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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Imaging of Electrothermal Filament Formation in a Mott Insulator

Resistive switching—the current- and voltage-induced change of electrical resistance—is at the core of memristive devices, which play an essential role in the emerging field of neuromorphic computing. This study is about resistive switching in a Mott insulator, which undergoes a thermally driven metal-to-insulator transition. Two distinct switching mechanisms are reported for such a system: electric-field-driven resistive switching and electrothermal resistive switching. The latter results from an instability caused by Joule heating. Here, we present the visualization of the reversible resistive switching in a planar V 2 O 3 thin-film device using high-resolution wide-field microscopy in combination with electric transport measurements. We investigate the interaction of the electrothermal instability with the strain-induced spontaneous phase separation in the V 2 O 3 thin film at the Mott transition. The photomicrographs show the formation of a narrow metallic filament with a minimum width ≲500 nm. Although the filament formation and the overall shape of the current-voltage characteristics (IVCs) are typical of an electrothermal breakdown, we also observe atypical effects such as oblique filaments, filament splitting, and hysteretic IVCs with sawtoothlike jumps at high currents in the low-resistance regime. We are able to reproduce the experimental results in a numerical model based on a two-dimensional resistor network. This model demonstrates that resistive switching in this case is indeed electrothermal and that the intrinsic heterogeneity is responsible for the atypical effects. This heterogeneity is strongly influenced by strain, thereby establishing a link between switching dynamics and structural properties.

42 ENGINEERING↗
DOE OSTI2020

Electronic energy gap closure and metal-insulator transition in dense liquid hydrogen

Here, using quantum Monte Carlo (QMC) calculations, we investigate the insulator-metal transition observed in liquid hydrogen at high pressure. Below the critical temperature of the transition from the molecular to the atomic liquid, the fundamental electronic gap closure occurs abruptly, with a small discontinuity reflecting the weak first-order transition in the thermodynamic equation of state. Above the critical temperature, molecular dissociation sets in while the gap is still open. When the gap closes, the decay of the off-diagonal reduced density matrix shows that the liquid enters a gapless, but localized, phase: there is a crossover between the insulating and the metallic liquids. Compared to different density functional theory (DFT) functionals, our QMC calculations provide larger values for the fundamental gap and the electronic density of states close to the band edges, indicating that optical properties from DFT potentially benefit from error cancellations.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Polaron-induced metal-to-insulator transition in vanadium oxides from density functional theory calculations

Vanadium oxides have been extensively studied as phase-change memory units in artificial synapses for neuromorphic computing due to their metal-insulator transitions (MIT) at or near room temperature. Recently, injection of charge carriers into vanadium oxides, e.g., via optically via a heterostructure, has been proposed as an alternative switching mechanism and also potentially as a means to tune the MIT temperature. In this study, we explore the formation of small polarons in the low temperature (LT) insulating phases for V 3 O 5 ,VO 2 , and V 2 O 3 , and the barriers to their migration using density functional theory calculations. We find that V 3 O 5 exhibits very low hole and electron polaron migration barriers (<100 meV) compared to V 2 O 3 and VO 2 , leading to much higher estimated polaronic conductivity. We also link the relative migration barriers to the amount of distortion that has to travel when the polaron migrate from one site to another. Polarons in V 3 O 5 also have smaller binding energies to vanadium and oxygen vacancy defects. Furthermore, these results suggest that the triggering of the MIT via injection of charge carriers are due to the formation of small polarons that can migrate rapidly through the crystal.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2012

Measure Guideline: Internal Insulation of Masonry Walls

This measure guideline provides recommendations for interior insulation assemblies that control interstitial condensation and durability risks; recommendations for acceptable thermal performance are also provided. An illustrated guide of high-risk exterior details (which concentrate bulk water), and recommended remediation details is provided. This is followed by a recommended methodology forrisk assessment of a masonry interior insulation project: a series of steps are suggested to assess the risks associated with this retrofit, with greater certainty with added steps.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2013

Project Overcoat - An Exploration of Exterior Insulation Strategies for 1-1/2-Story Roof Applications in Cold Climates

