Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “upgrading”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Active and passive cooling approaches for a Southern California residential community

This study assesses cooling strategies in a low-income community in Southern California that lacks air conditioning and struggles with heat and air pollution. We used an urban building energy model and an electric distribution system model to evaluate active and passive cooling measures. The most effective space cooling measures were high-performance air-source heat pumps, cool coatings, window films, and harnessing the space cooling effect from heat pump water heaters. The results show that combining heat pump water heaters with window films and cool coatings reduces heat index hazard hours within buildings by 95 % to 99 % but increases total energy costs (equipment costs plus changes in utility bills) by 20 % to 60 % where the higher end includes building electrical upgrades. These measures also led to increased space heater use during colder months to avoid overcooling. Replacing conventional heaters with air source heat pumps eliminated unsafe indoor temperatures and reduced total energy use, but increased cost by 125 % to 150 %. In total, using heat pumps for space and water heating could reduce primary energy use by up to 57 %. The higher cost of active and passive cooling measures can be mitigated by existing and emerging incentive programs, especially those that support heat pumps. Electric distribution upgrades to support community electrification are estimated to increase utility costs by $\$$25 to $\$$40 per ratepayer per year. The results underscore the potential and challenges of adapting building infrastructure in communities at risk from climate and environmental stressors.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Anodic electrocatalytic conversion of carboxylic acids on thin films of RuO 2 , IrO 2 , and Pt

The electrocatalytic upgrading of carboxylic acids, abundant biomass-derived molecules, remains a challenging task. In this paper, we report an electrocatalytic decarboxylation (ECDX) approach for the conversion of carboxylic acids into paraffins, olefins, and alcohols via (non-)Kolbe electrolysis on thin films (TFs). The ECDX rate, product selectivity, and current efficiency were potential and electrode dependent. For example, the ECDX activity of RuO 2 -TF was similar to that of Pt foil, but the selectivity to Kolbe products was lower on the former. RuO 2 -TF showed about five times higher rates for the oxygen evolution reaction than Pt foil, which resulted in lower current efficiency. The ECDX and O 2 evolution activities of IrO 2 -TF were potential dependent, but this electrode was selective to non-Kolbe products with low current efficiency (<10 %). This work highlights the performance of thin films as an alternative to bulk metals as anodes for oxidative upgrading of carboxylic acids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Integrated thermal and biological conversion of microalgal proteins to lipids

Microalgal composition varies with cultivation strategy, and low-cost approaches often produce high-protein biomass. This presents challenges for biorefineries designed around static, lipid-rich feedstocks. In particular, hydrolysates from high-protein algae are nitrogen-rich and sugar-poor, limiting microbial conversion and reducing product yields. This study develops a sequential thermal conditioning and biological upgrading strategy to integrate high-protein hydrolysate processing within conventional lipid extraction and upgrading designs. Oxidative deconstruction was used to break down proteins into ammonium and short-chain carboxylates. Ammonium was subsequently removed to yield a nitrogen-depleted, carboxylate-rich medium suitable for microbial lipid production. Bioconversion trials with Cutaneotrichosporon oleaginosum showed lipid accumulation only from hydrolysates treated with both oxidative deconstruction and nitrogen removal, reaching 1.2 g/L lipids at 30 % intracellular content. This integrated approach enables protein-to-lipid conversion and improves flexibility to process variable algal feedstocks, advancing fuel-oriented microalgal biorefineries.

09 BIOMASS FUELS↗
DOE OSTI2026

Advancing Ethanol-to-Jet cost Effectiveness via direct conversion to n -Butene-Rich olefins and Co-Product Valorization

