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At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

A comparison between N2/+/ 4278-A emission and electron flux in the auroral zone

Visual airglow and low-energy electron experiment data from the Atmosphere Explorer D satellite are used to measure variations in N2(+) density and mixing in the nighttime auroral zone. The intensity of the 4278-A N2(+) emission, proportional to energy flux deposited in N2 by energetic electrons, is determined by a method which corrects for ground reflection affecting the satellite data. Calculations related to electron energy flux are found to show a slight variance from the theoretical predictions of Rees and Luckey (1974). Evidence for high-energy proton precipitation on the southern edge of the aurora and for the presence of parallel electric fields in the altitude range 150 to 800 km is also discussed.

Kasting, J. F.↗
NASA NTRS2000

Constraints on Particles and Fields from X-Ray Data

We review emission processes for the handful of extragalactic radio sources which produce X-rays from hotspots and knots in radio jets. In almost all cases, the emitting feature shows a large gradient in radio brightness, indicative of the presence of a strong shock. Since both thermal and synchrotron self Compton models face severe difficulties (except for the hotspots of Cygnus A and 3C 295), the most likely explanation is the presence of gamma = 10(exp 7) electrons producing X-ray synchrotron emission. The major problems remaining are why so few features have been detected so far and why has no optical emission been detected in some cases. While a somewhat unique situation exists for 3C 390.3, serious problems remain for Pictor A, 3C 120, and the quasar jets in 3C 273 and PKS 0637.

Harris, D. E.↗
NASA NTRS1994

Mass-loss rates, ionization fractions, shock velocities, and magnetic fields of stellar jets

In this paper we calculate emission-line ratios from a series of planar radiative shock models that cover a wide range of shock velocities, preshock densities, and magnetic fields. The models cover the initial conditions relevant to stellar jets, and we show how to estimate the ionization fractions and shock velocities in jets directly from observations of the strong emission lines in these flows. The ionization fractions in the HH 34, HH 47, and HH 111 jets are approximately 2%, considerably smaller than previous estimates, and the shock velocities are approximately 30 km/s. For each jet the ionization fractions were found from five different line ratios, and the estimates agree to within a factor of approximately 2. The scatter in the estimates of the shock velocities is also small (+/- 4 km/s). The low ionization fractions of stellar jets imply that the observed electron densities are much lower than the total densities, so the mass-loss rates in these flows are correspondingly higher (approximately greater than 2 x 10(exp -7) solar mass/yr). The mass-loss rates in jets are a significant fraction (1%-10%) of the disk accretion rates onto young stellar objects that drive the outflows. The momentum and energy supplied by the visible portion of a typical stellar jet are sufficient to drive a weak molecular outflow. Magnetic fields in stellar jets are difficult to measure because the line ratios from a radiative shock with a magnetic field resemble those of a lower velocity shock without a field. The observed line fluxes can in principle indicate the strength of the field if the geometry of the shocks in the jet is well known.

Hartigan, Patrick↗
DOE OSTI2024

Unraveling sources of emission heterogeneity in Silicon Vacancy color centers with cryo-cathodoluminescence microscopy

