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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Environmental qualification testing of payload G-534, the Pool Boiling Experiment

Payload G-534, the prototype Pool Boiling Experiment (PBE), is scheduled to fly on the STS-47 mission in September 1992. This paper describes the purpose of the experiment and the environmental qualification testing program that was used to prove the integrity of the hardware. Component and box level vibration and thermal cycling tests were performed to give an early level of confidence in the hardware designs. At the system level, vibration, thermal extreme soaks, and thermal vacuum cycling tests were performed to qualify the complete design for the expected shuttle environment. The system level vibration testing included three axis sine sweeps and random inputs. The system level hot and cold soak tests demonstrated the hardware's capability to operate over a wide range of temperatures and gave wider latitude in determining which shuttle thermal attitudes were compatible with the experiment. The system level thermal vacuum cycling tests demonstrated the hardware's capability to operate in a convection free environment. A unique environmental chamber was designed and fabricated by the PBE team and allowed most of the environmental testing to be performed within the hardware build laboratory. The completion of the test program gave the project team high confidence in the hardware's ability to function as designed during flight.

Sexton, J. Andrew↗
NASA NTRS1992

Environmental qualification testing of the prototype pool boiling experiment

The prototype Pool Boiling Experiment (PBE) flew on the STS-47 mission in September 1992. This report describes the purpose of the experiment and the environmental qualification testing program that was used to prove the integrity of the prototype hardware. Component and box level vibration and thermal cycling tests were performed to give an early level of confidence in the hardware designs. At the system level, vibration, thermal extreme soaks, and thermal vacuum cycling tests were performed to qualify the complete design for the expected shuttle environment. The system level vibration testing included three axis sine sweeps and random inputs. The system level hot and cold soak tests demonstrated the hardware's capability to operate over a wide range of temperatures and gave the project team a wider latitude in determining which shuttle thermal altitudes were compatible with the experiment. The system level thermal vacuum cycling tests demonstrated the hardware's capability to operate in a convection free environment. A unique environmental chamber was designed and fabricated by the PBE team and allowed most of the environmental testing to be performed within the project's laboratory. The completion of the test program gave the project team high confidence in the hardware's ability to function as designed during flight.

Sexton, J. Andrew↗
DOE OSTI2014

PBX 9502 Multimode Damage Accumulation Cycles-to-Failure Study

In FY13, we performed a detailed cycles-to-failure study of PBX 9502 using 3- point bend specimens. In that study we examined the effect of temperature and cyclic frequency on the failure behavior of PBX 9502. We identified cycles-to-failure curves for samples tested at -20°C, ~19°C and 50°C and at cyclic frequencies of 0.0001 up to 1-Hz. We also did cyclic conditioning of parts in an effort to establish damage accumulation criteria that could then be used in predictive models. As follow-on to that work, in FY14 we have added multimode cycles-to-failure to our test suite. Work this year re-established the baseline cycles-to-failure behavior of the PBX 9502 material tested round ~19°C at 1-Hz and also looked at damage accumulation under a multimode loading environment. This fresh baseline development was performed to remove any time related or test rig related variables. The multimode loading was done because real-world applications are not mono-modal and we desire for our predictive capability to be robust and include more complex, realistic scenarios. In the following sections we briefly describe the test setup, we provide a summary of the new baseline results and we show the multimode cycles-to-failure data and how it compares to the mono-modal test data.

42 ENGINEERING↗
DOE OSTI2023

Impact of the fluorination degree of ether-based electrolyte solvents on Li-metal battery performance

Electrolytes using fluorinated solvents have proven effective in improving the cycling life of Li-metal batteries, by forming a robust solid–electrolyte interphase through decomposition of anion and fluorinated solvent molecules. Herein, we modulated the fluorination degree of ether-based electrolyte solvents to investigate their performance in Li-metal batteries. Here, we tuned the fluorination degree by installing a monofluoro substituent on one ethoxy group of 1,2-diethoxyethane (DEE) and varying the fluorination degree on the other one, providing three fluorinated DEE solvent molecules (i.e., F1F0, F1F1 and F1F2) with a relatively low fluorination degree. All three electrolytes showed improved solvation strength and ionic conductivities compared with previous highly fluorinated DEE electrolytes while retaining good oxidative stability. A full cell test using the Li-metal anode and nickel-rich cathode revealed that a higher degree of fluorination is beneficial to the cycling performance, and the cycling stability follows F1F0 < F1F1 < F1F2. Specifically, F1F0 exhibited poor cycling stability due to its instability against both the anode and cathode. While F1F1 and F1F2 both showed good stability against the Li metal anode, their relative long-term oxidative stability was responsible for the distinct performance, in which the cycle numbers at 80% capacity retention for F1F1 and F1F2 were ~20 and ~80, respectively. Finally, we demonstrated that F1F2 was able to achieve 90 cycles before reaching 80% capacity retention in practical lithium iron phosphate (LFP) pouch cells. This work shows the importance of modulating the fluorination degree of electrolyte solvents, and this approach is suitable for various cathode materials.

