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At least 1,225 records · Page 68

Method and system for treatment of a gas stream that contains carbon dioxide

A method for separating carbon dioxide (CO2) from a gas stream is disclosed, in which the gas stream is reacted with a lean aminosilicone solvent in an absorber, resulting in a rich aminosilicone solvent that is then treated in a desorber to release the CO2 and regenerate lean aminosilicone solvent in a desorption reaction. The regenerated solvent is directed into a steam-producing, indirect heat exchanger that is configured to supply steam to the desorber at a temperature high enough to augment the desorption reaction. Also, selected amounts of make-up water are added to the rich aminosilicone solvent at one or more process locations between the absorber and the desorber, to lower the viscosity of the solvent and to lower the temperature required for the desorption reaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Separations Consortium: Lignin Rich Stream Fractionation and Purification

In support of the Bioenergy Technologies Office in converting lignin to fuels and chemicals, this project develops scalable separations based on membranes and Electordeionization (EDI) to recover low molecular weight (LMW) compounds from lignin rich streams. The project addresses three technology barriers in developing the bioeconomy; (1) Cost of production (2) Selective separation of organic acid species, and (3) Advanced bioprocess development. Specifically, membrane cascades using Tangential Flow Filtration (TFF) are investigated for the recovery of LMW lignin compounds from lignin rich streams such as Alkaline Pretreatment Liquor (APL), Reductive Catalytic Fractionation (RCF) oil, and Catalytic Oxidation oil. Process concepts, including dynamic filtration, are investigated to meet specific performance targets indicated by the consortium's Industrial Advisory Board for the membrane filtration including maintaining permeance > 1 LMH/bar and an overall cost target of < $1/kg of LMW lignin. EDI is investigated as an integral part of the membrane cascade to recover LMW aromatic acids and as an alternative to nanofiltration. Economic analysis of the processes is presented with a focus on minimizing energy consumption and capital expenditure. Furthermore, a sensitivity analysis is presented to identify key cost drivers and optimize holistic process operating conditions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Next Generation Spectrophotometer System for Enhanced In-process Pu Monitoring of Effluent Waste Streams - 17268

The Next Generation Spectrophotometer (NGS) system is an in-process monitoring system developed by SRNL to determine Pu concentration in nuclear processing streams at the Savannah River Site (SRS). Development of the NGS system began from a need to replace aged Pu monitoring equipment whose measurement uncertainty greatly reduced process throughput. The NGS system implements absorption spectroscopy technology to determine total Pu concentration and Pu valence state distributions by measuring the light absorbance of a solution. The NGS system was completed and installed in the later part of 2016. It provides an excellent example of process intensification, i.e. replacement of aged systems with smarter, more accurate and operationally efficient systems. This paper will detail the capabilities of the NGS system, its application in the nuclear processing stream, and operational challenges working with Pu solutions. Discussion will include the development of the virtual instrument which negates the intrinsic differences between actual instruments and implements a technique that performs continuous intensity and waveform calibration. Other notable features discussed are the development of a new modeling application method which applies custom models based on the current operating region of the process and the ability to perform in-field calibrations using NIST-traceable standards. Lastly, the benefits encapsulated in the final system including the significant improvement in measurement certainty, process intensification efficiencies, and the ease of adaptability of this system for use with other actinide and chemical measurement applications will be discussed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development of High Strength HEPA Filters for Use in Demanding Air and Gas Streams - 17644

High-efficiency particulate air (HEPA) filters are used in a wide variety of applications, including the removal of radioactive particulate from process off-gas streams and the venting of waste storage containers. Porvair Filtration Group, specializing in the design and manufacture of robust filters in numerous industries, has worked to develop HEPA filter designs for use in such high-demand nuclear process-gas and air streams. Using the requirements of section FK of the American Society of Mechanical Engineers AG-1 Code on Nuclear Air and Gas Treatment (ASME AG-1) as a guide, Porvair Filtration Group has designed filters which can withstand upset conditions to include elevated temperatures, high relative humidity, high particle-loading, and an unconventionally high differential pressure across the filter media; while maintaining excellent removal efficiencies. The process by which Porvair Filtration Group has reached optimized designs was based upon an extended test and development program. Design, manufacture, and testing of flat sheet media samples, geometrically equivalent model filters, and full-scale prototypes was performed at several Porvair Filtration Group facilities located in the United States and the United Kingdom. The methods and results of this development program are outlined in the following paper. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Neutron Streaming Problem to Test Rattlesnake Methods for TREAT

