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All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Finite elastic-plastic deformation of polycrystalline metals

Applying Hill's self-consistent method to finite elastic-plastic deformations, the overall moduli of polycrystalline solids are estimated. The model predicts a Bauschinger effect, hardening, and formation of vertex or corner on the yield surface for both microscopically non-hardening and hardening crystals. The changes in the instantaneous moduli with deformation are examined, and their asymptotic behavior, especially in relation to possible localization of deformations, is discussed. An interesting conclusion is that small second-order quantities, such as shape changes of grains and residual stresses (measured relative to the crystal elastic moduli), have a first-order effect on the overall response, as they lead to a loss of the overall stability by localized deformation. The predicted incipience of localization for a uniaxial deformation in two dimensions depends on the initial yield strain, but the orientation of localization is slightly less than 45 deg with respect to the tensile direction, although the numerical instability makes it very difficult to estimate this direction accurately.

Iwakuma, T.↗
NASA NTRS1991

Analysis of metal-matrix composite structures. I - Micromechanics constitutive theory. II - Laminate analyses

The micromechanical constitutive theory is used to examine the nonlinear behavior of continuous-fiber-reinforced metal-matrix composite structures. Effective lamina constitutive relations based on the Abouli micromechanics theory are presented. The inelastic matrix behavior is modeled by the unified viscoplasticity theory of Bodner and Partom. The laminate constitutive relations are incorporated into a first-order deformation plate theory. The resulting boundary value problem is solved by utilizing the finite element method. Attention is also given to computational aspects of the numerical solution, including the temporal integration of the inelastic strains and the spatial integration of bending moments. Numerical results the nonlinear response of metal matrix composites subjected to extensional and bending loads are presented.

Arenburg, R. T.↗
NASA NTRS1989

Cosmogenic Cl-36 production rates in meteorites and the lunar surface

Activity vs. depth profiles of cosmic ray produced Cl-36 were measured in metal from two cores each in the St. Severin and Jilin chondrites and in lunar core 15008. Production of Cl-36 in these samples range from high-energy reactions with Fe and Ni to low-energy reactions with Ca and K and possibly neutron-capture reactions with Cl-36. The cross sections used in the Reedy-Arnold model for neutron-induced reactions were adjusted to get production rates that fit the measured Cl-36 activities in St. Severin metal and in the lunar soil of core 15008. The Cl-36 in metal from St. Severin has a fairly flat activity-vs-depth profile, unlike most other cosmogenic nuclides in bulk samples from St. Severin, which increase in concentration with depth. In metal from Jilin, a decrease in Cl-36 was observed near its center. The length of Jilin's most recent cosmic-ray exposure was approximately 0.5 My. Lunar core 15008 has an excess in Cl-36 of about 4 dpm/kg near its surface that was produced by solar-proton-induced reactions. The calculated production rates are consistent with these measured trends in 15008.

Nishiizumi, K.↗
NASA NTRS1999

Trapped Melt in IIIAB Irons: Solid/Liquid Elemental Partitioning During the Fractionation of the IIIAB Magma

Group IIIAB, the largest iron-meteorite group, shows compositional trends (including a three-order-of-magnitude It concentration range) indicating that it formed by fractional crystallization of a metallic magma. Because about 200 irons are available, and all degrees of crystallization are well represented, IIIAB offers an excellent set of samples for the study of crystallization at all depths of the asteroidal core. On log-log Ir-Au, and Ir-As diagrams IIIAB forms a broad band; the breadth represents real meteorite-to-meteorite variations, far outside experimental or sampling uncertainties. A successful model must explain the width of this band; I suggest that it mainly resulted from the trapping of parental magma within the crystallizing solid. Because S is essentially insoluble in metal, the abundance of FeS is a measure of the fraction of trapped liquid. The trapped-melt model is supported by the observation that irons having higher S contents plot closer to the inferred composition of the magmatic parental liquid. The lowest S values are found in the irons occupying the left envelope of the IIIAB Ir-Au or Ir-As compositional fields, thus it is this set of irons that should be interpreted as the solid products of a fractionating magma. This simplifies the modeling of the crystallization process and allows inferences regarding the distribution ratios for other elements in the evolved IIIAB system. The large (multiton) Cape York irons show wide variations in their trapped-melt fractions; their compositions seem best understood in terms of a low initial S content of the IIIAB magma, about 20 mg/g. The inferred initial IIIAB distribution coefficient for Ir, 4.6, is much higher than published values based on laboratory studies of low-S systems; I suggest that low-S (and low-P) partition-ratio measurements tend to err in the direction of unity. In IIIAB distribution coefficients for Au, As, and Ni were still < 1 when the most evolved IIIAB irons formed, another indication of a low initial S content.