25 ENERGY STORAGE↗
DOE OSTI2017

Systematic Investigation of the Alucone-Coating Enhancement on Silicon Anodes

Polyvinylidene fluoride (PVDF) is the most popular binder in commercial lithium-ion batteries but is incompatible with a silicon (Si) anode because it fails to maintain the mechanical integrity of the Si electrode upon cycling. Here in this paper, an alucone coating synthesized by molecular layer deposition has been applied on the laminated electrode fabricated with PVDF to systematically study the sole impact of the surface modification on the electrochemical and mechanical properties of the Si electrode, without the interference of other functional polymer binders. The enhanced mechanical properties of the coated electrodes, confirmed by mechanical characterization, can help accommodate the repeated volume fluctuations, preserve the electrode structure during electrochemical reactions, and thereby, leading to a remarkable improvement of the electrochemical performance. Owing to the alucone coating, the Si electrodes achieve highly reversible cycling performance with a specific capacity of 1490 mA h g -1 (0.90 mA h cm -2 ) as compared to 550 mA h g -1 (0.19 mA h cm -2 ) observed in the uncoated Si electrode. This research elucidates the important role of surface modification in stabilizing the cycling performance and enabling a high level of material utilization at high mass loading. It also provides insights for the future development of Si anodes.

25 ENERGY STORAGE↗
DOE OSTI2018

Effect of isothermal and non-isothermal aging on the low cycle fatigue behavior of an Al–Cu–Mg–Si forging alloy

Highlights: • Non-isothermal aging treatment is performed to improve low cycle fatigue performance of an Al-Cu-Mg-Si forging alloy. • Mixed precipitation characteristic manifested as shearable and non-shearable θ' phases is obtained by non-isothermal aging. • Planar slip associated with particle shearing mechanism contributes to the high fatigue crack propagation resistance. - Abstract: Low cycle fatigue (LCF) behavior of an Al–Cu–Mg–Si forging alloy was investigated at room temperature. Isothermal aging (T6) and non-isothermal aging (NIA) treatments were applied to produce different microstructures. Under the same strain amplitude, the LCF life of NIA specimen exceeded that of T6 specimen. Besides, NIA specimens exhibited cyclic stability behavior in contrast to cyclic hardening behavior of T6 specimens. The different LCF behaviors could be rationalized by different deformation mechanisms under cyclic straining. T6 specimens with non-shearable θ′-phases underwent Orowan bypassing mechanism leading to the cyclic hardening behavior. While NIA specimens with shearable and non-shearable θ′-phases suffered from both particle shearing and Orowan bypassing mechanisms resulting in the cyclic stability behavior. Non-shearable θ′-phases bypassed by dislocations introduced more stress concentration, while shearable θ′-phases cut through by dislocations caused less stress concentration. Therefore, fatigue life of NIA specimen is longer than that of T6 specimen.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Solvothermal-Derived S-Doped Graphene as an Anode Material for Sodium-Ion Batteries

Sodium–ion batteries (SIBs) have attracted enormous attention in recent years due to the high abundance and low cost of sodium. However, in contrast to lithium–ion batteries, conventional graphite is unsuitable for SIB anodes because it is much more difficult to intercolate the larger Na ions into graphite layers. Therefore, it is critical to develop new anode materials for SIBs for practical use. Here, heteroatom–doped graphene with high doping levels and disordered structures is prepared using a simple and economical thermal process. The solvothermal–derived graphene shows excellent performance as an anode material for SIBs. It exhibits a high reversible capacity of 380 mAh g –1 after 300 cycles at 100 mA g –1 , excellent rate performance 217 mAh g –1 at 3200 mA g –1 , and superior cycling performance at 2.0 A g –1 during 1000 cycles with negligible capacity fade.