Diamond color centers have proven to be versatile quantum emitters and exquisite sensors of stress, temperature, electric and magnetic fields, and biochemical processes. Among color centers, the silicon-vacancy (SiV - ) defect exhibits high brightness, minimal phonon coupling, narrow optical linewidths, and high degrees of photon indistinguishability. Yet the creation of reliable and scalable SiV - -based color centers has been hampered by heterogeneous emission, theorized to originate from surface imperfections, crystal lattice strain, defect symmetry, or other lattice impurities. Here, we advance high-resolution cryo-electron microscopy combined with cathodolumines cence spectroscopy and 4D scanning transmission electron microscopy (STEM) to elucidate the structural sources of heterogeneity in SiV - emission from nanodiamond with sub-nanometer-scale resolution. Our diamond nanoparticles are grown directly on TEM membranes from molecular-level seedings, representing the natural formation conditions of color centers in diamond. We show that individual subcrystallites within a single nanodiamond exhibit distinct zero-phonon line (ZPL) energies and differences in brightness that can vary by 0.1 meV in energy and over 70% in brightness. These changes are correlated with the atomic-scale lattice structure. We find that ZPL blue shifts result from tensile strain, while ZPL red shifts are due to compressive strain. We also find that distinct crystallites host distinct densities of SiV - emitters and that grain boundaries impact SiV - emission significantly. Finally, we interrogate nanodiamonds as small as 40 nm in diameter and show that these diamonds exhibit no spatial change to their ZPL energy. Our work provides a foundation for atomic-scale structure-emission correlation, e.g., of single atomic defects in a range of quantum and two-dimensional materials.

36 MATERIALS SCIENCE↗
NASA NTRS1976

Solar radio continuum storms

The paper reviews the current status of research on solar radio continuum emissions from metric to hectometric wave frequencies, emphasizing the role of energetic electrons in the 10-100 keV range in these emissions. It is seen that keV-energy electrons generated in active sunspot groups must be the sources of radio continuum storm emissions for wide frequency bands. These electrons excite plasma oscillations in the medium, which in turn are converted to electromagnetic radiation. The radio noise continuum sources are usually associated with type III burst activity observed above these sources. Although the mechanism for the release of the energetic electrons is not known, it seems they are ejected from storm source regions in association with rapid variation of associated sunspot magnetic fields due to their growth into complex types. To explain some of the observed characteristics, the importance of two-stream instability and the scattering of ambient plasma ions on energetic electron streams is pointed out.

Sakurai, K.↗
NASA NTRS1982

Positional characteristics of meter-decameter wavelength bursts associated with hard X-ray bursts

Isolated and grouped type III bursts have been observed in temporal association with impulsive hard X-ray bursts in the 26-154 keV range, down to frequencies as low as 30 MHz and out to a distance of 3.1 solar radii from the disk center. The bursts occurred in regions whose electron density may have been as much as 20 times higher than that of the Newkirk-Saito model. The present observations indicate that electron acceleration/injection occurs over a region covering a wide range of magnetic field lines. It is noted that, of the two gradual hard X-ray bursts observed in association with type IV bursts, one was accompanied by a type II event, while the other was not, although both exhibited the same characteristics. It is suggested that the gradual burst associated with a type IV only involved electrons which are trapped in the plasmoid which produces the meter-decameter emission, while another fraction of the population is trapped in the low-lying loops which produce the hard X-ray and centimeter radiation.

Kundu, M. R.↗
NASA NTRS1985

Observational evidence for thermal wave fronts in solar flares

Images in 3.5-30 keV X-rays obtained during the first few minutes of seven solar flares show rapid motions. In each case X-ray emission first appeared at one end of a magnetic field structure, and then propagated along the field at a velocity between 800 and 1700 km/s. The observed X-ray structures were 45,000-230,000 km long. Simultaneous H-alpha images were available in three cases; they showed brightenings when the fast-moving fronts arrived at the chromosphere. The fast-moving fronts are interpreted as electron thermal conduction fronts since their velocities are consistent with conduction at the observed temperatures of 1-3 x 10 to the 7th K. The inferred conductive heat flux of up to 10-billion ergs/s sq cm accounts for most of the energy released in the flares, implying that the flares were primarily thermal phenomena.

