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At least 1,225 records · Page 68

Power-Law Entanglement and Hilbert Space Fragmentation in Nonreciprocal Quantum Circuits

Quantum circuits utilizing measurement to evolve a quantum wave function offer a new and rich playground to engineer unconventional entanglement dynamics. Here, in this work, we introduce a hybrid, nonreciprocal setup featuring a quantum circuit, whose updates are conditioned on the state of a classical dynamical agent. In our example the circuit is represented by a Majorana quantum chain controlled by a classical N-state Potts chain undergoing pair flips. The local orientation of the classical spins controls whether randomly drawn local measurements on the quantum chain are allowed or not. This imposes a dynamical kinetic constraint on the entanglement growth, described by the transfer matrix of an N-colored loop model. It yields an equivalent description of the circuit by an SU(N)-symmetric Temperley-Lieb Hamiltonian or by a kinetically constrained surface growth model for an N-component height field. For N = 2, we find a diffusive growth of the half-chain entanglement toward a stationary profile S(L) ~ L 1/2 for L sites. For N ≥ 3, the kinetic constraints impose Hilbert space fragmentation, yielding subdiffusive growth toward S(L) ~ L 0.57 . This showcases how the control by a classical dynamical agent can enrich the entanglement dynamics in quantum circuits, paving a route toward novel entanglement dynamics in nonreciprocal hybrid circuit architectures.

1-dimensional spin chains↗

Supplement to the December 1974 Space Investigation Documentation System (SIDS) report

A listing and brief description of spacecraft and experiments designed to update the December 1974 Space Investigations Documentation System (SIDS) report to March 31, 1975 was presented. The information is given in two sections. In the first, spacecraft and experiment descriptions are sorted by spacecraft common name. Within each spacecraft lising, experiments are sorted by the principal investigator's or team leader's last name. Each spacecraft entry heading contains the spacecraft common name, alternate names, NSSDC ID code, last reported state of the spacecraft, actual or planned launch date, weight, launch site and vehicle, sponsor, orbit parameters, personnel. Each experiment entry heading contains the experiment name, NSSDC ID code, last reported status, the Office of Space Science (OSS) division, the relevant SIDS disciplines, personnel. In the second, all spacecraft and experiment names described in the previous section and in the December 1974 report are sorted out.

Source record↗

Lunar landing and launch facilities and operations

A preliminary definition of a lunar landing and launch facility (LLLF or Complex 391) has been formulated. A Phase 3 lunar base is considered. Without specifying specific lunar base scenarios, three traffic levels are envisioned: 6, 12, and 24 landings/launches per year. A single, multipurpose vehicle for the lunar module is assumed. The design and specification of the vehicle and of the lunar base are outside the scope of this study. However, these two items will impact those items considered within the scope of this study because of interactions at the system boundaries. The scope of this study is graphically portrayed with the systems diagram. Based upon this diagram, nine major design items or areas are considered. These items are: (1) landing/launch site considerations; (2) structure, shelter, safety, and environmental needs; (3) landing/launch guidance, communications, and computing needs; (4) lunar module surface transport system; (5) heavy cargo unloading/loading systems; (6) personnel unloading/loading systems; (7) propellant unloading/loading systems; (8) vehicle storage; and (9) maintenance, repair, test and check-out requirements. Initially, a general, conceptual description of each of these items is given. Then, preliminary sizes, capacities, and other relevant design data for some of these items are identified. The Earth-Moon transportation infrastructure and the baseline lunar module design are summarized.

Source record↗

Evaluation of Robotic Systems to Carry Out Traverse Execution, Opportunistic Science, and Landing Site Evaluation Tasks

This report covers the execution of and results from the activities proposed and approved in Exploration Analogs and Mission Development (EAMD) Field Test Protocol HMP2010: Evaluation of Robotic Systems to carry out Traverse Execution, Opportunistic Science, and Landing Site Evaluation Tasks. The field tests documented in this report examine one facet of a larger program of planetary surface exploration. This program has been evolving and maturing for several years, growing from a broad policy statement with a few specified milestones for NASA to an international effort with much higher fidelity descriptions of systems and operations necessary to accomplish this type of exploration.