This work demonstrates the progress made at Idaho National Laboratory in the neutronic modeling of neutron streaming in the TREAT reactor core. The streaming in the slotted elements is important because of its effect on the axial distribution and energy deposition in the experiment vehicle. Two methods implemented in Rattlesnake: 1) tensor diffusion coefficients and, 2) super-homogenization, yield much improved power distributions using a diffusion solution with homogenized fuel elements. The RMS difference in the power distribution decreases below 0.661% compared to a reference Monte Carlo simulation. The maximum differences are within 1.5% of this reference. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

ASC Poster - Concentration of Xe from Simulated Dissolver Off-gas Streams Utilizing a Solid Sorbent, AgZ-PAN

Idaho National Laboratory (INL) has developed and tested engineered sorbents to separate and capture volatile fission products such iodine (I), xenon (Xe), and krypton (Kr) from off-gas streams. As noble gases, Xe and Kr can be difficult to capture and separate. Historically, cryogenic distillation has been used to execute the separation, but this method can pose significant hazards. INL has successfully developed two sorbents for Xe and Kr capture, silver mordenite polyacrylonitrile (AgZ-PAN) and hydrogen mordenite polyacrylonitrile (HZ-PAN). Adsorption studies to date successfully separated and captured Xe from carrier gas streams, but those studies focused primarily on initial separation and capture. In addition, the ability to concentrate Xe through multiple adsorption and desorption cycles has not been studied and therefore is the focus on this presentation. Concentrating Xe during desorption is ideal to produce Xe that can be used for commercial and research applications.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A regional (land–ocean) comparison of the seasonal to decadal variability of the Northern Hemisphere jet stream 1871–2011

Seasonal to decadal variations in Northern Hemisphere jet stream latitude and speed over land (Eurasia, North America) and oceanic (North Atlantic, North Pacific) regions are presented for the period 1871–2011 from the Twentieth Century Reanalysis dataset. Significant regional differences are seen on seasonal to decadal timescales. Seasonally, the jet latitude range is lower over the oceans compared to land, reduced from 20° over Eurasia to 10° over the North Atlantic where the ocean meridional heat transport is greatest. The mean jet latitude range is at a minimum in winter (DJF), particularly along the western boundary of the North Pacific and North Atlantic, where the land-sea contrast and SST gradients are strongest. The 141-year trends in jet latitude and speed show differences on a regional basis. The North Atlantic has significant increasing jet latitude trends in all seasons, up to 3° in winter. Eurasia has significant increasing trends in winter and summer, however, no increase is seen across the North Pacific or North America. Jet speed shows significant increases evident in winter (up to 4.7 ms –1 ), spring and autumn over the North Atlantic, Eurasia and North America however, over the North Pacific no increase is observed. Long term trends are generally overlaid by multidecadal variability, particularly evident in the North Pacific, where 20-year variability in jet latitude and jet speed are seen, associated with the Pacific Decadal Oscillation which explains 50% of the winter variance in jet latitude since 1940. The results highlight that northern hemisphere jet variability and trends differ on a regional basis (North Atlantic, North Pacific, Eurasia and North America) on seasonal to decadal timescales, suggesting that different mechanisms are influencing the jet latitude and speed. This is important from a climate modelling perspective and for climate predictions in the near and longer term.