Rust, D. M.↗
NASA NTRS1996

The Supernova Remnant CTA 1

The supernova remnants G327.1-1.1 and G327.4+0.4 (Kes 27) are located 1.5 deg apart in the constellation Norma. In 1980, Einstein IPC observations discovered that both were irregular filled-center X-ray sources with possible point sources superposed. This paper describes new ROSAT position sensitive proportional counter (PSPC) observations which both map the diffuse structure and clearly show several unresolved sources in each field. Both remnants have bright emitting regions inside the limb which might indicate the presence of high energy electrons accelerated by a pulsar. The interior region is more prominent in G327.1-1.1 than in Kes 27. The spectra are relatively strongly absorbed, as expected from distant remnants close to the galactic plane. Comparison of the X-ray and radio maps of each remnant allows us to attribute some emission to a shell and some to the interior. With this information, a blast-wave model is used to derive approximate ages and energy release. Indications are that the Kes 27 supernova deposited approximately 10(exp 51) ergs in the surrounding medium. The G327.1-1.1 event probably deposited a factor of 3-10 less.

Seward, Frederick D.↗
NASA NTRS1996

Plasma Heating and Flow in an Auroral Arc

We report direct observations of the three-dimensional velocity distribution of selected topside ionospheric ion species in an auroral context between 500 and 550 km altitude. We find heating transverse to the local magnetic field in the core plasma, with significant heating of 0(+), He(+), and H(+), as well as tail heating events that occur independently of the core heating. The 0(+) velocity distribution departs from bi-Maxwellian, at one point exhibiting an apparent ring-like shape. However, these observations are shown to be aliased within the auroral arc by temporal variations that arc not well-resolved by the core plasma instrument. The dc electric field measurements reveal superthermal plasma drifts that are consistent with passage of the payload through a series of vortex structures or a larger scale circularly polarized hydromagnetic wave structure within the auroral arc. The dc electric field also shows that impulsive solitary structures, with a frequency spectrum in the ion cyclotron frequency range, occur in close correlation with the tail heating events. The drift and core heating observations lend support to the idea that core ion heating is driven at low altitudes by rapid convective motions imposed by the magnetosphere. Plasma wave emissions at ion frequencies and parallel heating of the low-energy electron plasma are observed in conjunction with this auroral form; however, the conditions are much more complex than those typically invoked in previous theoretical treatments of superthermal frictional heating. The observed ion heating within the arc clearly exceeds that expected from frictional heating for the light ion species H(+) and He(+), and the core distributions also contain hot transverse tails, indicating an anomalous transverse heat source.

Moore, T. E.↗
NASA NTRS2001

The Combined Detection of Morphological and Molecular Biomarkers: Implications for Astrobiology