The development of an alternative method to interior-applied insulation strategies or exterior applied 'band-aids' such as heat tapes and ice belts may help reduce energy needs of millions of 1-1/2 story homes while reducing the risk of ice dam formation. A potential strategy for energy improvement of the roof is borrowed from new construction best practices: Here an 'overcoat' of a continuous air, moisture, and thermal barrier is applied on the outside of the roof structure for improved overall performance. The continuous insulation of this approach facilitates a reduction in thermal bridging which could further reduce energy consumption and bring existing homes closer to meeting the Building America goals for energy reduction. Research favors an exterior approach to deep energy retrofits and ice dam prevention in existing homes. The greatest amount of research focuses on whole house deep energy retrofits leaving a void in roof-only applications. The research is also void of data supporting the hygrothermal performance, durability, constructability, and cost of roof-only exterior overcoat strategies. Yet, contractors interviewed for this report indicate an understanding that exterior approaches are most promising for mitigating ice dams and energy loss and are able to sell these strategies to homeowners.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2012

Measure Guideline: Internal Insulation of Masonry Walls

This measure guideline provides recommendations for interior insulation assemblies that control interstitial condensation and durability risks; recommendations for acceptable thermal performance are also provided. An illustrated guide of high-risk exterior details (which concentrate bulk water), and recommended remediation details is provided. This is followed by a recommended methodology for risk assessment of a masonry interior insulation project: a series of steps are suggested to assess the risks associated with this retrofit, with greater certainty with added steps.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2013

Evaluation of Two CEDA Weatherization Pilot Implementations of an Exterior Insulation and Over-Clad Retrofit Strategy for Residential Masonry Buildings in Chicago

This project examines the implementation of an exterior insulation and over-clad strategy for brick masonry buildings in Chicago—a free-standing two story two-family dwelling and a larger free-standing multifamily building. The test homes selected for this research represent predominant housing types for the Chicago area, in which high heating energy use typical in these buildings threaten housing affordability, and uninsulated mass masonry wall assemblies are uncomfortable for residents. In this project, the Community and Economic Development Association of Cook County, Inc. (CEDA) has secured a Sustainable Energy Resources for Consumers (SERC) innovation grant sponsored by DOE to pursue a pilot implementation of innovative approaches to retrofit in masonry wall enclosures. The retrofit measures are evaluated in terms of feasibility, cost and performance. Through observations of the strategies implemented, the research described in this report identifies measures critical to performance as well as conditions for wider adoption. The research also identifies common factors that must be considered in determining whether the exterior insulation and over-clad strategy is appropriate for the building.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2013

Recovery Act. Advanced Building Insulation by the CO 2 Foaming Process

In this project, ISTN proposed to develop a new "3rd" generation of insulation technology. The focus was a cost-effective foaming process that could be used to manufacture XPS and other extruded polymer foams using environmentally clean blowing agents, and ultimately achieve higher R-values than existing products while maintaining the same level of cost-efficiency. In the U.S., state-of-the-art products are primarily manufactured by two companies: Dow and Owens Corning. These products (i.e., STYROFOAM and FOAMULAR) have a starting thermal resistance of R-5.0/inch, which declines over the life of the product as the HFC blowing agents essential to high R-value exchange with air in the environment. In the existing technologies, the substitution of CO2 for HFCs as the primary foaming agent results in a much lower starting R-value, as evidenced in CO2-foamed varieties of XPS in Europe with R-4.2/inch insulation value. The major overarching achievement from this project was ISTN's development of a new process that uses CO2 as a clean blowing agent to achieve up to R-5.2/inch at the manufacturing scale, with a production cost on a per unit basis that is less than the cost of Dow and Owens Corning XPS products.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2018

Integrated Insulation System for Cryogenic Automotive Tanks (iCAT)

The objective of this project was to develop a state-of-the-art Integrated Insulation System for Cryogenic Automotive Tanks (iCAT) using new lightweight, commercially available materials applied with innovative methods that could demonstrate the DOE heat leak targets (< 5-7 W) for a 100 liter (L) cryogenic hydrogen storage tank and require little to no periodic maintenance. The project team focused on developing an integrated system based on a degraded vacuum (from 0.001 torr up to 0.1 torr) environment [Moderate Vacuum], and compared this system to the standard multi-layer insulation (MLI) high vacuum (HV) environment (< 10E-4 torr).