Ethanol is a promising feedstock for sustainable aviation fuel production; however, conventional routes face significant energy and cost challenges, particularly due to the ethanol dehydration step to ethylene. Here, this study leverages breakthrough experimental data to perform comprehensive techno-economic and life-cycle assessments of an innovative ethanol-to-jet process. The process employs a single-step catalytic conversion, enabled by multifunctional Cu-ZrO 2 /SBA-16 catalyst, to directly upgrade ethanol into a mixed olefin stream rich in n-butene. The single-step conversion eliminates the costly ethanol dehydration step in the conventional process. High selectivity toward n-butene offers key advantages: it simplifies downstream oligomerization into jet-range hydrocarbons and enables the co-production of renewable n-butene alongside sustainable aviation fuel. The analysis estimates a minimum fuel selling price as low as $\$$2.50 per gallon, whether using corn ethanol or cellulosic ethanol from corn stover. Life cycle CO 2 equivalent emissions are projected to be as low as 10.6 g CO 2 eq/MJ sustainable aviation fuel, representing over 70% reduction compared to conventional petroleum-based jet fuel. This one-step ethanol upgrading approach not only facilitates SAF and n-butene co-production but also provides operational flexibility. The ability to tailor product outputs allows the ethanol-to-jet process to adapt to varying feedstocks, incentive programs, and market dynamics, ultimately enhancing the economic viability of sustainable aviation fuel production.

Xu, Yiling [Pacific Northwest National Laboratory ↗
DOE OSTI2021

A quantum Monte Carlo study of systems with effective core potentials and node nonlinearities

In this report we study beryllium dihydride (BeH2) and acetylene (C2H2) molecules using real-space diffusion Monte Carlo (DMC) method. The molecules serve as perhaps the simplest prototypes that illustrate the difficulties with biases in the fixed-node DMC calculations that might appear with the use of effective core potentials (ECPs) or other nonlocal operators. This is especially relevant for the recently introduced correlation consistent ECPs (ccECPs) for 2s2p elements. Corresponding ccECPs exhibit deeper potential functions due to higher fidelity to all-electron counterparts, which could lead to larger local energy fluctuations. We point out that the difficulties stem from issues that are straightforward to address by upgrades of basis sets, use of T-moves for nonlocal terms, inclusion of a few configurations into the trial function and similar. The resulting accuracy corresponds to the ccECP target (chemical accuracy) and it is in consistent agreement with independent correlated calculations. Further possibilities for upgrading the reliability of the DMC algorithm and considerations for better adapted and more robust Jastrow factors are discussed as well.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Effects of sodium and calcium chloride ionic stresses on model yeast membranes revealed by molecular dynamics simulation

As efforts to move a renewable economy grow, it will be necessary to make use of microbial conversion strategies for the production of novel materials or the upgrading of waste to high-value products. One critical technical challenge currently limiting waste upgrading remains the difficulty in obtaining single-pot conversion techniques where physical, chemical, and biological conversion are performed in a single step. To overcome this challenge, a detailed understanding of how different stresses impact microbial membrane stability will be necessary. In this work, using all-atom molecular dynamics simulations, we examine the impacts of moderate concentrations of NaCl and CaCl 2 on a model yeast plasma membrane. Weak, though statistically significant, changes in membrane morphology and dynamics functions are observed that are consistent with swelling and stiffening. Additionally, an examination of the ion-lipid contacts and the behavior of water at the water-membrane interface suggests that the impacts of these common salts may, in part, be mediated through changes to water-membrane hydrogen-bonding and hydration water dynamics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Estimating the impact of tariff-driven behind-the-meter storage operation on distribution grid investments

Increasing growth of distributed solar photovoltaics (PV) and electric vehicles (EV) can strain local distribution networks and require costly upgrades. Distributed battery storage, often deployed alongside PV, can be used to mitigate those costs, depending on how batteries are operated. This study evaluates the potential deferral value of distributed battery storage across a range of tariff structures, focusing on the rate structures most commonly available to residential customers today and related variants. Deferrals are evaluated with a least-cost distribution grid expansion optimization model to identify requirements on line reconductoring, transformer upgrades, and voltage regulator installations under each tariff. Results show that TOU rates and net billing tariffs can yield meaningful deferral value, depending on specific tariff structure features. Under the best performing tariff structure tested, storage produced a median annualized deferral value of $7.18 per kW of storage capacity ( kW S ) across all feeders in the sample, though deferral values were considerably larger for feeders with peak loads that coincide with utility system peak, i.e., timing of TOU peak period. In contrast, under an unrestricted TOU design with no restrictions on grid charging or discharging, the median deferral value was $0/ kW S illustrating the critical importance of tariff structure details.