Wasson, John T.↗
NASA NTRS1985

Bulk Formation of Metallic Glasses and Amorphous Silicon from the Melt

By using metallic glass compositions with a high relative glass transition temperature, such as Pd40Ni40P20, homogeneous nucleation also becomes negligible. Large (5g) masses of this alloys were obtained using a molten B2O3 flux. Presently, bulk glass formation in iron based glasses is being investigated. It is expected that if an undercooling of about 250K can be achieved in a Ge or Si melt, formation of the amorphous semiconductor phase (rather than the crystal) may be kinetically favored. The volumetric behavior of undercooled liquid Ga droplet dispersion is investigated by dilatometry. A theoretical model (both analytical and numerical) was developed for transient nucleation in glass forming melts. The model, originally designed for isothermal conditions, was extended to continuous quenching. It is being applied to glass formation in various metallic and oxide systems. A further refinement will be the inclusion of diffusion controlled interfacial rearrangements governing the growth of the crystal embryos.

Spaepen, F.↗
NASA NTRS2000

Particle Engulfment and Pushing Micro-Gravity Experiments and Mathematical Modeling

The phenomenon of interaction of particles with solid-liquid interfaces that results in particle engulfment or pushing (PEP) has been Studied since mid 1960's. While the original interest stemmed from geology applications (frost heaving in soil), it was recognized early that understanding particle behavior at solidifying interfaces mi ht yield 9 practical benefits in other fields. In metallurgical applications the issue is the location of particles with respect to grain boundaries at the end of solidification. Considerable amount of experimental and theoretical research was lately focused on applications to metal matrix composites produced by casting; or spray forming techniques. Another application of PEP is in the growing of Y1Ba2CU3O7-delta(123) superconductor crystals from an undercooled liquid. The oxide melt contains Y2Ba1CU1O5 (211) precipitates, which act as flux pinning sites. The paper presents results of PEP micro-gravity research performed by the authors on two shuttle missions using metallic and polymeric materials. In addition. a discussion on the theoretical aspects of the physics of PEP is offered. Analytical and numerical models for planar solidification interfaces developed by the authors are used to explain the experimental results. Shortcomings of steady-state models are emphasized. A numerical model that includes the effect of the solutal field and of natural convection is introduced. A discussion of phenomena associated with dendritic solidification based on experimental observations is also offered. A mechanism of engulfment is proposed.

Stefanescu, Doru M.↗
NASA NTRSDate not supplied

Design and Analysis of Battery Thermal Management Systems

Thermal management of battery cell packs is a critically needed technology. The purpose of this work is to design new and improved Battery Thermal Management Systems (BTMS) for use in electric airplanes. The BTMS should be 3D printable and hold twelve to sixteen 18650 batteries. To minimize aircraft’s weight, an actively air-cooled battery pack was chosen to avoid the excess weight of water-cooled and phase change material (PCM) cooled packs. As a result, significant changes were made to remove all metal in the pack and replace it with lower density polymer matrix composites (PMCs) which can be additively manufactured. Two air cooled battery pack configurations (traditional propeller fans & bladeless fans) were designed, modeled, and compared. These packs were first modeled in SolidWorks 2021 3D CAD, then imported into COMSOL MultiPhysics to be studied using the “Heat Transfer in Solids and Fluids” module. The design with the bladeless fans eliminated the need to use high conductivity heavy metal to remove unwanted thermal energy. These bladeless fans were designed entirely out of PMCs. This thermal pack design weighs 0.04 kg less than that of the traditional propeller fans design and has increased the battery pack energy density by 8.25 Wh/kg.

Thermal Management System for Battery Packs↗
NASA NTRSDate not supplied

Performance of Heterogeneous Sulfate Aerosol Formation Mechanisms Against Aircraft and Ground-Based Observations in Seoul, South Korea

Haze events are a common occurrence in East Asia, where local meteorology combines with anthropogenic emissions under certain conditions to create rapid increases in secondary aerosol. Often these events are driven by rapid production of secondary sulfate-nitrate-ammonium (SIA) aerosol. Models have typically included simple parameterizations of the production of sulfate during these events which vary widely in their magnitude. There are a range of different mechanistic descriptions of the chemical processes occurring during these events in large part due to poor constraints on aerosol pH and transition metal content, both of which are important to determining the key pathway(s) driving aerosol production. Here, we use the GEOS-Chem chemical transport model to interpret detailed ground and aircraft observations from May and June 2016 during the Korea-United States Air Quality (KORUS-AQ) field study to evaluate the mechanistic pathways governing sulfate production during a haze event. We apply our model of sulfate production mechanisms to ground-based speciated aerosol measurements in winter, summer, and fall in Seoul.