Experience gathered by previous researchers during their hunt for evidence of early Earth life has shown the complexity in interpreting observations of possible microfossils and to establish the evidence to be positive. Similarly, the stillsimmering controversy on the nature of the nano-structures in Martian meteorite ALH84001 described by McKay et al. (1996) emphasizes the difficulties of conclusively identifying those structures as (a) fossilized bacterial cells and (b) establish their indigeneity. A better understanding of biological signatures in rocks is needed in order to identify traces of microbial life, which include morphological, mineralogical and chemical traces. It is thus considered crucial to tackle the problems emerging in the search for evidence of early life on Earth and in exopaleontological research with a multidisciplinary approach. With this is mind we applied surface sensitive Time of Flight-Secondary Ion Mass Spectroscopy (ToF-SIMS) to a previously described 25 m.y. old fossil bacterial biofilm. This technique allows in situ analysis with high mass resolution as well as molecular imaging of micron sized structures. As no extraction or derivatisation of the sample is required for ToF-SIMS analysis, electron microscopical investigation of the same samples subsequent to analysis is possible, thus allowing the combination of molecular and morphological biomarkers. The analysed fossil bacterial biofilms were associated with macrofossils from volcanoclastic lacustrine sediments from the Upper Oligocene Enspel formation (Germany). Preliminary scanning electron microscopy (SEM) studies have shown that a fossil structure interpreted as a coprolite purely consisted of fossilized bacterial biofilm. For ToF-SIMS investigation small particles were taken from the fossil biofilm and mounted onto Au-coated In-foil and analysed in a Phi Evans T-2000 TRIFT system. The ToF-SIMS analysed samples were Au/Pd-sputter coated and imaged using a Philips XL40 Field Emission Gun SEM (FEG-SEM). ToF-SIMS analysis of the organic rich fossil biofilm (TOC 29%) in the 0-100 Dalton (Da) range showed significant amounts of inorganic species, confirming the results obtained previously by EDX analysis, clearly showing the bacterial fossils to be mineralised. ToF-SIMS furthermore revealed the presence of a variety of low- and high-mass organic molecules and fragments thereof. These include peaks indicative of alkenes and alkanes, aromatic organic species and the polycyclic aromatic hydrocarbon naphthalene. More tentatively, peaks indicative of alkyl pyrroles and pyridyl-CH2 were identified. Other peaks of interest include peaks indicative of C(n)H(2n)O2 and C(n)H(2n-2)O2, which according to their general formula would suggest the presence of both saturated and unsaturated fatty acids although further in situ derivatisation experiments and GC-MS (Gas Chromatography MS) need to be applied to verify this beyond doubt. Furthermore, peaks at m/z 370, 384, 398, 412, 426, 440, 454 and 468 were identified, which indicate the potential presence of bacterial hopanes, a class of biomarkers indicative of bacteria. The main diagnostic peak for this group of chemicals is the fragment at m/z 191.18. Our studies conducted on purified hopane standards have shown that in the high-mass resolution mode differentiation of this diagnostic hopane peak and polyethylene at m/z 191.05 is possible. However, the spectra discussed here were collected in the lower resolution mapping mode, therefore this differentiation was not possible. The centroids of the possible hopane peaks obtained on the fossil biofilms are well within the range associated with bacterial hopanes. There is a strong possibility therefore that hopanoids may be associated with the fossil bacterial cells. Due to the non-destructive nature of ToF-SIMS, analysed samples can be studied using SEM, thus allowing the combination of morphological and molecular biomarkers. Subsequent SEM analysis of the ToF-SIMS analysed samples confirmed that the analysed material purely consists of fossil bacterial cells. This is thus the first successful effort to demonstrate the combination of spectral and morphological biomarkers. The advantages of highly sensitive non-destructive in situ analysis techniques for biomarker detection are invaluable, particularly with respect to envisaged Mars sample return missions, as it may allow us to identify remains and traces of former microbial life in both ancient terrestrial and extraterrestrial materials. This technique may prove particularly useful in the quest for extraterrestrial life with respect to precious extraterrestrial materials, as minute quantities are sufficient to conduct analysis.

Toporski, J.↗
NASA NTRS2005

Experimental Near Infrared Spectroscopy of Polycyclic Aromatic Hydrocarbons Between 0.7 to 2.5 microns

The near infrared (NIR) spectra and absolute band strengths of 27 polycyclic aromatic hydrocarbon (PAH) cations and anions ranging in size from C14H10 to C50H22, are reported. The spectra from 0.7 to 2.5 microns (14,000 to 4000/cm) are presented for the fifteen PAHs ranging in size from C40H18 to C50H22 whereas the spectra of the remaining twelve span the narrower range from 0.7 to 1.1 microns (14,000 to 9000/cm). The spectra of all the ionized PAHs we have studied to date have strong, broad absorption bands in the NIR arising from electronic transitions. This work shows that ionized PAHs have significant absorption bands at longer wavelengths than predicted by the current astronomical models which consider PAHs in their treatment of the radiation balance of the interstellar medium. Two implications are 1)-ionized interstellar PAHs should add weak, broad band structure to the NIR portion of the interstellar extinction curve and 2)- UV poor radiation fields can pump the PAH emission bands provided ionized PAHs are present.

