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At least 1,225 records · Page 68

Compressibility measurements of gases using externally heated pressure vessels.

Most of the data collected under conditions of high temperature and pressure have been determined using a thick-walled bomb of carefully measured and fixed volume which is externally heated by an electric furnace or a thermostatically controlled bath. There are numerous variations on the basic method depending on the pressure-temperature range of interest, and the particular gas or gas mixture being studied. The construction and calibration of the apparatus is discussed, giving attention to the pressure vessel, the volume of the bomb, the measurement of pressure, the control and measurement of temperature, and the measurement of the amount and composition of gas in the bomb.

Presnall, D. C.↗

The interpretation of total line intensities from optically thin gases. I, II, III.

Description of a general method for inferring, from the line emission of an optically thin medium, the physical state of a gas along the column in a line of sight. The method is devised for applications to astronomy, especially for studies of the solar corona, the chromosphere-corona transition region, planetary nebulae, and other optically thin sources. A unique specification is found in terms of a bivariate distribution function describing the partitioning of matter in a gas over density and temperature. It is shown that, given sufficient observational data, it is in principle possible to determine both this bivariate distribution function and the chemical composition. The formulation for a situation encountered in the solar corona illustrates the application of the method.

Jefferies, J. T.↗

Ion-molecule collision frequencies in gases determined by phase coherent pulsed ICR.

The transient method considered is analogous to similar phase coherence experiments performed in NMR and plasma physics. Using a pulsed ion cyclotron resonance (ICR) spectrometer equipped with a trapped ion analyzer cell, gaseous ions are formed by a pulse of an electron beam and then trapped in the cell by the combined effects of the magnetic and electrostatic fields. The results obtained in the experiments indicate that the classical mobility treatment of Wannier (1953) is helpful in the understanding of collision frequencies under the considered conditions.

Lieder, C. A.↗

Topological dissipation and the small-scale fields in turbulent gases.

It is shown that a large-scale magnetic field possesses a hydrostatic equilibrium only if the pattern of small-scale variations is uniform along the large-scale field. Thus equilibrium obtains only if the variations in the field consist of simple twisting of the lines, with the twists extending uniformly the full length of the field. Any more complicated topology, such as two or more flux tubes wrapped around each other to form a rope, or braided or knotted flux tubes, is without equilibrium, no matter what fluid pressures are applied along the individual lines of force. The result is rapid dissipation and field-line merging, which quickly reduces the topology to the simple equilibrium form. The effect explains the absence of strong small-scale fields in the solar photosphere and in interstellar space in spite of the vigorous turbulence.

Parker, E. N.↗

Non-isothermal laminar flow of gases through cooled tubes.

Numerical solutions of the laminar-flow equations in differential form are presented for gas flows through cooled tubes. For nearly isothermal flow there is good agreement with available experimental data, as is also found for the case of a large amount of wall cooling. This correspondence along with a check on the satisfaction of the global momentum and energy constraints allowed an appraisal of the effect of wall cooling on flow through tubes. In general, the effect of wall cooling was to decrease the wall friction and the change in pressure along tubes, but the average heat-transfer coefficient did not vary much.

Back, L. H.↗

Total absorption cross sections of several gases of aeronomic interest at 584 A.

Total photoabsorption cross sections have been measured at 584.3 A for N2, O2, Ar, CO2, CO, NO, N2O, NH3, CH4, H2, and H2S. A monochromator was used to isolate the He I 584 line produced in a helium resonance lamp, and thin aluminum filters were used as absorption cell windows, thereby eliminating possible errors associated with the use of undispersed radiation or windowless cells. Sources of error are examined, and limits of uncertainty are given. Previous relevant cross-sectional measurements and possible error sources are reviewed. Wall adsorption as a source of error in cross-sectional measurements has not previously been considered and is discussed briefly.

Starr, W. L.↗

On the measurement of Rayleigh scattering by gases at 6328A

The problem of laboratory measurements of Rayleigh scattering and depolarization ratio for atoms and molecules in the gaseous state is described. It is shown that, if the scattered radiation measurements are made at two angles, the normal depolarization ratio cannot be determined meaningfully. However, from scattering measurements, the Rayleigh scattering cross sections can be determined accurately. The measurements of Raleigh scattering from He, H2, Ar, O2, and N2 for unpolarized radiation at 6328A are reported and compared with similar measurements at 6943 and 1215.7A.

SHARDANAND↗

Acoustical studies of rotational relaxation in gases.

It is shown that the use of ultrasonics for studying rotational relaxation involved two major unresolved problems. First, the data are not very precise, because rotational relaxation at room temperature occurs usually at frequencies above 300 MHz/atm, at which the absorption due to viscosity and thermal conductivity is much greater than that due to relaxation. The second problem is that simple relaxation theory is not applicable to the relaxation of systems whose rotational energy levels are not evenly spaced. The need for an improved theory is emphasized.

Winter, T. G.↗

Study of exothermic processes in shock ignited gases by the use of laser shear interferometry.

The paper reports on the measurements of maximum exothermic power pulses attainable from a given chemical system. Experimental tests involved the use of a shock tube technique whereby the exothermic process of combustion was controlled by reflected shock so that it occurred under virtually inviscid flow conditions, the data having been obtained at a resolution commensurate with the actual rate of chemical reaction. Experimental observations were made by means of a novel method of laser shear interferometry. Chemical systems treated in this manner comprised of mixtures of stoichiometric hydrogen-oxygen with 80 and 90% argon, while the measurements covered the full permissible range of initial thermodynamic conditions.

Meyer, J. W.↗

Fluid undercutting in the successive channel flow of two gases.

A fluid piston technique wherein one gas displaces another gas from a horizontal channel was investigated experimentally in a laboratory simulation of the operating concept of a Mach number 9, true-energy wind tunnel. Tests were conducted over a Froude number range from 0.0015 to 0.543 at driver-to-driven gas density ratios from 0.637 to 11.0 to find the effect of fluid undercutting (or overcutting) on test duration. Other variables studied, either experimentally or analytically, include channel cross-sectional shape, channel inlet design, channel length-to-diameter ratio, Reynolds number, pretest pressurization, and channel inclination angle. Results from shadowgraph movies and pressure measurements provide a correlation of actual-to-ideal test durations for a wide range of Froude numbers and gas density ratios and indicate that the application of the fluid piston technique to the wind-tunnel concept is feasible. However, severe fluid undercutting (or overcutting) in horizontal channels occurs at lower Froude numbers and at density ratios significantly different from unity.

Guy, R. W.↗

Calculation of electron energy flux distributions in noble gases.

The electron flux spectrum has been calculated over the entire range from delta-ray energies to ionization-potential energies. Estimates based on the Born approximation indicate that electron-gas atom elastic losses can be neglected. Gryzinski's (1965) classical cross sections show that electron-thermalized electron interactions can be ignored. Under those conditions the energy degradation is primarily due to the excitation and ionization of background gas.

Lo, R.↗

Depth variation of cosmogenic noble gases in the approximately 120-kg Keyes chondrite.

Cosmic ray spallation produced He-3, Ne-21, Ne-22 and Ar-38 have been measured as a function of depth in three mutually perpendicular cores (56, 51, and 21 cm) taken from the 120-kg L chondrite found near Keyes, Oklahoma. The data obtained represent the first experimental determination of the depth variation in the production rates of these cosmogenic nuclides in a single stone meteorite. Fifteen samples across the 56-cm core showed maximum concentration changes of 14% He-3, 28% Ne-21, 19% He-3/Ne-21, and 5% Ne-22/Ne-21. The 51-cm core showed somewhat smaller concentration changes.

Wright, R. J.↗