Hoffman, Stephen J.↗

Immobilization of “Capping Arene” Cobalt(II) Complexes on Ordered Mesoporous Carbon for Electrocatalytic Water Oxidation

We report the synthesis, characterization, and electrocatalytic water oxidation activity of two cobalt complexes, (6-FP)Co(NO 3 ) 2 (1) (6-FP = 8,8'-(1,2-phenylene)diquinoline) and (5-FP)Co(NO 3 ) 2 (2) (5-FP = 1,2-bis(N-7-azaindolyl)benzene), containing "capping arene" bidentate ligands with nitrogen atom donors. The cobalt complexes 1 and 2 were supported on ordered mesoporous carbon (OMC) by π-π stacking, resulting in heterogenized cobalt materials 6-FP-Co-OMC-1 and 5-FP-Co-OMC-2, respectively, and studied for electrocatalytic water oxidation. We find that 6-FP-Co-OMC-1 exhibits an overpotential of 355 mV for a current density of 10 mA cm -2 and a turnover frequency (TOF) of ~0.53 s -1 at an overpotential of 400 mV at pH 14. 6-FP-Co-OMC-1 exhibits activity that is ~1.6 times that of 5-FP-Co-OMC-2, which gives a TOF of 0.32 s -1 at 400 mV overpotential. The structural stability of the single-atom Co site was demonstrated for 6-FP-Co-OMC-1 using X-ray absorption spectroscopy for the molecular complex supported on OMC, but slow degradation in catalyst activity can be attributed to eventual formation of Co oxide clusters. DFT computations of electrocatalytic water oxidation using the molecular complexes as models provide a description of the catalytic mechanism. These studies reveal that the mechanism for O-O bond formation involves an intermediate Co IV oxo complex that undergoes an intramolecular reductive O-O coupling to form a Co II -OOH species. Further, the calculations predict that the molecular 6-FP-Co structure is more active for electrocatalytic water oxidation than 5-FP-Co, which is consistent with experimental studies of 6-FP-Co-OMC-1 and 5-FP-Co-OMC-2, highlighting the possibility that the ligand structure influences the catalytic activity of the supported molecular catalysts.

25 ENERGY STORAGE↗

Maintenance of Time and Frequency in the DSN Using the Global Positioning System

The Deep Space Network must maintain time and frequency within specified limits in order to accurately track the spacecraft engaged in deep space exploration. The DSN has three tracking complexes, located approximately equidistantly around the Earth. Various methods are used to coordinate the clocks among the three complexes. These methods include Loran-C, TV Line 10, very long baseline interferometry (VLBI), and the Global Positioning System (GPS). The GPS is becoming increasingly important because of the accuracy, precision, and rapid availability of the data; GPS receivers have been installed at each of the DSN complexes and are used to obtain daily time offsets between the master clock at each site and UTC(USNO/NBS). Calculations are made to obtain frequency offsets and Allan variances. These data are analyzed and used to monitor the performance of the hydrogen masers that provide the reference frequencies for the DSN frequency and timing system (DFT). A brief history of the GPS timing receivers in the DSN, a description of the data and information flow, data on the performance of the DSN master clocks and GPS measurement system, and a description of hydrogen maser frequency steering using these data are presented.

Clements, P. A.↗

High-speed optical photometry of the DQ Herculis object H2215-086

The paper presents the results of high-time-resolution white-light photometry of H2215-086 obtained at Las Campanas Observatory and Cerro Tololo Inter-American Observatory during 1985-1987. Descriptions of periodic features, including power spectra due to rotational and orbital modulation, are presented as well as quasi-periodic features. It is found that H2215-086 displays large-amplitude modulations in its optical, IR, and X-ray emission on the 20.9 min rotational period of the white dwarf. Possible sites for this emission are discussed.

Steiman-Cameron, Thomas Y.↗

Constraints on the Lithological Variation near the Surface of the HED Planetoid from the Petrology of 91 & 92 Series Antarctic Achondrites

The petrography of a suite of meteorite sections: PCA91006,14; PCA91078,9; PCA91083,6; PCA91159,4; PCA91179,9; PCA91245,9; EET92003,14; EET92004,12; EET92015,4; EET92022,7; EET92026,4; and EET92027,5 is used as an initial sample of the lithological variation on the surface of the HED planetoid (presumably asteroid 4 Vesta). These samples will be combined with much larger arrays of petrographic data for the many Antarctic basaltic achondrites to provide a random sample of the surface of the body. The full variety of the lithologies existing on the parent body is only accessible when the polymict achondrites are considered. The polymict samples contain lithologies that sample multiple provenances as well as those not seen as monolithologic meteorites like eucrites and diogenites. Comparison of lithological variation within individual meteorites provides a subset of variations at the site of last impact. In aggregate, the variations within the achondrites now available may be close to a random sample of the parent body. In combination of microanalytical and imaging techniques now available permit a mass balanced assessment of the distribution and abundance of lithologies to be made. These initial results provide a description of methodology to be tested. All samples were studied and photographed on a polarizing microscope to provide location information. Major mineral phases and randomly selected points (on lines and grids) were analyzed in each thin section. In addition backscattered electron and X-ray imaging of clasts and sections provide the basis for high precision modal analyses of the abundance and distribution of both lithic and mineral clasts. These data provide objective, area based comparisons with other Antarctic samples.