08 HYDROGEN↗
DOE OSTI2023

Performance of Windows in Walls With Continuous Insulation

Window openings in walls are a significant contributor to poor thermal performance because of thermal bridging through the framing members (e.g., studs, joists, plates, bracing) and because windows lack the thermal properties of insulation. Window installation guidance for walls with continuous insulation (CI) is critical for continued market growth of this energy efficiency technology. This research project offers window manufacturers a starting point and a potential path toward developing installation instructions for windows over CI. The objectives of the research include evaluating the common method for installing windows in walls with CI, as well as establishing acceptance criteria for evaluating the performance of windows installed in walls with and without CI. The research measures: 1. The performance characteristics (e.g., water management, structural integrity) of windows in walls without CI. 2. The performance of different thicknesses and types of CI used in walls. 3. The performance of different types of window assemblies (e.g., double-hung windows, mulled double-hung windows, mulled casement windows, and slider windows) installed over CI. 4. The performance of window flange types (e.g., rigid mounting and less robust flanges) installed over CI. 5. Installing windows over CI using baseline installation instructions versus window manufacturer installation instructions. The project’s sequential testing protocol consists of the following: • A water penetration resistance testing adapted from two ASTM standards: E331 (uniform static air pressure in four steps) and E547 (cyclic static air pressure) • A temperature cycling adapted from ASTM E2264 Method B (convective hot air) • A service condition wind loading test adapted from ASTM E330 • A six-month vertical displacement observation phase prior to the structural performance testing • A final water penetration resistance test after vertical displacement observation • A structural performance test adapted from ASTM E330. Key research findings include: • The criterion for passing a water penetration resistance test is that there is no water overflowing at the interior face of the studs. If there is any bubbling or slight pooling of water at the sill, then it must recede after the pressure is removed. Excessive leakage and/or water leaking to the interior face of the framing around the window constitutes a failure. • All single double-hung windows installed directly to lumber or over oriented strand board passed all test protocols. • For most wall specimens, the test results showed that the use of foam sheathing did not affect the performance of the window for water leakage. • All wall specimens underwent temperature cycling. The results indicated that temperature cycling had little to no effect on windows installed over foam sheathing. • For wall specimens that underwent six-month vertical displacement monitoring, the results showed that windows installed over foam sheathing do not sag over time. • The single-hung and double-hung windows installed using window manufacturer installation instructions passed the structural performance test, compared to failures observed in windows that were installed using generic installation instructions. The generic and manufacturer installation methods differed on the following construction details: type of fasteners, fastening patterns on the flanges, and window shimming details. • Additional testing is required to determine methods to improve structural pressure performance of slider windows. Potential solutions that would require additional testing may include fastener spacing, different types of fasteners, masonry window clips, construction adhesive, foam sealant, stronger window flange material, and/or straps.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2016

