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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Chemical Imaging of Atmospheric Biomass Burning Particles from North American Wildfires

The effects of biomass burning aerosols (BBA) on radiative forcing and cloud formation depend on chemical composition and the internal structures of individual particles within smoke plumes. To improve our understanding of the chemical and physical properties of BBA emitted at different times of the day and their evolution during atmospheric aging, we conducted a study as a part of the Fire Influence on Regional to Global Environments and Air Quality field campaign. Particle samples were collected onboard a research aircraft from smoke plumes from a wildfire in eastern Oregon during late afternoon and nighttime flights on August 28, 2019. A time-resolved aerosol collector was used to collect samples on substrates for offline spectromicroscopic imaging to investigate the single-particle characteristics of BBA particles. Approximately 20,400 individual particles from 10 selected samples were analyzed using computer-controlled scanning electron microscopy coupled with energy-dispersive X-ray microanalysis, revealing their elemental composition, morphology, and viscosity. Elemental microanalysis indicated that aged potassium is likely found in the form of K 2 SO 4 , KNO 3 , and possible K-organic salts. Further chemical speciation and carbon bonding mapping within individual particles were conducted using synchrotron-based scanning transmission X-ray microscopy (STXM) coupled with near edge X-ray absorption fine structure (NEXAFS) spectroscopy. Real-time, water-soluble light absorption measurements were acquired using a particle-into-liquid sampler instrument coupled to a liquid waveguide capillary cell and total organic analyzer. In the late afternoon samples, 65% of the total particle number population consisted entirely of organic components, compared to 46% in the nighttime particles. These differences were attributed to discrepancies in composition at the time of emission and to the daytime condensation and accumulation of photochemically formed secondary organic material on existing BBA particles, a process that halts at night. Microscopy images indicated that particle viscosity was lower in the nighttime particles (<10 1 Pa·s), likely due to increased relative humidity and a higher contribution from hygroscopic inorganic components. The chemical heterogeneity of individual particles was quantified using STXM-derived mixing state parameters. The nature of carbon bonding within individual particles was inferred from the extent of carbon sp 2 hybridization derived from NEXAFS spectra. Average percentages of sp 2 hybridization range between 40% and 60%, with no noticeable differences between late afternoon and nighttime flights. These findings were compared with the online optical properties of both late afternoon and nighttime smoke plumes, providing valuable insights into the complex relationship between chemical composition and optical properties of BBA particles at different times of the day.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Development of a Freeze-Dried CRISPR-Cas12 Sensor for Detecting Wolbachia in the Secondary Science Classroom

Training the future synthetic biology workforce requires the opportunity for students to be exposed to biotechnology concepts and activities in secondary education. Detecting Wolbachia bacteria in arthropods using polymerase chain reaction (PCR) has become a common way for secondary students to investigate and apply recombinant DNA technology in the science classroom. Despite this important activity, cutting-edge biotechnologies such as clustered regularly interspaced short palindromic repeat (CRISPR)-based diagnostics have yet to be widely implemented in the classroom. To address this gap, we present a freeze-dried CRISPR-Cas12 sensing reaction to complement traditional recombinant DNA technology education and teach synthetic biology concepts. The reactions accurately detect Wolbachia from arthropod-derived PCR samples in under 2 h and can be stored at room temperature for over a month without appreciable degradation. Here, the reactions are easy-to-use and cost less than $40 to implement for a classroom of 22 students including the cost of reusable equipment. We see these freeze-dried CRISPR-Cas12 reactions as an accessible way to incorporate synthetic biology education into the existing biology curriculum, which will expand biology educational opportunities in science, technology, engineering, and mathematics.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Impact of microkinetic modeling assumptions on predicted kinetics and mechanisms over undercoordinated sites

Accurate modeling of catalytic reactions on undercoordinated sites requires accounting for the structural and ensemble-specific nature of the active sites. This study examines how common microkinetic modeling (MKM) assumptions affect predicted kinetics and mechanisms on the stepped Pt(211) facet for the ethane dehydrogenation (EDH) and the ethane hydrogenolysis (EH). Six (211) MKMs were developed, differing in (i) the number of active sites represented, (ii) adsorbate site occupancy treatment, and (iii) inclusion of cross-facet interactions. These models are benchmarked against a particle-based microkinetic model (PB-MKM), which best represents step-edge behavior. MKM assumptions caused deviations in turnover frequencies exceeding ten orders of magnitude and led to contrasting mechanistic and selectivity predictions. Multi-site MKMs overestimate activity by inflating free site availability, single-site models underestimate activity, and uniform occupancy models overpredict coverage of multi-dentate intermediates, leading to reaction-specific artifacts. Overall, the Combined Site Edge Model (CSEM), a single-site MKM accounting for site occupancy and cross-facet interactions, most closely approximates PB-MKM predictions. All models predict similar kinetics when surfaces are clean or primarily occupied by monodentate species. This work provides practical guidance for selecting MKM frameworks for undercoordinated catalytic surfaces and highlights the critical role of modeling assumptions in catalytic predictions.

