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All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

Spatial and Temporal Analysis of Global Landslide Reporting Using a Decade of the Global Landslide Catalog

Rainfall-triggered landslides can result in devastating loss of life and property damage and are a growing concern from local to global scale. NASA’s Global Landslide Catalog (GLC) compiles a record of rainfall-triggered landslide events from media reports, academic articles, and existing databases at global scale. The database consists of all types of mass movement events that are triggered by rainfall and represents a minimum number of events occurring between 2007 – 2018. The research presented here evaluates global patterns in landslide reporting from events in the GLC. The evaluation includes an analysis of the spatial and temporal distribution of global landslide events and associated casualties and comparisons with other landslide inventories. This database has been used to estimate landslide hotspots, evaluate geographic patterns in landslides, and train and validate landslide models from local to global scales. The most notable landslide hotspots are in the Pacific Northwest of North America, High Mountain Asia, and the Philippines. Additionally, the relationship between country GDP and income status with landslide occurrence was determined to have a positive correlation between economic status and landslide reporting. The GLC also indicates a reporting bias towards English-speaking countries. The general goal of this research is to assess the decade of global landslide reports from the GLC and show how this database can be used for rainfall-triggered landslide research.

Global Landslide Catalog↗
NASA NTRSDate not supplied

Evaluating the Performance of GPM IMERG Products for Extreme Precipitation Estimation in Volta River Basin of Ghana

The Volta River basin in West Africa, covering a substantial area of Ghana, faces significant water management challenges due to highly variable rainfall and limited availability of high temporal resolution rain gauges. This study, developed under the 2024 Global Precipitation Measurement (GPM) Mission mentorship program, evaluates precipitation in the Volta River basin using high-resolution satellite-derived data from the Integrated Multi-satellite Retrievals for GPM (IMERG). In the absence of sub-daily rainfall data, comparisons were made between daily, monthly, and seasonal precipitation from local gauges and IMERG V06 and V07 (early and final) runs. Results indicated a very weak correlation between daily precipitation estimates from IMERG and gauge data, but a significantly improved correlation for monthly and seasonal estimates. Additionally, IMERG data were used to identify heavy rainfall events and drought periods, which were compared to known occurrences in the region. By addressing these objectives, this study contributes to more accurate extreme precipitation estimation in the Volta River basin, thereby enhancing disaster risk management and climate resilience in Ghana.

Jessica Sutton↗
DOE OSTI2021

Daily grass reference evapotranspiration with Meteosat Second Generation shortwave radiation and reference ET products

