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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Understanding Proton Movement in [Fe-Fe] Hydrogenases

Nature uses specialized metalloenzymes to carry out small molecule activation reactions, including CO 2 fixation, O 2 activation, and proton reduction, with unparalleled efficiency, rates, and selectivity. The latter reactions are performed by hydrogenases, protein metallo-complexes that interconverts H 2 to protons and electrons (H 2 oxidation) and the reverse reaction (H 2 production) with incredibly low energy input and amazingly fast kinetics. Reproducing both the activity and efficiency of metalloenzymes in sustainable anthropogenic systems remains one of the “holy grails” of inorganic chemistry. However, identifying the precise molecular components responsible for these desirable properties has been challenging in the natural metalloenzymes, hindering efforts to develop analogous processes in synthetic compounds. Considering the inherent complexity of a metalloenzyme and the many interactions, both strong and weak, that contribute to the function of an enzyme, we have elected to model natural metalloenzymes on a biochemical platform. Towards this end, we have a developed structural, functional, and mechanistic mimic of the [Ni-Fe] hydrogenases within a robust protein scaffold, rubredoxin, to understand the influence of the secondary coordination environment on the metal center. This involved preparing a series of three rubredoxin constructs containing a single point mutation at Val positions and making the NMR chemical shift assignments for the paramagnetic (nickel-substituted) and non-paramagnetic (zinc-substituted) form. These physical studies were complemented with in silico molecular dynamic studies on proteins with [Fe-S] clusters to engineer new proton channels to test in vitro . To assist our search for new natural metalloprotein scaffolds within the vast number of sequenced genomes, we created a neural network-based program to identify proteins with specific metal-binding sites. These computational and physical studies with metalloenzymes provide direct insight into the fundamental chemical principles driving the natural systems and offer design principles for developing catalysts that utilize analogous principles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1980

Development of a nitrogen generation system

An eight-stage nitrogen generation module was developed. The design integrated a hydrazine catalytic dissociator, three ammonia dissociation stages and four palladium/silver hydrogen separator stages. Alternating ammonia dissociation and hydrogen separation stages are used to remove hydrogen and ammonia formed in the dissociation of hydrazine which results in negligible ammonia and hydrogen concentrations in the product nitrogen stream. An engineering breadboard nitrogen supply subsystem was also developed. It was developed as an integratable subsystem for a central spacecraft air revitalization system. The subsystem consists of the hydrazine storage and feed mechanism, the nitrogen generation module, the peripheral mechanical and electrical components required to control and monitor subsystem performance, and the instrumentation required to interface with other subsystems of an air revitalization system. The breadboard nitrogen supply subsystem was integrated and tested with a one-person capacity experimental air revitalization system. The integration, checkout and testing was successfully accomplished.

Heppner, D. B.↗
NASA NTRS1981

Investigation of a method for repairing the hot gas system branch 2 of the Symphonie-Satellite MV2 in orbit

The failure of all engines on the Symphonie MV2 satellite is attributed to blockage of the oxidizer branch caused by metal salts precipitating and forming a gel which constricts the narrow passage. Laboratory tests and other simulations conducted to observe the behavior of artificially produced jellies on a vacuum show that a removal or at least a reduction of the blockage in the oxidizer branch is possible by evacuation. The greatest blockage appears to occur in the filter. This fact restricts the capability to perform repairs in orbit because the filter installed ahead of the valve cannot by subjected to a vacuum.

Braun, H.↗
NASA NTRS1982

Advanced ceramic coating development for industrial/utility gas turbines

A program was conducted with the objective of developing advanced thermal barrier coating (TBC) systems. Coating application was by plasma spray. Duplex, triplex and graded coatings were tested. Coating systems incorporated both NiCrAly and CoCrAly bond coats. Four ceramic overlays were tested: ZrO2.82O3; CaO.TiO2; 2CaO.SiO2; and MgO.Al2O3. The best overall results were obtained with a CaO.TiO2 coating applied to a NiCrAly bond coat. This coating was less sensitive than the ZrO2.8Y2O3 coating to process variables and part geometry. Testing with fuels contaminated with compounds containing sulfur, phosphorus and alkali metals showed the zirconia coatings were destabilized. The calcium titanate coatings were not affected by these contaminants. However, when fuels were used containing 50 ppm of vanadium and 150 ppm of magnesium, heavy deposits were formed on the test specimens and combustor components that required frequent cleaning of the test rig. During the program Mars engine first-stage turbine blades were coated and installed for an engine cyclic endurance run with the zirconia, calcium titanate, and calcium silicate coatings. Heavy spalling developed with the calcium silicate system. The zirconia and calcium titanate systems survived the full test duration. It was concluded that these two TBC's showed potential for application in gas turbines.

