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At least 1,225 records · Page 68

A Unified Mechanism on the Formation of Acenes, Helicenes, and Phenacenes in the Gas Phase

Abstract A unified low‐temperature reaction mechanism on the formation of acenes, phenacenes, and helicenes—polycyclic aromatic hydrocarbons (PAHs) that are distinct via the linear, zigzag, and ortho ‐condensed arrangements of fused benzene rings—is revealed. This mechanism is mediated through a barrierless, vinylacetylene mediated gas‐phase chemistry utilizing tetracene, [4]phenacene, and [4]helicene as benchmarks contesting established ideas that molecular mass growth processes to PAHs transpire at elevated temperatures. This mechanism opens up an isomer‐selective route to aromatic structures involving submerged reaction barriers, resonantly stabilized free‐radical intermediates, and systematic ring annulation potentially yielding molecular wires along with racemic mixtures of helicenes in deep space. Connecting helicene templates to the Origins of Life ultimately changes our hypothesis on interstellar carbon chemistry.

Zhao, Long↗

Voyager 1 observations of the interstellar magnetic field and the transition from the heliosheath

Voyager 1 (V1) has been observing interstellar magnetic fields for more than one year beginning ≈2012/209, when V1 crossed a current sheet, a 'CS0' having the structure of a tangential discontinuity. The inclination of this current sheet is consistent with an interstellar magnetic field B draped on a blunt heliopause. Two other current sheets (sector boundaries) were observed at ≈2012/167 and ≈2011/276 with high inclinations (99° ± 10° and 89° ± 10°, respectively). From 2013.0 to ≈2013.6, the difference between the azimuthal angle λ of B from the Parker spiral angle at the latitude 34.°6 of V1 was λ – λ{sub P} = 22° ± 3° and the corresponding difference of the elevation angle δ was δ – δ{sub P} = 23° ± 8°. During 2012, the deviation from the Parker spiral angle was somewhat smaller. The interstellar magnetic field has a 'west to east polarity,' opposite to the direction of planetary motions. The magnitude of B varied smoothly in the range 0.38-0.59 nT with an average B = 0.486 ± 0.045 after 2012/237.7. The transition from heliosheath to interstellar magnetic fields is related to a 'two-step' increase in the cosmic ray intensity observed by V1 from ≈2012.30 to ≈2012.65. The first step increase began near the end of an unusual 'away-polarity' sector, and it reached a plateau when V1 moved into a 'toward-polarity' sector that ended at CS0. The second step increase began slowly after V1 crossed CS0, and it ended abruptly at 2012/237.728.

79 ASTRONOMY AND ASTROPHYSICS↗

Far-UV spectroscopy of the planet-hosting star WASP-13: High-energy irradiance, distance, age, planetary mass-loss rate, and circumstellar environment

Several transiting hot Jupiters orbit relatively inactive main-sequence stars. For some of those, the logR{sub HK}{sup ′} activity parameter lies below the basal level (−5.1). Two explanations have been proposed so far: (i) the planet affects the stellar dynamo, (ii) the logR{sub HK}{sup ′} measurements are biased by extrinsic absorption, either by the interstellar medium (ISM) or by material local to the system. We present here Hubble Space Telescope/COS far-UV spectra of WASP-13, which hosts an inflated hot Jupiter and has a measured logR{sub HK}{sup ′} value (−5.26), well below the basal level. From the star’s spectral energy distribution we obtain an extinction E(B − V) = 0.045 ± 0.025 mag and a distance d = 232 ± 8 pc. We detect at ≳4σ lines belonging to three different ionization states of carbon (C i, C ii, and C iv) and the Si iv doublet at ∼3σ. Using far-UV spectra of nearby early G-type stars of known age, we derive a C iv/C i flux ratio–age relation, from which we estimate WASP-13's age to be 5.1 ± 2.0 Gyr. We rescale the solar irradiance reference spectrum to match the flux of the C iv 1548 doublet. By integrating the rescaled solar spectrum, we obtain an XUV flux at 1 AU of 5.4 erg s{sup −1} cm{sup −2}. We use a detailed model of the planet’s upper atmosphere, deriving a mass-loss rate of 1.5 × 10{sup 11} g s{sup −1}. Despite the low logR{sub HK}{sup ′} value, the star shows a far-UV spectrum typical of middle-aged solar-type stars, pointing toward the presence of significant extrinsic absorption. The analysis of a high-resolution spectrum of the Ca ii H and K lines indicates that the ISM absorption could be the origin of the low logR{sub HK}{sup ′} value. Nevertheless, the large uncertainty in the Ca ii ISM abundance does not allow us to firmly exclude the presence of circumstellar gas.

