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At least 1,225 records · Page 68

High sensitivity real-time NVR monitor

A real time non-volatile residue (NVR) monitor, which utilizes surface acoustic wave (SAW) resonators to detect molecular contamination in a given environment. The SAW resonators operate at a resonant frequency of approximately 200 MHz-2,000 MHz which enables the NVR monitor to detect molecular contamination on the order of 10.sup.-11 g-cm.sup.-2 to 10.sup.-13 g-cm.sup.2. The NVR monitor utilizes active temperature control of (SAW) resonators to achieve a stable resonant frequency. The temperature control system of the NVR monitor is able to directly heat and cool the SAW resonators utilizing a thermoelectric element to maintain the resonators at a present temperature independent of the environmental conditions. In order to enable the direct heating and cooling of the SAW resonators, the SAW resonators are operatively mounted to a heat sink. In one embodiment, the heat sink is located in between the SAW resonators and an electronic circuit board which contains at least a portion of the SAW control electronics. The electrical leads of the SAW resonators are connected through the heat sink to the circuit board via an electronic path which prevents inaccurate frequency measurement.

Bowers, William D.↗

NuSTAR Study of Hard X-ray Morphology and Spectroscopy G21.5-0.9

We present NuSTAR high-energy X-ray observations of the pulsar wind nebula (PWN)/supernova remnant G21.5−0.9. We detect integrated emission from the nebula up to approx. 40 keV, and resolve individual spatial features over a broad X-ray band for the first time. The morphology seen by NuSTAR agrees well with that seen by XMM-Newton and Chandra below 10 keV. At high energies, NuSTAR clearly detects non-thermal emission up to approx. 20 keV that extends along the eastern and northern rim of the supernova shell. The broadband images clearly demonstrate that X-ray emission from the North Spur and Eastern Limb results predominantly from non-thermal processes. We detect a break in the spatially integrated X-ray spectrum at approx. 9 keV that cannot be reproduced by current spectral energy distribution models, implying either a more complex electron injection spectrum or an additional process such as diffusion compared to what has been considered in previous work. We use spatially resolved maps to derive an energy-dependent cooling length scale, E(sup m) is directly proportional to L(E) with m = −0.21 plus or minus 0.01. We find this to be inconsistent with the model for the morphological evolution with energy described by Kennel & Coroniti. This value, along with the observed steepening in power-law index between radio and X-ray, can be quantitatively explained as an energy-loss spectral break in the simple scaling model of Reynolds, assuming particle advection dominates over diffusion. This interpretation requires a substantial departure from spherical magnetohydrodynamic, magnetic-flux-conserving outflow, most plausibly in the form of turbulent magnetic-field amplification.

radiation mechanisms↗

Power Electronic Substrates for Space Restricted Application

High-power modules use substrates to house the semiconductor device and for electrical insulation. These substrates are constructed with thermally conductive dielectric material sandwiched between two metals to extract heat from semiconductor chips. Thus, the required cooling performance of a power module is linked to the substrate’s thermal performance and can vary based on the substrate technologies. In this study, four substrate technologies were evaluated for space-restricted applications: direct-bonded copper, an insulated metal substrate, a thermally annealed pyrolytic graphite–based insulated metal substrate, and direct-bonded aluminum, where the heat sink is directly attached without thermal interface materials. The finite element results suggest that the popular direct-bonded copper substrate has better thermal performance than the rest of the substrates for space-restricted applications. Furthermore, a modified direct-bonded copper is proposed to further improve thermal performance. The evaluation results show that the modified substrate can handle 30% more losses than its traditional counterpart.