Mattioda, A. L.↗
DOE OSTI2023

Effects of the surface termination and the oxygen vacancy position on LaNiO 3 ultra-thin films: First-principles study

In this study, while ultra-thin layers of the LaNiO 3 film exhibit a remarkable metal-insulator transition as the film thickness becomes smaller than a few unit cell (u.c.), the formation of possible oxygen vacancies and their effects on the correlated electronic structure have been rarely studied using first principles. Here, we investigate the effects of the surface termination and the oxygen vacancy position on the electronic properties and vacancy energetics of LaNiO 3 ultra-thin films under the compressive strain using density functional theory plus U (DFT + U). We find that oxygen vacancies can be easily formed in the Ni layers with the NiO 2 terminated surface (0.5 u.c. and 1.5 u.c. thickness) compared to the structures with the LaO terminated surface and the in-plane vacancy is energetically favored than the out-of-plane vacancy. When two vacancy sites are allowed, the Ni square plane geometry is energetically more stable in most cases as two oxygen vacancies tend to stay near a Ni ion. Strong anisotropy between the in-plane and out-of-plane vacancy formation as well as the layer and orbital dependent electronic structure occur due to strain, surface termination, charge reconstruction, and quantum confinement effects. The in-plane vacancy of the NiO 2 terminated structure is favored since the released charge due to the oxygen vacancy can be easily accommodated in the d x 2 -y 2 orbital, which is less occupied than the d z 2 orbital. Remarkably, the oxygen vacancy structure containing the Ni square-plane geometry becomes an insulating state in DFT + U with a sizable band gap of 1.2 eV because the large crystal field splitting between d z 2 and d x 2 -y 2 orbitals in the square-plane favors an insulating state and the Mott insulating state is induced in other Ni sites due to strong electronic correlations. In the thin-film structure without oxygen vacancies, the strong correlation effect in DFT + U drives a pseudogap ground state at the Fermi energy, similarly as the experimental photo-emission spectra; however, the variation of the DFT + U electronic structure depending on the surface termination becomes weaker compared to those obtained in DFT.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Generative Physics-Informed Neural Network Solving Multi-Scale and Multi-Phase Plasma Chemical Flow Field

Low-temperature plasmas (LTPs) are non-equilibrium systems with near-room-temperature gas and highly energetic electrons. This makes them ideal for delicate applications in biomedicine and semiconductor manufacturing, enabling processes like wound healing, sterilization, etching, and plasma-enhanced chemical vapor deposition without thermal damage. However, LTPs involve complex chemistries, with hundreds of species and thousands of reactions, complicating their diagnosis, prediction, and control. Conventional diagnostics, such as Fourier-transform infrared spectroscopy (FTIR), laser-induced fluorescence (LIF), and optical emission spectroscopy (OES), offer limited species detection, while mass spectrometry (MS) struggles with low-sensitivity species. Additionally, LTP simulations face multi-scale challenges, as macroscopic fluid dynamics and microscopic particle collisions operate on vastly different timescales. To address these issues, we developed an artificial intelligence (AI) based diagnostic system: a generative physics-informed neural network (PINN-Gen) that can predict spatially resolved species concentrations and temperatures in LTPs by integrating experimental data from planar LIF with microscopic plasma chemical kinetics and macroscopic fluid mechanics, including plasma-liquid interactions at the interface between two phases. PINN-Gen solves no equations but checks the errors of physical laws by substituting the output from neural network, and the comparison with the experimental results. Thus, it naturally avoids the multi-scale difficulty of numerical simulations and predicts the results of conventionally unsolvable multi-scale and multi-phase problems. The real-time prediction will be robust due to the physical information used in the training of such a neural network, and only very limited input of condition required due to its generative feature.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Intrinsic and Extrinsic Exciton Recombination Pathways in AgInS 2 Colloidal Nanocrystals