Katherine R Travis↗
NASA NTRS1989

Thin film deployable reflector model for ET gamma ray imaging telescope system (ET-GRITS)

The Marshall Space Flight Center is developing a thin film reflector for a Gamma Ray Imaging Telescope System (GRITS) using the Shuttle External Tank (ET). The concept is to install an inflatable reflector in the ET that could be transferred from the orbiter in orbit. This is a study of a scale model reflector for the ET GRITS application. The approach is to form 1/2 mil film into a spherical mirror mounted on a seven-foot diameter metal ring. The ring mount is sealed and slightly evacuated to pressurize the film into shape. Several different fabrication techniques were investigated using seamed gore designs to form the reflector. Also studied was casting a film into a seamless circular sheet. The goal for this model was to achieve a one milliradian (rms) surface curvature error over 90 percent of the reflector area. This curvature was measured by a laser scanning instrument. The results show how different reflector designs and fabrication techniques contribute to surface curvature and focusing errors.

Huegele, Vinson B.↗
NASA NTRS2016

Astrophysical Implications of the Binary Black Hole Merger GW150914

The discovery of the gravitational-wave (GW) source GW150914 with the Advanced LIGO detectors provides the first observational evidence for the existence of binary black hole (BH) systems that in spiral and merge within the age of the universe. Such BH mergers have been predicted in two main types of formation models, involving isolated binaries in galactic fields or dynamical interactions in young and old dense stellar environments. The measured masses robustly demonstrate that relatively heavy BHs (> or approx. 25 Stellar Mass) can form in nature. This discovery implies relatively weak massive-star winds and thus the formation of GW150914 in an environment with a metallicity lower than about 12 of the solar value. The rate of binary-BH (BBH) mergers inferred from the observation of GW150914 is consistent with the higher end of rate predictions (> or approx. 1/cu Gpc/yr) from both types of formation models. The low measured redshift (z approx. = 0.1) of GW150914 and the low inferred metallicity of the stellar progenitor imply either BBH formation in a low-mass galaxy in the local universe and a prompt merger, or formation at high redshift with a time delay between formation and merger of several Gyr. This discovery motivates further studies of binary-BH formation astrophysics. It also has implications for future detections and studies by Advanced LIGO and Advanced Virgo, and GW detectors in space.

stars↗
NASA NTRS2003

Modeling of Carbon Nanotube Schottky Barrier Reduction for Holes in Air

A model is proposed for the previously reported lower Schottky barrier for holes Phi(sub Bh) in air than in vacuum at a metallic electrode - semiconducting carbon nanotube (CNT) junction. We consider that there is a transition region between the electrode and the CNT, and an appreciable potential can drop there. The role of the oxidation is to increase this potential drop with negatively charged oxygen molecules on the CNT, leading to lower Phi(sub Bh) after oxidation. The mechanism prevails in both p- and n-CNTs, and the model consistently explains the key experimental findings.

Yamada, Toshishige↗
NASA NTRS2016

First-Order SPICE Modeling of Extreme-Temperature 4H-SiC JFET Integrated Circuits

A separate submission to this conference reports that 4H-SiC Junction Field Effect Transistor (JFET) digital and analog Integrated Circuits (ICs) with two levels of metal interconnect have reproducibly demonstrated electrical operation at 500 C in excess of 1000 hours. While this progress expands the complexity and durability envelope of high temperature ICs, one important area for further technology maturation is the development of reasonably accurate and accessible computer-aided modeling and simulation tools for circuit design of these ICs. Towards this end, we report on development and verification of 25 C to 500 C SPICE simulation models of first order accuracy for this extreme-temperature durable 4H-SiC JFET IC technology. For maximum availability, the JFET IC modeling is implemented using the baseline-version SPICE NMOS LEVEL 1 model that is common to other variations of SPICE software and importantly includes the body-bias effect. The first-order accuracy of these device models is verified by direct comparison with measured experimental device characteristics.

JFET↗
NASA NTRS1987

Dendritic growth of undercooled nickel-tin. I, II

A comparison is made between high speed cinematography and optical temperature measurements of the solidification of an undercooled Ni-25 wt pct Sn alloy. The first part of this study notes that solidification during the recalescence period at all undercoolings studied occurred in the form of a dendritelike front moving across the sample surface, and that the growth velocities observed agree with calculation results for the dendrite growth model of Lipton et al. (1986); it is concluded that the coarse structure observed comprises an array of much finer, solute-controlled dendrites. In the second part, attention is given to the solidification of levitated metal samples within a transparent glass medium for the cases of two undercooled Ni-Sn alloys, one of which is eutectic and another hypoeutectic. The data obtained suggest a solidification model involving dendrites of very fine structure growing into the melt at temperatures near the bulk undercooling temperature.

