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At least 1,225 records · Page 68

How Proton Incorporation Reshapes Lattice Dynamics In BaSnO 3 ‐Type Proton Conductors

Proton conduction in acceptor-doped perovskites is fundamentally a vibronic process: mobile H + and D + do not move independently, but dynamically co-vibrate with the surrounding oxygen–metal framework. Direct experimental evidence for this behavior is presented using in situ 119⁢ 𝑆⁢𝑛 nuclear resonance vibrational spectroscopy (NRVS) on hydrated, deuterated, and dry 𝐵⁢𝑎⁢𝑆⁢𝑛 1−𝑥⁢ 𝑌 𝑥 ⁢𝑂 3−𝛿 . Hydration induces systematic redistributions in the Sn-projected phonon density of states (PDOS), including an upshift of the first spectral moment by about 0.4 meV, indicating a stiffening of the extended Sn–O network. H/D isotopic substitution leaves the Sn-projected PDOS largely unchanged, with only subtle isotope-dependent spectral reweighting, demonstrating that protonic degrees of freedom are not localized oscillators but are embedded in collective lattice modes. These results are rationalized using a classical coupled proton–phonon oscillator model that links the observed PDOS variations to changes in effective force constants and vibrational mass terms. The model captures how H + and D + participate in cooperative lattice dynamics rather than forming isolated OH/OD entities. Overall, NRVS probes proton–lattice coupling in ceramic proton conductors and quantitatively describes how protonic defects modulate host lattice dynamics to enable phonon-assisted long-range proton transport.

36 MATERIALS SCIENCE↗

Normal modes of a spin cycloid or helix

Although spin cycloids and helices are quite common, remarkably little is known about the normal modes of a spin cycloid or helix with finite length on a discrete lattice. Based on simple one-dimensional lattice models, we numerically evaluate the normal modes of a spin cycloid or helix produced by either Dzyaloshinskii-Moriya (DM) or competing exchange (CE) interactions. The normal modes depend on the type of interaction and on whether the nearest-neighbor exchange is antiferromagnetic (AF) or ferromagnetic (FM). In the AF/DM and FM/DM cases, there is only a single Goldstone mode; in the AF/CE and FM/CE cases, there are three. For FM exchange, the spin oscillations produced by non-Goldstone modes contain a mixture of tangential and transverse components. For the DM cases, we compare our numerical results with analytic results in the continuum limit. Examples are given of materials that fall into all four cases.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Miniature Sapphire Acoustic Resonator - MSAR

A room temperature sapphire acoustics resonator incorporated into an oscillator represents a possible opportunity to improve on quartz ultrastable oscillator (USO) performance, which has been a staple for NASA missions since the inception of spaceflight. Where quartz technology is very mature and shows a performance improvement of perhaps 1 dB/decade, these sapphire acoustic resonators when integrated with matured quartz electronics could achieve a frequency stability improvement of 10 dB or more. As quartz oscillators are an essential element of nearly all types of frequency standards and reference systems, the success of MSAR would advance the development of frequency standards and systems for both groundbased and flight-based projects. Current quartz oscillator technology is limited by quartz mechanical Q. With a possible improvement of more than x 10 Q with sapphire acoustic modes, the stability limit of current quartz oscillators may be improved tenfold, to 10(exp -14) at 1 second. The electromagnetic modes of sapphire that were previously developed at JPL require cryogenic temperatures to achieve the high Q levels needed to achieve this stability level. However sapphire fs acoustic modes, which have not been used before in a high-stability oscillator, indicate the required Q values (as high as Q = 10(exp 8)) may be achieved at room temperature in the kHz range. Even though sapphire is not piezoelectric, such a high Q should allow electrostatic excitation of the acoustic modes with a combination of DC and AC voltages across a small sapphire disk (approximately equal to l mm thick). The first evaluations under this task will test predictions of an estimated input impedance of 10 kilohms at Q = 10(exp 8), and explore the Q values that can be realized in a smaller resonator, which has not been previously tested for acoustic modes. This initial Q measurement and excitation demonstration can be viewed similar to a transducer converting electrical energy to mechanical energy and back. Such an electrostatic tweeter type excitation of a mechanical resonator will be tested at 5 MHz. Finite element calculation will be applied to resonator design for the desired resonator frequency and optimum configuration. The experiment consists of the sapphire resonator sandwiched between parallel electrodes. A DC+AC voltage can be applied to generate a force to act on a sapphire resonator. With the frequency of the AC voltage tuned to the sapphire resonator frequency, a resonant condition occurs and the sapphire Q can be measured with a high-frequency impedance analyzer. To achieve high Q values, many experimental factors such as vacuum seal, gas damping effects, charge buildup on the sapphire surface, heat dissipation, sapphire anchoring, and the sapphire mounting configuration will need attention. The effects of these parameters will be calculated and folded into the resonator design. It is envisioned that the initial test configuration would allow for movable electrodes to check gap spacing dependency and verify the input impedance prediction. Quartz oscillators are key components in nearly all ground- and space-based communication, tracking, and radio science applications. They play a key role as local oscillators for atomic frequency standards and serve as flywheel oscillators or to improve phase noise in high performance frequency and timing distribution systems. With ultra-stable performance from one to three seconds, an Earth-orbit or moon-based MSAR can enhance available performance options for spacecraft due to elimination of atmospheric path degradation.

