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At least 1,225 records · Page 68
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NASA NTRS1982

The redox potential of boron nitride and implications for its use as a crucible material in experimental petrology

The suitability of boron nitride for use as a crucible material in silicate and oxygen-bearing metal sulfide systems has been investigated. Boron nitride is unsatisfactory for use with many silicate systems because its presence in combination with a source of oxygen establishes the oxygen fugacity at values below that of the assemblage quartz + fayalite + iron, reducing transition metal ions such as Ni(2+) and Fe(2+) to the metallic state. B2O3, resulting from the oxidation of BN, acts as a flux to promote formation of melt.

Wendlandt, R. F.↗
NASA NTRS1982

Ceramic applications in turbine engines

In the past the potential of vehicular gas engines could not be realized because component materials served to limit the turbine operating temperature, thereby restricting fuel economy and initial cost. It was, therefore, not possible for the vehicular gas turbine to compete with more conventional engines. The emergence of low-cost, high-temperature ceramic components has the potential to reverse this situation. For example, the Allison GT404 engine, operating with ceramic components at turbine inlet temperatures up to 2350 F to 2500 F, has the potential of a fuel economy which is better than that of current Diesel engines. The Allison AGT100 engine operating with ceramic components offers the possibility of a 30% improvement in fuel economy over 1985 spark ignition engines. The materials considered for an employment in the ceramic components include silicon carbide, silicon nitride, aluminum silicate, and lithium aluminum silicate.

Byrd, J. A.↗
NASA NTRS1982

Evidence for primitive nebular components in chondrules from the Chainpur chondrite

In view of the fact that the least equilibrated ordinary chondrites contain chondrules that have changed little since the time of their formation in the early solar system, and are therefore excellent indicators of the physical and chemical nature of the solar nebula, 36 chondrules were separated from the Chainpur chondrite and analyzed for 20 elements and petrographic properties. The dominant nebular components found are: (1) a mixture of metal and sulfide whose composition is similar to whole rock metal and sulfide, (2) Ir-rich metal, (3) olivine-rich silicates, (4) pyroxene-rich silicates, and possibly (5) a component containing the more volatile lithophiles. Although etching experiments confirm that chondrule rims are enriched in metal, troilite and moderately volatile elements relative to the bulk chondrules, a large fraction of the volatiles remains in the unetched interior.

Grossman, J. N.↗
NASA NTRS1982

Optical and infrared observations of bright comets in the range 0.5 micrometers to 20 micrometers

The paper reviews IR observations of comets Ikeya-Seki 1965 VIII, Bennett 1970 II, Kohoutek 1973 XII, Bradfield 1974 III, Kobayashi-Berger-Milon 1975 IX, West 1976 VI, Bradfield 1980t, and P/Encke. It is shown that four of the five dusty comets observed (1970 II, 1974 III, 1976 VI, and 1980t) exhibited a silicate signature at 10 and 18 microns, indicating the presence of small refractory grains less than 5 microns in radius, and that the antitail of the fifth (1973 XII) did not have the silicate feature, suggesting the presence of large particles more than 30 microns in radius. A detailed study of Comet 1975 IX is discussed which indicates thermal emission from large grains. The dependence of comet brightness on diaphragm diameter is found to suggest a dust model in which the number of grains satisfies the continuity equation.

Ney, E. P.↗
NASA NTRS1982

Interpreting the thermal properties of cometary dust

The characteristics of the thermal emission from cometary dust are discussed and the observations compared with models for absorbing and silicate grains. The observed JHK colors are discussed and suggested observations of future comets are outlined. The observed 4.8 microns/3.5 microns flux ratio can be fit with absorbing grains, with a variation in particle size less than a factor of 2 for all comets observed. The relative number of silicate grains necessary to produce an observable feature at 10 microns is a strong function of their temperature. If they are cold (no absorption at visual wavelengths), a considerable number could be present without producing a detectable feature above the thermal continuum from the hot absorbing grains.