Here we assess the accuracy of estimating daily grass reference evapotranspiration (PM-ET o ) using daily shortwave radiation (R s ) and reference evapotranspiration (ET REF ) products provided by the Meteosat Second Generation (MSG) geostationary satellite delivered by the Satellite Applications Facility on Land Surface Analysis (LSA-SAF) framework. The accuracy of using reanalysis ERA5 shortwave radiation data (R s ERA5 ) provided by the European Center for Medium-Range Weather Forecasts (ECMWF) is also evaluated. The assessments were performed using observed weather variables at 37 weather stations distributed across continental Portugal, where climate conditions range from semi-arid to humid, and 12 weather stations located in Azores islands, characterized by humid, windy and often cloudy conditions. This study&#x27;s use of data from a variety of climate conditions contributed to a unique and innovative assessment of the usability of LSA-SAF and ERA5 products for ET o estimation. The first assessment focused on comparing LSA-SAF estimates of R s (R s LSA-SAF ) against ground stations (R s ground ). The results showed a good matching between the two R s data sets for continental Portugal but a tendency for R s LSA-SAF to under-estimate R s ground in the cloudy islands of Azores. ET o values computed using R s LSA-SAF data and observed temperature, humidity and wind speed (ET o LSA-SAF ) were then compared with PM-ET o estimates with ground-based data, which were used as benchmark; input data of temperature and humidity needed for PM-ET o were quality checked for surface aridity effects. It was observed that ET o LSA-SAF is strongly correlated with PM-ET o (R 2 > 0.97) for most locations in continental Portugal, with regression coefficient of a linear regression forced to the origin ranging between 0.95 and 1.05, mean root mean square error (RMSE) of 0.13 mm d –1 , and Nash and Sutcliff efficiency of modeling (EF) above 0.95. For most Azores locations, ET o LSA-SAF over-estimated PM-ET o . This is likely a consequence of the high spatio-temporal heterogeneity of weather conditions that occur in these oceanic islands together with the different footprints of satellite (averaged over the pixel) and station observations. Reanalysis ERA5 shortwave radiation data presented similar behavior to the LSA-SAF products, however with slightly lower accuracy. The daily LSA-SAF ET REF product (ET REF LSA-SAF ) was assessed and results have shown a good accuracy of this product, with acceptable RMSE and high EF values, for continental Portugal but a low accuracy for the Azores islands. A simplified bias correction approach was shown to improve both ET o derived from the LSA-SAF products, namely for Azores stations, which seem to be representative of smaller areas. The use of the FAO-PM temperature approach (PMT) was also assessed using the R s LSA-SAF and R s ERA5 data, which showed a superiority of the LSA-SAF product for ET o estimations (ET o PMT LSA-SAF ). No significant differences (p < 0.05) were observed in terms of the median value of the RMSE when adopting ET o PMT and ET REF LSA-SAF . Differently, results showed that using the R s LSA-SAF in the PMT approach (ET o PMT LSA-SAF ) produces significantly better RMSE results than ET o PMT and ET REF LSA-SAF . Overall, the performed assessment allows concluding that the use of R s LSA-SAF, and to a lesser extent the use of the R s ERA5 , highly improves the accuracy of computation of ET o when R s observations are not available, including when only temperature data are accessible. The use of the ET REF LSA-SAF product is a good alternative when observed weather data are not available.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Temporal evolution of scalar modes in Richtmyer–Meshkov instability of inclined interface using high-speed PIV and PLIF measurements at 60 kHz

Abstract The current work presents simultaneous, high-speed measurements at 60,000 fields per second of velocity and mole fraction using particle image velocimetry (PIV) and planar laser induced acetone-fluorescence in a Richtmyer–Meshkov instability of an inclined interface (Atwood number, At = 0.22). Specifically, around 2 ms of temporal evolution of the vortex structures and their associated scalar modes immediately following the interface-reshock interaction is presented. Two initial interface conditions are discussed—(a) a sharp, inclined ‘single mode’ interface and (b) a ‘multi-mode’ interface where small perturbations are imposed on the single mode case. A 2D wavelet decomposition of the scalar flow field shows a highly intermittent distribution of small-scale variance throughout the interface even at late times. These are correlated strongly with the vortex structures and local turbulence intensity, where each small-scale scalar mode is sandwiched between two co-rotating vortex structures. This indicates that the interstitial regions between the vortices are significant hotspots of entrainment, which is then dispersed by the induced, counter-flow velocity fields. The multimode case demonstrates similar organization at large scales, while the scalar field is much more homogeneous at smaller scales. These observations highlight the importance of capturing the early time vortex evolution to accurately estimate any late time intermittency, especially where deposition of intense vorticity on sharp interfaces is present.

Engineering↗
NASA NTRS1990

Relationship between tropical heating and subtropical westerly maxima in the Southern Hemisphere during SOP-1, FGGE

FGGE Level III-b analyses, produced by the Goddard Laboratory for Atmospheres, NASA, are used to investigate the relationship between tropical heating and subtropical westerly maxima in the Southern Hemisphere during SOP-1 (January 5 - March 4, 1979). The mean state of two 15-day periods is examined, as well as day-to-day variations for the entire 59-day period. In Period 1 (January 6-20), the central South Pacific was extremely active convectively, while in Period 2 (February 3-17), convective activity over the western Indian Ocean was enhanced. Episodes of strong outflow in the tropics, as measured by the upper tropospheric velocity potential, were found to be well correlated with the strengthening and propagation of westerly wind maxima in the subtropics. The average location of the westerly maximum over the South Pacific and Indian oceans was about 16 deg latitudes south, and slightly east, of its corresponding heat source. For a cyclone case study which is presented, however, this distance was considerably less. The response time between the upper level tropical outflow and subtropical westerly enhancement appears to be less than 12 hours; however, an exact temporal scale was difficult to identify.

