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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Understanding the reversible electrodeposition of aluminum in low-cost room-temperature molten salts

Aluminum is the most earth-abundant metal, trivalent, and inert in ambient air; it also has a density approximately five times that of lithium at room temperature, making it attractive for cost-effective, long-duration storage in batteries. Here, we investigate structural requirements and physicochemical and transport properties of ionic liquid (IL) electrolytes thought to enable high reversibility of Al battery anodes. We find that intentionally designed, low-cost IL analogs, including ammonium-based molten salts, offer comparable Al anode reversibility to state-of-the-art imidazolium-based IL melts. A critical ratio of solvated Al-ion species is required to balance the effects of Lewis acidity needed to continuously etch native Al 2 O 3 and form a stable solid electrolyte interphase on Al. Our findings open new opportunities for developing simple, cost-effective, room-temperature Al batteries that enable long-duration electrical energy storage.

25 ENERGY STORAGE↗
DOE OSTI2024

Speciation and Organic Phase Structure in Nitric Acid Extraction with Trioctylamine

Understanding chemical speciation and intermolecular interactions in multicomponent liquids is essential to understanding their phase and chemical equilibria, which underpin chemical separation processes, including solvent extraction. Here we report on the extraction of nitric acid from its aqueous solutions into organic solutions of trioctylamine (TOA) in toluene, investigated with spectroscopic, X-ray scattering, and computational tools to understand molecular speciation in the organic phase and its relationship with the nanoscale structure of the organic phase. Trends in acid and water extraction clearly show two and three regimes, respectively, indicating different stoichiometric relationships, but speciation of HNO 3 , water, and amine in these regimes is not apparent. 1 H NMR of the organic phase shows that there are at least two distinct acidic protons in the organic phase while ATR-FTIR results show that the organic phase with excess acid extraction is a mixture of trioctylammonium-nitrate ion pairs (TOAHNO 3 ), and undissociated HNO 3 molecules. Comparison with DFT-computed IR spectra show that the chain-like configurations of TOAHNO 3 HNO 3 H 2 O are favored over TOAHNO 3 H 2 OHNO 3 , i.e., direct interaction between the nitrate and HNO 3 molecules is more favored compared to a water-mediated interaction. SAXS of the organic phases were modeled as sums of Ornstein-Zernike (O-Z) scattering and a prepeak feature in the higher Q region that corresponds to extractant packing. The extraction of undissociated HNO 3 by the ion pairs leads to an increased X-ray scattering contrast in the organic phase without any significant change in the correlation length. These results show that the organic phase nanostructure is more sensitive to the concentration of TOAHNO 3 and is relatively unaffected by excess acid extraction. Finally, these findings will enable a molecular understanding of the mechanisms behind metal extraction from acidic media with basic extractants.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Field-induced quantum critical point in the itinerant antiferromagnet Ti 3 Cu 4

New phases of matter emerge at the edge of magnetic instabilities, which can occur in materials with moments that are localized, itinerant or intermediate between these extremes. In local moment systems, such as heavy fermions, the magnetism can be tuned towards a zero-temperature transition at a quantum critical point (QCP) via pressure, chemical doping, and, rarely, magnetic field. By contrast, in itinerant moment systems, QCPs are more rare, and they are induced by pressure or doping; there are no known examples of field induced transitions. This means that no universal behaviour has been established across the whole itinerant-to-local moment range—a substantial gap in our knowledge of quantum criticality. Here we report an itinerant antiferromagnet, Ti 3 Cu 4 , that can be tuned to a QCP by a small magnetic field. We see signatures of quantum criticality and the associated non-Fermi liquid behaviour in thermodynamic and transport measurements, while band structure calculations point to an orbital-selective, spin density wave ground state, a consequence of the square net structural motif in Ti 3 Cu 4 . Ti 3 Cu 4 thus provides a platform for the comparison and generalisation of quantum critical behaviour across the whole spectrum of magnetism.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Hydration structure of flat and stepped MgO surfaces

We investigate the solvation structure of flat and stepped MgO(001) in neutral liquid water using ab initio molecular dynamics based on a hybrid density functional with dispersion corrections. Our simulations show that the MgO surface is covered by a densely packed layer of mixed intact and dissociated adsorbed water molecules in a planar arrangement with strong intermolecular H-bonds. The water dissociation fractions in this layer are >20% and >30% on the flat and stepped surfaces, respectively. Slightly above the first water layer, we observe metastable OH groups perpendicular to the interface, similar to those reported in low temperature studies of water monolayers on MgO. Here, these species receive hydrogen bonds from four nearby water molecules in the first layer and have their hydrophobic H end directed toward bulk water, while their associated protons are bound to surface oxygens. The formation of these OH species is attributed to the strong basicity of the MgO surface and can be relevant for understanding various phenomena from morphology evolution and growth of (nano)crystalline MgO particles to heterogeneous catalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Low Mach number fluctuating hydrodynamics model for ionic liquids