(211) facet↗
DOE OSTI2017

Inter-layer coupling induced valence band edge shift in mono- to few-layer MoS 2

In this study, recent progress in the synthesis of monolayer MoS 2 , a two-dimensional direct band-gap semiconductor, is paving new pathways toward atomically thin electronics. Despite the large amount of literature, fundamental gaps remain in understanding electronic properties at the nanoscale. Here,we report a study of highly crystalline islands of MoS 2 grown via a refined chemical vapor deposition synthesis technique. Using high resolution scanning tunneling microscopy and spectroscopy (STM/STS), photoemission electron microscopy/spectroscopy (PEEM) and μ-ARPES we investigate the electronic properties of MoS 2 as a function of the number of layers at the nanoscale and show in-depth how the band gap is affected by a shift of the valence band edge as a function of the layer number. Green’s function based electronic structure calculations were carried out in order to shed light on the mechanism underlying the observed bandgap reduction with increasing thickness, and the role of the interfacial Sulphur atoms is clarified. Our study, which gives new insight into the variation of electronic properties of MoS 2 films with thickness bears directly on junction properties of MoS2, and thus impacts electronics application of MoS 2 .

36 MATERIALS SCIENCE↗
DOE OSTI2014

Synergistic effect of V/N codoping by ion implantation on the electronic and optical properties of TiO{sub 2}

Performance of the material depends directly on the electronic and energy band structure, to improve the photoactivity of TiO{sub 2} and decrease carrier recombination centers induced by monodoping, the TiO{sub 2} thin film has been modified with V and N codopants by ion implantation for tailing and controlling the electronic structure and energy band structure. Compared to monodopant, codopants of V and N exhibit a synergistic effect in the photoactivity enhancement of TiO{sub 2}. X-ray photoelectron spectroscopy (XPS) studies demonstrate that the implanted V and N ions are introduced into the lattice of TiO{sub 2} through V and N substituting Ti and O, respectively. The electronic structure of V/N codoped TiO{sub 2} was calculated by First-principles calculations based on density-functional theory, the results show the band edges of TiO{sub 2} can be tailored by V and N codopants. UV-vis spectra consistently show the absorption edge of V/N codoped TiO{sub 2} film is widen to visible light region. More importantly, the photoactivity of TiO{sub 2} film has been significantly improved after V/N codoping. The enhanced photocatalytic performance is believed to be due to the V and N codopants induced synergistic effect that not only enhances the absorption of visible light but also promotes the separation of photogenerated electrons and holes in TiO{sub 2}. Besides, there exists an optimum for V/N ions implantation fluence. The capability of improving TiO{sub 2} photoactivity by V/N codoping could open up new opportunities in the development of highly efficient photocatalysts and photoelectrodes for solar energy and environmental applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Thermal fluctuation noise in Mo/Au superconducting transition-edge sensor microcalorimeters

In many superconducting transition-edge sensor (TES) microcalorimeters, the measured electrical noise exceeds theoretical estimates based on a thermal model of a single body thermally connected to a heat bath. In this work, we report on noise and complex impedance measurements of a range of designs of TESs made with a Mo/Au bilayer. We have fitted the measured data using a two-body model, where the x-ray absorber and the TES are connected by an internal thermal conductance G ae . We find that the so-called excess noise measured in these devices is consistent with the noise generated from the internal thermal fluctuations between the x-ray absorber and the TES. Our fitted parameters are consistent with the origin of G ae being from the finite thermal conductance of the TES itself. These results suggest that even in these relatively low resistance Mo/Au TESs, the internal thermal conductance of the TES may add significant additional noise and could account for all the measured excess noise. Furthermore, we find that around regions of the superconducting transition with rapidly changing derivative of resistance with respect to temperature, an additional noise mechanism may dominate. These observations may lead to a greater understanding of TES devices and allow the design of TES microcalorimeters with improved performance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

