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At least 1,225 records · Page 68

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DOE OSTI2020

Quantum Super-resolution Bioimaging using Massively Entangled Multimode Squeezed Light

This report presents a new method for realizing a super-resolution quantum imaging using massively entangled multimode squeezed light (MEMSL). Each branch of the entangled multimode light interacts with the sample and bears the spatially varying optical phase delay. When imaging optics with finite pupil sizes are used, information is lost. Thanks to the analyticity in the Fourier plane, a noiseless measurement would recover the lost information and accomplish super resolution imaging beating the Rayleigh diffraction limit. I proved rigorously in a fully quantum formalism and presented that (1) such information recovery is possible and (2) the information recovery can be accomplished with much less resources when MEMSL is used than those needed in any non-entangled or non-squeezed classical imaging method. Furthermore, the action of the optical loss in the imaging system that degrades the imaging performance is also rigorously analyzed and presented. Several bioimaging applications that can benefit tremendously from the proposed quantum imaging scheme are also suggested.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2022

Direct Observation of the Pressure-Induced Structural Variation in Gold Nanoclusters and the Correlated Optical Response

The ability to gradually modify the atomic structures of nanomaterials and directly identify such structural variation is important in nanoscience research. Here, we present the first example of a high-pressure single-crystal X-ray diffraction analysis of atomically precise metal nanoclusters. The pressure-dependent, subangstrom structural evolution of an ultrasmall gold nanoparticle, Au 25 S 18 , has been directly identified. We found that a 0.1 Å decrease of the Au–Au bond length could induce a blue-shift of 30 nm in the photoluminescence spectra of gold nanoclusters. From theoretical calculations, the origins of the blue-shift and enhanced photoluminescence under pressure are investigated, which are ascribed to molecular orbital symmetry and conformational locking, respectively. Here, the combination of the high-pressure in situ X-ray results with both theoretical and experimental optical spectra provides a direct and generalizable avenue to unveil the underlying structure–property relations for nanoclusters and nanoparticles which cannot be obtained through traditional physical chemistry measurements.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

DOE OSTI2022

Developing CdTe homojunctions applying high throughput deposition

In this project, we attempted to make CdTe homojunctions using single crystal p-type doped substrates and closed-space sublimation epitaxy (CSSE) n-type doped films. The project included modeling which determined the ideal thickness for the n-type layer as being <200 nm. Boules of high concentration indium-doped CdTe and CdSe 0.4 Te 0.6 (CST) were grown using modified vertical Bridgman (MVB) methods. Similarly, iodine-doped CdTe crystals were grown for the first time. Washington State University (WSU) stock phosphorus-doped CdTe was used as the p-type substrate layer. The crystals were characterized by Hall effect and time-resolved photoluminescence (TRPL, for electrical properties), photoluminescence microscopy (for uniformity), X-ray diffraction (for crystal structure), and glow discharge mass spectrometry (GDMS, for dopant and impurity concentration). CdTe:I crystals were also characterized by visible and infrared transmission measurements, and various Cd or Te heat treatments were performed to assess changes in optical and electrical properties. The grown n-type materials – CdTe:In, CdSe0.4Te0.6:In, and CdTe:I – were provided to the National Renewable Energy Laboratory (NREL) for growth of CSSE thick films for characterization by two photon TRPL (for carrier lifetime), electron back-scatter diffraction (EBSD, to assess epitaxy), and Hall effect. Several measurements of secondary ion mass spectroscopy (SIMS) were performed. Nearly 100% of the indium from the crystal was incorporated into the measured thick films, while only ~2-22% of the iodine from the crystal was incorporated. The net result of the diffusion issue is that homojunction devices created using CSSE have a buried homojunction, as indicated by the near infrared peak in the external quantum efficiency (EQE). Various parameterization of front and back contacts suggested that the poor device performance was primarily a result of this buried junction and not due to other effects. There may also be an issue with the CSSE film lifetime in addition to the dopant profile.

