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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Water vapor absorption in the atmospheric window at 239 GHz

Absolute absorption rates of pure water vapor and mixtures of water vapor and nitrogen have been measured in the atmospheric window at 239 GHz. The dependence on pressure as well as temperature has been obtained. The experimental data are compared with several theoretical or empirical models, and satisfactory agreement is obtained with the models involving a continuum; in the case of pure water vapor, the continuum contribution based upon recent theoretical developments gives good results. The temperature dependence is stronger than that proposed in a commonly used atmospheric transmission model.

Bauer, A.↗
NASA NTRS1998

Investigation of Anomalous Behavior in Metallic-Based Materials Under Compressive Loading

An anomalous material response has been observed under the action of applied compressive loads in fibrous SiC/Ti (both Ti-6242 and Ti-15-3 alloys) and the monolithic nickel-base alloy IN-718 in the aged condition. The observed behavior is an increase, rather than a decrease, in the instantaneous Young's modulus with increasing load. This increase is small, but can be significant in yield surface determination tests, where an equivalent offset strain on the order of 10 micron(1 x 10(exp -6) m/m) is being used. Stiffening has been quantified by calculating offset strains from the linear elastic loading line. The offset strains associated with stiffening during compressive loading are positive and of the same order as the target offset strains in yield surface determination tests. At this time we do not have a reasonable explanation for this response nor can we identify a deformation mechanism that might cause it. On the other hand, we are not convinced that it is an artifact of the experimental procedure because a number of issues have been identified and seemingly ruled out. In fact, stiffening appears to be temperature dependent, since it decreases as the temperature increases.

Gil, Christopher M.↗
NASA NTRS2018

Thermal Model Performance for the James Webb Space Telescope OTIS Cryo-Vacuum Test

The James Webb Space Telescope (JWST), set to launch in mid-2020, is currently undergoing a series of system-level environmental tests to verify its workmanship and end-to-end functionality. As part of this series, the Optical Telescope Element and Integrated Science Instrument Module (OTIS) Cryo-Vacuum (CV) test, the most complex cryogenic test executed to date by NASA, has recently been completed at the Johnson Space Center's Chamber A facility. The OTIS CV test was intended as a comprehensive test of the integrated instrument and telescope systems to fully understand its optical, structural, and thermal performance within its intended flight environment. Due to its complexity, extensive pre-test planning was required to ensure payload safety and compliance with all limits and constraints. A system-level pre-test thermal model was constructed which fully captured the behavior of the payload, ground support equipment, and surrounding test chamber. This thermal model simulated both the transient cooldown to and warmup from a 20 K flight-like environment, as well as predicted the payload performance at cryo-stable conditions. The current work is an assessment of thermal model pre-test prediction performance against actual payload response during the OTIS CV test. Overall, the thermal model performed exceedingly well at predicting schedule and payload response. Looking in depth, this work examines both the benefits and shortcomings of assumptions made pre-test to simplify model execution when compared against test data. It explores in detail the role of temperature-dependent emissivities during transition to cryogenic temperatures, as well as the impact that model geometry simplifications have on tracking of critical hardware limits and constraints. This work concludes with a list of recommendations to improve the accuracy of thermal modeling for future large cryogenic tests. The insight gained from the OTIS CV test thermal modeling will benefit planning and execution for upcoming cryogenic missions.

Testing↗
NASA NTRS2018

Thermal Model Performance for the James Webb Space Telescope OTIS Cryo-Vacuum Test