Chowdhury, Shajjad↗

Oxidation resistant porous material for transpiration cooled vanes

Porous metal sheet with controlled permeability was made by space winding and diffusion bonding fine wire. Two iron-chromium-aluminum alloys and three-chromium alloys were used: GE 1541 (Fe-Cr-Al-Y), H 875 (Fe-Cr-Al-Si), TD Ni Cr, DH 245 (Ni-Cr-Al-Si) and DH 242 (Ni-Cr-Si-Cb). GE 1541 and H 875 were shown in initial tests to have greater oxidation resistance than the other candidate alloys and were therefore tested more extensively. These two materials were cyclic furnace oxidation tested in air at 1800 and 2000 F for accumulated exposure times of 4, 16, 64, 100, 200, 300, 400, 500, and and 600 hours. Oxidation weight gain, permeability change and mechanical properties were determined after exposure. Metallographic examination was performed to determine effects of exposure on the porous metal and electron beam weld joints of porous sheet to IN 100 strut material. Hundred hour stress rupture life and tensile tests were performed at 1800 F. Both alloys had excellent oxidation resistance and retention of mechanical properties and appear suitable for use as transpiration cooling materials in high temperature gas turbine engines.

Madsen, P.↗

Solar flare model atmospheres

Solar flare model atmospheres computed under the assumption of energetic equilibrium in the chromosphere are presented. The models use a static, one-dimensional plane-parallel geometry and are designed within a physically self-consistent coronal loop. Assumed flare heating mechanisms include collisions from a flux of nonthermal electrons and X-ray heating of the chromosphere by the corona. The heating by energetic electrons accounts explicitly for variations of the ionized fraction with depth in the atmosphere. X-ray heating of the chromosphere by the corona incorporates a flare loop geometry by approximating distant portions of the loop with a series of point sources, while treating the loop leg closest to the chromospheric footpoint in the plane-parallel approximation. Coronal flare heating leads to increased heat conduction, chromospheric evaporation and subsequent changes in coronal pressure; these effects are included self-consistently in the models. Cooling in the chromosphere is computed in detail for the important optically thick H I, Ca II and Mg II transitions using the non-local thermodynamic equilibrium (non-LTE) prescription in the program MULTI. Hydrogen ionization rates from X-ray photoionization and collisional ionization by nonthermal electrons are included explicitly in the rate equations. The models are computed in the 'impulsive' and 'equilibrium' limits, and in a set of intermediate 'evolving' states. The impulsive atmospheres have the density distribution frozen in the pre-flare configuration, while the equilibrium models assume the entire atmosphere is in hydrostatic and energetic equilibrium. The evolving atmospheres represent intermediate stages where hydrostatic equilibrium has been established in the chromosphere and corona, but the corona is not yet in energetic equilibrium with the flare heating source. Thus, for example, chromospheric evaporation is still in the process of occurring. We have computed the chromospheric radiation that results from a range of coronal heating rates, with particular emphasis on the widely observed diagnostic H(alpha). Our conclusion is that the H(alpha) fluxes and profiles actually observed in flares can only be produced under conditions of a low-pressure corona with strong beam heating. Therefore we suggest that H(alpha) in flares is produced primarily at the footprints of newly heated loops where significant evaporation has not yet occurred. As a single loop evolves in time, no matter how strong the heating rate may become, the H(alpha) flux will diminish as the corona becomes denser and hence more effective at stopping the beam. This prediction leads to several observable consequences regarding the spatial and temporal signatures of the X-ray and H(alpha) radiation during flares.

Hawley, Suzanne L.↗

Time-resolved photoelectron imaging of complex resonances in molecular nitrogen

We have used the FERMI free-electron laser to perform time-resolved photoelectron imaging experiments on a complex group of resonances near 15.38 eV in the absorption spectrum of molecular nitrogen, N-2, under jet-cooled conditions. The new data complement and extend the earlier work of Fushitani et al. [Opt. Express 27, 19702-19711 (2019)], who recorded time-resolved photoelectron spectra for this same group of resonances. Time-dependent oscillations are observed in both the photoelectron yields and the photoelectron angular distributions, providing insight into the interactions among the resonant intermediate states. In addition, for most states, we observe an exponential decay of the photoelectron yield that depends on the ionic final state. This observation can be rationalized by the different lifetimes for the intermediate states contributing to a particular ionization channel. Finally, although there are nine resonances within the group, we show that by detecting individual photoelectron final states and their angular dependence, we can identify and differentiate quantum pathways within this complex system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Experimental evaluation of the vapor box divertor concept with an open vapor box module in Magnum-PSI