Rodriguez-Garcia, Luis↗
DOE OSTI2026

A review of United States energy-only generator interconnection service policy and considerations for reform

Grid interconnection has emerged as a significant obstacle to the development of new electricity resources. There is growing interest in energy-only interconnection, which is an interconnection service option meant to allow the interconnection of new generators without ensuring their energy deliverability during all hours through the transmission system to customers. This approach potentially avoids upfront congestion-related transmission upgrades but could increase curtailment risk. Interest in energy-only interconnection is shaped by incomplete understanding of how interconnection policy functions in different jurisdictions, a knowledge gap that makes it difficult to determine how energy-only interconnection might be better used or re-designed. In this paper, we provide a regulatory review of energy-only interconnection in U.S. interconnection policy and practice, identifying jurisdictions in which rules are close to -or farther from-the theoretical concept of energy-only interconnection service. We find substantial jurisdictional differences in how energy-only interconnection is implemented, driven by differences in resource adequacy frameworks, real-time transmission operations, and state-level procurement practices. U.S. regulators have preferred local jurisdictional flexibility over federal prescription of interconnection study methods and procedures, which also contributes to differences among regions. Such findings raise fundamental questions about whether competition policies in electricity markets should extend beyond spot energy markets and into more prescriptive guidelines around interconnection rules and market entry. This paper sheds light on tensions that energy-only interconnection raises in allowing generators to access the transmission system on an as available basis and discusses how controlling thresholds for congestion-related network upgrades may be a barrier to electricity market entry.

Gorman, Will↗
DOE OSTI2020

Real-time gas cooling of flowing liquid lithium limiter for the EAST

A novel continuously flowing liquid lithium limiter (FLiLi) which employs an in-vessel electro-magnetic pump to drive liquid Li flowing on the surface of limiter has been successfully designed and tested in the experimental advanced superconducting tokamak (EAST) device in 2014. In order to better control the surface temperature, an upgraded design and the real-time gas cooling were performed in 2016. Two kinds of cooling gas, helium (He) and argon (Ar) were tested on the FLiLi system prior to the experiment. It was found that the cooling rates of He and Ar at 2.5 MPa are 34.2 °C/min, 10.2 °C/min or 31.7 °C/kL and 28.1 °C/kL, respectively. The cooling performance of He is more effective than Ar. Experimental results show that the real-time He cooling could effectively contain the FLiLi surface temperature increase and prevent the strong passive evaporation of lithium during plasma discharges. Limiter heat flux up to 0.2 MW/m2 was removed during ohmic discharge with 2.5 MPa He gas. Finally, Because of the upgraded design and real-time gas cooling, the surface of FLiLi was not damaged by heat flux after entire plasma discharge.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Core-shell and egg-shell zeolite catalysts for enhanced hydrocarbon processing

Developing structure-performance relationships with the underlying goal of optimizing known zeolite catalysts involves the manipulation of their physicochemical properties. Here, we systematically assessed the impact of mesoscopic gradients in acid site concentration, which has generally received little attention in the design of zeolite catalysts for hydrocarbon upgrading. A series of core–shell MEL-type zeolites were synthesized with catalytically active ZSM-11 cores and passivated silicalite-2 shells of varying thickness. Our findings revealed that ZSM-11@silicalite-2 particles with ultrathin shells (<10 nm) have enhanced mass transport, characteristic of relatively smaller particles, compared to the corresponding ZSM-11 core. Additionally, catalytic testing using the methanol-to-hydrocarbon (MTH) reaction showed that core–shell zeolites exhibit longer lifetimes, higher total turnovers, and an unexpected promotion of the aromatic cycle in the hydrocarbon pool mechanism. Time-resolved acid titration of core and core–shell catalysts confirmed that the siliceous shell introduces a hydrophobic exterior that impacts molecular diffusion. In comparison, prepared MFI core-shells (ZSM-5@silicalite-1) showed similar enhancement in catalyst performance. Moreover, we prepared egg-shell configurations of each zeolite, silicalite-2@ZSM-11 and silicalite-1@ZSM-5, comprised of an inert core and catalytically active shell. This inverse design of the egg-shell created pseudo nanosheets with total turnovers that were markedly higher than their homogeneous counterparts. Collectively, this study demonstrated that mesoscopic gradients in acid concentration via the design of core–shell and egg-shell zeolites significantly improve catalyst performance over conventional analogues for hydrocarbon upgrading.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Cosmology intertwined: A review of the particle physics, astrophysics, and cosmology associated with the cosmological tensions and anomalies