Vogan, J. W.↗
NASA NTRS1989

NASA/RAE cooperation on a knowlede based flight status monitor

As part of a US/UK cooperative aeronautical research pragram, a joint activity between the Dryden Flight Research Facility of the NASA Ames Research Center (Ames-Dryden) and the Royal Aerospace Establishment (RAE) on Knowledge Based Systems was established. Under the agreement, a Flight Status Monitor Knowledge base developed at Ames-Dryden was implemented using the real-time IKBS toolkit, MUSE, which was developed in the UK under RAE sponsorship. The Flight Status Monitor is designed to provide on-line aid to the flight test engineer in the interpretation of system health and status by storing expert knowledge of system behavior in an easily accessible form. The background to the cooperation is described and the details of the Flight Status Monitor, the MUSE implementation are presented.

Butler, G. F.↗
NASA NTRS1989

Reusable rocket engine turbopump health monitoring system, part 3

Degradation mechanisms and sensor identification/selection resulted in a list of degradation modes and a list of sensors that are utilized in the diagnosis of these degradation modes. The sensor list is divided into primary and secondary indicators of the corresponding degradation modes. The signal conditioning requirements are discussed, describing the methods of producing the Space Shuttle Main Engine (SSME) post-hot-fire test data to be utilized by the Health Monitoring System. Development of the diagnostic logic and algorithms is also presented. The knowledge engineering approach, as utilized, includes the knowledge acquisition effort, characterization of the expert's problem solving strategy, conceptually defining the form of the applicable knowledge base, and rule base, and identifying an appropriate inferencing mechanism for the problem domain. The resulting logic flow graphs detail the diagnosis/prognosis procedure as followed by the experts. The nature and content of required support data and databases is also presented. The distinction between deep and shallow types of knowledge is identified. Computer coding of the Health Monitoring System is shown to follow the logical inferencing of the logic flow graphs/algorithms.

Perry, John G.↗
NASA NTRS1993

Fail-Safe Pressure Plug

Protective plug resists slowly built-up pressure or automatically releases itself if pressure rises suddenly. Seals out moisture at pressures ranging from 50 micrometers of mercury to 200 pounds per square inch. Designed to seal throat of 38 Reaction Control Thrusters on Space Shuttle protecting internal components from corrosion. Plug conforms to contour of nozzle throat, where O-ring forms pressure seal. After plug inserted, cover attached by use of cover-fitting assembly. Modified versions useful in protecting engines, pumps, reaction vessels, and other industrial equipment during shipment and maintenance.

Svejkovsky, Paul A.↗
NASA NTRS1993

The theory of interface slicing

Interface slicing is a new tool which was developed to facilitate reuse-based software engineering, by addressing the following problems, needs, and issues: (1) size of systems incorporating reused modules; (2) knowledge requirements for program modification; (3) program understanding for reverse engineering; (4) module granularity and domain management; and (5) time and space complexity of conventional slicing. The definition of a form of static program analysis called interface slicing is addressed.

Beck, Jon↗
NASA NTRS1992

Capacitance-type blade-tip clearance measurement system using a dual amplifier with ramp/dc inputs and integration

The analysis and prototype results of a dual-amplifier circuit for measuring blade-tip clearance in turbine engines are presented. The capacitance between the blade tip and mounted capacitance electrode within a guard ring of a probe forms one of the feedback elements of an operational amplifier (op amp). The differential equation governing the circuit taking into consideration the nonideal features of the op amp was formulated and solved for two types of inputs (ramp and dc) that are of interest for the application. Under certain time-dependent constraints, it is shown that (1) with a ramp input the circuit has an output voltage proportional to the static tip clearance capacitance, and (2) with a dc input, the output is proportional to the derivative of the clearance capacitance, and subsequent integration recovers the dynamic capacitance. The technique accommodates long cable lengths and environmentally induced changes in cable and probe parameters. System implementation for both static and dynamic measurements having the same high sensitivity is also presented.

Sarma, Garimella R.↗
NASA NTRS1939

A simplified method for the calculation of airfoil pressure distribution

A method is presented for the rapid calculation of the pressure distribution over an airfoil section when the normal-force distribution and the pressure distribution over the "base profile" (i.e., the profile of the same airfoil were the camber line straight and the resulting airfoil at zero angle of attack) are known. This note is intended as a supplement to N.A.C.A. Report Nos. 631 and 634 wherein methods are presented for the calculation of the normal-force distribution over plain and flapped airfoils, respectively, but not of the pressures on the individual surfaces. Base-profile pressure-coefficient distributions for the usual N.A.C.A. family of airfoils, which are also suitable for several other commonly employed airfoils, are included in tabular form. With these tabulated base-profile pressures and the computed normal-force distributions, pressure distributions adequate for most engineering purposes can be obtained.