79 ASTRONOMY AND ASTROPHYSICS↗

Interstellar gas heating by primordial black holes

Interstellar gas heating is a powerful cosmology-independent observable for exploring the parameter space of primordial black holes (PBHs) formed in the early Universe that could constitute part of the dark matter (DM). We provide a detailed analysis of the various aspects for this observable, such as PBH emission mechanisms. Using observational data from the Leo T dwarf galaxy, we constrain the PBH abundance over a broad mass-range, M PBH ~ O(1)M ⊙ – 10 7 M ⊙ , relevant for the recently detected gravitational wave signals from intermediate-mass BHs. Here, we also consider PBH gas heating of systems with bulk relative velocity with respect to the DM, such as Galactic clouds.

79 ASTRONOMY AND ASTROPHYSICS↗

A Foreshock Model for Interstellar Shocks of Solar Origin: Voyager 1 and 2 Observations

The Voyager 1 (V1) and Voyager 2 (V2) spacecraft were launched in 1977 on a mission to explore the outer planets and reach the heliopause, the boundary between the hot solar plasma and the relatively cool interstellar plasma. V1 reached the heliopause on 2012 August 25, at 121.6 au, and V2 reached the heliopause on 2018 November 5, at 119.0 au. One of their remarkable discoveries was the detection of shocks propagating into the interstellar plasma from energetic solar events. These shocks are typically preceded by electron plasma oscillations excited by electron beams streaming along interstellar magnetic field lines ahead of the shocks. The frequencies of the plasma oscillations have now provided radial electron density profiles in the outer heliosphere and in the interstellar medium to radial distances of more than 145 au. The oscillations are typically preceded by bursts of high-energy ∼5–100 MeV electrons. These electron bursts are interpreted as being due to the reflection (and acceleration) of cosmic-ray electrons by the shock at the time the shock first contacts the magnetic field line that passes through the spacecraft. Relative timing between the cosmic rays reflected by the shock and the onset of the plasma oscillations allow us, for the first time, to estimate the energy, ∼20–100 eV, of the electron beams responsible for the plasma oscillations. These observations are combined into a self-consistent model called the foreshock model that describes the interaction of shocks of solar origin with the interstellar plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Antenna technology for orbital Very Long Baseline Interferometry (VLBI)

Since it is not economically feasible to construct steerable antennas much larger than 100 meters on Earth (400 meters for fixed telescopes), radio interferometry became a very useful technique for high resolution astronomy observations of quasars, galactic nuclei, and interstellar hydroxyl (OH) and water vapor (H2O) masers. The subsystems necessary to do the space VLBI experiment appear are available but require space qualifications. There are several 50-meter antenna concepts that could be used. Certainly there are problems to be solved. Feed positioning with respect to reflector, pointing such a large structure to accuracy indicated, and integration into the Shuttle control system are all significant engineering challenges. However, there are no problems that are insurmountable in the latter part of this decade.

Hamilton, E. C.↗

Protostellar formation in rotating interstellar clouds. V - Nonisothermal collapse and fragmentation

Numerical calculations are presented for rigorous models spanning a four-dimensional parameter space of initial conditions of the three-dimensional collapse of rotating protostellar clouds, encompassing radiative transfer in the Eddington approximation and detailed thermodynamical relations. It is found that protostellar formation may involve a few stages of hierarchical fragmentation terminated by increased thermal pressure in the nonisothermal regime, that high thermal energy clouds remain nearly axisymmetric during the first dynamic collapse phase, and that very slowly rotating clouds can fragment. The presolar nebula was probably formed from a cloud with very little initial rotation.