54 ENVIRONMENTAL SCIENCES↗

WHONDRS River Corridor Sediment and Water Geochemistry and In Situ Sensor Data from 7 Perennial and 7 Intermittent Streams across San Antonio, Texas (v3)

This dataset supports a broader study examining the effects of intermittency on sediment respiration. The dataset provides sediment and surface water geochemistry and in situ sensor data from 7 perennial and 7 intermittent streams in San Antonio, Texas. Each stream/site was visited both in summer during base flow (July-September 2023) and winter during peak flow (January-February 2024). Related data were collected and will be published separately in collaboration with A. Veach. The data package was originally published in April 2025. It was updated in June 2025 (v2; modified and new files) and September 2025 (v3; modified files). See the change history section in the readme for more details. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. This dataset is comprised of two folders of field photos and videos, one folder of raw Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) data and one main data folder containing (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) readme; (5) international generic sample number (IGSN) mapping file; (6) field protocol; (7) a subfolder with sample data; and (8) a subfolder with sensor data. The sample data subfolder contains (1) surface water and sediment dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data and averages; (2) surface water and sediment total nitrogen data and averages; (3) sediment grain size data; (4) sediment iron (II) data and averages; (5) wet sediment mass, dry sediment mass, water mass, and wet sediment volume in incubation and sediment ICR vials; (7) sediment incubation respiration rate data and averages; (8) normalized respiration rate data and averages; (9) methods codes; (10) sediment percent carbon and nitrogen; (11) sediment X-ray diffraction (XRD) data; (12) gravimetric moisture and averages; (13) a subfolder with sediment incubation respiration data, scripts, and plots; (14) surface water and sediment FTICR methods; and (15) a subfolder of 9.4 Tesla (9.4T) FTICR-MS data. This folder contains five subfolders, one containing the sediment .xml data files, one containing the water .xml files, one containing the sediment CoreMS output files, one containing the water CoreMS output files, and the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). The sensor data subfolder contains (1) a subfolder with miniDOT dissolved oxygen and temperature data and plots; (2) miniDOT dissolved oxygen and temperature summary data; and (3) miniDOT installation methods. All files are .csv, .pdf, .R, .xml, .d, .html, .Rmd, .py, .cal, .json, .jpg, .jpeg, .png, .mov, or .mp4. CORRECTION: The data processing methods for FTICR described in “v3_WHONDRS_AV1_Methods_Codes.csv” mistakenly indicate that users should process the data in Formultitude. The corrected description should read: “Both unprocessed and processed data are provided to allow users flexibility in data processing. Instructions and scripts for processing the data using CoreMS are included.” CORRECTION: Carbon and nitrogen content are reported as percentages. The current column headers "01395_C_percent_per_mg" and "01397_N_percent_per_mg" are incorrect. These should read "01395_C_percent" and "01397_N_percent" and will be corrected in the next version of this data package.

54 ENVIRONMENTAL SCIENCES↗

Substantial soil organic carbon retention along floodplains of mountain streams

Small, snowmelt–dominated mountain streams have the potential to store substantial organic carbon in floodplain sediment because of high inputs of particulate organic matter, relatively lower temperatures compared with lowland regions, and potential for increased moisture conditions. This work (i) quantifies mean soil organic carbon (OC) content along 24 study reaches in the Colorado Rocky Mountains using 660 soil samples, (ii) identifies potential controls of OC content based on soil properties and spatial position with respect to the channel, and (iii) and examines soil properties and OC across various floodplain geomorphic features in the study area. Stepwise multiple linear regression (adjusted r 2 = 0.48, p < 0.001) indicates that percentage of silt and clay, sample depth, percent sand, distance from the channel, and relative elevation from the channel are significant predictors of OC content in the study area. Principle component analysis indicates limited separation between geomorphic floodplain features based on predictors of OC content. A lack of significant differences among floodplain features suggests that the systematic random sampling employed in this study can capture the variability of OC across floodplains in the study area. Mean floodplain OC (6.3 ± 0.3%) is more variable but on average greater than values in uplands (1.5 ± 0.08% to 2.2 ± 0.14%) of the Colorado Front Range and higher than published values from floodplains in other regions, particularly those of larger rivers.