Wang, Rabi T.↗

Nonadiabatic anharmonic electron transfer

The effect of an inner sphere, local mode vibration on an electron transfer is modeled using the nonadiabatic transition probability (rate) expression together with both the anharmonic Morse and the harmonic oscillator potential. For an anharmonic inner sphere mode, a variational analysis uses harmonic oscillator basis functions to overcome the difficulties evaluating Morse-model Franck-Condon overlap factors. Individual matrix elements are computed with the use of new, fast, robust, and flexible recurrence relations. The analysis therefore readily addresses changes in frequency and/or displacement of oscillator minimums in the different electron transfer states. Direct summation of the individual Boltzmann weighted Franck-Condon contributions avoids the limitations inherent in the use of the familiar high-temperature, Gaussian form of the rate constant. The effect of harmonic versus anharmonic inner sphere modes on the electron transfer is readily seen, especially in the exoergic, inverted region. The behavior of the transition probability can also be displayed as a surface for all temperatures and values of the driving force/exoergicity {Delta}=-{Delta}G. The temperature insensitivity of the transfer rate is clearly seen when the exoergicity equals the collective reorganization energy ({Delta}={Lambda}{sub s}) along a maximum ln (w) vs. {Delta} ridge of the surface. The surface also reveals additional regions for {Delta} where ln (w) appears to be insensitive to temperature, or effectively activationless, for some kinds of inner sphere contributions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High-Power Microwave Oscillator of Twistron Type with Efficiency of 55% for Electron Energy of 180 keV

Highly effective mode of generation of a relativistic microwave oscillator of twistron type is calculated by numerical simulation using an axisymmetric version of completely electromagnetic PiC-code KARAT. With accelerating voltage of 180 kV, electron beam current of 1.2 kA, and 1.9 T guiding magnetic field strength, the simulated stationary generation power is 120 MW at an operating frequency of 10.7 GHz. The efficiency of electron beam power conversion to electromagnetic radiation is 55%, and the electronic efficiency of the oscillator calculated from the change of the initial electron energy is 64%.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

HOW PECULIAR WAS THE RECENT EXTENDED MINIMUM: A HINT TOWARD DOUBLE MINIMA

In this paper, we address the controversy regarding the recent extended solar minimum as seen in helioseismic low- and intermediate-degree mode frequencies: studies from different instruments identify different epochs of seismic minima. Here we use mode frequencies from a network of six identical instruments, the Global Oscillation Network Group, continuously collecting data for more than 15 years, to investigate the epoch of minimum in solar oscillation frequencies prior to the beginning of solar cycle 24. We include both low- and intermediate-degree modes in the l range of 0-120 and frequency range of 2.0-3.5 mHz. In this analysis, we demonstrate that there were indeed two minima in oscillation frequencies, depending upon the degree of modes, or more precisely the lower turning point radius of the propagating wave. We also analyze frequencies as a function of latitude to identify the beginning of solar cycle 24. We observe two minima at high latitudes and a single minimum at mid/low latitudes. This scenario is in contrast to cycle 23 where the epoch of seismic minimum did not change with latitude or depth. Our results also hint at a possible role of the relic magnetic field in modifying the oscillation frequencies of modes sampling deeper layers.