A promising approach to handle the intense plasma heat flux in the divertor region of a tokamak is the Vapor Box Divertor (VBD). Here plasma-lithium interaction creates a dense lithium vapor cloud which interacts with the incoming plasma, effectively shielding the tungsten surface beneath, therefore preventing overheating and sputtering of the tungsten and increasing the component’s lifetime. Two key steps must be addressed to validate this concept: investigating plasma-Li interactions and the transport mechanism of the latter in the presence of plasma. To explore this, a Vapor Box Module (VBM) has been designed for use with the linear plasma generator Magnum-PSI. The VBM consists of a series of three cylindrical boxes, with Li being evaporated at a controlled temperature in the central box (CB). Divertor-like plasma enters the VBM from an upstream aperture, interacts with the Li vapor cloud and exits through a downstream aperture ultimately impacting a target equipped with a calorimetry system. Optical diagnostics Thomson scattering, Filtered fast camera Imaging and optical emission spectroscopy provided information on plasma parameters in terms of electron density n e , temperature T e and plasma composition before and after this interaction. A significant reduction in plasma power was observed upon the establishment of lithium vaporization determined via cooling water calorimetry and embedded thermocouples at the downstream target. This resulted in a drop of the target temperature from ∼800 °C to ∼350 °C (57%) at the highest applied power (11.1 MW m −2 ) and CB temperature (∼700 °C). Lithium condensation at the side boxes of the VBM in combination with strong plasma momentum transfer effectively prevented upstream migration of lithium, while enhancing Li transport toward the target. The achievement of the two main goals of reducing plasma power and confining the Li in the VBM, are consistent with earlier published preliminary SOLPS-ITER simulations. This study shows that the presence of lithium in a VBD-like configuration can result in a strong reduction of power to the target surface, while at the same time the lithium vapor is effectively confined by the VBM, aided by the incoming plasma, preventing its escape from the VBM geometry. This represents a valuable step toward validating the feasibility of the VBD configuration in future fusion reactors.

Magnum-PSI↗

Coexisting Multiple Martensites in Ni 57-x Mn 21+x Ga 22 Ferromagnetic Shape Memory Alloys: Crystal Structure and Phase Transition

A comprehensive study of the crystal structure and phase transition as a function of temperature and composition in Ni 57–x Mn 21+x Ga 22 (x = 0, 2, 4, 5.5, 7, 8) (at. %) magnetic shape memory alloys was performed by a temperature-dependent synchrotron X-ray diffraction technique and transmission electron microscopy. A phase diagram of this Ni 57–x Mn 21+x Ga 22 alloy system was constructed. The transition between coexisting multiple martensites with monoclinic and tetragonal structures during cooling was observed in the Ni 51.5 Mn 26.5 Ga 22 (x = 5.5) alloy, and it was found that 5M + 7M multiple martensites coexist from 300 K to 160 K and that 5M + 7M + NM multiple martensites coexist between 150 K and 100 K. The magnetic-field-induced transformation from 7M martensite to NM martensite at 140 K where 5M + 7M + NM multiple martensites coexist before applying the magnetic field was observed by in situ neutron diffraction experiments. The present study is instructive for understanding the phase transition between coexisting multiple martensites under external fields and may shed light on the design of novel functional properties based on such phase transitions.

