeroshell front-face stagnation point. To allow for extrapolation of the ground test data to flight conditions, the back face and payload heating levels were correlated as a function of aeroshell front-face peak momentum thickness Reynolds numbers.

Hollis, Brian R.↗

Planning of reach-and-grasp movements: effects of validity and type of object information

Individuals are assumed to plan reach-and-grasp movements by using two separate processes. In 1 of the processes, extrinsic (direction, distance) object information is used in planning the movement of the arm that transports the hand to the target location (transport planning); whereas in the other, intrinsic (shape) object information is used in planning the preshaping of the hand and the grasping of the target object (manipulation planning). In 2 experiments, the authors used primes to provide information to participants (N = 5, Experiment 1; N = 6, Experiment 2) about extrinsic and intrinsic object properties. The validity of the prime information was systematically varied. The primes were succeeded by a cue, which always correctly identified the location and shape of the target object. Reaction times were recorded. Four models of transport and manipulation planning were tested. The only model that was consistent with the data was 1 in which arm transport and object manipulation planning were postulated to be independent processes that operate partially in parallel. The authors suggest that the processes involved in motor planning before execution are primarily concerned with the geometric aspects of the upcoming movement but not with the temporal details of its execution.

Cues↗

Advanced Atmospheric Ensemble Modeling Techniques

Ensemble modeling (EM), the creation of multiple atmospheric simulations for a given time period, has become an essential tool for characterizing uncertainties in model predictions. We explore two novel ensemble modeling techniques: (1) perturbation of model parameters (Adaptive Programming, AP), and (2) data assimilation (Ensemble Kalman Filter, EnKF). The current research is an extension to work from last year and examines transport on a small spatial scale (<100 km) in complex terrain, for more rigorous testing of the ensemble technique. Two different release cases were studied, a coastal release (SF6) and an inland release (Freon) which consisted of two release times. Observations of tracer concentration and meteorology are used to judge the ensemble results. In addition, adaptive grid techniques have been developed to reduce required computing resources for transport calculations. Using a 20- member ensemble, the standard approach generated downwind transport that was quantitatively good for both releases; however, the EnKF method produced additional improvement for the coastal release where the spatial and temporal differences due to interior valley heating lead to the inland movement of the plume. The AP technique showed improvements for both release cases, with more improvement shown in the inland release. This research demonstrated that transport accuracy can be improved when models are adapted to a particular location/time or when important local data is assimilated into the simulation and enhances SRNL’s capability in atmospheric transport modeling in support of its current customer base and local site missions, as well as our ability to attract new customers within the intelligence community.

54 ENVIRONMENTAL SCIENCES↗

Crystal Structure and Conformational Dynamics of Pyrococcus furiosus Prolyl Oligopeptidase

Enzymes in the prolyl oligopeptidase family possess unique structures and substrate specificities that are important for their biological activity and for potential biocatalytic applications. In this work, the crystal structures of Pyrococcus furiosus (Pfu) prolyl oligopeptidase (POP) and the corresponding S477C mutant were determined to 1.9 and 2.2 Å resolution, respectively. The wild type enzyme crystallized in an open conformation, indicating that this state is readily accessible, and it contained bound chloride ions and a prolylproline ligand. These structures were used as starting points for molecular dynamics simulations of Pfu POP conformational dynamics. The simulations showed that large-scale domain opening and closing occurred spontaneously, providing facile substrate access to the active site. Movement of the loop containing the catalytically essential histidine into a conformation similar to those found in structures with fully formed catalytic triads also occurred. This movement was modulated by chloride binding, providing a rationale for experimentally observed activation of POP peptidase catalysis by chloride. Thus, the structures and simulations reported in this study, combined with existing biochemical data, provide a number of insights into POP catalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Analysis of land-based CSEM data for CO2 monitoring at Bell Creek, MT

Monitoring subsurface fluid migration is critical to any CO2 injection operation like enhanced oil recovery or carbon storage. The controlled-source electromagnetic (CSEM) method provides a promising low-cost, non-invasive alternative to conventional monitoring methods. To investigate the use of CSEM for monitoring CO2 injection, we are conducting a time-lapse charged well casing CSEM survey at the Bell Creek oil field. There, CO2 is injected into the reservoir for enhanced oil recovery, which also results in incidental carbon storage. From October 2017 to October 2018 we completed three field campaigns, and we plan to complete one more in July 2019. We have analyzed the signal strength and variance of the time-lapse CSEM data. Difference data signal strength well exceeds the standard deviation of the data, and it agrees with estimates of expected signal strength derived from numerical modeling. This analysis indicates that our survey can detect the change in conductivity within the reservoir due to fluid movement.

time-lapse, land CSEM, monitoring, processing↗

A Review of Classical Swine Fever Virus and Routes of Introduction into the United States and the Potential for Virus Establishment

Classical swine fever (CSF) is caused by CSF virus (CSFV) which can be the source of substantial morbidity and mortality events in affected swine. The disease can take one of several forms (acute, chronic, or prenatal) and depending on the virulence of the inoculating strain may result in a lethal infection irrespective of the form acquired. Because of the disease-free status of the United States and the high cost of a viral incursion, a summary of US vulnerabilities for viral introduction and persistence is provided. The legal importation of live animals as well as animal products, byproducts, and animal feed serve as a potential route of viral introduction. Current import regulations are described as are mitigation strategies that are commonly utilized to prevent pathogens, including CSFV, from entering the US. The illegal movement of suids and their products as well as an event of bioterrorism are both feasible routes of viral introduction but are difficult to restrict or regulate. Ultimately, recommendations are made for data that would be useful in the event of a viral incursion. Population and density mapping for feral swine across the United States would be valuable in the event of a viral introduction or spillover; density data could further contribute to understanding the risk of infection in domestic swine. Additionally, ecological and behavioral studies, including those that evaluate the effects of anthropogenic food sources that support feral swine densities far above the carrying capacity would provide invaluable insight to our understanding of how human interventions affect feral swine populations. Further analyses to determine the sampling strategies necessary to detect low levels of antibody prevalence in feral swine would also be valuable.

Veterinary Sciences↗

Sea-surface circulation, sediment transport, and marine mammal distribution, Alaska continental shelf

The author has identified the following significant results. Even though nonsynchronous, the ERTS-1 imagery of November 4, 1972, showed a striking similarity to the ground truth data obtained in late August and September, 1972. The comparison of the images with ground truth data revealed that the general water circulation pattern in Lower Cook Inlet is consistent through the Fall season and that ERTS-1 images in MSS bands 4 and 5 are capable of delineating water masses with a suspended load as low as 1 mg/liter. The ERTS-1 data and the ground truth data demonstrate clearly that the coriolis effect dominates circulation in Lower Cook Inlet. The configuration of plumes in Nushagak and Kuskokwim bays further indicates the influence of the coriolis effect on the movement of sea water at high latitudes. Comparison of MSS bands 4, 5, 6, and 7 suggest MSS-1 penetration of several meters into the water column. Sea ice analysis of available imagery was exceptionally rewarding. The imagery provided a rapid method to delineate and describe the ice types apparent in the photos. The ice types ranged from newly formed grease ice to heavy flows of disintegrating shore-fast ice. Sea ice maps showing the extent of different ice zones in the Chukchi Sea are being compiled.

Wright, F. F.↗

Video simulator with electronic ranging

Gimbal orientation, raster shrinkage and deflection, and track movement are used to simulate attitude and range. Key component in system is video digitizer that converts vidicon camera signal to digital form, processes it to reduce image size, and reconverts processed data to analog signal for display on cathode ray tube.

Kraemer, W.↗