The James Webb Space Telescope (JWST), set to launch in early 2019, is currently undergoing a series of system-level environmental tests to verify its workmanship and end-to-end functionality. As part of this series, the Optical Telescope Element and Integrated Science Instrument Module (OTIS) Cryo-Vacuum (CV) test, the most complex cryogenic test executed to date by NASA, has recently been completed at the Johnson Space Center's Chamber A facility. The OTIS CV test was intended as a comprehensive test of the integrated instrument and telescope systems to fully understand its optical, structural, and thermal performance within its intended flight environment. Due to its complexity, extensive pre-test planning was required to ensure payload safety and compliance with all limits and constraints. A system-level pre-test thermal model was constructed which fully captured the behavior of the payload, ground support equipment, and surrounding test chamber. This thermal model simulated both the transient cooldown to and warmup from a 20K flight-like environment, as well as predicted the payload performance at cryo-stable conditions. The current work is a preliminary assessment of thermal model performance against actual payload response during the OTIS CV test. It examines both the benefits and shortcomings of assumptions made pre-test to simplify model execution when compared against test data. It explores in detail the role of temperature-dependent emissivities during transition to cryogenic temperatures, as well as the impact that model geometry simplifications have on tracking of critical hardware limits and constraints. This work concludes with a list of recommendations to improve the accuracy of thermal modeling for future large cryogenic tests. It is hoped that the insight gained from the OTIS CV test thermal modeling will benefit planning and execution for upcoming cryogenic missions.

JWST↗
NASA NTRS2018

Thermal Model Performance for the James Webb Space Telescope OTIS Cryo-Vacuum Test

The James Webb Space Telescope (JWST), set to launch in early 2019, is currently undergoing a series of system-level environmental tests to verify its workmanship and end-to-end functionality. As part of this series, the Optical Telescope Element and Integrated Science Instrument Module (OTIS) Cryo-Vacuum (CV) test, the most complex cryogenic test executed to date by NASA, has recently been completed at the Johnson Space Center’s Chamber A facility. The OTIS CV test was intended as a comprehensive test of the integrated instrument and telescope systems to fully understand its optical, structural, and thermal performance within its intended flight environment. Due to its complexity, extensive pre-test planning was required to ensure payload safety and compliance with all limits and constraints. A system-level pre-test thermal model was constructed which fully captured the behavior of the payload, ground support equipment, and surrounding test chamber. This thermal model simulated both the transient cooldown to and warmup from a 20K flight-like environment, as well as predicted the payload performance at cryo-stable conditions. The current work is a preliminary assessment of thermal model performance against actual payload response during the OTIS CV test. Overall, the thermal model performed exceedingly well at predicting schedule and payload response. Looking in depth, this work examines both the benefits and shortcomings of assumptions made pre-test to simplify model execution when compared against test data. It explores in detail the role of temperature-dependent emissivities during transition to cryogenic temperatures, as well as the impact that model geometry simplifications have on tracking of critical hardware limits and constraints. This work concludes with a list of recommendations to improve the accuracy of thermal modeling for future large cryogenic tests. It is hoped that the insight gained from the OTIS CV test thermal modeling will benefit planning and execution for upcoming cryogenic missions.

Yang, Kan↗
DOE OSTI2019

Metal–Insulator Phase Transition in Thin Films of a Nickel-Doped Vanadium Dioxide

The electrical conductivity of thin polycrystalline VNi{sub x}O{sub 2} films has been studied in a wide range of temperatures, which covers the regions of both metallic and insulator phase. It is shown that the metal–insulator phase transition temperature decreases as the nickel concentration increases, and the temperature range of coexistence of the phases increases monotonically. The temperature dependence of the conductivity of the insulating VNi{sub x}O{sub 2} phase is explained using the hopping conduction model that takes into account the influence of thermal atomic vibrations on the resonance integral. Parameter ε has been calculated as a function of the doping level of VO{sub 2}.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Multiscale, mechanistic modeling of cesium transport in silicon carbide for TRISO fuel performance prediction

Understanding cesium (Cs) transport in TRistructural ISOtropic (TRISO) particle fuel is crucial for predicting fission product release in high-temperature reactors. However, current challenges include significant scatter in diffusivity data and unexplained temperature-dependent diffusion regimes in the silicon carbide layer. This study addresses these challenges by developing a multiscale, mechanistic Cs transport model integrating atomistic simulations and phase field modeling. Our model quantifies temperature and grain size effects on Cs diffusivity, attributing experimentally observed regimes to a transition from bulk-dominated diffusivity at high temperatures to grain boundary-dominated diffusivity at lower temperatures. The model, validated against diffusion measurements and advanced gas reactor (AGR)-1 and AGR-2 post-irradiation fission product release data, enhances the predictive capability of the BISON fuel performance code. This study advances our understanding of Cs release from TRISO particles and its dependence on temperature and silicon carbide grain size, with implications for the safety and efficiency of high-temperature nuclear reactors.