Campins, H.↗
NASA NTRS1982

The geology of Io

A preliminary geologic map of 34.8 percent of the surface of Io has been compiled using best-resolution Voyager 1 images. Nine volcanic units are identified, including materials of mountains, plains, flows, cones, and crater vents, in addition to six types of structural features. Photogeologic evidence indicates a dominantly silicate composition for the mountain material. Sulfur flows of diverse viscosity and sulfur-silicate mixtures may compose the extensive plans. Pit-crater and shield-crater vent-wall scarps reach heights of over two km, and layered-plains boundary scarps have estimated heights of 150 to 1700 m, indicating a material with considerable strength. A cumulative size-frequency distribution plot for 170 volcanic craters with diameters over 14 km is similar to the curves for impact craters on other bodies in the solar system, attesting to a similar nonrandom distribution of crater diameters and a surplus of small craters. A total of 151 lineaments and grabens forming two nearly orthogonal sets is recognized.

Schaber, G. G.↗
NASA NTRS1982

Sulfide saturation of basalt and andesite melts at high pressures and temperatures

When the sulfur content of an Fe-bearing magma exceeds the saturation limit for the bulk composition, an immiscible iron sulfide melt fraction separates. For an understanding of the geochemistry of sulfur-bearing magmatic systems, more information is needed regarding the solubility of metal sulfide in silicate melt at its source and the solubility changes as a function of changing intensive and extensive variables. In the present investigation, the sulfur saturation surface is determined for the pressure range from 12.5 to 30 kbar and the temperature range from 1300 to 1460 C for three silicate melt compositions representing a range of SiO2 and FeO compositions.

Wendlandt, R. F.↗
NASA NTRS1983

Ganymede and Callisto

It is noted that even though the two moons have very similar masses and densities and formed in the same part of the solar system, Ganymede underwent widespread geologic activity whereas Callisto appears to have remained dormant. It is believed that the reason for this may involve several factors. Callisto has undoubtedly experienced at least some internal differentiation; if, however, the differentiation was less complete than for Ganymede or if it took place more slowly, some expansion could have occurred without the crust ever having been fractured. All the major heat sources in these moons produce more heat in Ganymede than in Callisto. Since Ganymede is more massive and dense than Callisto, its silicate content is significantly higher. Because the major radioactive elements are present only in the silicates, radiogenic heating is greater for Ganymede than for Callisto (by an estimated 60%) Ganymede has also undergone significantly more accretional heating than Callisto, not only because of its greater mass and stronger gravitational attraction, which lead to higher impact velocities, but also because it lies closer to Jupiter. The strong gravitational attraction of Jupiter greatly increases the impact velocities of any debris coming from outside the Jupiter system.

Squyres, S. W.↗
NASA NTRS1983

Optical properties of the ash from El Chichon volcano

The visible wavelength optical properties of the ash from the 1982 El Chichon eruptions are measured using ash samples collected at three surface sites at distances between 12 and 80 km from the volcano. The most distant sample is assumed to be the most representative of the silicate ash injected into the stratosphere. The measured optical properties are presented as a complex refractive index n, while the aerosol absorption is expressed as the imaginary component of the refractive index, n sub IM. Results show that each of these samples exhibited low values of absorption, with n sub IM at 500 nm ranging from 0.0015 for the 12 km sample to 0.001 for the 80 km sample. Based on these measurements, it is estimated that n for the stratospheric silicate ash is given by n = 1.53 - 0.001i.

Patterson, E. M.↗
NASA NTRS1983

Saturn's icy satellites - Thermal and structural models

Thermal history models which assume formation as homogeneous ice-silicate mixtures are constructed for the small, icy Saturnian satellites Mimas, Tethys, Dione, Rhea, and Iapetus, including the effects of radiogenic and accretional heating, conductive and subsolidus convective heat transfer, and lithosphgeric growth. Accretional heating is not likely to have melted the water ice in the interiors of these bodies, and solid state creep of the ice-dominated material precludes melting by radiogenic heating. The four largest satellites are sufficiently large and rich in heat-producing silicates to possess a solid state convection system beneath a rigid lithosphere, irrespective of initial conditions. The model thermal histories are qualitatively consistent with the present appearances of these satellites.