Boss, Alan R.↗

High-Resolution Mid-Infrared Molecular Line Survey of the Orion Hot Core

The basic building blocks of life are synthesized in space as part of the natural stellar evolutionary cycle, whereby elements ejected into the interstellar medium by dying stars are incorporated back into the dense clouds, which form the next generation of stars and planets. The formation of stars and planets are fundamental to the evolution of matter in the Universe as complex molecules are created and destroyed during this step. Understanding these processes will allow us to answer “What is the relation between the molecules we see in the ISM and the molecular inventory of Earth and the terrestrial planets in the Solar System?” Measuring and cataloging the inventory of organic molecules and understanding their evolution requires observations over a broad wavelength range (IR, MIR, FIR, (sub)mm, and radio) to cover all stages of this evolutionary cycle needed to link interstellar material to that delivered to planets. High-resolution molecular line surveys provide chemical inventories for star forming regions and are essential for studying their chemistry, kinematics and physical conditions. Previous high spectral resolution surveys have been limited to radio, sub-mm and FIR wavelengths; however, Mid-infrared observations are the only way to study symmetric molecules that have no dipole moment and thus cannot be detected in the (sub)mm line surveys from ALMA. Past midinfrared missions such as ISO and Spitzer had low to moderate resolving power that were only able to link broad features with particular molecular bands and could not resolve the individual rovibrational transitions. JWST will provide exceptional sensitivity in the MIR, but will also not have sufficient spectral resolution, which can lead to confusion in identifying the contribution from strong to moderate strength molecular species. We present new results from an on-going high resolution (R ~ 60,000) line survey of the Orion hot core between 12.5 - 28.3 μm and 7 - 8 μm, using the EXES instrument on the SOFIA airborne observatory. SOFIA's higher-resolution and smaller beam compared to ISO allows us to spatially and spectrally isolate the emission towards the hot core. This survey will provide the best infrared measurements (to date) of molecular column densities and physical conditions, providing strong constraints on the current chemical network models for star forming regions. This survey will greatly enhance the inventory of resolved line features in the MIR, making it an invaluable reference to be used by the JWST and ALMA scientific communities.

Rangwala, Naseem↗

Electronic spectroscopy of PAHs and PAH derivatives in supersonic jet

Polycyclic Aromatic Hydrocarbon (PAHs) molecules are attracting much attention in the astrophysical and astrochemical communities because of their ubiquitous presence in space due to their ability to survive in the harsh environmental conditions of the interstellar medium(ISM). The objective of this work is to provide gas phase, high-resolution spectroscopic data on the electronic and vibronic transitions of PAHs and their nitrogenated derivatives measured in astrophysically relevant conditions.

CRDS↗

New astronomy space experiments with television scanning.

Application of data from the Celescope Catalog of Ultraviolet Observations to various problems of stellar and interstellar astrophysics. These include refinements in the incorporation of line blanketing in theoretical stellar-atmosphere models, variations in the law of interstellar extinction from one region of the sky to another, and selection and identification of various types of peculiar stars for further investigation. In addition, the data were analyzed to determine the photometric and astrometric accuracy of the Celescope equipment.

Davis, R. J.↗

An introduction to the problem of interstellar communication

Man's place in the universe is considered, taking into account the earth and the sun as viewed from space. The solar system lies far out towards the edge of the galactic disk, some 30,000 light-years away from the center of a lens-shaped galaxy. Questions concerning a search for extraterrestrial intelligence are discussed. Current radio astronomical techniques make it potentially possible to communicate with 200 million stars. Attention is given to the fraction of stars with planetary systems, the number of planets suitable for life, the fraction of life-bearing planets with intelligence, and the fraction of intelligent communities developing a technical phase.

Sagan, C.↗

STATISTICAL AND SCALING FEATURES OF FLUCTUATIONS IN THE DISSIPATION RANGE DURING A RECONNECTION EVENT

Reconnection events in space plasmas are accompanied by the occurrence of large-amplitude turbulent fluctuations of the magnetic and electric field, covering a wide range of temporal and spatial scales. Here, we study the scaling and statistical features of magnetic and electric field fluctuations below the ion-gyroperiod (i.e., in the dissipation domain) by carefully investigating the occurrence of local or global scaling features during a reconnection event studied by Eastwood et al . Our results point toward the presence of a global scale invariance, i.e., a mono-fractal nature, of fluctuations above the ion-cyclotron frequency and at spatial scales near the ion-inertial length.