79 ASTRONOMY AND ASTROPHYSICS↗

Self-induced neutrino flavor conversion without flavor mixing

Neutrino-neutrino refraction in dense media can cause self-induced flavor conversion triggered by collective run-away modes of the interacting flavor oscillators. The growth rates were usually found to be of order a typical vacuum oscillation frequency Δ m{sup 2}/2E. However, even in the simple case of a ν{sub e} beam interacting with an opposite-moving ν-bar {sub e} beam, and allowing for spatial inhomogeneities, the growth rate of the fastest-growing Fourier mode is of order μ=√2 G{sub F} n{sub ν}, a typical ν–ν interaction energy. This growth rate is much larger than the vacuum oscillation frequency and gives rise to flavor conversion on a much shorter time scale. This phenomenon of 'fast flavor conversion' occurs even for vanishing Δ m{sup 2}/2E and thus does not depend on energy, but only on the angle distributions. Moreover, it does not require neutrinos to mix or to have masses, except perhaps for providing seed disturbances. We also construct a simple homogeneous example consisting of intersecting beams and study a schematic supernova model proposed by Ray Sawyer, where ν{sub e} and ν-bar {sub e} emerge with different zenith-angle distributions, the key ingredient for fast flavor conversion. What happens in realistic astrophysical scenarios remains to be understood.

79 ASTRONOMY AND ASTROPHYSICS↗

Binary Oscillatory Crossflow Electrophoresis

Electrophoresis has long been recognized as an effective analytic technique for the separation of proteins and other charged species, however attempts at scaling up to accommodate commercial volumes have met with limited success. In this report we describe a novel electrophoretic separation technique - Binary Oscillatory Crossflow Electrophoresis (BOCE). Numerical simulations indicate that the technique has the potential for preparative scale throughputs with high resolution, while simultaneously avoiding many problems common to conventional electrophoresis. The technique utilizes the interaction of an oscillatory electric field and a transverse oscillatory shear flow to create an active binary filter for the separation of charged protein species. An oscillatory electric field is applied across the narrow gap of a rectangular channel inducing a periodic motion of charged protein species. The amplitude of this motion depends on the dimensionless electrophoretic mobility, alpha = E(sub o)mu/(omega)d, where E(sub o) is the amplitude of the electric field oscillations, mu is the dimensional mobility, omega is the angular frequency of oscillation and d is the channel gap width. An oscillatory shear flow is induced along the length of the channel resulting in the separation of species with different mobilities. We present a model that predicts the oscillatory behavior of charged species and allows estimation of both the magnitude of the induced convective velocity and the effective diffusivity as a function of a in infinitely long channels. Numerical results indicate that in addition to the mobility dependence, the steady state behavior of solute species may be strongly affected by oscillating fluid into and out of the active electric field region at the ends of the cell. The effect is most pronounced using time dependent shear flows of the same frequency (cos((omega)t)) flow mode) as the electric field oscillations. Under such conditions, experiments indicate that solute is drawn into the cell from reservoirs at both ends of the cell leading to a large mass build up. As a consequence, any initially induced mass flux will vanish after short times. This effect was not captured by the infinite channel model and hence numerical and experimental results deviated significantly. The revised model including finite cell lengths and reservoir volumes allowed quantitative predictions of the time history of the concentration profile throughout the system. This latter model accurately describes the fluxes observed for both oscillatory flow modes in experiments using single protein species. Based on the results obtained from research funded under NASA grant NAG-8-1080.S, we conclude that binary separations are not possible using purely oscillatory flow modes because of end effects associated with the cos((omega)t) mode. Our research shows, however, that a combination of cos(2(omega)t) and steady flow should lead to efficient separation free of end effects. This possibility is currently under investigation.

Molloy, Richard F.↗

Evidence of nonlinear coupling in the edge harmonic oscillation sustaining quiescent high confinement in a tokamak plasma

In a tokamak plasma, we measure nonlinear coupling between harmonics comprising a saturated edge oscillation, as predicted by nonlinear magnetohydrodynamic simulations. The coherent structure formed by this coupling suppresses bursty edge-localized modes that cause energy and particle loss. We also measure nonlinear coupling of the edge harmonic oscillation to core-resonant magnetic tearing modes. When tearing modes are present, the edge oscillation harmonics decouple, and edge-localized modes return. In this article, we conclude that nonlinear interaction with tearing modes interrupts the formation of the edge harmonic oscillation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ultrafast dynamics in the high-symmetry and in the charge density wave phase of 2 H –NbSe 2