BISON↗
DOE OSTI2023

Aerosol jet printing of piezoelectric surface acoustic wave thermometer

Abstract Surface acoustic wave (SAW) devices are a subclass of micro-electromechanical systems (MEMS) that generate an acoustic emission when electrically stimulated. These transducers also work as detectors, converting surface strain into readable electrical signals. Physical properties of the generated SAW are material dependent and influenced by external factors like temperature. By monitoring temperature-dependent scattering parameters a SAW device can function as a thermometer to elucidate substrate temperature. Traditional fabrication of SAW sensors requires labor- and cost- intensive subtractive processes that produce large volumes of hazardous waste. This study utilizes an innovative aerosol jet printer to directly write consistent, high-resolution, silver comb electrodes onto a Y-cut LiNbO 3 substrate. The printed, two-port, 20 MHz SAW sensor exhibited excellent linearity and repeatability while being verified as a thermometer from 25 to 200 ∘ C. Sensitivities of the printed SAW thermometer are $$-96.9\times 1{0{}^{-6}}^{\circ }$$ − 96.9 × 1 0 − 6 ∘ C −1 and $$-92.0\times 1{0{}^{-6}}^{\circ }$$ − 92.0 × 1 0 − 6 ∘ C −1 when operating in pulse-echo mode and pulse-receiver mode, respectively. These results highlight a repeatable path to the additive fabrication of compact high-frequency SAW thermometers.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2022

Apex hydrogen bonds in dendron assemblies modulate close-packed mesocrystal structures

The close-packed mesocrystal structures from soft-matter assemblies have recently received attention due to their structural similarity to atomic crystals, displaying various sphere-packing Frank–Kasper (FK) and quasicrystal structures. Herein, diverse mesocrystal structures are explored in second-generation dendrons (G2-X) designed with identical wedges, in which the terminal functionalities X = CONH 2 and CH 2 NH 2 represent two levels of the strong and weak hydrogen-bonding apexes, respectively. The cohesive interactions at the core apex, referred to as the core interactions, are effectively modulated by forming heterogeneous hydrogen bonds between these two functional units. For the dendron assemblies compositionally close to each pure component of G2-CONH 2 and G2-CH 2 NH 2 , their own FK A15 and C14 phases dominate other phases, respectively. We show the existence of the wide-range FK σ including the dodecagonal quasicrystal (DDQC) phases from the dendron mixtures between G2-CONH 2 and G2-CH 2 NH 2 , providing an experimental phase sequence of A15–σ–DDQC–C14 as the core interactions are alleviated. Intriguingly, the temperature dependence of particle sizes shows that the high plateau values of particle sizes are maintained equivalently until each threshold temperature (T th ), followed by a prompt decrease above the T th . A decrease in T th by alleviating the core interactions and its composition dependence suggest that the more size-dispersed particles, the more susceptibility to chain exchange with increasing temperature. Here our results on the formation of supramolecular dendron assemblies provide a guide to understand the core-interaction-dependent mesocrystal structures toward the fundamental principle underlying the temperature dependence of their particle sizes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

On Temperature Limits for the Outer Surface of a Container in a Disposal Facility - 20313