14 SOLAR ENERGY↗

NASA NTRS1992

High resolution imaging at Palomar

For the last two years we have embarked on a program of understanding the ultimate limits of ground-based optical imaging. We have designed and fabricated a camera specifically for high resolution imaging. This camera has now been pressed into service at the prime focus of the Hale 5 m telescope. We have concentrated on two techniques: the Non-Redundant Masking (NRM) and Weigelt's Fully Filled Aperture (FFA) method. The former is the optical analog of radio interferometry and the latter is a higher order extension of the Labeyrie autocorrelation method. As in radio Very Long Baseline Interferometry (VLBI), both these techniques essentially measure the closure phase and, hence, true image construction is possible. We have successfully imaged binary stars and asteroids with angular resolution approaching the diffraction limit of the telescope and image quality approaching that of a typical radio VLBI map. In addition, we have carried out analytical and simulation studies to determine the ultimate limits of ground-based optical imaging, the limits of space-based interferometric imaging, and investigated the details of imaging tradeoffs of beam combination in optical interferometers.

Kulkarni, Shrinivas R.↗

DOE OSTI2024

Observation of a Picosecond Light-Induced Spin Transition in Polymeric Nanorods

Spin transition (ST) materials are attractive for developing photoswitchable devices, but their slow material transformations limit device applications. Size reduction could enable faster switching, but the photoinduced dynamics at the nanoscale remains poorly understood. Here, we report a femtosecond optical pump multimodal X-ray probe study of polymeric nanorods. Simultaneously tracking the ST order parameter with X-ray emission spectroscopy and structure with X-ray diffraction, we observe photodoping of the low-spin–lattice within ~150 fs. Above a ~16% photodoping threshold, the transition to the high-spin phase occurs following an incubation period assigned to vibrational energy redistribution within the nanorods activating the molecular spin switching. Above ~60% photodoping, the incubation period disappears, and the transition completes within ~50 ps, preceded by the elastic nanorod expansion in response to the photodoping. These results support the feasibility of ST material-based GHz optical switching applications.

36 MATERIALS SCIENCE↗

NASA NTRS1984

Study of alternate optical and fine guidance sensor designs for the space infrared telescope facility (SIRTF)

A unique optical design was developed that compensates for the coma degraded images caused by field chopping in SIRTF. The conic constants of a Cassegrain telescope were altered to compensate for the coma induced by the secondary mirror tilt. The modulation transfer function is essentially independent of secondary mirror tilt, and diffraction limited image quality is maintained over a several arcminute field during chopping. With an untilted secondary mirror, the coma compensated (CC) design has a smaller field than the unchopped Ritchey-Chretien design; but use of relay optics, such as the inverted Cassegrain design developed for the fine guidance sensor (FGS), can increase the CC telescope's field size. A reactionless secondary mirror chopper mechanism that uses superconducting magnets was studied. The heart producing elements are confined to a reaction plate that is not directly viewed by the IR focal plane. A design was also developed for a low moment of inertia, reticulated HIP beryllium secondary mirror consistent with blank fabrication technology and optical finishing requirements.

Wissinger, A.↗

NASA NTRS1994

Numerical Simulations of Self-Focused Pulses Using the Nonlinear Maxwell Equations

This paper will present results in computational nonlinear optics. An algorithm will be described that solves the full vector nonlinear Maxwell's equations exactly without the approximations that are currently made. Present methods solve a reduced scalar wave equation, namely the nonlinear Schrodinger equation, and neglect the optical carrier. Also, results will be shown of calculations of 2-D electromagnetic nonlinear waves computed by directly integrating in time the nonlinear vector Maxwell's equations. The results will include simulations of 'light bullet' like pulses. Here diffraction and dispersion will be counteracted by nonlinear effects. The time integration efficiently implements linear and nonlinear convolutions for the electric polarization, and can take into account such quantum effects as Kerr and Raman interactions. The present approach is robust and should permit modeling 2-D and 3-D optical soliton propagation, scattering, and switching directly from the full-vector Maxwell's equations. Abstract of a proposed paper for presentation at the meeting NONLINEAR OPTICS: Materials, Fundamentals, and Applications, Hyatt Regency Waikaloa, Waikaloa, Hawaii, July 24-29, 1994, Cosponsored by IEEE/Lasers and Electro-Optics Society and Optical Society of America