We present a new mesoscale model for ionic liquids based on a low Mach number fluctuating hydrodynamics formulation for multicomponent charged species. The low Mach number approach eliminates sound waves from the fully compressible equations leading to a computationally efficient incompressible formulation. The model uses a Gibbs free energy functional that includes enthalpy of mixing, interfacial energy, and electrostatic contributions. These lead to a new fourth-order term in the mass equations and a reversible stress in the momentum equations. We calibrate our model using parameters for [DMPI+][F6P-], an extensively-studied room temperature ionic liquid (RTIL), and numerically demonstrate the formation of mesoscopic structuring at equilibrium in two and three dimensions. In simulations with electrode boundaries the measured double layer capacitance decreases with voltage, in agreement with theoretical predictions and experimental measurements for RTILs. Finally, we present a shear electroosmosis example to demonstrate that the methodology can be used to model electrokinetic flows.

42 ENGINEERING↗
DOE OSTI2026

Meteor over New York City: Brines in a primitive CM asteroid

The CI (Ivuna-type) carbonaceous material returned from asteroids Ryugu and Bennu contain mobilized sodium from the evaporation or freezing of liquid water into brines, shedding light on the internal structure of ice-rich CI-type worlds and the formation of prebiotic organic compounds. The formation of brines has not been demonstrated in CM (Mighei-type) carbonaceous chondrites, which also supplied organic matter to the early Earth. Here, we announce the fall of a primitive meteorite from a daytime fireball over the New York metropolitan area in July 2024. It is a CM2 breccia that contains unique CM1 clasts rich in water and sodium. The meteorite contains abundant amino acids and other products of organic chemistry in brines that reveal subsurface processes on CM-type asteroid parent bodies.

Geosciences↗
DOE OSTI2022

Experimental Validation and Continuous Testing of an On-Purpose High-Yield Pitch Synthesis Process for Producing Carbon Fiber from US Domestic Coal

This project aims to develop technology that converts domestic United States (US) raw coal to high quality, high value, and marketable carbon fiber. More specifically, the project aims to significantly improve the selectivity and yield of carbon fiber produced per ton of coal over conventional coal pitch-based production by using low-severity direct coal conversion technology to maximize the yield of pitch from coal, suitable for production of carbon fiber. To meet the stated objective of developing a technology platform, capable of producing high quality, high-value and marketable carbon fiber from domestic US coal, the proposed scope of work involves testing of a low-severity direct coal liquefaction (LS-DCL) process approach. The isotropic pitch produced from the LS-DCL process will be thermally treated using conventional processes to convert to a liquid crystal or “mesophase” pitch as a precursor for structural carbon fibers. This mesophase pitch will then be melt-spun into fiber, oxygen stabilized, and carbonized using conventional processes. The resulting carbon fiber will be evaluated for mechanical properties and suitability for structural applications such as automotive parts and spars for wind turbine blades. The overall process is expected to significantly lower the cost of fiber compared to state of the art fibers produced from polyacrylonitrile (PAN) precursors.

01 COAL, LIGNITE, AND PEAT↗
NASA NTRS1968

Panelized high performance multilayer insulation

Multilayer insulation coverings with low conductivity foam spacers are interleaved with quarter mil aluminized polymer film radiation shields to cover flight type liquid hydrogen tankage of space vehicles with a removable, structurally compatible, lightweight, high performance cryogenic insulation capable of surviving extended space mission environments.

Burkley, R. A.↗
NASA NTRS1973

Liquid oxygen-compatible filament-winding matrix resin

Polyurethanes derived from hydroxy terminated polyperfluoro propylene oxide prepolymers were evaluated as matrix resins for filament wound composites which would be exposed to liquid (and 100% gaseous) oxygen environments. A number of structural modifications were brought about by variations in prepolymer molecular weight, and alternative curing agents which allowed retention of the oxygen compatibility. Although satisfactory performance was achieved at sub-ambient temperatures, the derived composites suffered considerable property loss at ambient or slightly elevated temperatures. To attain overall effectiveness of the composite system, upgrading of the polymer thermomechanical properties must first be achieved.

Harrison, E. S.↗
NASA NTRS1974

Quantum crystals in neutron stars

Using the many-body techniques appropriate for quantum crystals it is shown that the deep interior of a neutron star is most likely an orderly arrangement of neutrons, protons and hyperons forming a solid. It is shown that a liquid or gas arrangement would produce higher energy. If so, a neutron star can be viewed as two solids (crust and core) permeated by a layer of ordinary or (perhaps) superfluid liquid. Astronomical evidence is in favor of such a structure: the sudden jumps in the periods of the Crab and Vela pulsars that differ by a factor of about 100 can be easily explained by the star-quake model. If the Crab is less massive than Vela (i.e., if it is not dense enough to have a solid core), the star-quakes take place in the crust whereas for Vela they occur in the core.