The temperature in a disposal facility for high-level radioactive waste (HLRW) is an issue for safety. When the recommencement of the search for and selection of a site for a disposal facility for HLRW in Germany was stipulated by the Site Selection Act (StandAG 2017) in 2017, a precautionary temperature limit of 100 deg. C on the outer surface of the containers with high-level radioactive waste in the disposal facility section was set. This precautionary temperature limit shall be applied in preliminary safety analyses provided that the 'maximum physically possible temperatures' in the respective host rocks have not yet been determined due to pending research. Therefore, this issue is addressed and discussed in this paper, contributing to 'pending research' by a review of the literature. This paper briefly discusses a few examples of thermohydraulic, mechanical, chemical and biological processes in a disposal facility, because temperature limits are derived based on safety impacts regarding THMCB-processes. The temperature-dependent processes have been extracted from databases for features, events and processes (FEP-databases). Furthermore, it is discussed if the feasibility to retrieve and recover HLRW is hampered at high temperatures. A design temperature concerning single components of a disposal facility for the preservation of their features can be derived when a safety concept is established. However, the interactions of all relevant processes in a disposal concept must be considered to determine a specific temperature limit for the outer surface of the containers. Therefore, applicable temperature limits may vary for particular safety and disposal concepts in the following host rocks: rock salt, clay stone and crystalline rock. Technical solutions for retrieval and design options for recovery seem to be viable up to temperatures of 200 deg. C with different, sometimes severe, downsides according to expert judgement. Temperature limits regarding the outer surface of the containers can be derived specifically for each safety concept and design of the disposal facility in a host rock. General temperature limits without reference to specific safety concepts or the particular design of the disposal facility may narrow down the possibilities for optimisation of the disposal facility and could adversely affect the site selection process in finding the best suitable site. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Coexistence of positive and negative exchange bias effect in Pr-doped NdCrO 3 samples

Positive and negative exchange bias effects are observed in Nd 1-x Pr x CrO 3 (0.00 ≤ x ≤ 1.00) polycrystalline samples. The shift of hysteresis loops, either opposing or following the direction of the field cooling, depends on the concentration of praseodymium. The temperature dependence of magnetization reveals a magnetic transition at T ≈ 220 K likely ascribed to the N é el temperature of Cr 3+ magnetic moments. The non-Kramer Pr 3+ ion seems to play an important role in the magnetic properties of this compound. In the range 0.00 ≤ x ≤ 0.60, all samples presented a decrease in the magnetization below TN and a clear compensation point. Pr-rich samples (x ≥ 0.70) show a paramagnetic-like behavior down to low temperatures. We report the most impressive result is the relation between reversal magnetization and the signal of exchange bias effect which seems be tuned by the Pr-doping.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Complex pressure-temperature structural phase diagram of the honeycomb iridate Cu 2 IrO 3

Cu 2 IrO 3 is among the newest layered honeycomb iridates and a promising candidate to harbor a Kitaev quantum spin liquid state. Here, we investigate the pressure and temperature dependence of its structure through a combination of powder x-ray diffraction and x-ray absorption fine structure measurements, as well as ab initio evolutionary structure search. At ambient pressure, we revise the previously proposed C2/c solution with a related but notably more stable P2 1 /c structure. Pressures below 8 GPa drive the formation of Ir-Ir dimers at both ambient and low temperatures, similar to the case of Li 2 IrO 3 . At higher pressures, the structural evolution dramatically depends on temperature. Furthermore, a large discontinuous reduction of the Ir honeycomb interplanar distance is observed around 15 GPa at room temperature, likely driven by a collapse of the O-Cu-O dumbbell bonds. At 15 K, pressures beyond 20 GPa first lead to an intermediate phase featuring a continuous reduction of the interplanar distance, which then collapses at 30 GPa across yet another phase transition. However, the resulting structure around 40 GPa is not the same at room and low temperatures. Remarkably, the reduction in interplanar distance leads to an apparent healing of the stacking faults at room temperature, but not at 15 K. Possible implications on the evolution of electronic structure of Cu 2 IrO 3 with pressure are discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1977

Temperature and pressure dependence of dichloro-difluoromethane (CF2C12) absorption coefficients for CO2 waveguide laser radiation

Measurements were performed to determine the pressure and temperature dependence of CFM-12 absorption coefficients for CO2 waveguide laser radiation. The absorption coefficients of CFM-12 for CO2 waveguide laser radiation were found to have no spectral structure within small spectral bandwidths around the CO2 waveguide laser lines in the CO2 spectral band for pressures above 20 torr. All of the absorption coefficients for the CO2 laser lines studied are independent of pressure above 100 torr, except for the P(36) laser CO2 spectral band. The absorption coefficients associated with the P(42) line in the same band showed the greatest change with temperature, and it also has the largest value of all the lines studied.