36 MATERIALS SCIENCE↗

Defect chemistry and characterization Hg(1-x)Cd(x)Te

Iodine doped single crystal samples of mercury cadmium telluride were annealed at temperatures varying from 450 C to 600 C in Hg vapor and quenched to room temperature. Hall effect measurements at 77 K on the crystals cooled to room temperature indicate the samples to be n-type after anneals at high Hg pressures whereas they turn p-type after anneals at low Hg pressures; the electron concentration increases with increase in Hg pressure. The results are explained on the basis that the crystals are saturated with (Hg,Cd)I2, with a fraction of the iodine being present as donor occupying tellurium lattice sites and a fraction being present as acceptors resulting from the iodine on tellurium lattice sites pairing with the doubly ionized native acceptor defects. The solubility of the donor species increases with increase in Hg pressure, whereas that of the acceptor species increases with decrease in Hg pressure. Equilibrium constants for the incorporation of the iodine species as well as the pairing reaction were established.

Vydyanath, H. R.↗

Superconducting Mixers for Far-Infrared Spectroscopy

The goal of this project was to fabricate and test planar arrays of superconducting mixers for the 2-6 THz band. The technology is intended for multi-beam receivers aboard Explorer-class missions and the SOFIA Airborne Observatory. The mixer technology is the superconducting transition-edge microbolometer, which is more commonly known as the Hot-Electron micro-Bolometer (HEB). As originally proposed, two superconducting technologies were to be developed: (1) low-Tc niobium HEBs which could approach quantum-noise-limited sensitivities but require cooling to 2- 4 K, and (2) high-Tc YBCO HEBs with sensitivities 10 times worse but with a relaxed cooling requirement of 30-60 K. The low-Tc devices would be best for astronomy applications on SOFIA, whereas the high-Tc devices would be more suitable for planetary missions using systems without stored cryogens. The work plan called for planar micro-fabrication and initial testing of HEB devices at the NIST Boulder clean-room facility. Subsequent assembly and RF testing of selected devices would be done at the CASA laboratory at U. Colorado. Approximately 1-year after work began on this project, Dr. Eyal Gerecht joined the NIST group, and assumed day-to-day responsibility for Nb-HEB development at NIST outside of micro-fabrication. The YBCO-HEB work was to be guided by Dr. Ron Ono, who was the NIST expert in YBCO technology. Unfortunately, recurrent health problems limited the time Ron could devote to the project in its first year. These problems became aggravated in early 2001, and sadly led to Ron's death in October, 2001. His loss was not only a blow to his friends and associates at NIST, but was mounted by the US superconductivity community at large. With his passing, work on high-Tc HEBs ceased at NIST. There was no one to replace him or his expertise. Our work subsequently shifted solely to Nb-HEB devices. In the sections which follow, our progress in the development of diffusion-cooled Nb-HEB mixers is detailed. To simplify the terminology, these devices will subsequently be called DHEB mixers to distinguish them from phonon-cooled devices (PHEBs).

Betz, A. L.↗

Meteor wake in high frame-rate images--implications for the chemistry of ablated organic compounds

Extraterrestrial organic matter may have been chemically altered into forms more ameanable for prebiotic chemistry in the wake of a meteor after ablation. We measured the rate of cooling of the plasma in the meteor wake from the intensity decay just behind a meteoroid by freezing its motion in high frame-rate 1000 frames/s video images, with an intensified camera that has a short phosphor decay time. Though the resulting cooling rate was found to be lower than theoretically predicted, our calculations indicated that there would have been insufficient collisions to break apart large organic compounds before most reactive radicals and electrons were lost from the air plasma. Organic molecules delivered from space to the early Earth via meteors might therefore have survived in a chemically altered form. In addition, we discovered that relatively small meteoroids generated far-ultraviolet emission that is absorbed in the immediate environment of the meteoroid, which may chemically alter the atmosphere over a much larger region than previously recognized.