58 GEOSCIENCES↗

Exploratory Visual Analysis of Anomalous Runtime Behavior in Streaming High Performance Computing Applications

Online analysis of runtime behavior is essential for performance tuning in streaming scientific workflows. Integration of anomaly detection and visualization is necessary to support human-centered analysis, such as verification of candidate anomalies utilizing domain knowledge. In this work, we propose an efficient and scalable visual analytics system for online performance analysis of scientific workflows toward the exascale scenario. Here, our approach uses a call stack tree representation to encode the structural and temporal information of the function executions. Based on the call stack tree features (e.g., execution time of the root function or vector representation of the tree structure), we employ online anomaly detection approaches to identify candidate anomalous function executions. We also present a set of visualization tools for verification and exploration in a level-of-detailed manner. General information, such as distribution of execution times, are provided in an overview visualization. The detailed structure (e.g., function invocation relations) and the temporal information (e.g., message communication) of the execution call stack of interest are also visualized. The usability and efficiency of our methods are verified in a real-world HPC application.

97 MATHEMATICS AND COMPUTING↗

Variation in natural attenuation rates of polychlorinated biphenyls (PCBs) in fish from streams and reservoirs in East Tennessee observed over a 35-year period

Environmental contamination due to human activities is a major concern, particularly for persistent chemicals. Within catchments, persistent chemicals linked to negative health outcomes such as polychlorinated biphenyls (PCBs) have great potential to be transported, through adsorption or biological uptake, with downstream locations acting as sinks for accumulation. Here we present long-term trends in PCB bioaccumulation in fish found in lower-order tributaries on the Oak Ridge Reservation, an impacted US Department of Energy property in East Tennessee, USA, and a large reservoir system adjacent to it composed of parts of the Clinch and Tennessee Rivers. Given that the reservoir system has experienced no direct PCB mitigation activities, this record offers an opportunity to explore potential natural attenuation of PCBs within a large lotic ecosystem. Additionally, attenuation rates ranged from 0% to 8% yr -1 in minnows and sunfish at stream sites and 5.4–11.3% yr -1 in catfish at reservoir sites. These rates are comparable to findings from similar studies in other regions, suggesting a consistency in responses since the banning of PCB production in 1979. Further, results suggest that PCB sources from discharge outfalls are important locally but are not primarily responsible for sustaining PCB contamination in downstream reservoirs.

54 ENVIRONMENTAL SCIENCES↗

Near wake evolution of a tidal stream turbine due to asymmetric sheared turbulent inflow with different integral length scales

Tidal stream turbines deployed at highly energetic open water sites are subjected to sheared inflow in the rotor plane. The inflow shear is expected to cause asymmetric loading on the rotor blades and affect the downstream wake. In the current study, two different turbulent inflow conditions, static-high shear and dynamic shear, were generated via an active-grid turbulence generator. A 1:20 scaled three-bladed horizontal axis tidal turbine model was tested in those conditions. The results were compared to a quasi-laminar case with no imposed turbulence or shear. The results show that the high shear reduces the average performance, with a drop of up to 16% in the optimal power coefficient. Besides, the shear profiles increase torque fluctuations and induce significant differences in wake hydrodynamics between the high-speed (upper) and low-speed (lower) regions. The large integral length scales further enhance the load fluctuations perceived by the rotor but have a negligible effect on the mean wake field quantities and the wake recovery. The lower half region featured a faster breakdown of tip vortex structure and a rapid drop of swirl number, a phenomenon conjectured to be a consequence of the strong turbulence intensities and Reynolds stresses in the lower half region. Furthermore, the sheared turbulent inflow also results in a very intensive energy redistribution process towards large-scale, low-frequency motions, which is important to the downstream turbines.