Goorjian, Peter M.↗

NASA NTRS1994

Numerical Simulations of Light Bullets, Using the Full Vector, Time Dependent, Nonlinear Maxwell Equations

Goorjian, Peter M.↗

NASA NTRS1995

Numerical Simulations of Light Bullets, Using The Full Vector, Time Dependent, Nonlinear Maxwell Equations

This paper will present results in computational nonlinear optics. An algorithm will be described that solves the full vector nonlinear Maxwell's equations exactly without the approximations that we currently made. Present methods solve a reduced scalar wave equation, namely the nonlinear Schrodinger equation, and neglect the optical carrier. Also, results will be shown of calculations of 2-D electromagnetic nonlinear waves computed by directly integrating in time the nonlinear vector Maxwell's equations. The results will include simulations of 'light bullet' like pulses. Here diffraction and dispersion will be counteracted by nonlinear effects. The time integration efficiently implements linear and nonlinear convolutions for the electric polarization, and can take into account such quantum effects as Karr and Raman interactions. The present approach is robust and should permit modeling 2-D and 3-D optical soliton propagation, scattering, and switching directly from the full-vector Maxwell's equations.

Goorjian, Peter M.↗

NASA NTRS1994

Numerical Simulations of Light Bullets, Using The Full Vector, Time Dependent, Nonlinear Maxwell Equations

Goorjian, Peter M.↗

DOE OSTI2021

Beamline K11 DIAD: a new instrument for dual imaging and diffraction at Diamond Light Source

The Dual Imaging and Diffraction (DIAD) beamline at Diamond Light Source is a new dual-beam instrument for full-field imaging/tomography and powder diffraction. This instrument provides the user community with the capability to dynamically image 2D and 3D complex structures and perform phase identification and/or strain mapping using micro-diffraction. The aim is to enable in situ and in operando experiments that require spatially correlated results from both techniques, by providing measurements from the same specimen location quasi-simultaneously. Using an unusual optical layout, DIAD has two independent beams originating from one source that operate in the medium energy range (7–38 keV) and are combined at one sample position. Here, either radiography or tomography can be performed using monochromatic or pink beam, with a 1.4 mm × 1.2 mm field of view and a feature resolution of 1.2 µm. Micro-diffraction is possible with a variable beam size between 13 µm × 4 µm and 50 µm × 50 µm. One key functionality of the beamline is image-guided diffraction, a setup in which the micro-diffraction beam can be scanned over the complete area of the imaging field-of-view. This moving beam setup enables the collection of location-specific information about the phase composition and/or strains at any given position within the image/tomography field of view. The dual beam design allows fast switching between imaging and diffraction mode without the need of complicated and time-consuming mode switches. Real-time selection of areas of interest for diffraction measurements as well as the simultaneous collection of both imaging and diffraction data of (irreversible) in situ and in operando experiments are possible.

36 MATERIALS SCIENCE↗

NASA NTRS1989

Hubble Space Telescope - New view of an ancient universe

Scheduled for a March 1990 Shuttle launch, the Hubble Space Telescope (HST) will give astronomers a tool of unprecedented accuracy to observe the universe: an optically superb instrument free of the atmospheric turbulence, distortion, and brightness that plague all earthbound telescopes. The observatory will carry into orbit two cameras, a pair of spectrographs, a photometer, and fine guidance sensors optimized for astrometry. The diffraction limit for the 2.4-m aperture of the HST corresponds to 90 percent of the radiation from a point source falling within a circle of 0.1 arcsec angular radius at a wavelength of 633 nm. The 15-year mission will make observations in the ultraviolet as well as the optical spectral region, thus, widening the wavelength window to a range extending from the Lyman alpha wavelengnth of 122 nm to just about 2 microns. The observational program that awaits the HST will include the study of planetary atmospheres, in particular the search for aerosols; the study of globular star clusters within the Galaxy; and the determination of the present rate of expansion of the universe. The HST will achieve resolutions of 0.1 arcsec consistently, regardless of observation duration. The HST engineering challenge is also discussed.