Bjonnes, Emily E.↗

Denudation, solute export, landscape evolution modeling, and geographic information system data for the East River watershed, Colorado, USA (2020-2024)

This data package contains geographic information system (GIS) layers and tabular datasets associated with the study of lithologic controls on denudation, solute export, carbon-scaling relationships, and transient landscape evolution in the East River watershed near Crested Butte, Colorado, USA. The package includes GIS layers used to produce the Figure 2 map, including drainage, hillshade, lithology, sample locations, and basin polygons, together with comma-separated value (CSV) tables and matching CSV data dictionaries. One group of tables reports sample-level and catchment-level information for river-sediment samples analyzed for in situ-produced cosmogenic beryllium-10 (10Be), including sample names, outlet elevations, geographic coordinates, upstream drainage area, rock-type classes, production-rate scaling scheme, analyzed nuclide, catchment-averaged denudation rates, and associated lower and upper analytical uncertainties. Sample and catchment attributes provide the basis for comparing denudation rates across intrusive, shale, sedimentary, and mixed-lithology settings. A second group of tables reports supporting information for landscape-evolution modeling and the mapped geologic framework of the study area. Included files list parameter values and definitions for the two-phase landscape-evolution simulations, summarize full-domain model erosion fluxes and topographic metrics for different simulation configurations, provide a fixed-area carbon-model scaling table, and summarize mapped geologic units within the East River study domain, including geologic code, formation name, lithologic description, mapped area, and lithologic class grouping. Model outputs and geologic summaries support interpretation of transient landscape behavior and its relation to the mapped distribution of shale, intrusive, sedimentary, and surficial units. A third group of tables reports hydrologic and hydrochemical information used to quantify dissolved export from the watershed. Included files provide site-level values for drainage area, mean annual solute export, standard error of annual export, area-normalized solute yield, and equivalent weathering rate for five East River monitoring sites, along with metadata describing the number, sampling cadence, and date range of discharge records and partial and full total dissolved solids observations used in the solute-yield analyses. The package also contains a supplementary daily ion-load time series with daily mean discharge, discharge observation counts, dissolved concentrations, and daily loads for calcium, magnesium, sodium, potassium, chloride, sulfate, nitrate, fluoride, dissolved silica, charge-balance bicarbonate, and total dissolved solids. The package contains GIS files, comma-separated value files (.csv), CSV data dictionaries, a file-level metadata table, a package-tree text file, and a readme text file.

10Be↗

NRAP-Open-IAM Multisegmented Wellbore Reduced-Order Model

Geologic carbon storage is one of the promising strategies to mitigate climate change by reducing the emission of carbon dioxide to the atmosphere. As part of the National Risk Assessment Partnership (NRAP), a systems-level stochastic analysis tool called the open source integrated assessment model, NRAP-Open-IAM, has been developed to estimate and manage the risk of containment loss at a geological carbon sequestration site. NRAP-Open-IAM contains several wellbore leakage model components that estimate the fluid leak rate that may occur through compromised legacy wells due to the increase in pressure resulting from CO 2 injection activities. Coupled to a reservoir component model, these components estimate the leakage of CO 2 and/or brine from a storage reservoir to overlying aquifer layers and the atmosphere through legacy wells. This report presents the theoretical framework and quality testing of the multisegmented wellbore reduced-order model. The model allows for segmenting of the legacy wells passing through the overlying stratigraphy into several intervals to simulate a site’s specific stratigraphic and hydrogeologic properties. For quality assurance, the analytical model is validated against numerical reservoir flow simulations for single and multiple aquifer(s) models. The results indicate that the model accurately predicts the transport of two-phase fluids (brine and injected CO 2 ) through the well over time. A detailed description of the model helps users to understand the model and provides a basis for future improvements.

58 GEOSCIENCES↗

Performance Analysis of Terrain Relative Navigation Using Blue Origin New Shepard Suborbital Flight Telemetry

As part of a NASA Tipping Point Partnership with Blue Origin to mature precision lunar landing technologies, two test flights of the Blue Origin New Shepard vehicle carrying a NASA-developed sensor suite were conducted on 10/13/2020 and 08/26/2021 at the West Texas Launch Site (LS-1). Part of the acquired datasets, comprising data from an inertial measurement unit and a downward facing camera, was postprocessed through a JPL-developed prototype Visual Odometry and Map Relative Localization software (TRNVOSIM), and compared against ground truth acquired by the host vehicle navigation system. In this paper, we provide a description of the algorithms, the test setup, and the processed results.