The standard Λ Cold Dark Matter (ΛCDM) cosmological model provides a good description of a wide range of astrophysical and cosmological data. However, there are a few big open questions that make the standard model look like an approximation to a more realistic scenario yet to be found. In this paper, we list a few important goals that need to be addressed in the next decade, taking into account the current discordances between the different cosmological probes, such as the disagreement in the value of the Hubble constant H 0 , the σ 8 – S 8 tension, and other less statistically significant anomalies. While these discordances can still be in part the result of systematic errors, their persistence after several years of accurate analysis strongly hints at cracks in the standard cosmological scenario and the necessity for new physics or generalisations beyond the standard model. In this paper, we focus on the 5.0 σ tension between the Planck CMB estimate of the Hubble constant H 0 and the SH0ES collaboration measurements. After showing the H 0 evaluations made from different teams using different methods and geometric calibrations, we list a few interesting new physics models that could alleviate this tension and discuss how the next decade's experiments will be crucial. Moreover, we focus on the tension of the Planck CMB data with weak lensing measurements and redshift surveys, about the value of the matter energy density Ω m , and the amplitude or rate of the growth of structure ( σ 8 , f σ 8 ). We list a few interesting models proposed for alleviating this tension, and we discuss the importance of trying to fit a full array of data with a single model and not just one parameter at a time. Additionally, we present a wide range of other less discussed anomalies at a statistical significance level lower than the H 0 – S 8 tensions which may also constitute hints towards new physics, and we discuss possible generic theoretical approaches that can collectively explain the non-standard nature of these signals. Finally, we give an overview of upgraded experiments and next-generation space missions and facilities on Earth that will be of crucial importance to address all these open questions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Heat pumps for all? Distributions of the costs and benefits of residential air-source heat pumps in the United States

Electrification of fossil-fuel combustion in buildings is a key component of achieving global greenhouse gas emissions targets. We use physics simulations of 550,000 statistically representative households to analyze distributions of the costs and benefits of three air-to-air heat pump performance levels, with and without insulation upgrades, across the diversity of the US housing stock. We find positive greenhouse gas reductions in every US state for all performance levels across five 2022-2038 electric grid scenarios, with full adoption reducing national emissions by 5%-9%. We find that air-to-air heat pumps could be cost effective without subsidies in 59% of households (65 million). However, efficiency is key: whereas minimum-efficiency equipment could increase energy bills in 39% of households, this fraction is only 19% when also upgrading insulation or 5% when using higher-efficiency equipment, though both strategies have higher upfront costs. Such affordability challenges could be addressed through supportive incentives, policy, and innovation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Systematic error analysis in the absolute hydrogen gas jet polarimeter at RHIC

The Polarized Atomic Hydrogen Gas Jet Target polarimeter (HJET) is operated at the Relativistic Heavy Ion Collider (RHIC) since 2004 to measure the absolute polarization of each colliding proton beam. Polarimeter detectors and data acquisition were upgraded in 2015 to increase the solid angle, energy range, and to improve the energy and time resolution. These upgrades along with an improved beam intensity and polarization allowed us to greatly reduce the statistical and systematic errors for the proton polarization measurements in RHIC Runs 15 (E beam = 100 GeV) and 17 (255 GeV). For a typical 8 hour RHIC store, the measured proton beam average polarization was about P beam ~ 55 ± 2.0 stat ± 0.3 syst %. The elastic pp analyzing power, AN(t)~0.04, was determined with a precision of about |δA N (t)|~0.0002 in the momentum transfer squared range 0.001<-t<0.020 GeV 2 . In this paper we present a detailed systematic error analysis of the polarization measurements at HJET. Perspectives of using the HJET based absolute polarimeters in the future Electron Ion Collider (EIC) will be also discussed.