Canuto, V.↗
NASA NTRS1976

Waves in active and passive periodic structures - A review

The theory and recent applications of waves in periodic structures are reviewed. Both the Floquet and coupled waves approach are analyzed in some detail. The theoretical part of the paper includes wave propagation in unbounded and bounded active or passive periodic media, wave scattering from periodic boundaries, source radiation (dipole, Cerenkov, transition, and Smith-Purcell) in periodic media, and pulse transmission through a periodic slab. The applications part covers the recent development in a variety of fields: distributed feedback oscillators, filters, mode converters, couplers, second-harmonic generators, deflectors, modulators, and transducers in the fields of integrated optics and integrated surface acoustics. Work on insect compound eyes, mechanical structures, ocean waves, pulse compressions, temperature waves, and cholesteric liquid crystals, and particles interaction with crystals is briefly reviewed, especially in the case of zeolite crystals and superlattices. Recent advances in fabrication techniques for very fine gratings are also covered.

Elachi, C.↗
NASA NTRS1981

Constricted double-heterojunction AlGaAs diode lasers - Structures and electrooptical characteristics

Constricted double-heterojunction (CDH) diode lasers are presented as a class of nonplanar-substrate devices for which the lasing cavity is on the least resistive electrical path between the contact and the substrate. Various CDH structures are discussed while treating such topics as liquid-phase epitaxy over channeled substrates, lateral mode control, and current control in nonplanar-substrate devices. Ridge-guide CDH lasers with positive-index lateral mode confinement provides single-mode CW operation to 7 mW/facet at room temperature and to 3 mW/facet at 150 C, while exhibiting light-current characteristics with second-harmonic distortions as low as -57 dB below the fundamental level. Semileaky guide CDH lasers with an asymmetric leaky cavity provide single-mode operation to 15-20 mW/facet CW, and to 50 mW/facet at 50% duty cycle.

Botez, D.↗
NASA NTRS1985

Promising quantitative nondestructive evaluation techniques for composite materials

Some recent results in the area of the ultrasonic, acoustic emission, thermographic, and acousto-ultrasonic NDE of composites are reviewed. In particular, attention is given to the progress in the use of ultrasonic attenuation, acoustic emission (parameter) delay, liquid-crystal thermography, and the stress wave factor in structural integrity monitoring of composite materials. The importance of NDE flaw significance characterizations is emphasized since such characterizations can directly indicate the appropriate NDE technique sensitivity requirements. The role of the NDE of flawed composites with and without overt defects in establishing quantitative accept/reject criteria for structural integrity assessment is discussed.

Williams, J. H., Jr.↗
NASA NTRS1987

Research and technology, 1987

Three broad goals were presented by NASA as a guide to meet the challenges of the future: to advance scientific knowledge of the planet Earth, the solar system, and the universe; to expand human presence beyond the Earth into the solar system; and to strengthen aeronautics research and technology. Near-term and new-generation space transportation and propulsion systems are being analyzed that will assure the nation access to and presence in space. Other key advanced studies include large astronomical observatories, space platforms, scientific and commercial payloads, and systems to enhance operations in Earth orbit. Longer-range studies include systems that would allow humans to explore the Moon and Mars during the next century. Research programs, both to support the many space missions studied or managed by the Center and to advance scientific knowledge in selected areas, involve work in the areas of atmospheric science, earth science, space science (including astrophysics and solar, magnetospheric, and atomic physics), and low-gravity science. Programs and experiment design for flights on the Space Station, free-flying satellites, and the Space Shuttle are being planned. To maintain a leadership position in technology, continued advances in liquid and solid propellant engines, materials and processes; electronic, structural, and thermal investigations; and environmental control are required. Progress during the fiscal year 1987 is discussed.

Source record↗
NASA NTRS1987

Advanced heavy lift launch vehicles

The performance requirements of advanced technology-incorporating, next-generation heavy lift launch vehicles (HLLVs) for LEO missions are discussed, and the configurational features facilitated by those technologies are evaluated. These 1990s 'cargo' vehicles will capitalize on advanced avionics, software and automation, novel hot structure and thermal insulation materials, and more powerful liquid-fuel rockets employing either hydrogen or hydrocarbons. The configurations considered include a winged booster. The use of Space Shuttle components is a major cost-minimization strategy in many of these HLLV design efforts.

Shelton, Billy W.↗
NASA NTRS1992

Experimental investigation of freezing blowby in a copper/water heat pipe

An experimental investigation designed to evaluate and better define the overall characteristics of freezing blowby in a copper/water heat pipe was conducted. The results from various rates of restart heat addition and channel blockage, indicate that upon breakthrough the depressurization of the evaporator may result in an effective heat transport capacity far in excess of the steady-state transport limit. The resulting transient conditions imposed on the heat pipe by the effective increased heat transport capacity can cause a loss of liquid in the evaporator and potential dryout. Evidence is presented which indicates that in order to prevent either temporary or permanent dryout, sufficient liquid inventory must be present in the evaporator wicking structure to accommodate the increased transient thermal load and allow sufficient time for the capillary wicking structure to reprime.

Ochterbeck, J. M.↗