16 TIDAL AND WAVE POWER↗

Characterization of Gulf Stream energy resources: A 30-year high-resolution simulation study

The strength and proximity of the Gulf Stream (GS) along the U.S. coast offers opportunities for marine energy extraction. Leveraging high-resolution (up to 400 m) long-term (30-year) hindcasts based on an unstructured grid model, this study characterizes the energy potential of the GS in two viable locations: the Florida Straits (FS) and Cape Hatteras (CH). Results reveal distinct characteristics in the kinetic energy flux (KEF) and kinetic energy density (KED) for the two regions. The 30-year mean KEF at CH is 27.50 GW, surpassing the 19.74 GW estimated for the FS, which is attributed to the wider cross-section of the GS in CH. Additionally, CH exhibits higher KEF variability due to GS’s larger path shifts and meanders. Estimated KEDs at ADCP site locations reach up to 2,908 W/m 2 in the FS and 1,512 W/m 2 in the CH at a depth of 20 m. High-energy zones are closer to shore in the FS, whereas energy-rich areas at CH are located further offshore. A depth-based KED analysis shows significant decreases across typical energy extraction depths (20 to 100 m), with reductions up to 44%. Finally, this study provides high-resolution resource characterization, forming a foundation for optimized site selection and marine hydrokinetic system design.

16 TIDAL AND WAVE POWER↗

Shock formation processes due to interactions of two plasmas in a magnetic field and modified two-stream instabilities

The study of interactions of exploding and surrounding plasmas in an external magnetic field [K. Yamauchi and Y. Ohsawa, Phys. Plasmas 14, 053110 (2007)] is verified with two-dimensional (2D) electromagnetic particle simulations, for a case in which the initial velocity of the exploding plasma is perpendicular to the external magnetic field. The 2D simulations show essentially the same shock-formation processes as those in the previous one-dimensional simulation, including penetration of exploding ions into surrounding plasma, formation of a strong magnetic-field pulse due to deceleration of the exploding ions, ion reflection by the pulse, and subsequent splitting of the pulse into two magnetosonic pulses which then develop into forward and reverse shock waves. Furthermore, the 2D structure of electromagnetic fields in the region, where the exploding and surrounding ions overlap, is investigated with particular attention to the linear and nonlinear evolution of modified two-stream instabilities in the magnetic field that is being gradually compressed. The effects of these instabilities on ion reflection and on 2D magnetic fluctuations in the two generated pulses are also discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Transient growth of droplet instabilities in a stream

Droplet deformation is the first stage of all aerodynamically induced-breakups, considerably affecting the characteristics of the atomization. In the present study, using an adaptive volume of fluid method, two and three-dimensional direct numerical simulations have been performed to understand droplet deformation. A high Reynolds number and a range of relatively high Weber numbers are chosen, addressing the shear breakup of droplets in a stream. The study is focused on the initiation and growth of instabilities over the droplet. The role of Kelvin-Helmholtz and Rayleigh-Taylor instabilities in wave formation and azimuthal transverse modulation are shown and the obtained results for the most amplified wave-numbers are compared with instability theories for zero and non-zero vorticity layers. The present results for the most amplified wave-numbers and deformation topologies are in good agreement with the previous experimental results.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

An axially propagating two-stream instability in the Hall thruster plasma

Collective Thomson scattering experiments reveal the presence of high-frequency, axial electron density fluctuations at millimetric wavelengths in the Hall thruster plasma. The properties of these fluctuations are investigated experimentally and via linear kinetic theory. The relative drift of electrons and ions in the axial direction is found to be insufficient to cause excitation of the observed mode. Instead, the mode is determined to be a two-stream instability arising due to the velocity difference between singly and doubly charged ion populations in the plume.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Oscillating two-stream instability in a magnetized electron-positron-ion plasma

Oscillating two-stream instability (OTSI) in a magnetized electron-ion plasma has been thoroughly studied, e.g., in ionospheric heating experiments [C. S. Liu and V. K. Tripathi, Interaction of Electromagnetic Waves With Electron Beams and Plasmas (World Scientific, 1994); V. K. Tripathi and P. V. Siva Rama Prasad, J. Plasma Phys. 41, 13 (1989); K. Ramachandran and V. K. Tripathi, IEEE Trans. Plasma Sci. 25, 423 (1997)]. In this paper, OTSI is investigated in a magnetized electron-positron-ion plasma. The dispersion relation of the process is established. The pump field threshold, along with the maximum growth rate of the instability is assessed using the Arecibo and HAARP parameters.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