43 PARTICLE ACCELERATORS↗
DOE OSTI2020

Strip sensor performance in prototype modules built for ATLAS ITk

ATLAS experiment is preparing an upgrade of its detector for High-Luminosity LHC (HL-LHC) operation. The upgrade involves installation of the new all-silicon Inner Tracker (ITk). In the context of the ITk preparations, more than 80 strip modules were built with prototype barrel sensors. They were tested with electrical readout on a per-channel basis. In general, an excellent performance was observed, consistent with previous ASIC-level and sensor-level tests. However, the lessons learned included two phenomena important for the future phases of the project. First was the need to store and test the modules in a dry environment due to humidity sensitivity of the sensors. The second was an observation of high noise regions for 2 modules. The high noise regions were tested further in several ways, including monitoring the performance as a function of time and bias voltage. Additionally, direct sensor-level tests were performed on the affected channels. The inter-strip resistance and bias resistance tests showed low values, indicating a temporary loss of the inter-strip isolation. A subsequent recovery of the noise performance was observed. Here we present the test details, an analysis of how the inter-strip isolation affects the module noise, and the relationship with sensor-level quality control tests.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Performance of position-sensitive resistive silicon detectors in the Forward Array Using Silicon Technology (FAUST)

The silicon telescopes of the Forward Array Using Silicon Technology (FAUST) have been recently upgraded with silicon detectors which use resistive charge-splitting to measure the position of charged particles. This is in addition to the measurement of the total energy that these charged particles deposit in the detector. The upgrade results in increased angular resolution with a much smaller number of signals than silicon strip detectors with similar resolution. Here, a novel method of calibration has been used to demonstrate the efficacy of these position-sensitive detectors, and the detectors have been used in a commissioning experiment.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Fatigue analysis of the Spallation Neutron Source 2 MW target design

Upgrades to the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory are under way with two major projects. The first project is the Proton Power Upgrade (PPU), which will double the power capacity of the SNS accelerator system to enable the operation of a future second neutron source target station—the second project. PPU also will increase power to the SNS first target station – which currently operates at 1.4 MW with 1.0 GeV protons – to 2 MW with 1.3 GeV protons. Final design of the PPU 2 MW target module is finished, including all necessary design and analysis calculations. The fatigue evaluation described herein is an assessment of the fitness of the PPU 2 MW target mercury vessel to resist failure from cyclic loading from the pulsed 60 Hz proton beam and thermal changes from disrupted operation. In addition to the reliability predictions, the method, detail, and depth of this fatigue evaluation are superior to those of past target design assessments. Furthermore, the thermal fatigue life is predicted to exceed 3125 thermal cycles per 1250 h of operation for all load cases. The design also meets the (relative) fatigue design goal for combined thermal and pulse loading of greater than 0.5 times the minimum fatigue life calculated for a jet-flow target design operating at 1.4 MW—the most robust design to date in terms of resistance to fatigue failure. From the onset of the PPU, it has been known that pulse loading requires effective application of helium gas injection into the target mercury to reduce beam pressure loading. For the PPU 2 MW target, none of the pulse load cases requires a maximum strain reduction from gas injection of more than 50% (for base material) to meet the fatigue design goal. This level of reduction is achievable from gas injection, according to historical strain measurements from 1.4 MW target operation. Overall, the PPU 2 MW target design is predicted to have superior resistance to fatigue failure compared with past target designs.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Advancements of the nSpec system

For this study, a new characterization of the detector response for the EJ301 liquid scintillator based nSpec system has been conducted at the Los Alamos Neutron Science Center. The new characterization was accomplished in two orders of magnitude less time and with better statistics than the previous characterization. The new and old characterization methods were compared by conducting both types of characterization on two detectors (one EJ301 and one EJ301D). The two methods show consistent results and compare well to results previously published in the literature; however, the results from the characterization of the original nSpec detector show discrepancies that have been identified as being caused by oxygen being absorbed into the detector due to a leak. The new characterized detector response shows improved spectrum unfolding performance than the previous characterization. The cross talk of the detector system was also characterized as a function of incident neutron energy and found to have a negligible impact on spectrum unfolding results. Alternative materials (EJ301D and stilbene) were also characterized in a first step towards an upgraded system. The different materials show little difference in unfolding performance, but the comparison is ongoing. A SiPM based stilbene detector was used to evaluate the use of SiPMs in a future system upgrade. The SiPM provides adequate performance, but the custom SiPM readout results in a much longer pulse width than PMT based systems. The measured light output of the SiPM based stilbene compares well with the results in literature. Future work will look at additional materials (deuterated stilbene and organic glass) and optimizing the SiPM readout to decrease the pulse width.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