Leckrone, David S.↗

NASA NTRS2000

Recent Trends in the Analysis of Quasioptical Systems

The recent trend in microwave instruments is the use of multiple millimeter and submillimeter wavelength bands. These systems are typically analyzed by using physical optics, Gaussian beams or ray tracing techniques. Physical optics offers high accuracy at the expense of computation time. This trade-off becomes particularly apparent in the analysis of multiple reflector antennas, such as beam waveguide antennas, where physical optics is used to compute the current on each reflector from the current on the previous reflector. At the other end of the spectrum is ray tracing approaches that ignore diffraction effects entirely. These methods are fast but sacrifice the ability to predict some effects accurately. An intermediate approach is to use an appropriate set of expansion functions to model the field between the reflectors. If the set is chosen wisely only a few coefficients need to be determined from each reflector current. The field is then computed at the next reflector through the use of the expansion functions and their coefficients rather than by using the previous reflector current. For a beam waveguide system with no enclosing tubes an excellent set of expansion functions is the Gaussian beam mode set. In many cases a preliminary design which includes the effects on diffraction may be obtained by considering only the fundamental mode and a thin lens model for the reflectors. Higher-order modes are included to model the effects of the curved reflector, which include asymmetric distortion of the beam, cross polarization, and beam truncation. This paper describes a computer code implementing higher-order Gaussian beam scattering by multiple reflector systems. There are four essential steps in the algorithm. (1) Compute the current on the first reflector using physical optics using either a feed model or by an incident set of Gaussian beam modes. (2) Find the direction of propagation for the reflected Gaussian beam-set using ray tracing. (3) Determine the waist size and location for the output beam set by examining the amplitude and phase distribution of the current on the reflector. (4) Compute the amplitudes of the individual modes in the output mode set. These steps are then repeated for each addition reflector in the chain. In each of these cases the previous Gaussian beam set provides the input field for the current calculation. Details of the four steps discussed above will be discussed. Examples will compare results from the Gaussian beam approach to pure physical optics, illustrating both its merits and limitations. Hybrid approaches capable of eliminating some of the limitations will also be discussed.

Hoppe, D. J.↗

NASA NTRS1992

Reconfigurable optical interconnection network for multimode optical fiber sensor arrays

A single-source, single-detector architecture has been developed to implement a reconfigurable optical interconnection network multimode optical fiber sensor arrays. The network was realized by integrating LiNbO3 electrooptic (EO) gratings working at the Raman Na regime and a massive fan-out waveguide hologram (WH) working at the Bragg regime onto a multimode glass waveguide. The glass waveguide utilized the whole substrate as a guiding medium. A 1-to-59 massive waveguide fan-out was demonstrated using a WH operating at 514 nm. Measured diffraction efficiency of 59 percent was experimentally confirmed. Reconfigurability of the interconnection was carried out by generating an EO grating through an externally applied electric field. Unlike conventional single-mode integrated optical devices, the guided mode demonstrated has an azimuthal symmetry in mode profile which is the same as that of a fiber mode.

Chen, R. T.↗

NASA NTRS2002

Imaging Forming Planetary Systems: The HST/STIS Legacy and Prospects for Future Missions

The first indication that debris and protoplanetary disks associated with other, young planetary systems were sufficiently nearby to image came with the IRAS detection of infrared excesses around $\beta$ Pic, Vega, Fomalhaut, and $\epsilon$ Eri. Moving beyond analysis of the infrared excess to optical and near-IR imaging requires access to high Strehl ratio and high contrast imaging techniques, with the ability to efficiently reject the residual scattered and diffracted light from the star to reveal the fainter scattered light and circumstellar emission originating from the vicinity of the star. HST/STIS imaging studies have made use of incomplete Lyot coronagraphic imaging modes to reveal the warped, inner disk of $\beta$ Pic, provide the highest spatial resolution images of young debris disk systems such as HR 4796A, have revealed the presence of azimuthally symmetric structure in HD 141569 and HD 163296, and have demonstrated that currently active, collimated outflows survive to higher stellar masses than previously expected, and through more of the star's pre-main sequence lifetime than anticipated. The HST/STIS coronagraphic imaging legacy will be discussed, together with the implications for future NIR and optical high contrast imaging capabilities.