Here we investigate carrier and collective mode dynamics in 2H-NbSe 2 using time-resolved optical pump-probe spectroscopy and compare the results with first-principles calculations. Broadband ultrafast reflectivity studies of 2H-NbSe 2 in a wide temperature interval covering the normal, charge density wave (CDW) and superconducting phase were performed. Spectral features observed in the transient reflectivity experiment were associated with specific optical transitions obtained from band structure calculations. Displacive excitation of coherent phonons showed CDW-associated coherent oscillations of the soft phonon mode across the whole spectral range. Temperature evolution of this coherent phonon mode in the low-excitation linear regime shows softening of the mode down to the CDW transition temperature T CDW with subsequent hardening below T CDW . The global fit of the broadband probe data reveals four different relaxation times associated with characteristic electron-electron, electron-phonon, and phonon-phonon relaxation processes. From first-principles calculations of electron-phonon coupling we associate the few picosecond electron-phonon relaxation time $\tau_2$ with a specific group of phonons with frequencies around 20 meV. On the other hand, the anomalously long relaxation time of $\tau_3 \sim$ to 100 ps is associated with anharmonicity-driven phonon-phonon scattering. All relaxation processes result from anomalies near the second order CDW phase transition that are reflected in the temperature dependencies of the characteristic relaxation times and amplitudes of coherent oscillations. At the highest fluences we observe electronic melting of the CDW and disappearance of the mode hardening below T CDW .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Principal Modes of Precipitation Variability from Preliminary Series of IMERG Data

The Integrated Multi-satellitE Retrievals for the Global Precipitation Measurement (GPM) mission, IMERG, is the unified U.S. algorithm that provides merged Microwave Infrared (IR) satellite precipitation product for the U.S. GPM team. Even though IMERG record is still very short, 2014-2016, it is tempting to test if it captures ENSO and NAO signals as compared to the popular, still on-going, TRMM Multi-satellite Precipitation Analysis, TMPA. El Nino Southern Oscillation (ENSO) is the most significant mode of interannual variability of tropical ocean atmosphere. North Atlantic Oscillation (NAO) impact is on monthly scales and is mostly an atmospheric mode in the North Atlantic. There exist well-defined, multivariate, indexes that represent ENSO and NAO conditions and phase.

climate variability↗

Fast-to-Alfvén mode conversion mediated by the Hall current. I. Cold plasma model

The photospheric temperature minimum in the Sun and solar-like stars is very weakly ionized, with an ionization fraction f as low as 10{sup −4}. In galactic star-forming regions, f can be 10{sup −10} or lower. Under these circumstances, the Hall current can couple low-frequency Alfvén and magnetoacoustic waves via the dimensionless Hall parameter ϵ=ω/Ω{sub i}f, where ω is the wave frequency and Ω{sub i} is the mean ion gyrofrequency. This is analyzed in the context of a cold (zero-β) plasma and in less detail for a warm plasma. It is found that Hall coupling preferentially occurs where the wavevector is nearly field-aligned. In these circumstances, Hall coupling in theory produces a continual oscillation between fast and Alfvén modes as the wave passes through the weakly ionized region. At low frequencies (mHz), characteristic of solar and stellar normal modes, ϵ is probably too small for more than a fraction of one oscillation to occur. On the other hand, the effect may be significant at the far higher frequencies (Hz) associated with magnetic reconnection events. In another context, characteristic parameters for star-forming gas clouds suggest that O(1) or more full oscillations may occur in one cloud crossing. This mechanism is not expected to be effective in sunspots, due to their high ion gyrofrequencies and Alfvén speeds, since the net effect depends inversely on both and therefore inverse quadratically on field strength.

79 ASTRONOMY AND ASTROPHYSICS↗

Galactic oscillations

Long-lived oscillations that act like normal modes are described. The total kinetic energy is found to vary with time by amounts far in excess of the fluctuations expected from the virial theorem, and the variation shows periodic patterns that suggest oscillations. Experimental results indicate that oscillation amplitudes depend on the nature of the model. It is noted that it is difficult to answer questions about likely amplitudes in real galaxies with any confidence at the present time.