Hurrel, James W.↗
NASA NTRS2004

Distributive On-line Processing, Visualization and Analysis System for Gridded Remote Sensing Data

The ability to use data stored in the current Earth Observing System (EOS) archives for studying regional or global phenomena is highly dependent on having a detailed understanding of the data's internal structure and physical implementation. Gaining this understanding and applying it to data reduction is a time- consuming task that must be undertaken before the core investigation can begin. This is an especially difficult challenge when science objectives require users to deal with large multi-sensor data sets that are usually of different formats, structures, and resolutions, for example, when preparing data for input into modeling systems. The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) has taken a major step towards meeting this challenge by developing an infrastructure with a Web interface that allows users to perform interactive analysis online without downloading any data, the GES-DISC Interactive Online Visualization and Analysis Infrastructure or "Giovanni." Giovanni provides interactive, online, analysis tools for data users to facilitate their research. There have been several instances of this interface created to serve TRMM users, Aerosol scientists, Ocean Color and Agriculture applications users. The first generation of these tools support gridded data only. The user selects geophysical parameters, area of interest, time period; and the system generates an output on screen in a matter of seconds. The currently available output options are: Area plot averaged or accumulated over any available data period for any rectangular area; Time plot time series averaged over any rectangular area; Time plots image view of any longitude-time and latitude-time cross sections; ASCII output for all plot types; Image animation for area plot. In the future, we will add correlation plots, GIS-compatible outputs, etc. This allow user to focus on data content (i.e. science parameters) and eliminate the need for expensive learning, development and processing tasks that are redundantly incurred by an archive's user community. The current implementation utilizes the GrADS-DODS Server (GDS), a stable, secure data server that provides subsetting and analysis services across the Internet for any GrADS-readable dataset. The subsetting capability allows users to retrieve a specified temporal and/or spatial subdomain from a large dataset, eliminating the need to download everything simply to access a small relevant portion of a dataset. The analysis capability allows users to retrieve the results of an operation applied to one or more datasets on the server. In our case, we use this approach to read pre-processed binary files and/or to read and extract the needed parts from HDF or HDF-EOS files. These subsets then serve as inputs into GrADS processing and analysis scripts. It can be used in a wide variety of Earth science applications: climate and weather events study and monitoring; modeling. It can be easily configured for new applications.

Leptoukh, G.↗
NASA NTRSDate not supplied

Wildfire Emission Transport and Its Impact on the Local Air Quality – Case Study Example from the LISTOS Campaign

The high O3 concentration and large aerosol backscatter were measured in New York City(NYC) region and Connecticut (CT) coastline between August 15-16, 2018 during the Long Island Sound Tropospheric Ozone Study (LISTOS) campaign. Two TOLNet ozone lidar systems, NASA Goddard Space Flight Center Tropospheric Ozone Differential Absorption Lidar (GSFC TROPOZ DIAL)and Langley Research Center (LaRC) Mobile Ozone Lidar (LMOL),were used to obtain vertical and temporal variation of local O3 concentration. The airborne High Altitude Lidar Observatory (HALO) system was used to detect the regional aerosol characteristic during this episode. The complex relationship between ozone and aerosol characteristics of wildfire emission layers was investigated. The HYSPLIT back-trajectory of the measured air parcel shows that the increase of the O3 concentration and aerosol backscatter are attributed to the significant wildfires in the Pacific Northwest and British Columbia regions during August 2018. Through correlation analyses, unique clustering relationships are identified between ozone and aerosol for different air mass types. This case study is further investigated in relation to satellite data from MODIS, MISR and CALIPSO to characterize plume behavior during transport. The importance of wildfire emission transport will be discussed in context of its impact to surface air quality at significant distances from fire events.