A GENERAL RELATIVISTIC NULL HYPOTHESIS TEST WITH EVENT HORIZON TELESCOPE OBSERVATIONS OF THE BLACK HOLE SHADOW IN Sgr A*

The half opening angle of a Kerr black hole shadow is always equal to (5 ± 0.2)GM/Dc{sup 2}, where M is the mass of the black hole and D is its distance from the Earth. Therefore, measuring the size of a shadow and verifying whether it is within this 4% range constitutes a null hypothesis test of general relativity. We show that the black hole in the center of the Milky Way, Sgr A*, is the optimal target for performing this test with upcoming observations using the Event Horizon Telescope (EHT). We use the results of optical/IR monitoring of stellar orbits to show that the mass-to-distance ratio for Sgr A* is already known to an accuracy of ∼4%. We investigate our prior knowledge of the properties of the scattering screen between Sgr A* and the Earth, the effects of which will need to be corrected for in order for the black hole shadow to appear sharp against the background emission. Finally, we explore an edge detection scheme for interferometric data and a pattern matching algorithm based on the Hough/Radon transform and demonstrate that the shadow of the black hole at 1.3 mm can be localized, in principle, to within ∼9%. All these results suggest that our prior knowledge of the properties of the black hole, of scattering broadening, and of the accretion flow can only limit this general relativistic null hypothesis test with EHT observations of Sgr A* to ≲10%.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Studies of Reynolds stress and the turbulent generation of edge poloidal flows on the HL-2A tokamak

Several new results on the physics linking edge poloidal flows to turbulent momentum transport are reported. These are based on experiments on the HL-2A tokamak. Significant deviation from the neoclassical prediction for mean poloidal flow in Ohmic and electron cyclotron resonance heating (ECRH) heated L-mode discharges is derived from direct measurement of the turbulent Reynolds stress. The deviation increases prominently with ECRH power. The turbulent poloidal viscosity is synthesized from fluctuation data, and is found to be comparable to the turbulent particle diffusivity. The intrinsic poloidal torque characterized by the divergence of the non-diffusive residual stress is deduced from synthesis for the first time in a tokamak plasma. Experimental evidence which demonstrates the dynamics of spectral symmetry breaking in drift wave turbulence is in good agreement with the development of the poloidal torque. Finally, taken together, these results elucidate the connections between power injection, turbulence development, pressure gradient and residual stress from symmetry breaking.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

High Luminosity LHC: Challenges and plans

The Large Hadron Collider (LHC) is one of the largest scientific instruments ever built. Since opening up a new energy frontier for exploration in 2010, it has gathered a global user community working in fundamental particle physics and the physics of hadronic matter at extreme temperature and density. To sustain and extend its discovery potential, the LHC will undergo a major upgrade in the 2020s. This will increase its rate of collisions by a factor of five beyond the original design value and the integrated luminosity by a factor ten. The new configuration, known as High Luminosity LHC (HL-LHC), will rely on a number of key innovations that push accelerator technology beyond its present limits. Among these are cutting-edge 11–12 T superconducting magnets, including Nb 3 Sn-based magnets never used in accelerators before, compact superconducting cavities for longitudinal beam rotation, new technology and physical processes for beam collimation. As a result, the dynamics of the HL-LHC beams will be also particularly challenging and this aspect is the main focus of this paper.

43 PARTICLE ACCELERATORS↗
DOE OSTI2017

X-ray absorption of liquid water by advanced ab initio methods

In this work, oxygen K-edge x-ray absorption spectra of liquid water are computed based on configurations from advanced ab initio molecular dynamics simulations, as well as an electron excitation theory from the GW method. One the one hand, the molecular structures of liquid water are accurately predicted by including both van der Waals interactions and a hybrid functional (PBE0). On the other hand, the dynamic screening effects on electron excitation are approximately described by the recently developed enhanced static Coulomb-hole and screened-exchange approximation of W. Kang and M. S. Hybertsen. The resulting spectra of liquid water are in better quantitative agreement with the experimental spectra due to the softened hydrogen bonds and the slightly broadened spectra originating from the better screening model.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Correlation of Diffusion Limited Oxidation to Color Difference in Accelerated Aging of Electrical Cable Insulation