25 ENERGY STORAGE↗
DOE OSTI2026

Low-Rate Cycling Regeneration Sustains NMC811–Graphite Battery Performance through Extreme Ultrafast Charging

Urban air mobility (UAM) systems, such as electric vertical takeoff and landing (eVTOL) aircraft, require batteries capable of extreme ultrafast charging to support high-frequency operations. Here, in this work, we evaluate the electrochemical stability of NMC811–graphite full cells using a complex mixed-modal protocol designed to simulate the aggressive turnaround demands of UAM missions. We demonstrate that incorporating a periodic low-rate (0.3C) “regeneration” cycle enables cells to maintain 96% capacity retention over 900 cycles, despite repeated exposure to ultrafast pulses. To validate the efficacy of this regeneration mechanism, we performed simplified control experiments comparing continuous 10C charging against a 10C–0.3C interleaved protocol. Advanced characterization reveals that while mechanical particle fracture is pervasive at these rates, the regeneration cycles decelerate the electrochemical degradation by resolving spatially heterogeneous Ni oxidation states and relaxing lithium-ion concentration gradients. These findings provide a vital mechanistic framework for battery operation, proving that restorative charging can effectively delay and mitigate failure in demanding UAM applications.

batteries↗
NASA NTRS1999

Effects of menstrual cycle phase and oral contraceptives on alertness, cognitive performance, and circadian rhythms during sleep deprivation

The influence of menstrual cycle phase and oral contraceptive use on neurobehavioral function and circadian rhythms were studied in healthy young women (n = 25) using a modified constant routine procedure during 24 h of sleep deprivation. Alertness and performance worsened across sleep deprivation and also varied with circadian phase. Entrained circadian rhythms of melatonin and body temperature were evident in women regardless of menstrual phase or oral contraceptive use. No significant difference in melatonin levels, duration, or phase was observed between women in the luteal and follicular phases, whereas oral contraceptives appeared to increase melatonin levels. Temperature levels were higher in the luteal phase and in oral contraceptive users compared to women in the follicular phase. Alertness on the maintenance of wakefulness test and some tests of cognitive performance were poorest for women in the follicular phase especially near the circadian trough of body temperature. These observations suggest that hormonal changes associated with the menstrual cycle and the use of oral contraceptives contribute to changes in nighttime waking neurobehavioral function and temperature level whereas these factors do not appear to affect circadian phase.

NASA Discipline Regulatory Physiology↗
NASA NTRS1952

Loitering and range performance of turbojet-powered aircraft determined by off-design engine cycle analysis

The loitering and range performance of airplanes equipped with several different turbojet engines was analytically investigated by applying the results of off-design cycle analyses to specific airplane characteristics. The method of off-design cycle analysis is presented herein and is verified by a check with experimental data. For all engines considered, the loitering and the range fuel flows obtained with rated tail-pipe nozzle area, variable engine speed operations were within 2 or 3 percent of the optimum fuel flow obtainable with any method of engines operation. The optimum loitering altitude generally occurred between approximately 25,000 and 35,000 feet with corresponding optimum flight Mach numbers of 0.4 to 0.65. In general, the optimum range fuel flows occurred at 3000 to 5000 feet higher altitude and at approximately 0.15 higher flight Mach numbers than the optimum loitering fuel flow.

Koutz, Stanley L↗
DOE OSTI2024

Impact of cycling conditions on lithium-ion battery performance for electric vertical takeoff and landing applications

The development of better electrochemical energy storage systems has sparked significant interest in using Li-ion batteries for electric vertical takeoff and landing (eVTOL) applications. To ensure the optimal performance and safety of onboard batteries, their behavior under different charging/discharging protocols and environmental conditions must be understood. Here, this paper presents a comprehensive evaluation of commercial Li-ion batteries for eVTOL applications, focusing on their responses to varying charging/discharging strategies and mechanical vibrations experienced during flight. Through controlled experiments, the effects of rapid cycling on battery performance were investigated, including effects on lifespan, capacity, and internal resistance. Additionally, the impact of mechanical vibrations on battery behavior was assessed to identify potential challenges for onboard batteries. The results of this study revealed intriguing insights into the interplay between temperature, vibration, and battery performance. This work contributes to the broader adoption of electric aerial transportation, promising a greener and safer future for urban mobility.