Miller, R. H.↗

Mathematical and computational studies of the stability of axisymmetric annular capillary free surfaces

Of principal interest is the stability of a perfectly wetting liquid in an inverted, vertical, right circular-cylindrical container having a concave spheroidal bottom. The mathematical conditions that the contained liquid be in stable static equilibrium are derived, including those for the limiting case of zero contact angle. Based on these results, a computational investigation is carried out for a particular container that is used for the storage of liquid fuels in NASA Centaur space vehicles, for which the axial ratio of the container bottom is 0.724. It is found that for perfectly wetting liquids the qualitative nature of the onset of instability changes at a critical liquid volume, which for the Centaur fuel tank corresponds to a mean fill level of approximately 0.503 times the tank's radius. Small-amplitude periodic sloshing modes for this tank were calculated; oscillation frequencies or growth rates are given for several Bond numbers and liquid volumes, for normal modes having up to six angular nodes.

Albright, N.↗

Ultrafast intersystem crossings in Fe-Co Prussian blue analogues

Ultrafast spincrossover is studied in Fe-Co Prussian blue analogues using a dissipative quantum-mechanical model of a cobalt ion coupled to a breathing mode. All electronic interactions are treated on an equal footing. It is theoretically demonstrated that the divalent cobalt ion reaches 90% of the S = 3/2 value within 20 fs after photoexciting a low-spin Co 3+ ion by an iron-to-cobalt charge transfer. The doublet-to-quartet spin crossover is significantly faster than the oscillation period of the breathing mode. The system relaxes to the lowest manifold of divalent cobalt ( 4 T 1 ) in 150-200 fs. In conclusion, strong oscillations in spin-orbit coupling and the involvement of higher-lying quartets are found.

36 MATERIALS SCIENCE↗

Stable coaxial-waveguide gyrotron backward-wave oscillator with distributed losses

This study analyzes the performance of a coaxial-waveguide gyrotron backward-wave oscillator (gyro-BWO) operating at the fundamental harmonic by considering mode competition, which may be attributed to higher-order axial modes and competing transverse modes. In the coaxial waveguide with a short length and uniform cross section, the threshold currents of the higher-order axial modes are substantially higher than the operating current. Additionally, when the beam voltage or the magnetic field is adjusted, the oscillation that neighbors the minimum start-oscillation current of a transverse mode has a positive-k{sub z} field profile, and is excited near the cutoff frequency. As a result, the distributed wall losses at the downstream end of the interaction structure effectively damp the positive-k{sub z} field, and raise significantly the minimum start-oscillation currents of the competing transverse modes. This study also investigates how the parameters, including lossy section length, outer wall resistivity, inner wall resistivity, and ratio of the outer radius to the inner radius, affect the start-oscillation currents of the competing transverse modes in order to obtain stable operation conditions in the frequency tuning range. As is forecasted, when using a 15 A electron beam, the Ka-band coaxial gyro-BWO produces an output power of 137 kW and 3 dB bandwidth of 4.2% by magnetic tuning and an output power of 145 kW and 3dB bandwidth of 2.0% by beam voltage tuning.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Sources of Subseasonal-To-Seasonal Predictability of Atmospheric Rivers and Precipitation in the Western United States

Atmospheric rivers (ARs) account for a large portion of winter precipitation in the western US. To evaluate the sources of AR and precipitation predictability at subseasonal-to-seasonal timescales, we examine the relationships between two climate modes, the El Niño/Southern Oscillation (ENSO) and Madden-Julian oscillation (MJO), and winter hydroclimate in the western US. Our analysis uses a large ensemble of the Weather Research and Forecast (WRF) model simulations from 1981 to 2017, facilitating the assessment of uncertainty in climate mode-AR relationship due to climate variability and short length of observations. Over the North Pacific basin, we find ENSO-related latitudinal shifts of ARs, but ENSO has little effect on basin-wide averaged AR frequency. Over the western US, there is some uncertainty in the ENSO-AR connection due to the impacts of ENSO indices and datasets. However, extreme El Niño events defined by the ENSO longitude index are consistently linked to increased landfalling AR activity. The MJO can lead to significantly enhanced or suppressed landfalling AR activity in the large-ensembles, depending on the phase of MJO and time lag, while observations are too short in length to robustly show this signal. ENSO substantially modulates the MJO-AR relationship, triggering variegated responses of landfalling ARs and AR precipitation in La Niña and El Niño years. Our findings highlight the need to evaluate concurrent effects of different climate modes on ARs and precipitation, and may shed light on a path toward more accurate subseasonal-to-seasonal prediction of ARs and precipitation over the western US.

54 ENVIRONMENTAL SCIENCES↗