Harward, C. N.↗
NASA NTRS1978

Partitioning of Ni/2+/ between basaltic and synthetic melts and olivines An experimental study

Olivine/liquid distribution coefficients for Ni in basaltic and simple synthetic melts are found in the 1400-1070 C temperature range. The results suggest that: (1) the Ni distribution coefficients and NiO activity coefficients are strongly temperature dependent, (2) the Ni distribution coefficients are functions of melt composition and structure at a constant temperature although the dependence is small for most basaltic magmas, (3) differences in melt composition do not significantly influence generally 'basaltic' melts, (4) the Ni distribution coefficients may be used as geothermometers to predict the olivine crystallization temperatures of basaltic magmas to within plus or minus 50 C, (5) the Ni distribution coefficients are greater than one at all natural magmatic temperatures, and (6) the Ni distribution coefficients do not significantly vary as functions of the Ni content of the melt to at least one mole percent.

Leeman, W. P.↗
DOE OSTI2021

Critical Experiment Design Phase 2 Report for Integral Request 304

This report documents the second phase of the critical experiment design process (CED-2) conducted as part of integral experiment request (IER) 304. The purpose of IER-304 is to develop a temperature-dependent critical experiment capability at the Sandia National Laboratories critical experiment facility using low-enriched uranium oxide fuel. Only a few benchmark quality critical experiments are currently available to validate criticality safety computational methods at temperatures other than room temperature. Recent advancements in computational techniques such as implementation of on-the-fly Doppler broadening techniques and advanced treatment of thermal scattering data necessitate the development of additional experimental capabilities in this area. The work described in this report developed representative configurations using 7uPCX and BUCCX fuels, analyzed the physics exercised by the different arrays, and analyzed the estimated experimental uncertainties. This report also scopes the information necessary for performing modifications to the reactor to accommodate operation at elevated and reduced temperatures.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Modeling fission product diffusion in TRISO fuel particles with BISON

Diffusion of fission products in intact TRISO particles depends on particle geometry, fission product source rates, time, temperature, and temperature-dependent diffusion coefficients. Simulating this diffusion process requires models for source rates and diffusion coefficients, plus computation of the temperature field if not prescribed. In addition, simulation quality depends on discretization of the geometry, appropriate time stepping, and the accuracy of the solution method. In this paper, we explore the simulation of fission product diffusion in TRISO fuel particles using the finite element method via the fuel performance code Bison. Recent material model development has occurred in Bison for each material present in tri-structural isotropic (TRISO) fuel particles: the buffer, inner pyrolytic carbon, silicon carbide, and outer pyrolytic carbon layers, as well as the fuel kernel. Also, new mesh generation and fission product release fraction capabilities have been added. Diffusion capabilities are shown to converge to the correct solution via formal verification tests. A large number of code benchmarking problems are also given, with good results, showing that Bison’s computed release fractions closely match those of other software tools. Finally, a significant validation effort is detailed in which fission product release, measured as part of the AGR-1 capsule experiments, is compared to Bison outputs. Bison outputs compare very well to the experimental data and to PARFUME results.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2004

Application of Satellite-Derived Land Surface Temperature to Minimum Temperature Forecasting

Satellite-derived land surface temperature (LST) is studied for the purpose of understanding regional skin temperature dependency and variability, and its relationship to corresponding, site-specific air temperature. Skin temperature is highly correlated with surface-air temperature although it differs depending on land surface characteristics, terrain, and atmospheric conditions on a diurnal and seasonal scale. The high temporal resolution of the Geostationary Operational Environmental Satellite (GOES) -12 sounder is used to compare the diurnal cycles of LST and surface-air temperature. The minimum for both temperatures occurs near sunrise and LST is found to agree closely with surface-air temperatures a period of hours before sunrise on clear sky nights. The Moderate Resolution Imaging Spectroradiometer (MODIS)-derived LST renders more horizontal temperature structure - with its high spatial resolution (1 km at nadir) compared to the GOES-12 sounder (10 km). Nighttime MODIS-derived LST is extrapolated to the time of minimum temperature for a number of case study days and these are grouped by season and atmospheric conditions. These composites show that the variation in LST mirror the variation in minimum surface-air temperature under similar conditions.

Jones, P. R.↗