Grady, Carol↗

NASA NTRS1989

Catadioptric Optics for laser Doppler velocimeter applications

In the design of a laser velocimeter system, attention must be given to the performance of the optical elements in their two principal tasks: focusing laser radiation into the probe volume, and collecting the scattered light. For large aperture applications, custom lens design and fabrication costs, long optical path requirements, and chromatic aberration (for two color operation) can be problematic. The adaptation of low cost Schmidt-Cassegrain astronomical telescopes to perform these laser beam manipulation and scattered light collection tasks is examined. A generic telescope design is analyzed using ray tracing and Gaussian beam propagation theory, and a simple modification procedure for converting from infinite to near unity conjugate ratio operation with image quality near the diffraction limit was identified. Modification requirements and performance are predicted for a range of geometries. Finally, a 200-mm-aperture telescope was modified for f/10 operation; performance data for this modified optic for both laser beam focusing and scattered light collection tasks agree well with predictions.

Dunagan, Stephen E.↗

DOE OSTI2021

Cs absorption capacity and selectivity of crystalline and amorphous Hf and Zr phosphates

Removal of radioactive Cs from sodium-rich solutions is a technical challenge that goes back to post World War II nuclear waste storage and treatment; and interest in this topic was reinvigorated by the Fukushima-Daiichi nuclear power plant disaster, 10 years ago. Since the 1960's there has been considerable focus on layered Zr phosphates as robust inorganic sorbents for separation of radionuclides such as Cs. Here we present synthesis and characterization, and direct comparison of Cs sorption capacity and selectivity of four related materials: 1) crystalline α-Zr phosphate and α-Hf phosphate, and 2) amorphous analogues of these. Powder X-ray diffraction, thermogravimetry, solid-state 31P magic angle spinning nuclear magnetic resonance (MAS-NMR) spectroscopy, and compositional analysis (inductively coupled plasma optical emission spectroscopy and mass spectroscopy, ICP OES and ICP MS) provided formulae; respectively M(HPO4)2∙1H2O and M(HPO4)2∙4H2O (M = Hf, Zr) for crystalline and amorphous analogues. Maximum Cs loading, competitive Cs-Na selectivity and maximum Cs-Na loading followed by the above characterizations plus 133Cs MAS-NMR spectroscopy revealed that amorphous analogues are considerably better Cs-sorbents (based on maximum Cs-loading and selectivity over Na) than the well-studied crystalline Zr-analogue. Additionally, crystalline α-Hf phosphate is better Cs-sorbent than crystalline α-Zr phosphate. All these studies consistently show that Hf phosphate is less crystallize than Zr phosphate, when obtained under similar or identical synthesis conditions. We attribute this to lower solubility of Hf phosphate compared to Zr phosphate, preventing ‘defect healing’ during the synthesis process.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2025

Selective reduction in epitaxial SrFe 0.5 Co 0.5 O 2.5 and its reversibility

Oxygen-vacancy engineering in transition metal oxides enables programmable functionalities by modulating the valence states and local coordination of constituents. Here, we report the selective reduction of cobalt ions in epitaxial SrFe 0.5 Co 0.5 O 2.5 thin films under reducing gas environments, while iron ions remain unchanged. X-ray absorption spectroscopy reveals an absorption edge shift of 1.65 eV in the Co L-edge upon reduction, and multiplet simulations estimate a decrease in the average Co valence from Co 2.91+ to Co 2.00+ . This site- and element-specific reduction leads to the formation of a structurally distinct oxygen-deficient phase stabilized by oxygen vacancies at tetrahedral sites, as confirmed by density functional theory. Optical spectroscopy reveals an increase in the bandgap from 2.47 eV to 3.04 eV, accompanied by enhanced transparency. Furthermore, simultaneous in situ diffraction and transport measurements confirm fully reversible redox-driven transitions among three phases: reduced defective perovskite, brownmillerite, and oxygen-rich perovskite phases. These findings demonstrate that selective redox control in multi-cation oxides enables the realization of chemically and functionally distinct oxygen-deficient phases.

Fuel cells↗