Diffusion limited oxidation (DLO) as a phenomenon has complicated material lifetime predictions from accelerated aging studies. Many methods to analyze DLO have been developed in recent years. However, an analytical tool for high throughput and low-cost analysis of DLO affected samples remains absent from the literature. Color differences in polymers exposed to oxidative conditions have recently been observed and correlated to increased concentrations of oxidation products. Herein, total color difference was utilized to rapidly quantify DLO in ethylene propylene rubber (EPR) polymeric cable insulation specimens. Insulation specimens were aged at 121 °C, 136 °C, 150 °C, and 165 °C and a 10% ?E*ab difference between the specimen edge and specimen center was used as the threshold for DLO. Based on these specifications DLO was observed in EPR insulation specimen at temperatures of 136 °C and above, with an increasing degree of DLO observed as the time of exposure increased. The method presented in this work represents a quantitative and high-throughput method for the investigation of DLO with a low cost barrier for entry.

diffusion limited oxidation, DLO, nuclear, electri↗
DOE OSTI2014

Characteristic performance evaluation of a photon counting Si strip detector for low dose spectral breast CT imaging

Purpose: The possible clinical applications which can be performed using a newly developed detector depend on the detector's characteristic performance in a number of metrics including the dynamic range, resolution, uniformity, and stability. The authors have evaluated a prototype energy resolved fast photon counting x-ray detector based on a silicon (Si) strip sensor used in an edge-on geometry with an application specific integrated circuit to record the number of x-rays and their energies at high flux and fast frame rates. The investigated detector was integrated with a dedicated breast spectral computed tomography (CT) system to make use of the detector's high spatial and energy resolution and low noise performance under conditions suitable for clinical breast imaging. The aim of this article is to investigate the intrinsic characteristics of the detector, in terms of maximum output count rate, spatial and energy resolution, and noise performance of the imaging system. Methods: The maximum output count rate was obtained with a 50 W x-ray tube with a maximum continuous output of 50 kVp at 1.0 mA. A{sup 109}Cd source, with a characteristic x-ray peak at 22 keV from Ag, was used to measure the energy resolution of the detector. The axial plane modulation transfer function (MTF) was measured using a 67 μm diameter tungsten wire. The two-dimensional (2D) noise power spectrum (NPS) was measured using flat field images and noise equivalent quanta (NEQ) were calculated using the MTF and NPS results. The image quality parameters were studied as a function of various radiation doses and reconstruction filters. The one-dimensional (1D) NPS was used to investigate the effect of electronic noise elimination by varying the minimum energy threshold. Results: A maximum output count rate of 100 million counts per second per square millimeter (cps/mm{sup 2}) has been obtained (1 million cps per 100 × 100 μm pixel). The electrical noise floor was less than 4 keV. The energy resolution measured with the 22 keV photons from a {sup 109}Cd source was less than 9%. A reduction of image noise was shown in all the spatial frequencies in 1D NPS as a result of the elimination of the electronic noise. The spatial resolution was measured just above 5 line pairs per mm (lp/mm) where 10% of MTF corresponded to 5.4 mm{sup −1}. The 2D NPS and NEQ shows a low noise floor and a linear dependence on dose. The reconstruction filter choice affected both of the MTF and NPS results, but had a weak effect on the NEQ. Conclusions: The prototype energy resolved photon counting Si strip detector can offer superior imaging performance for dedicated breast CT as compared to a conventional energy-integrating detector due to its high output count rate, high spatial and energy resolution, and low noise characteristics, which are essential characteristics for spectral breast CT imaging.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

Thermal regulation of tightly packed solid-state photodetectors in a 1 mm{sup 3} resolution clinical PET system