Meteoroids↗

Potassium-bearing Iron-Nickel Sulfides in Nature and High-Pressure Experiments: Geochemical Consequences of Potassium in the Earth's Core

Introduction: Potassium (K) as a large ion lithophile element has dominantly been concentrated in the Earth s crust and the mantle through differentiation, and in the form of K-40 contributes to the planet s heat budget. However, whether or not K also enters core-forming phases, has been debated for over three decades. Arguments favoring entry of K in the core are based on: (1) K-sulfide (with Fe, Ni, Cu, Na, and Cl; djerfisherite) found in highly reduced enstatite chondrites (or aubrites, enstatite achondrites); (2) demonstration that K, owing to an s-d electronic switch at high-pressure, exhibits transition- element like character, (3) solubility of measurable K in Fe-Ni-S liquids at high pressure, temperature conditions, and (4) models of cooling of the core that seem to require, besides convection, some form of radioactivity, and thus lending support to the experimental work. In this contribution, we assess the effect of sequestering K in the core, as it is perhaps an element that is a key to reconciling geochemistry, paleomagnetism, accretion, and thermal evolution models for the planet.

Keshav, S.↗

Fuel Flexible Gas Turbine Combustor Flametube Facility Upgraded

In fiscal year 2003, test cell 23 of the Research Combustion Laboratory (RCL 23) at the NASA Glenn Research Center was upgraded with the addition of gaseous hydrogen as a working propellant and the addition of a 450-psig air-supply system. Test flexibility was further enhanced by upgrades to the facility control systems. RCL 23 can now test with gaseous hydrogen flow rates up to 0.05 lbm/sec and jet fuel flow rates up to 0.62 lbm/sec. Research airflow rates up to 3 lbm/sec are possible with the 450-psig supply system over a range of inlet temperatures. Nonvitiated, heated air is supplied from a shell and tube heat exchanger. The maximum nonvitiated facility air temperature is 1100 F at 1.5 lbm/sec. Research-section exhaust temperatures are limited to 3200 F because of material and cooling capacity limits. A variety of support systems are available depending on the research hardware configuration. Test section ignition can be provided via either a hydrogen air torch system or an electronic spark system. Emissions measurements are obtained with either pneumatically or electromechanically actuated gas sample probes, and the electromechanical system allows for radial measurements at a user-specified axial location for measurement of emissions profiles. Gas analysis data can be obtained for a variety of species, including carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NO and NOx), oxygen (O2), unburnt hydrocarbons, and unburnt hydrogen. Facility control is accomplished with a programmable logic control system. Facility operations have been upgraded to a system based on graphical user interface control screens. A data system is available for real-time acquisition and monitoring of both measurements in engineering units and performance calculations. The upgrades have made RCL 23 a highly flexible facility for research into low emissions gas turbine combustor concepts, and the flame tube configuration inherently allows for a variety of fuel nozzle configurations to be tested in a cost-effective manner. RCL 23 is poised to be a leading facility for developing modern low-emission fuel nozzles for use with jet fuel and alternative fuels.

Little, James E.↗

A Chandra Search for Coronal X Rays from the Cool White Dwarf GD 356

We report observations with the Chandra X-ray Observatory of the single, cool, magnetic white dwarf GD 356. For consistent comparison with other X-ray observations of single white dwarfs, we also re-analyzed archival ROSAT data for GD 356 (GJ 1205), G 99-47 (GR 290 = V1201 Ori), GD 90, G 195-19 (EG250 = GJ 339.1), and WD 2316+123 and archival Chandra data for LHS 1038 (GJ 1004) and GD 358 (V777 Her). Our Chandra observation detected no X rays from GD 356, setting the most restrictive upper limit to the X-ray luminosity from any cool white dwarf - Lx less than 6.0 x 10(exp 25) erg s(sup -1), at 99.7% confidence, for a 1- keV thermal-bremsstrahlung spectrum. The corresponding limit to the electron density is no less than 4.4x10(exp 11) per cubic centimeter. Our re-analysis of the archival data confirmed the non-detections reported by the original investigators. We discuss the implications of our and prior observations on models for coronal emission from white dwarfs. For magnetic white dwarfs, we emphasize the more stringent constraints imposed by cyclotron radiation. In addition, we describe (in an appendix) a statistical methodology for detecting a source and for constraining the strength of a source, which applies even when the number of source or background events is small.