79 ASTRONOMY AND ASTROPHYSICS↗

Light-element abundances in Population II dwarfs

This paper reviews the abundances of the light elements lithium, beryllium, and boron in main-sequence and subgiant, Population II stars. Li is important to cosmology because it is synthesized in the Big Bang, but is also used to study stellar structure. Beryllium is useful for studying galactic chemical evolution because its formation in the interstellar medium involves different physics to stellar nucleosynthesis, and it thus provides independent data on the evolution of the halo. Some (though not all) inhomogeneous Big Bang nucleosynthesis codes predict a significant primordial component to this element, so its observed abundance may constrain such models. Boron, observations of which became feasible with the operation of the Hubble Space Telescope, provides complementary data to Be, helping check the element ratios predicted by calculations of spallation reactions in the interstellar medium, and will indicate whether the observed Be abundance has an excess over the expected spallation component, indicating a possible primordial component.

Ryan, Sean G.↗

A high-resolution survey of interstellar Na I D1 lines

We present high-resolution (0.5 km/s) spectra, obtained with the McDonald Observatory 2.7 m coude echelle spectrograph, of interstellar Na I D1 absorption toward 38 bright stars. Numerous narrow, closely blended absorption components, showing resolved Na I hyperfine structure, are evident in these spectra; such narrow components appear in both low halo and quite local gas, as well as in gas toward more distant disk stars. We have used the method of profile fitting in an attempt to determine column densities, line widths, and velocities for the individual interstellar clouds contributing to the observed absorption lines. The resulting sample of 276 clouds is significantly larger, and likely more complete, than several previous samples of 'individual' interstellar clouds, and allows more precise investigation of various statistical properties. We find that the cloud column density (N) and line width parameter (b) are not correlated, for 0.3 km/s approximately less than b approximately less than 1.5 km/s and 10.0/sq cm approximately less than log (N(Na I)) approximately less than 11.6/sq cm. The median b is about 0.73 km/s, the median log N is about 11.09/sq cm, and the median separation between adjacent components is about 2.0 km/s. All these are overestimates of the true median values, however, due to our inability to completely resolve all the component structure present in some cases; even at a resolution of 0.5 km/s, we may have discerned only 60% of the full number of individual components actually present. The one-dimensional dispersion of component velocities, in the local standard of rest, is approximately 8.6 km/s; the distribution of velocities is broader and displaced to more negative velocities for the weaker components. If 80 K is a representative temperature for the interstellar clouds seen in Na I absorption, then at least 38% (and probably the majority) of the clouds have subsonic internal turbulent motions. The range in N(H I) observed at a given N(Na I) increases as N(Na I) decreases below about 10(exp 11)/sq cm, so that N(Na I) becomes a less reliable predictor of N(H I) at low column densities. These spectra will be quite useful in future detailed studies of these lines of sight with the Hubble Space Telescope (HST) Goddard High Resolution Spectrograph (GHRS) echelle -- to determine accurate velocities and to reveal the detailed interstellar component structures that cannot be discerned at the 3.5 km/s resolution available with the GHRS.