Liqiao Lei↗
DOE OSTI2024

In-situ digital image correlation and thermal monitoring in directed energy deposition

A method and a system for digital image correlation and thermal monitoring during directed energy deposition are provided. The method and the system include global off-axis 3D mapping of surfaces features at high frame rates using the natural surface roughness of the additive build. Infrared thermography is projected onto these surface features to record the thermo-mechanical history of the finished component. As set forth herein, the method and the system provide a low-cost solution to monitoring and optimizing the unique temporal artifacts induced by complex scan strategies.

Haley, James↗
NASA NTRS1996

Kinematic/Dynamic Characteristics for Visual and Kinesthetic Virtual Environments

Work was carried out on two topics of principal importance to current progress in virtual environment research at NASA Ames and elsewhere. The first topic was directed at maximizing the temporal dynamic response of visually presented Virtual Environments (VEs) through reorganization and optimization of system hardware and software. The final results of this portion of the work was a VE system in the Advanced Display and Spatial Perception Laboratory at NASA Ames capable of updating at 60 Hz (the maximum hardware refresh rate) with latencies approaching 30 msec. In the course of achieving this system performance, specialized hardware and software tools for measurement of VE latency and analytic models correlating update rate and latency for different system configurations were developed. The second area of activity was the preliminary development and analysis of a novel kinematic architecture for three Degree Of Freedom (DOF) haptic interfaces--devices that provide force feedback for manipulative interaction with virtual and remote environments. An invention disclosure was filed on this work and a patent application is being pursued by NASA Ames. Activities in these two areas are expanded upon below.

Bortolussi, Michael R.↗
NASA NTRS1988

Infrared Measurements of Atmospheric Gases Above Mauna Loa, Hawaii, in February 1987

Infrared solar absorption spectra recorded at 0.02/ cm resolution from the National Oceanic and Atmospheric Administration (NOAA) Geophysical Monitoring for Climate Change (GMCC) program station at Mauna Loa, Hawaii (latitude 19.5 deg N, longitude 155.6 deg W, elevation 3.40 km), in February 1997 have been analyzed to determine simultaneous total vertical column amounts for 13 atmospheric gases. Average tropospheric concentrations of CO2, N2O, CH4, and CHCIF2 and the daytime diurnal variations or the total columns of NO and NO2 have also been inferred. The retrieved total columns (in molecules /sq cm) of the nondiurnally varying gases are 1.6 +/- 0.2 x 10(exp 15) for HCl, 5.9 +/- 1.2 x 10(exp 15) for HNO3, 2.0 +/- 0.2 x 10(exp 21) for H2O16, 4.4 +/- 0.7 x 10(exp 18) for H2O18, 2.7 +/- 0.1 x 10(exp 17) for HDO, 2.3 +/- 0.2 x 10(exp 19) for CH4, 5.0 +/- 0.5 x 10(exp 21) for CO2, 6.7 +/- 0.8 x 10(exp 18) for O3, 4.3 +/- 0.4 x 10(exp 18) for N2O, 1.0 +/- 0.2 x 10(exp 16) for C2H6, and 9.7 +/- 2.5 x 10(exp 14) for CHClF2. We compare the total column measurements of HCl and HNO3 with previously reported ground-based, aircraft, and satellite measurements. The results for HCl are or particular interest because of the expected temporal increase in the concentration of this gas in the stratosphere. However, systematic differences among stratospheric HCl total column measurements from 1978 to 1980 and the absence of observations of free tropospheric HCl above Mauna Loa make it impossible to obtain a reliable estimate of the trend in the total burden of HCl. The measured HNO3 total column is consistent with aircraft measurements from approx. 12 km altitude. The O3 total column deduced from the IR spectra agrees with correlative Mauna Loa Umkehr measurements within the estimated error limits. The column-averaged D/H ratio of water vapor is (68 +/- 9) x- 10(exp -6), which is 0.44 +/- 0.06 times the reference value of 155.76 x 10(exp -6) for standard mean ocean water (SMOW). This large depletion in the D content of water vapor is similar to published measurements of the upper troposphere and lower stratosphere. Average tropospheric concentrations deduced for CO2, N2O, and CH4 are in good agreement with correlative NOAA GMCC surface data, indicating consistency between the measurement techniques for determining tropospheric volume mixing ratios. Results of the present study indicate that Mauna Loa is a favorable site for infrared monitoring of atmospheric gases. The site is particularly favorable for monitoring the tropospheric volume mixing ratios of long-lived gases, since the high altitude of the tropopause reduces corrections required to account for the decrease in volume mixing ratio in the stratosphere.