Weisskopf, Martin C.↗

Direct Laser Writing Crystal Polymorphs of Organic Semiconductors for Phase Change Electronics

The many diverse polymorphic behaviors observed in organic electronic materials offer opportunities to modulate electronic properties through reversibly switching crystal structures. Here, we access the prolific polymorphism observed in two-dimensional quinoidal terthiophene via laser writing to locally heat and direct the phase transitions. We access a metastable polymorph IV through rapid cooling and observe distinct symmetry as well as packing through grazing incidence X-ray diffraction (GIXD). Using our open-source PolyChemPrint patterning platform, we direct laser heating to initiate the IV-I transition, switching the conductance by >2 orders of magnitude. Here, this is confirmed via a combination of GIXD and Raman spectroscopy. Finally, we demonstrate switching of transistor devices as well as discrete tuning of conductance via laser writing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Shallow core levels, or how to determine the doping and T c of Bi 2 Sr 2 CaCu 2 O 8 + δ and Bi 2 Sr 2 CuO 6 + δ without cooling

In this study, determining the doping level in high-temperature cuprate superconductors is crucial for understanding the origin of superconductivity in these materials and for unlocking their full potential. However, accurately determining the doping level remains a significant challenge due to a complex interplay of factors and limitations in various measurement techniques. In particular, in Bi 2 Sr 2 CuO 6+δ and Bi 2 Sr 2 CaCu 2 O 8+δ , where the mobile carriers are introduced by non-stoichiometric oxygen δ, the determination has been extremely problematic. Here, we study the doping dependence of the electronic structure of these materials in angle-resolved photoemission and find that both the doping level, p, and the superconducting transition temeprature, T c can be precisely determined from the binding energy of the Bi 5d core-levels. The measurements can be performed at room temperature, enabling the determination of p and T c without cooling the samples. This should be very helpful for further studies of these materials

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Final Report

This grant was made to fund two accepted proposals to observe with the ASCA satellite: (1) Debunking the myth of two-temperature coronae of active stars, and (2) Dynamic coronae of dMe stars. We obtained the requested observations and have now completed two papers that will be published in the Astrophysical Journal. The RS CVn binary star UX Ari was observed for 14 hours with all four detectors onboard the ASCA satellite. The X-ray emission was at a constant, quiescent level during the first 12 hours, after which time a powerful flare with a peak luminosity of 1.4 x 10(exp 32) ergs/s started. The flare was observed until shortly after its peak. We present a spectral and temporal analysis of the UX Ari observations and analyze the data with a two-ribbon flare model including estimates for cooling losses. A time-dependent reconstruction of the emission measure (EM) distribution shows that two separate plasma components evolve during the flare (one being identified with the quiescent EM). Most of the flare EM reaches temperatures between 50 MK and 100 MK or more. Magnetic confinement requires the loop arcade to be geometrically large, with length scales on the order of one stellar radius. The electron densities inferred from the model decrease from initial values around 10(exp 12)/cc early in the flare to about 10(exp 11)/cc at the flare peak. The best-fit models require surface magnetic field strengths of a few hundred G, compatible with the maximum photospheric fields expected from equipartition. The flare parameters imply a (conductive and radiative) cooling loss time of less than one hour at flare peak. The elemental abundances increase significantly during the flare rise, with the abundances of the low-FIP elements Fe, Mg, Si, and Ni typically increasing to higher levels than the high-FIP elements such as S or Ne. The Fe abundance increases from (17 +/- 4)% of the solar photospheric value during quiescence up to (89 +/- 18)% at flare peak. A fractionation process that occurs during the chromospheric evaporation phase may selectively enrich low-FIP elements as in the solar corona; alternatively, the chromospheric evaporation may itself bring metal-rich plasma into the metal-poor corona.

Linsky, Jeffrey L.↗