18650 cells↗
DOE OSTI2023

An optical-input Maximum Likelihood Estimation feedback system demonstrated on tokamak horizontal equilibrium control

A readily parallelized Maximum Likelihood Estimation (MLE) algorithm with linear computational complexity is demonstrated in real time using only measurements from an extreme ultraviolet (EUV) diagnostic to control the horizontal position of a tokamak plasma. A set of trial emissivity profiles are parameterized by the control quantity of interest (R m ), and the MLE is identified from the profile which minimizes the signal reconstruction residual. The algorithm depends on an empirically determined likelihood function with exponential form. EUV emission (λ ≈ 15eV-1keV) is captured in a poloidal plane by four 16-channel AXUV diodes mounted at different poloidal angles with radial and angular resolution sufficient to discern plasma equilibrium evolution in HBT-EP. Calculations of the plasma major radius by the system are consistent within diagnostic uncertainty for the majority of the discharge with those of: a weighted average of vertical soft X-ray or EUV chords, magnetic sensors, and an equilibrium reconstruction. The feedback system corrects for a horizontal displacement of the major radius equal to 20% of the plasma minor radius by adjusting the vertical field produced from 40 in-vessel control coils in real time. The MLE calculation is performed on a GPU in a 15 μs cycle, with similar performance in this application to a simple weighted average of vertical chords. Finally, results demonstrate horizontal position control using magnetic actuators and an optical observer.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2013

Nuclear Energy Return on Energy Investment

This report provides a methodology and requisite data to assess the potential Energy Return on (Energy) Investment (EROI) for nuclear fuel cycle alternatives, and applies that methodology to an example “once-through” fuel cycle using low enrichment uranium (LEU) in conventional light water cooled reactors (LWRs). Within the DOE Office of Nuclear Energy Science and Technology - Fuel Cycle Technologies program, the Fuel Cycle Options Campaign “performs integrating analyses of nuclear energy and fuel cycle systems to inform fuel cycle R&D, programmatic decisions, strategy formulation, and policy development”. Campaign objectives include development of relevant fuel cycle metrics, and development of tools and associated data for analysis of fuel cycle systems. This study represents an extension of a prior evaluation of EROI as a metric for fuel cycle facilities, processes and technologies. That prior study [Simon 2011] addressed the energy return on the addition of fuel recycle to an existing nuclear energy system. Limited to just the addition of fuel recycle, that study did not include all the energy investments required to create, operate and decommission the underlying nuclear fuel cycle, such as uranium mining, fuel fabrication, reactor construction, and used fuel disposition. This extension of the prior work adds these remaining pieces of the fuel cycle to provide a basic evaluation framework and initial data to enable evaluation of EROI for nuclear energy in general. It is intended as a basis for evaluation of alternative fuel cycle options in the future with the addition of pertinent details for other fuel cycle scenarios. In the prior work, a spreadsheet tool was constructed for the specific purpose of this energy input/output analysis of nuclear fuel cycle facilities. This tool allows the user to enter the parameters of the nuclear fuel cycle and assumptions about energy use in reprocessing. In the current analysis, energy consumption for an entire nuclear energy enterprise is considered, including facility construction, materials, facility operation, and decommissioning. The analysis tool has been extended to include the entire fuel cycle for a representative scenario of a once-through LWR nuclear energy system. Energy content data have been developed for an initial representation. In many cases where there is a valid range of plausible energy content, the range is discussed and a representative value selected for demonstration of the evaluation methodology. In this analysis, energy produced is the energy output of power reactors within the fuel cycle. The spreadsheet calculates both Primary EROI and Final EROI for the fuel cycle entered. The EROI is the ratio of the output energy divided by the consumed energy. The intent for this study was to develop the methodology and analysis tool for a complete fuel cycle. It is not the intent of the study to fully explore the wide range of potential energy intensities, or to reconcile the disparate values found in the literature. Representative numbers were used in this demonstration. The methodology and tool do provide a framework for future exploration of the key energy intensity values and for conducting sensitivity studies on specific values, either to assess improved understanding of the values, or to explore the potential for alternative technologies to impact EROI. The Primary and Final Energy EROI values calculated for the representative scenario were ~ 52 and 24, respectively.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1984