Rinsland, C. P.↗
NASA NTRS2003

An evaluation of the use of new Doppler methods for detecting longitudinal function abnormalities in a pacing-induced heart failure model

BACKGROUND: Doppler tissue echocardiography and color M-mode Doppler flow propagation velocity have proven useful in evaluating cross-sections of patients with left ventricular (LV) dysfunction, but experience with serial changes is limited. Purpose and methods: We tested their use by evaluating the temporal changes of LV function in a pacing-induced congestive heart failure model. Rapid ventricular pacing was initiated and maintained in 20 dogs for 4 weeks. Echocardiography was performed at baseline and weekly during brief pacing cessation. RESULTS: With rapid pacing, LV volume significantly increased and ejection fraction (57%-28%), stroke volume (37-18 mL), and mitral annulus systolic velocity (16.1-6.6 cm/s) by Doppler tissue echocardiography significantly decreased, with ejection fraction and mitral annulus systolic velocity closely correlated (r = 0.706, P <.0001). In contrast to the mitral inflow velocities, mitral annulus early diastolic velocity decreased steadily (12.3-7.3 cm/s) resulting in a dramatic decrease in mitral annulus early/late (1.22-0.57) diastolic velocity with no tendency toward pseudonormalization. The color M-mode Doppler flow propagation velocity also showed significant steady decrease (57-24 cm/s) throughout the pacing period. Multiple regression analysis chose mitral annulus systolic velocity (r = 0.895, P <.0001) and propagation velocity (r = 0.782, P <.0001) for the most important factor predicting LV systolic and diastolic function, respectively. CONCLUSIONS: Doppler tissue echocardiography and color M-mode Doppler flow could evaluate the serial deterioration in LV dysfunction throughout the pacing period. These were more useful in quantifying progressive LV dysfunction than conventional ehocardiographic techniques, and were probably relatively independent of preload. These techniques could be suitable for longitudinal evaluation in addition to the cross-sectional study.

Evaluation Studies↗
NASA NTRS2004

Stereomotion speed perception: contributions from both changing disparity and interocular velocity difference over a range of relative disparities

The role of two binocular cues to motion in depth-changing disparity (CD) and interocular velocity difference (IOVD)- was investigated by measuring stereomotion speed discrimination and static disparity discrimination performance (stereoacuity). Speed discrimination thresholds were assessed both for random dot stereograms (RDS), and for their temporally uncorrelated equivalents, dynamic random dot stereograms (DRDS), at relative disparity pedestals of -19, 0, and +19 arcmin. While RDS stimuli contain both CD and IOVD cues, DRDS stimuli carry only CD information. On average, thresholds were a factor of 1.7 higher for DRDS than for RDS stimuli with no clear effect of relative disparity pedestal. Results were similar for approaching and receding targets. Variations in stimulus duration had no significant effect on thresholds, and there was no observed correlation between stimulus displacement and perceived speed, confirming that subjects responded to stimulus speed in each condition. Stereoacuity was equally good for our RDS and DRDS stimuli, showing that the difference in stereomotion speed discrimination performance for these stimuli was not due to any difference in the precision of the disparity cue. In addition, when we altered stereomotion stimulus trajectory by independently manipulating the speeds and directions of its monocular half-images, perceived stereomotion speed remained accurate. This finding is inconsistent with response strategies based on properties of either monocular half-image motion, or any ad hoc combination of the monocular speeds. We conclude that although subjects are able to discriminate stereomotion speed reliably on the basis of CD information alone, IOVD provides a precise additional cue to stereomotion speed perception.