Ellsworth, K.↗
NASA NTRS1983

HL Tauri and its circumstellar disk

New far infrared observations of HL Tau which support the identification of an edge-on disk surrounding the star are presented. A bolometric luminosity for the star of 7.2 solar luminosities and a ratio of infrared to optical luminosity of 630 are indicated. A circumstellar A(V) of about 7.0 mag is produced, consistent with the silicate optical depth to the star. Data on HL Tau's effective temperature and radius and its position on the HR diagram suggest that the star has recently completed its accretion phase and is only 100,000 yr old. The column masses of ice and silicates are combined with the disk dimensions to build a simple model of the disk for comparison with the primitive solar nebula. Estimates of the far-infrared emitting mass provide independent probes of the mass in larger grains around HL Tau.

Cohen, M.↗
NASA NTRS1983

Petrology and chemistry of two 'large' granite clasts from the moon

Pristine granite clasts in Apollo-14 breccias 14321 and 14303 have estimated masses of 1.8 and 0.17 g, respectively. The 14321 clast is about 60 percent K-feldspar and 40 percent quartz, with traces of extremely Mg-poor mafic silicates and ilmenite. The 14303 clast is roughly 33 percent plagioclase, 32 percent K-feldspar, 23 percent quartz, 11 percent pyroxene, and 1 percent ilmenite; pyroxene and ilmenite are moderately Mg-rich; plagioclase and pyroxene are strongly zoned. Both clasts are severely brecciated, but monomict (pristine). Both have abundant graphic integrowths of K-feldspar with quartz. Unlike the majority of similar earth rocks, both clasts are devoid of hydrous phases. The bulk composition of the 14321 clast is similar to those of several other lunar granitic samples, but the 14303 clast is unique: it bears as close a resemblance to KREEP as it does to other lunar granites. Silicate liquid immiscibility may explain why the granites are low in REE relative to KREEP.

Warren, P. H.↗
NASA NTRS1983

Research on the use of space resources

The second year of a multiyear research program on the processing and use of extraterrestrial resources is covered. The research tasks included: (1) silicate processing, (2) magma electrolysis, (3) vapor phase reduction, and (4) metals separation. Concomitant studies included: (1) energy systems, (2) transportation systems, (3) utilization analysis, and (4) resource exploration missions. Emphasis in fiscal year 1982 was placed on the magma electrolysis and vapor phase reduction processes (both analytical and experimental) for separation of oxygen and metals from lunar regolith. The early experimental work on magma electrolysis resulted in gram quantities of iron (mixed metals) and the identification of significant anode, cathode, and container problems. In the vapor phase reduction tasks a detailed analysis of various process concepts led to the selection of two specific processes designated as ""Vapor Separation'' and ""Selective Ionization.'' Experimental work was deferred to fiscal year 1983. In the Silicate Processing task a thermophysical model of the casting process was developed and used to study the effect of variations in material properties on the cooling behavior of lunar basalt.

Carroll, W. F.↗
NASA NTRS1984

Microanalytical study of some cosmic dust discovered in sea-floor sediments in China

The study of cosmic dust can provide useful data in the investigation of the origin of the Earth and the evolution of celestial bodies. Three types of cosmic dust (ferriginous, siliceous, and glassy) were discovered in the seafloor sediments near China. Their chemical composition and microstructure were examined by X-ray diffraction, fractography, and electron microscopy. The major mineral in an iron-containing cosmic dust is magnetite. The silicate spheres contain sundry metals and metal oxides. Glassy microtektites are similar in composition to tektites, and are found in all the major meteorite areas worldwide.