Purpose: Silicon photodetectors are of significant interest for use in positron emission tomography (PET) systems due to their compact size, insensitivity to magnetic fields, and high quantum efficiency. However, one of their main disadvantages is fluctuations in temperature cause strong shifts in gain of the devices. PET system designs with high photodetector density suffer both increased thermal density and constrained options for thermally regulating the devices. This paper proposes a method of thermally regulating densely packed silicon photodetectors in the context of a 1 mm{sup 3} resolution, high-sensitivity PET camera dedicated to breast imaging. Methods: The PET camera under construction consists of 2304 units, each containing two 8 × 8 arrays of 1 mm{sup 3} LYSO crystals coupled to two position sensitive avalanche photodiodes (PSAPD). A subsection of the proposed camera with 512 PSAPDs has been constructed. The proposed thermal regulation design uses water-cooled heat sinks, thermoelectric elements, and thermistors to measure and regulate the temperature of the PSAPDs in a novel manner. Active cooling elements, placed at the edge of the detector stack due to limited access, are controlled based on collective leakage current and temperature measurements in order to keep all the PSAPDs at a consistent temperature. This thermal regulation design is characterized for the temperature profile across the camera and for the time required for cooling changes to propagate across the camera. These properties guide the implementation of a software-based, cascaded proportional-integral-derivative control loop that controls the current through the Peltier elements by monitoring thermistor temperature and leakage current. The stability of leakage current, temperature within the system using this control loop is tested over a period of 14 h. The energy resolution is then measured over a period of 8.66 h. Finally, the consistency of PSAPD gain between independent operations of the camera over 10 days is tested. Results: The PET camera maintains a temperature of 18.00 ± 0.05 °C over the course of 12 h while the ambient temperature varied 0.61 °C, from 22.83 to 23.44 °C. The 511 keV photopeak energy resolution over a period of 8.66 h is measured to be 11.3% FWHM with a maximum photopeak fluctuation of 4 keV. Between measurements of PSAPD gain separated by at least 2 day, the maximum photopeak shift was 6 keV. Conclusions: The proposed thermal regulation scheme for tightly packed silicon photodetectors provides for stable operation of the constructed subsection of a PET camera over long durations of time. The energy resolution of the system is not degraded despite shifts in ambient temperature and photodetector heat generation. The thermal regulation scheme also provides a consistent operating environment between separate runs of the camera over different days. Inter-run consistency allows for reuse of system calibration parameters from study to study, reducing the time required to calibrate the system and hence to obtain a reconstructed image.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

Counting Characteristics of the Registration System for the Baksan Experiment on Sterile Transitions

— Counting characteristics of the system for recording rare events of the {sup 71}Ge decay in the radiochemical gallium Baksan Experiment on Sterile Transitions (BEST) are presented. Events are recorded simultaneously along eight counting channels in the energy range 0.3–16 keV, which include {sup 71}Ge decays in the region of L and K peaks with a total efficiency of up to 75%. The data analysis is based on the recording of the full shape of the leading edge of the charge pulses using a digital oscilloscope.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

Photoacoustic Generation with Surface Noble Metal Nanostructures

Thin layers of noble metal (Ag, Au) nanoparticles on the surface of optical fiber edge are studied from the viewpoint of photoacoustic fiber-optic generation. In this paper we present theoretical investigation of laser radiation absorbtion by the monolayer of noble metal nanoparticles deposited on the surface of the optical fiber edge. Different nanostructures on the edge of the optical fiber are proposed for effective photoacoustic generation based on lasers with wavelength of 405, 445, 450, 510–530 nm.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2020

Spike-based graph centrality measures

We derive several spike-based routines that compute or establish bounds on radial centrality measures for undirected graphs and trees without the use of matrix multiplication. These spike-based centrality measures utilize a direct embedding of graph nodes and edges into neurons and synapses, can be implemented with static synapses or plastic synapses, and rely on minimal post-processing of spike rasters. This work contributes to the growing set of graphical applications for neuromorphic hardware.

Hamilton, Kathleen↗
DOE OSTI2017

Electrode Slurry Particle Density Mapping Using X-ray Radiography

The internal structure of a porous electrode strongly influences battery performance. Understanding the dynamics of electrode slurry drying could aid in engineering electrodes with desired properties. For instance, one might monitor the dynamic, spatially-varying thickness near the edge of a slurry coating, as it should lead to non-uniform thickness of the dried film. This work examines the dynamic behavior of drying slurry drops consisting of SiO x and carbon black particles in a solution of carboxymethylcellulose and deionized water, as an experimental model of drying behavior near the edge of a slurry coating. An X-ray radiography-based procedure is developed to calculate the evolving spatial distribution of active material particles from images of the drying slurry drops. To the authors’ knowledge, this study is the first to use radiography to investigate battery slurry drying, as well as the first to determine particle distributions from radiography images of drying suspensions. The dynamic results are consistent with tomography reconstructions of the static, fully-dried films. It is found that active material particles can rapidly become non-uniformly distributed within the drops. Heating can promote distribution uniformity, but seemingly must be applied very soon after slurry deposition. Higher slurry viscosity is found to strongly restrain particle redistribution.

25 ENERGY STORAGE↗