Ternary I-III-VI 2 nanocrystals (NCs), such as AgInS 2 and CuInS 2 , are garnering interest as heavy-metal-free materials for photovoltaics, luminescent solar concentrators, LEDs, and bioimaging. The origin of the emission and absorption properties in this class of NCs is still a subject of debate. Recent theoretical and experimental studies revealed that the characteristic Stokes-shifted and long-lived luminescence of stoichiometric CuInS 2 NCs arises from the detailed structure of the valence band featuring two sublevels with different parity. The same valence band substructure is predicted to occur in AgInS 2 NCs, yet no experimental confirmation is available to date. Here, we use complementary spectroscopic, spectro-electrochemical, and magneto-optical investigations as a function of temperature to investigate the band structure and the excitonic recombination mechanisms in stoichiometric AgInS 2 NCs. Transient transmission measurements reveal the signatures of two subbands with opposite parity, and photoluminescence studies at cryogenic temperatures evidence a dark state emission due to enhanced exchange interaction, consistent with the behavior of stoichiometric CuInS 2 NCs. Lowering the temperature as well as applying reducing electrochemical potentials further suppress electron trapping, which represents the main nonradiative channel for exciton decay, leading to nearly 100% emission efficiency.

36 MATERIALS SCIENCE↗
NASA NTRS1977

A new concept in laser-assisted chemistry - The electronic-field representation

Electronic-field representation is proposed as a technique for laser-assisted chemistry. Specifically, it is shown that several field-assisted chemical processes can be described in terms of mixed matter-field quantum states and their associated energies. The technique may be used to analyze the effects exerted by an intense laser on both bound and unbound molecular systems, and to investigate other field-induced effects including multiphoton processes, emission, and photodissociation.

George, T. F.↗
NASA NTRS1982

The structure of Titan's wake from plasma wave observations

The electron density profile inferred from plasma wave emissions detected during the Voyager 1 flyby of Titan exhibits three distinct peaks with densities of about 40/cu cm, the first peak corresponding to the entry into the magnetic tail, the second corresponding to the neutral sheet crossing from the northern to the southern tail lobe, and the third corresponding to the outbound exit from the tail. Large depressions in the magnetic field strength are observed coincident with each of the density peaks, indicating that a dense plume of plasma is being carried downstream of Titan by the interaction with the rapidly rotating magnetosphere of Saturn. The 8600 K plasma temperature estimated suggests that the plasma originates from the ionosphere of Titan, probably forming a plasma plume with a theta or H cross section extending downstream from Titan.

Gurnett, D. A.↗
NASA NTRS1988

Theory and simulation of electromagnetic beam modes and whistlers

Using particle-in-cell simulations and analytical methods, a study of the nonlinear evolution of electromagnetic instabilities driven by an anisotropic electron beam in an external magnetic field is performed. The unstable waves are either whistlerlike or beam-mode-like depending on the external field strength and beam velocity. The evolution of the particle distribution differs significantly in the two regimes. Even in the presence of a faster electrostatic instability, the electromagnetic waves grow to a significant amplitude. In certain cases, an energetic tail is formed, resulting in enhanced Cerenkov emission of electrostatic waves. The initial evolution of the particle distribution is explained in terms of the interaction of a given linearly unstable wave with the self-consistent perturbed distribution.

Newman, David L.↗
NASA NTRS1991

A preliminary characterization of applied-field MPD thruster plumes

Electric probes, quantitative imaging, and emission spectroscopy were used to study the plume characteristics of applied field magnetohydrodynamic thrusters. The measurements showed that the applied magnetic field plays the dominant role in establishing the plume structure, followed in importance by the cathode geometry and propellant. The anode radius had no measurable impact on the plume characteristics. For all cases studied the plume was highly ionized, though spectral lines of neutral species were always present. Centerline electron densities and temperatures ranged from 2 times 10 (exp 18) to 8 times 10 (exp 18) m(exp -3) and from 7500 to 20,000 K, respectively. The plume was strongly confined by the magnetic field, with radial density gradients increasing monotonically with applied field strength. Plasma potential measurements show a strong effect of the magnetic field on the electrical conductivity and indicate the presence of radial current conduction in the plume.

Myers, Roger M.↗