A comparative look at sunspot cycles

On the basis of cycles 8 through 20, spanning about 143 years, observations of sunspot number, smoothed sunspot number, and their temporal properties were used to compute means, standard deviations, ranges, and frequency of occurrence histograms for a number of sunspot cycle parameters. The resultant schematic sunspot cycle was contrasted with the mean sunspot cycle, obtained by averaging smoothed sunspot number as a function of time, tying all cycles (8 through 20) to their minimum occurence date. A relatively good approximation of the time variation of smoothed sunspot number for a given cycle is possible if sunspot cycles are regarded in terms of being either HIGH- or LOW-R(MAX) cycles or LONG- or SHORT-PERIOD cycles, especially the latter. Linear regression analyses were performed comparing late cycle parameters with early cycle parameters and solar cycle number. The early occurring cycle parameters can be used to estimate later occurring cycle parameters with relatively good success, based on cycle 21 as an example. The sunspot cycle record clearly shows that the trend for both R(MIN) and R(MAX) was toward decreasing value between cycles 8 through 14 and toward increasing value between cycles 14 through 20. Linear regression equations were also obtained for several measures of solar activity.

Wilson, R. M.↗
NASA NTRS1987

Effect of storage and LEO cycling on manufacturing technology IPV nickel-hydrogen cells

Yardney Manufacturing Technology (MANTECH) 50 A-hr space weight individual pressure vessel nickel-hydrogen cells were evaluated. This consisted of investigating: the effect of storage and charge/discharge cycling on cell performance. For the storage test the cells were precharged with hydrogen, by the manufacturer, to a pressure of 14.5 psia. After undergoing activation and acceptance tests, the cells were discharged at C/10 rate (5A) to 0.1 V or less. The terminals were then shorted. The cells were shipped to NASA Lewis Research Center where they were stored at room temperature in the shorted condition for 1 year. After storage, the acceptance tests were repeated at NASA Lewis. A comparison of test results indicate no significant degradation in electrical performance due to 1 year storage. For the cycle life test the regime was a 90 minute low earth orbit at deep depths of discharge (80 and 60 percent). At the 80 percent DOD the three cells failed on the average at cycle 741. Failure for this test was defined to occur when the cell voltage degraded to 1 V prior to completion of the 35 min discharge. The DOD was reduced to 60 percent. The cycle life test was continued.

Smithrick, John J.↗
NASA NTRS1987

Effect of storage and LEO cycling on manufacturing technology IPV nickel-hydrogen cells

Yardney Manufacturing Technology (MANTECH) 50 A-hr space weight individual pressure vessel nickel-hydrogen cells were evaluated. This consisted of investigating: the effect of storage and charge/discharge cycling on cell performance. For the storage test the cells were precharged with hydrogen, by the manufacturer, to a pressure of 14.5 psia. After undergoing activation and acceptance tests, the cells were discharged at C/10 rate (5A) to 0.1 V or less. The terminals were then shorted. The cells were shipped to NASA Lewis Research Center where they were stored at room temperature in the shorted condition for 1 year. After storage, the acceptance tests were repeated at NASA Lewis. A comparison of test results indicate no significant degradation in electrical performance due to 1 year storage. For the cycle life test the regime was a 90 minute low earth orbit at deep depths of discharge (80 and 60 percent). At the 80 percent DOD the three cells failed on the average at cycle 741. Failure for this test was defined to occur when the cell voltage degraded to 1 V prior to completion of the 35 min discharge. The DOD was reduced to 60 percent. The cycle life test was continued.

Smithrick, John J.↗
DOE OSTI2020

Inter-module fuel shuffling

A method of loading fuel in multiple reactor cores associated with a plurality of fuel cycles. The method includes, in a first fuel cycle, loading a first reactor core with a first fuel assembly selected from a first batch of fuel, loading the first reactor core with a first partially spent fuel assembly from a second batch of fuel, loading a second reactor core with a second fuel assembly from the first batch of fuel, and loading the second reactor core with a second partially spent fuel assembly from the second batch of fuel. In a second fuel cycle, which is performed after a completion of the first fuel cycle, the method includes loading the second reactor core with a fresh fuel assembly, and loading the second reactor core with the first fuel assembly from the first batch of fuel.

Kitto, Allyson↗