Spray Foam Exterior Insulation with Stand-Off Furring - New York

IBACOS and Green Homes America 1 (GHA) collaborated with the New York State Energy Research and Development Authority (NYSERDA) Advanced Buildings Program to research a variation of a commercial curtain wall assembly for residential construction as part of a comprehensive whole-house deep energy retrofit (DER) package. The advantages of this strategy include minimizing the physical connections to each individual existing wall stud, using closedcell spray foam to encapsulate existing siding materials including lead paint, and creating a vented rain screen assembly to promote drying. As Moore (2011) states, "Closed-cell foam acts as air-sealing, insulation, and secondary drainage plane..." Field installations on a limited number of houses indicate that the incremental cost when installed as part of a typical siding and window replacement job adds approximately $10/ft2 of wall area. 2 x 4 framing members were attached to the wall at band joists and top plates using "L" clips, and spray foam was used to insulate the wall after the framing was installed. Windows were installed as the framing was put up, including extension jambs. Key lessons learned include the following: (1) The installed cost of the spray foam system was comparable to the installed cost of the rigid foam and furring strips. (2) Spray foam should be applied in such a way that it locks the framing members in place before the remaining foam is installed in the field of the wall. The spray foam has a tendency to move the new wall framing as it expands. Best practice is to "picture frame" the wall framing with spray foam and then apply the spray foam in the field of each bay. (3) Variations in the existing siding conditions must be accounted for when attaching the ledger boards and wall framing. A best practice is to uniformly shim the ledger boards off the walls so the new framing is a uniform distance from the ledger boards and the inside surface of the interior framing. This is important primarily for window and door installation and the associated extension jambs and trim. (4) From a sequencing perspective, it is advantageous to replace the windows at the same time as the exterior walls are being built. This requires a crew that can perform a number of different tasks (e.g., framing, flashing, window install, trim carpentry) and does not lend itself to subcontracting this approach piecemeal (e.g., framing subcontractor, window installer, drainage plane installer, trim carpenter). (5) Application of the brackets and associated fastener screws was more time consuming than anticipated. (6) It is important for the spray foam contractor to perform all preparatory work, which in this case included placing plastic over the windows and exposed foundation to minimize or eliminate the possibility of damage due to overspray.

Array↗
NASA NTRS2017

Development Path for Cryogenic Insulation Systems Supporting NASA Exploration

The currently stated exploration plan for NASA includes the possibilities ranging from short (several hour duration) upper stage missions sending astronauts towards the vicinity of the moon to multiyear missions to Mars and even making and liquefying propellant on the surface of Mars. As such, NASA has developed a plan to develop multilayer insulation (MLI) at a level it can be engineered for large space craft and upper stage mission durations between several hours to several days. The Evolvable Cryogenics project has been investigating design details related to the design of large MLI blankets for in-space application. Basic MLI performance for large upper stages is scheduled to be demonstrated in 2018 on the Evolvable Cryogenics projects Structural Heat Intercept, Insulation, and Vibration Evaluation Rig (SHIIVER). Different paths are being pursued for Mars Surface applications and these concepts are much less defined and still being traded.

Insulation systems↗
NASA NTRSDate not supplied

Engineered Interfaces in Extruded Polyphenylsulfone-Boron Nitride Composite Insulation

Improving matrix-filler interactions is critical for optimizing dielectric performance in composite insulation; however, the technique used to introduce inorganic fillers into an organic matrix varies in its ability to satisfactorily reduce the size of cavities and interfaces. This study reports effects from changing the filler incorporation strategy on the rheology, dielectric performance and thermal conductivity of extruded polyphenylsulfone (PPSU) – hexagonal boron nitride (hBN) composite insulation. Depending on the technique used to introduce BN into the host matrix, the viscosity, torque, and melt viscosity temperature of the polymer were reduced, enabling better mixing, heat transfer, and smaller voids. This corresponded to an increase in dielectric strength compared to other formulations at either a similar or lower filler loading. On the other hand, the thermal conductivity in these specimens shifted further away from the thermal conductivity target of 1 W/m·K, which was an indication of a larger separation distance between the particles in samples with smaller interfaces. A trade-off between dielectric strength and thermal conductivity may exist when maximizing thermal conduction without sacrificing dielectric strength.

Polyphenylsulfone↗
DOE OSTI2013

Technology Solutions Case Study: Cladding Attachment Over Thick Exterior Insulating Sheathing

The addition of insulation to the exterior of buildings is an effective means of increasing the thermal resistance of wood-framed walls and mass masonry wall assemblies. Insulation on the exterior of the structure has many direct benefits, including better effective R-value from reduced thermal bridging, better condensation resistance, reduced thermal stress on the structure, as well as other commonly associated improvements such as increased airtightness and improved water management. Although the approach has proven effective, there is resistance to its widespread implementation due to a lack of research and understanding of the mechanisms involved in the development of the vertical displacement resistance capacity. In addition, the long-term in-service performance of the system has been questioned due to potential creep effects of the assembly under the sustained dead load of the cladding and effects of varying environmental conditions. In addition, the current International Building Code (IBC) and International Residential Code (IRC) do not have a provision that specifically allows this assembly. In this project, researchers from Building Science Corporation, a Building America team, investigated these issues to better understand the mechanics behind this method of cladding attachment