Depth Perception/physiology↗
NASA NTRS2012

Tropical Atlantic Dust and Smoke Aerosol Variabilities Related to the Madden-Julian Oscillation in MODIS and MISR Observations

In this study, MODIS fine mode fraction and MISR non-spherical fraction are 2used to derive dust and smoke AOT components (tau(sub dust) and tau(sub smoke)) over the tropical Atlantic, and their variabilities related to the Madden-Julian Oscillation (MJO) are then investigated. Both MODIS and MISR show a very similar dust and smoke winter climatology. tau(sub dust) is found to be the dominant aerosol component over the tropical Atlantic while tau(sub smoke) is significantly smaller than tau(sub dust). The daily MODIS and MISR tau(sub dust) are overall highly correlated, with the correlation coefficients typically about 0.7 over the North Atlantic. The consistency between the MODIS and MISR dust and smoke aerosol climatology and daily variations give us confidence to use these two data sets to investigate their relative contributions to the total AOT variation associated with the MJO. However, unlike the MISR dust discrimination, which is based on particle shape retrievals, the smoke discrimination is less certain, based on assumed partitioning of maritime aerosol for both MISR and MODIS. The temporal evolution and spatial patterns of the tau(sub dust) anomalies associated with the MJO are consistent between MODIS and MISR. The tau(sub dust) anomalies are very similar to those of tau anomalies, and are of comparable magnitude. In contrast, the MJO-related tau(sub smoke) anomalies are rather small, and the tau(sub mar) anomalies are negligible. The consistency between the MODIS and MISR results suggests that dust aerosol is the dominant component on the intra-seasonal time scale over the tropical Atlantic Ocean.

Guo, Yanjuan↗
DOE OSTI2021

Assessment of Updraft Modeling Bias Using Computational Fluid Dynamics

Golden Eagle (Aquila chrysaetos) habitats may overlap with wind energy development in some regions of the US. Eagles, and similar soaring bird species, are therefore at risk of collision with wind turbines when flying through wind farms. Recently developed behavioral modeling approaches can predict the presence of eagles near turbines within the rotor-swept layer but require reliable prediction of atmospheric flowfield conditions. In particular, the vertical component of the wind speed dictates a soaring bird's ability to maintain or gain altitude, since they rely on updrafts to subsidize their flight. In this work, we investigate the atmospheric conditions around a wind farm in complex terrain and compare methods for atmospheric characterization. We use computational fluid dynamics (specifically, large-eddy simulations, or LES) to simulate the atmospheric boundary layer over a region encompassing multiple wind farms with high temporal and spatial resolution (seconds and 10's of meters, respectively). We compare traditional non-simulation-based methods of determining the orographic updraft potential based on wind direction, terrain slope and aspect, with the flowfields from LES that include both orographic updrafts alone and combined thermal and orographic updrafts. Preliminary analysis suggests that although the model captures the horizontal pattern of vertical updrafts, their magnitude can be improved with information about the surface heat flux, which is usually correlated with time of the day. Within our study region, we found that the low-fidelity model may over- or underestimate updraft potential by up to 400% at 80 m AGL, depending on local orographic features. This can result in an inaccurate representation of eagle presence and, consequently, risk. Another important finding is that flowfield time-averaging can hide important details about the flight environment, including how thermally generated flow structures within the atmospheric boundary layer (e.g., convective rolls and/or cells) may be important drivers of eagle flight.

atmospheric turbulence↗
NASA NTRS1981

Temporal spectral response of a corn canopy

Techniques developed for the prediction of winter wheat yields from remotely sensed data indicating crop status over the growing season are tested for their applicability to corn. Ground-based spectral measurements in the Landsat Thematic Mapper bands 3 (0.62-0.69 microns), 4 (0.76-0.90 microns) and 5 (1.55-1.75 microns) were performed at one-week intervals throughout the growing season for 24 plots of corn, and analyzed to derive spectral ratios and normalized spectral differences of the IR and shortwave IR bands with the red. The ratios of the near IR and shortwave IR bands are found to provide the highest and most consistent correlations with corn yield and dry matter accumulation, however the value of band 5 could not be tested due to the absence of water stress conditions. Integration of spectral ratios over several dates improved the correlations over those of any single date by achieving a seasonal, rather than instantaneous, estimate of crop status. Results point to the desirability of further tests under other growth conditions to determine whether satellite-derived data will be useful in providing corn yield information.