Wu, Y.↗
NASA NTRSDate not supplied

Computational Fluid Dynamics Models of the NASA White Sands Test Facility Particle Impact Test Nozzles

The particle impact ignition mechanism is considered to be the most effective means for igniting metals in gaseous oxygen environments and is a concern for every oxygen system. For this reason, the National Aeronautics and Space Administration (NASA) commits a large amount of resources attempting to understand and defend against this phenomenon. The most practical means of accomplishing this is through extensive of testing. To this end, over the years NASA has developed and built a facility and various apparatuses to test material or component vulnerability to a particle impact ignition. In testing materials, NASA uses sub-sonic and supersonic nozzles to replicate the conditions that a material is expected to experience in service. However, challenges include obtaining an understanding of the gas dynamics and of the particle behavior through and up to the point of impact at the material under test. One means of addressing these challenges is the use of computational fluid dynamics (CFD). If a CFD model can be built and validated, the model can then be used to confidently interrogate changes to inlet conditions and particle geometries, as well as changes to nozzle geometries to better simulate a material’s in-situ conditions and greatly reduce or eliminate trial-and-error approaches in testing. This paper will show NASA’s approach to and results of using CFD to better understand their particle impact nozzles.

Computational Fluid Dynamics↗
NASA NTRS2007

Constraining Galaxy Evolution Using Observed UV-Optical Spectra

Our understanding of galaxy evolution depends on model spectra of stellar populations, and the models are only as good as the observed spectra and stellar parameters that go into them. We are therefore evaluating modem UV-optical model spectra using Hubble's Next Generation Spectral Library (NGSL) as the reference standard. The NGSL comprises intermediate-resolution (R is approximately 1000) STIS spectra of 378 stars having a wide range in metallicity and age. Unique features of the NGSL include its broad wavelength coverage (1,800-10,100 A) and high-S/N, absolute spectrophotometry. We will report on a systematic comparison of model and observed UV-blue spectra, describe where on the HR diagram significant differences occur, and comment on current approaches to correct the models for these differences.

Heap, Sally↗
NASA NTRS1983

Cyclic oxidation of superalloys

The development of mathematical/computer models of cyclic oxidation in high-temperature alloys is described. The acceleration of oxidation attack caused by the spalling of protective oxide scales is discussed. The COREST paralinear model based on empirical data, designed by Barrett and Pressler, is found to be of limited value. Basic research on the spalling process in different alloy systems is reviewed, and the phenomenon is characterized: occurring mainly within the oxide, it is caused by the different thermal expansion coefficients of oxide and metal and is a linear function of the total retained oxide. This information has been used in the development of the discrete oxide-spall model COSP and in its modification by addition of a diffusion-zone-profile model to predict the failure of components (Heckel and Nesbitt, unpublished). The COSP model is shown to produce good predictions of cyclic oxidation under a variety of conditions, using data from simple isothermic tests.

Lowell, C. E.↗
NASA NTRS1999

Deformation Behaviors of HIPped Foil Compared with Those of Sheet Titanium Alloys

Micromechanics-based modeling of composite material behaviors requires an accurate assessment of the constituent properties and behaviors. For the specific case of continuous-fiber-reinforced metal matrix composites (MMC's) manufactured from a foil/fiber/foil process, much emphasis has been placed on characterizing foil-based matrix materials that have been fabricated in the same way as the composite. Such materials are believed to yield mechanical properties and behaviors that are representative of the matrix constituent within the composite (in situ matrix). Therefore, these materials are desired for micromechanics modeling input. Unfortunately, such foils are extremely expensive to fabricate and procure because of the labor-intensive rolling process needed to produce them. As a potential solution to this problem that would maintain appropriately representative in situ properties, the matrix constituent could be characterized with sheet-based materials, which are considerably less expensive to manufacture than foils, are more readily procured, and result in fewer plies to obtain a desired panel thickness. The critical question is, however, does the consolidated sheet material exhibit the same properties and behaviors as do the consolidated foils? Researchers at NASA Lewis Research Center's Life Prediction Branch completed a detailed experimental investigation to answer this question for three titanium alloys commonly used in metal matrix composite form.

Castelli, Michael G.↗