Pedrotty, Samuel M.↗

Data Science-Driven Analysis of Substrate-Permissive Diketopiperazine Reverse Prenyltransferase NotF: Applications in Protein Engineering and Cascade Biocatalytic Synthesis of (-)-Eurotiumin A

Prenyltransfer is an early-stage carbon-hydrogen bond (C-H) functionalization prevalent in the biosynthesis of a diverse array of biologically active bacterial, fungal, plant, and metazoan diketopiperazine (DKP) alkaloids. Toward the development of a unified strategy for biocatalytic construction of prenylated DKP indole alkaloids, we sought to identify and characterize a substrate-permissive C2 reverse prenyltransferase (PT). As the first tailoring event within the biosynthesis of cytotoxic notoamide metabolites, PT NotF catalyzes C2 reverse prenyltransfer of brevianamide F. Solving a crystal structure of NotF (in complex with native substrate and prenyl donor mimic dimethylallyl S-thiolodiphosphate (DMSPP)) revealed a large, solvent-exposed active site, intimating NotF may possess a significantly broad substrate scope. To assess the substrate selectivity of NotF, we synthesized a panel of 30 sterically and electronically differentiated tryptophanyl DKPs, the majority of which were selectively prenylated by NotF in synthetically useful conversions (2 to > 99%). Quantitative representation of this substrate library and development of a descriptive statistical model provided insight into the molecular origins of NotF's substrate promiscuity. This approach enabled the identification of key substrate descriptors (electrophilicity, size, and flexibility) that govern the rate of NotF-catalyzed prenyltransfer, and the development of an "induced fit docking (IFD)-guided" engineering strategy for improved turnover of our largest substrates. We further demonstrated the utility of NotF in tandem with oxidative cyclization using flavin monooxygenase, BvnB. This one-pot, in vitro biocatalytic cascade enabled the first chemoenzymatic synthesis of the marine fungal natural product, (-)-eurotiumin A, in three steps and 60% overall yield.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optimizing Mars Sphere of Influence Maneuvers for NASA's Evolvable Mars Campaign

NASA's Human Spaceflight Architecture Team is refining human exploration architectures that will extend human presence to the Martian surface. For both Mars orbital and surface missions, NASA's Evolvable Mars Campaign assumes that cargo and crew can be delivered repeatedly to the same destination. Up to this point, interplanetary trajectories have been optimized to minimize the total propulsive requirements of the in-space transportation systems, while the pre-deployed assets and surface systems are optimized to minimize their respective propulsive requirements separate from the in-space transportation system. There is a need to investigate the coupled problem of optimizing the interplanetary trajectory and optimizing the maneuvers within Mars's sphere of influence. This paper provides a description of the ongoing method development, analysis and initial results of the effort to resolve the discontinuity between the interplanetary trajectory and the Mars sphere of influence trajectories. Assessment of Phobos and Deimos orbital missions shows the in-space transportation and crew taxi allocations are adequate for missions in the 2030s. Because the surface site has yet to be selected, the transportation elements must be sized to provide enough capability to provide surface access to all landing sites under consideration. Analysis shows access to sites from elliptical parking orbits with a lander that is designed for sub-periapsis landing location is either infeasible or requires expensive orbital maneuvers for many latitude ranges. In this case the locus of potential arrival perigee vectors identifies the potential maximum north or south latitudes accessible. Higher arrival velocities can decrease reorientation costs and increase landing site availability. Utilizing hyperbolic arrival and departure vectors in the optimization scheme will increase transportation site accessibility and provide more optimal solutions.

Merrill, Raymond G.↗

Full spectrum (350-2500 nm) canopy spectral reflectance, Seward Peninsula, Alaska, 2018