Allen, H Julian↗
NASA NTRS1926

Comparison of Tests on Air Propellers in Flight with Wind Tunnel Model Tests on Similar Forms

The purpose of this investigation was to determine the performance, characteristics, and coefficients of full-sized air propellers in flight and to compare these results with those derived from wind-tunnel tests on reduced scale models of similar geometrical form. The full-scale equipment comprised five propellers in combination with a VE-7 airplane and Wright E-4 engine. This part of the work was carried out at the Langley Memorial Aeronautical Laboratory, between May 1 and August 24, 1924, and was under the immediate charge of Mr. Lesley. The model or wind-tunnel part of the investigation was carried out at the Aerodynamic Laboratory of Stanford University and was under the immediate charge of Doctor Durand. A comparison of the curves for full-scale results with those derived from the model tests shows that while the efficiencies realized in flight are close to those derived from model tests, both thrust developed and power absorbed in flight are from 6 to 10 per cent greater than would be expected from the results of model tests.

Durand, W F↗
NASA NTRS1993

On the design of structural components using materials with time-dependent properties

The application of the elastic-viscoelastic correspondence principle is presented as a design tool for structural design engineers for composite material applications. The classical problem of cantilever beams is used as the illustration problem. Both closed-form and approximate numerical solutions are presented for several different problems. The application of the collocation method is presented as a viable and simple design tool to determine the time-dependent behavior and response of viscoelastic composite beams under load.

Rodriguez, Pedro I.↗
NASA NTRS1999

Evaluation of the Linear Aerospike SR-71 Experiment (LASRE) Oxygen Sensor

The Linear Aerospike SR-71 Experiment (LASRE) was a propulsion flight experiment for advanced space vehicles such as the X-33 and reusable launch vehicle. A linear aerospike rocket engine was integrated into a semi-span of an X-33-like lifting body shape (model), and carried on top of an SR-71 aircraft at NASA Dryden Flight Research Center. Because no flight data existed for aerospike nozzles, the primary objective of the LASRE flight experiment was to evaluate flight effects on the engine performance over a range of altitudes and Mach numbers. Because it contained a large quantity of energy in the form of fuel, oxidizer, hypergolics, and gases at very high pressures, the LASRE propulsion system posed a major hazard for fire or explosion. Therefore, a propulsion-hazard mitigation system was created for LASRE that included a nitrogen purge system. Oxygen sensors were a critical part of the nitrogen purge system because they measured purge operation and effectiveness. Because the available oxygen sensors were not designed for flight testing, a laboratory study investigated oxygen-sensor characteristics and accuracy over a range of altitudes and oxygen concentrations. Laboratory test data made it possible to properly calibrate the sensors for flight. Such data also provided a more accurate error prediction than the manufacturer's specification. This predictive accuracy increased confidence in the sensor output during critical phases of the flight. This paper presents the findings of this laboratory test.

Ennix, Kimberly A.↗
NASA NTRS1999

Evaluation of the Linear Aerospike SR-71 Experiment (LASRE) Oxygen Sensor

The Linear Aerospike SR-71 Experiment (LASRE) was a propulsion flight experiment for advanced space vehicles such as the X-33 and reusable launch vehicle. A linear aerospike rocket engine was integrated into a semi-span of an X-33-like lifting body shape (model), and carried on top of an SR-71 aircraft at NASA Dryden Flight Research Center. Because no flight data existed for aerospike nozzles, the primary objective of the LASRE flight experiment was to evaluate flight effects on the engine performance over a range of altitudes and Mach numbers. Because it contained a large quantity of energy in the form of fuel, oxidizer, hypergolics, and gases at very high pressures, the LASRE propulsion system posed a major hazard for fire or explosion. Therefore, a propulsion-hazard mitigation system was created for LASRE that included a nitrogen purge system. Oxygen sensors were a critical part of the nitrogen purge system because they measured purge operation and effectiveness. Because the available oxygen sensors were not designed for flight testing, a laboratory study investigated oxygen-sensor characteristics and accuracy over a range of altitudes and oxygen concentrations. Laboratory test data made it possible to properly calibrate the sensors for flight. Such data also provided a more accurate error prediction than the manufacturer's specification. This predictive accuracy increased confidence in the sensor output during critical phases of the flight. This paper presents the findings of this laboratory test.