Welty, Daniel E.↗

INTERSTELLAR-MEDIUM MAPPING IN M82 THROUGH LIGHT ECHOES AROUND SUPERNOVA 2014J

We present multiple-epoch measurements of the size and surface brightness of the light echoes from supernova (SN) 2014J in the nearby starburst galaxy M82. Hubble Space Telescope ( HST ) ACS/WFC images were taken ∼277 and ∼416 days after B -band maximum in the filters F 475 W , F 606 W , and F 775 W . Observations with HST WFC3/UVIS images at epochs ∼216 and ∼365 days are included for a more complete analysis. The images reveal the temporal evolution of at least two major light-echo components. The first one exhibits a filled ring structure with position-angle-dependent intensity. This radially extended, diffuse echo indicates the presence of an inhomogeneous interstellar dust cloud ranging from ∼100 to ∼500 pc in the foreground of the SN. The second echo component appears as an unresolved luminous quarter-circle arc centered on the SN. The wavelength dependence of scattering measured in different dust components suggests that the dust producing the luminous arc favors smaller grain sizes, while that causing the diffuse light echo may have sizes similar to those of the Milky Way dust. Smaller grains can produce an optical depth consistent with that along the supernova-Earth line of sight measured by previous studies around maximum light. Therefore, it is possible that the dust slab from which the luminous arc arises is also responsible for most of the extinction toward SN 2014J. The optical depths determined from the Milky Way-like dust in the scattering matters are lower than the optical depth produced by the dust slab.

79 ASTRONOMY AND ASTROPHYSICS↗

EVIDENCE FOR A WEAK WIND FROM THE YOUNG SUN

The early history of the solar wind has remained largely a mystery due to the difficulty of detecting winds around young stars that can serve as analogs for the young Sun. Here we report on the detection of a wind from the 500 Myr old solar analog π{sup 1} UMa (G1.5 V), using spectroscopic observations from the Hubble Space Telescope. We detect H I Lyα absorption from the interaction region between the stellar wind and interstellar medium, i.e., the stellar astrosphere. With the assistance of hydrodynamic models of the π{sup 1} UMa astrosphere, we infer a wind only half as strong as the solar wind for this star. This suggests that the Sun and solar-like stars do not have particularly strong coronal winds in their youth.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA's Astromaterials Database: Enabling Research Through Increased Access to Sample Data, Metadata and Imagery

The Astromaterials Acquisition & Curation Office at NASA's Johnson Space Center (JSC) is the designated facility for curating all of NASA's extraterrestrial samples. Today, the suite of collections includes the lunar samples from the Apollo missions, cosmic dust particles falling into the Earth's atmosphere, meteorites collected in Antarctica, comet and interstellar dust particles from the Stardust mission, asteroid particles from Japan's Hayabusa mission, solar wind atoms collected during the Genesis mission, and space‐exposed hardware from several missions. To support planetary science research on these samples, JSC's Astromaterials Curation Office hosts NASA's Astromaterials Curation digital repository and data access portal [http://curator.jsc.nasa.gov/], providing descriptions of the missions and collections, and critical information about each individual sample. Our office is designing and implementing several informatics initiatives to better serve the planetary research community. First, we are re‐hosting the basic database framework by consolidating legacy databases for individual collections and providing a uniform access point for information (descriptions, imagery, classification) on all of our samples. Second, we continue to upgrade and host digital compendia that summarize and highlight published findings on the samples (e.g., lunar samples, meteorites from Mars). We host high resolution imagery of samples as it becomes available, including newly scanned images of historical prints from the Apollo missions. Finally we are creating plans to collect and provide new data, including 3D imagery, point cloud data, micro CT data, and external links to other data sets on selected samples. Together, these individual efforts will provide unprecedented digital access to NASA's Astromaterials, enabling preservation of the samples through more specific and targeted requests, and supporting new planetary science research and collaborations on the samples.

Evans, Cindy↗

A Unified Mechanism on the Formation of Acenes, Helicenes, and Phenacenes in the Gas Phase

A unified low-temperature reaction mechanism on the formation of acenes, phenacenes, and helicenes—polycyclic aromatic hydrocarbons (PAHs) that are distinct via the linear, zigzag, and ortho-condensed arrangements of fused benzene rings—is illustrated. This mechanism is mediated through a barrierless, vinylacetylene mediated gas-phase chemistry utilizing tetracene, [4]phenacene, and [4]helicene as benchmarks contesting established ideas that molecular mass growth processes to PAHs transpire at elevated temperatures. This mechanism opens up an isomer-selective route to aromatic structures involving submerged reaction barriers, resonantly stabilized free-radical intermediates, and systematic ring annulation potentially yielding molecular wires along with racemic mixtures of helicenes in deep space. Thus, connecting helicene templates to the Origins of Life ultimately changes our hypothesis on interstellar carbon chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