BSC↗
DOE OSTI2020

Tuning Fermi Levels in Intrinsic Antiferromagnetic Topological Insulators MnBi 2 Te 4 and MnBi 4 Te 7 by Defect Engineering and Chemical Doping

MnBi 2 Te 4 and MnBi 4 Te 7 are intrinsic antiferromagnetic topological insulators, offering a promising materials platform for realizing exotic topological quantum states. However, high densities of intrinsic defects in these materials not only cause bulk metallic conductivity, preventing the measurement of quantum transport in surface states, but may also affect magnetism and topological properties. In this paper, systematic density functional theory calculations reveal specific material chemistry and growth conditions that determine the defect formation and dopant incorporation in MnBi 2 Te 4 and MnBi 4 Te 7 . The large strain induced by the internal heterostructure promotes the formation of large-size-mismatched antisite defects and substitutional dopants. The results here show that the abundance of antisite defects is responsible for the observed n-type metallic conductivity. Additionally, a Te-rich growth condition is predicted to reduce the bulk free electron density, which is confirmed by experimental synthesis and transport measurements in MnBi 2 Te 4 . Furthermore, Na doping is proposed to be an effective acceptor dopant to pin the Fermi level within the bulk band gap to enable the observation of surface quantum transport. The defect engineering and doping strategies proposed here should stimulate further studies for improving synthesis and for manipulating magnetic and topological properties in MnBi 2 Te 4 , MnBi 4 Te 7 , and related magnetic topological insulators.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Surface-Driven Evolution of the Anomalous Hall Effect in Magnetic Topological Insulator MnBi 2 Te 4 Thin Films

We report understanding the effects of the interfacial modification to the functional properties of magnetic topological insulator thin films is crucial for developing novel technological applications from spintronics to quantum computing. Here, a large electronic and magnetic response is reported to be induced in the intrinsic magnetic topological insulator MnBi 2 Te 4 by controlling the propagation of surface oxidation. It is shown that the formation of the surface oxide layer is confined to the top 1–2 unit cells but drives large changes in the overall magnetic response. Specifically, a dramatic reversal of the sign of the anomalous Hall effect is observed to be driven by finite thickness magnetism, which indicates that the film splits into distinct magnetic layers each with a unique electronic signature. These data reveal a delicate dependence of the overall magnetic and electronic response of MnBi 2 Te 4 on the stoichiometry of the top layers. This study suggests that perturbations resulting from surface oxidation may play a non-trivial role in the stabilization of the quantum anomalous Hall effect in this system and that understanding targeted modifications to the surface may open new routes for engineering novel topological and magnetic responses in this fascinating material.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Spectroscopic Studies on the Metal-Insulator Transition Mechanism in Correlated Materials

Here, the metal–insulator transition (MIT) in correlated materials is a novel phenomenon that accompanies a large change in resistivity, often many orders of magnitude. It is important in its own right but its switching behavior in resistivity can be useful for device applications. From the material physics point of view, the starting point of the research on the MIT should be to understand the microscopic mechanism. Here, an overview of recent efforts to unravel the microscopic mechanisms for various types of MITs in correlated materials is provided. Research has focused on transition metal oxides (TMOs), but transition metal chalcogenides have also been studied. Along the way, a new class of MIT materials is discovered, the so–called relativistic Mott insulators in 5d TMOs. Distortions in the MO 6 (M = transition metal) octahedron are found to have a large and peculiar effect on the band structure in an orbital dependent way, possibly paving a way to the orbital selective Mott transition. In the final section, the character of the materials suitable for applications is summarized, followed by a brief discussion of some of the efforts to control MITs in correlated materials, including a dynamical approach using light.

36 MATERIALS SCIENCE↗