Ennix, Kimberly A.↗
NASA NTRS2002

Global Reference Atmospheric Model and Trace Constituents

Global Reference Atmospheric Model (GRAM-99) is an engineering-level model of the Earth's atmosphere. It provides both mean values and perturbations for density, temperature, pressure, and winds, as well as monthly- and geographically-varying trace constituent concentrations. From 0-27 km, thermodynamics and winds are based on National Oceanic and Atmospheric Administration Global Upper Air Climatic Atlas (GUACA) climatology. Above 120 km, GRAM is based on the NASA Marshall Engineering Thermosphere (MET) model. In the intervening altitude region, GRAM is based on Middle Atmosphere Program (MAP) climatology that also forms the basis of the 1986 COSPAR Intemationa1 Reference Atmosphere (CIRA). MAP data in GRAM are augmented by a specially-derived longitude variation climatology. Atmospheric composition is represented in GRAM by concentrations of both major and minor species. Above 120 km, MET provides concentration values for N2, O2, Ar, O, He, and H. Below 120 km, species represented also include H2O, O3, N2O, CO, CH, and CO2. Water vapor in GRAM is based on a combination of GUACA, Air Force Geophysics Laboratory (AFGL), and NASA Langley Research Center climatologies. Other constituents below 120 km are based on a combination of AFGL and h4AP/CIRA climatologies. This report presents results of comparisons between GRAM Constituent concentrations and those provided by the Naval Research Laboratory (NRL) climatology of Summers (NRL,/MR/7641-93-7416, 1993). GRAM and NRL concentrations were compared for seven species (CH4, CO, CO2, H2O, N2O, O2, and O3) for months January, April, July, and October, over height range 0-115 km, and latitudes -90deg to + 90deg at 10deg increments. Average GRAM-NRL correlations range from 0.878 (for CO) to 0.975 (for O3), with an average over all seven species of 0.936 (standard deviation 0.049).

Justus, C.↗
NASA NTRS1976

Heart Sonar Images

Stanford University cardiologists, with the help of Ames engineers, have validated the operation of the echo-cardioscope to monitor cardiac functions of astronauts in flight. This device forms images of internal structures using high-frequency sound. The instrument is compact, lightweight, portable, and DC powered for safety. The battery powered ultrasonic device, being isolated from its electrical environment, has an inherent safety advantage especially with infants.

Source record↗
NASA NTRS2003

Overview of NASA's UEET and TBCC/RTA Programs

A general overview of NASA's Ultra Efficient Engine Technology (UEET) and Turbine Based Combined Cycle (TBCC)/Revolutionary Turbine Accelerator (RTA) is presented. This paper is in viewgraph form.

Shaw, Robert J.↗
NASA NTRS2004

Earth GRAM-99 and Trace Constituents

Global Reference Atmospheric Model (GRAM-99) is an engineering-level model of Earth's atmosphere. It provides both mean values and perturbations for density, temperature, pressure, and winds, as well as monthly- and geographically-varying trace constituent concentrations. From 0-27 km, GRAM thermodynamics and winds are based on National Oceanic and Atmospheric Administration Global Upper Air Climatic Atlas (GUACA) climatology. Above 120 km, GRAM is based on the NASA Marshall Engineering Thermosphere (MET) model. In the intervening altitude region, GRAM is based on Middle Atmosphere Program (MAP) climatology that also forms the basis of the 1986 COSPAR International Reference Atmosphere (CIRA). Atmospheric composition is represented in GRAM by concentrations of both major and minor species. Above 120 km, MET provides concentration values for N2, O2, Ar, O, He, and H. Below 120 km, species represented also include H2O, O3, N2O, CO, CH4, and CO2. At COSPAR 2002 a comparison was made between GRAM constituents below 120 km and those provided by Naval Research Laboratory (NRL) climatology. No current need to update GRAM constituent climatology in that height range was identified. This report examines GRAM (MET) constituents between 100 and 1000 km altitudes. Discrepancies are noted between GRAM (MET) constituent number densities and mass density or molecular weight. Near 110 km altitude, there is up to about 25% discrepancy between MET number density and mass density (with mass density being valid and number densities requiring adjustment). Near 700 km altitude there is also up to about 25% discrepancy between MET number density and mean molecular weight (with molecular weight requiring adjustment). In neither case are MET mass density estimates invalidated. These discrepancies have been traced to MET subroutines SLV (which affects 90-170 km height range) and SLVH (which affects helium above 440 km altitude). With these discrepancies corrected, results are presented to illustrate GRAM (MET) constituent mole fractions in terms of height-latitude cross sections from 100 to 1000 km altitude, and latitude-longitude 'maps' at 450 km (approximate height of International Space Station). Plans are discussed for an update of MET (and GRAM) to correct these constituent inconsistencies and to incorporate several new thermospheric model features.

Justus, C. G.↗