Full-range (350-2500 nm) canopy reflectance spectra of various Arctic tundra ecosystem endmembers, including canopy-scale species endmember spectra, plot-scale spectra, and transect spectra as well as non-vegetated surface (NVS) spectra. The datasets were collected at the three core NGEE-Arctic watersheds, Kougarok, Teller, and Council, as well as the supplemental Kougarok Mile 80 site within the larger Seward Peninsula, Alaska region. The data were collected in July 2018 using a full-range Spectra Vista Corporation (SVC) HR-1024i spectroradiometer. Canopy-scale reflectance was collected with an 8-degree field-of-view (FOV) foreoptic lens. All spectral measurements were collected as calibrated surface radiance and converted to surface reflectance using a 99.99% reflective Spectralon white reference standard. For those canopy spectra collected with associated functional trait data, the FOV of the instrument was positioned to include the same leaves harvested for functional trait measurements, including leaf mass per area (LMA) and foliar carbon and nitrogen content (see associated dataset). Species included in the spectra and functional trait dataset include Alnus viridis, Betula nana, Betula glandulosa, Arctous alpina, and Salix pulchra. This data package includes 35 files in a variety of formats including processed canopy spectra (*.csv), processed dGPS locations (*.csv and *.kmz), digital photographs of spectral targets (*.jpg) and raw data from spectroradiometer and dGPS instruments (compressed as tar.gz). Metadata files include data descriptions (_dd.csv) for tabular data and a key to species symbols used in data files. All included files are listed and described in NGA208_flmd.csv.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

A contribution with review to the description of mineralization of bone and other calcified tissues in vivo

This manuscript considers certain aspects of mineral deposition in bone and other vertebrate calcifying tissues in order to examine physical, chemical, and biological factors important in the mineralization process. The paper in a discussion format principally presents a new data and the formulation of concepts based on such data as well as a summary of background material as necessary review. Mineralization is found to occur at spatially independent sites throughout the organic extracellular tissue matrices. Matrix vesicles and collagen fibrils each may serve as independent nucleation centers for mineral with vesicle mineralization being local and collagen mineralization dominating the tissues as a whole. Collagen fibril organization is suggested to be such that hole zones are aligned in three dimensions, creating extensive channels for mineral accommodation. Nucleation occurs initially in hole zones and crystal growth leads to the development of plate-like mineral particles whose orientation, disposition, and sizes within fibrils are detailed. Effects of diffusion, crystallinity, and critical nucleation and growth events are described with respect to their influence on mineral deposition in bulk and local regions of tissue matrices.

Review↗

Texture etching of (100) silicon for solar cells

A chemical means of creating the proper kind of light collection texture on (100) silicon slices is discussed. Texturing of (100) silicon surfaces in sodium or potassium hydroxides occurs by the growth of a reaction product in a random array of surface sites, which leads to pyramids remaining at the sites after other parts of the surface dissolve away. A new texture-promoting influence, a proximity effect, was discovered in this work. An attempt was made to quantify the various promotional effects. The purpose of the present paper is to: (1) explain in detail the attempt at understanding and quantifying texturing; (2) give an experimental description with observations on the proximity effect and the effect of additions of water glass that were discovered during this work; and (3) show that the precipitate or growth models account for almost all of the known promotional effects.

Dyer, L. D.↗

Laboratory for Atmospheres: 2004 Technical Highlights

The report describes our role in NASA's mission, gives a broad description of our research, and summarizes our scientists' major accomplishments in 2004. The report also contains useful information on human resources, scientific interactions, outreach activities, and the transformation our laboratory has undergone. This report is published in two versions: 1) an abbreviated print version, and 2) an unabridged electronic version at our Laboratory for Atmospheres Web site: http://atmospheres.gsfc.nasa.gov/.

Source record↗

Opportunities for gas-phase science at short-wavelength free-electron lasers with undulator-based polarization control

Free-electron lasers (FELs) are the world's most brilliant light sources with rapidly evolving technological capabilities in terms of ultrabright and ultrashort pulses over a large range of photon energies. Their revolutionary and innovative developments have opened new fields of science regarding nonlinear light-matter interaction, the investigation of ultrafast processes from specific observer sites, and approaches to imaging matter with atomic resolution. A core aspect of FEL science is the study of isolated and prototypical systems in the gas phase with the possibility of addressing well-defined electronic transitions or particular atomic sites in molecules. Notably for polarization-controlled short-wavelength FELs, the gas phase offers new avenues for investigations of nonlinear and ultrafast phenomena in spin-orientated systems, for decoding the function of the chiral building blocks of life as well as steering reactions and particle emission dynamics in otherwise inaccessible ways. This roadmap comprises descriptions of technological capabilities of facilities worldwide, innovative diagnostics and instrumentation, as well as recent scientific highlights, novel methodology, and mathematical modeling. The experimental and theoretical landscape of using polarization controllable FELs for dichroic light-matter interaction in the gas phase will be discussed and comprehensively outlined to stimulate and strengthen global collaborative efforts of all disciplines. Published by the American Physical Society 2025

Ilchen, Markus↗