Shijie, Z.↗
NASA NTRS1984

Petrography and classification of Ca, Al-rich and olivine-rich inclusions in the Allende CV3 chondrite

The results of a detailed, systematic petrographic survey of Ca, Al-rich and olivine-rich inclusions in the Allende CV3 chondrite are reported, and a new classification system based on clearly defined and readily applied petrographic criteria is presented. Most Allende inclusions are aggregates containing one or more of three distinct constituents: (1) rimmed concentric objects enriched in Al- and Ti-rich oxide minerals and various amounts of Ca-rich silicates; (2) porous, 'fine-grained' chaotic material enriched in Ca-rich silicates, especially clinopyroxenes and garnets; and (3) porous, 'fine-grained', mafic inclusion matrix, enriched in olivine, pyroxene, and feldspathoids. Two texturally distinct varieties of inclusions consist primarily of inclusion matrix: unrimmed olivine aggregates and rimmed olivine aggregates. Ca, Al-rich inclusions are classified on the basis of the size and abundance of their constituent concentric objects. Some fundamental relationships among Allende inclusions that previusly have not been emphasized are discussed.

Kormacki, A. S.↗
NASA NTRS1984

The unusual 8-13 micron spectrum of Markarian 231

An 8-13 micron spectrum was obtained of the Seyfert galaxy Markarian 231 with a spectral resolution of 0.22 micron per point. The spectrum is unlike any previously published spectrum at these wavelengths. The spectrum can be attributed to a combination of absorption and reemission by crystalline silicates which must have formed under conditions quite different from those in which silicates form in the Galaxy. Comparison of the data with previously published data indicates that the infrared emission is extended and not dominated by a bright central source.

Bregman, J. D.↗
NASA NTRS1984

Specular reflectance of optical-black coatings in the far infrared

Far-infrared specular reflectance spectra of seven optically black coatings near normal incidence are presented. Seven photometric spectra were obtained using eleven bandpass transmission filters in the wavelength range between 12 and 500 microns, and three interferometric spectra were obtained for corroboration. Data on the construction, thickness, and rms surface roughness of the coatings are also presented. The chemical composition of three coatings can be distinguished from that of the others by a strong absorption feature between 20 and 40 microns, which can be largely attributed to amorphous silicate material. At 100 microns, the most and least reflective coatings differ by nearly 3 orders of magnitude. Inverse relationships observed between the spectra and the roughness and thickness of the coatings led to development of a reflecting-layer model for the measured reflectance. The model successfully describes the spectra at wavelengths outside the silicate absorption, and optical constants are deduced from a nonlinear least squares fit to the data. Parametric errors are estimated by chi-square analysis, and sensitivity tests are performed to determine which parameters control reflectance in different spectral regions.

Smith, S. M.↗
NASA NTRS1984

Saturn's rings - 3-mm low-inclination observations and derived properties

To determine a more precise brightness temperature and more accurate properties for Saturn's rings, 3.3 mm low inclination observations have been made at 90 GHz with the Aerospace 4.6 m radio telescope. A mean brightness temperature of 17 plus or minus 4 K has been determined by comparing the data with the variation of the inclination of the total flux from the planet and rings predicted by a simple model with uniformly bright A and B rings. Variation of the normal optical depth from 0.4 to 1.0 resulted in a total variation of about 1.5 K in A and B brightness. A portion of the brightness attributed to ring particle thermal emission has been determined to be at a temperature of 11 plus or minus 5 K. If the maximum particle radius (approximately 5 m) deduced from Voyager bistatic radar observations is correct, results indicate a particle distribution ranging between 1 cm and several meters radius of the form r exp -s with s = 3.3-3.6, or a material absorption coefficient ranging between 3 and 10 times lower than that of pure water ice at 85 K, or both. An increase in the porosity of the ice particles through a decrease in their density will not produce the observed particle albedo. If the rocky material is uniformly distributed, low ring brightness temperature would allow a silicate upper limit of approximately 10 percent by mass; however, the silicate material could be more abundant if it is separated from the icy material.

Epstein, E. E.↗