Markham, B. L.↗
DOE OSTI2020

Observation of Variations in Condensed Carbon Morphology Dependent on Composition B Detonation Conditions

Carbon particulates generated during detonation depend upon high explosive type, composition, and detonation conditions. Although explosive composition greatly affects particulates, the focus of this work is on how detonation geometries that induce much higher temperatures and pressures in the high explosive lead to differing particulate morphologies. In this study, two geometries were used: Detonations were initiated in Composition B cylinders at one end in conventional detonations and initiated at both ends to produce colliding detonations. Each of these detonations was observed on the sub-μs timescale using fast radiography capturing images of the front moving through the cylinder, and colliding detonation fronts in real-time. These imaging experiments were complemented with time-resolved small-angle x-ray scattering (SAXS) experiments that were able to observe and determine the varying condensed carbon morphologies at different locations and times in each detonation. The detonations could be timed in such a way that the spatial and temporal dependence of the carbon morphology could be superimposed onto radiography images collected at the same point in time. The complementary approach is able to show that the carbon condensates are much larger when formed in the elevated temperature and pressure conditions near the location of colliding detonation fronts. Thermochemical modeling suggests that these larger particulates form either in the diamond phase or on the liquidus line of the carbon phase diagram. The increase in size observed by SAXS may correlate well with the increased residence time deeply in the diamond phase. Finally, these particulates can be described as nano-sized phases with some surface texture or otherwise near-surface intra-particle heterogeneity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Decadal forest soil respiration following stem girdling

Soil respiration (Rs) represents the largest flux of carbon (C) from forests to the atmosphere, but the long-term influence of phloem-disrupting disturbance on Rs is poorly understood, limiting robust forecasts of ecosystem C balance. Using a decade of observations from the Forest accelerated succession experiment (FASET), we examined relationships among Rs, soil temperature, soil moisture, and leaf area index (LAI) following the stem girdling-induced mortality of 40% of all canopy trees within a 39-ha area. Mean annual Rs declined by about 20% relative to the control two years after disturbance, but recovered to near pre-disturbance values within five years; this reduction correlated with LAI losses and lower Rs temperature sensitivity (i.e., Q 10 ), with the latter counteracting soil warming caused by partial canopy defoliation. These observations are consistent with progressive reductions in belowground labile C causing reductions in Rs. In conclusion, we conclude that the effects of stem girdling on Rs (1) were not immediate, occurring two years after the treatment, (2) were primarily influenced by biotic rather than soil microclimate changes, and (3) persisted for nearly a decade but were temporally dynamic, underscoring the value of long-term experiments.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Microbial potentiometric sensor: A new approach to longstanding challenges

The underlying hypothesis of this study is that simple potentiometric measurements between sensing electrodes and a shared reference electrode - Microbial Potentiometric Sesnor (MPS) system - can be employed in a long-term, continuous mode of operation to resolve the spatial and temporal changes in environmental systems. To address the hypothesis, (1) a conceptual description of the MPS system and its postulated principle of operation are provided; (2) the MPS system performance is documented under controlled laboratory conditions; and (3) the capabilities of the MPS system are documented under quiescent and dynamic field condition. In a laboratory setting, the variability among different MPS signals was insignificant confirming the postulated high accuracy and reproducibility of the sensor performance. It also demonstrated statistically significant correlations with dissolved oxygen (DO) and oxidation-reduction potential (ORP) sensors, while showing capabilities of operating under anoxic and anaerobic conditions. Regardless of their locations in the model wetland system, three MPS sensors functioned without interruption and cleaning for a period >2 years, and thus demonstrating long-term durability of the MPS technology. In real batch-wastewater treatment facility, the deployed MPS system signals were able to describe the organic carbon trends and correlate with each treatment phase in a cycle. Data reproducibility and reliability exceeded the expectations better describing the carbon treatment levels than the DO and ORP sensors (p < 4.4 × 10 –162 vs phase adjusted p < 3.0 × 10 –58 ). While MPS signals correlate with specific parameters that describe the local process or environments, it is more prudent to employ both the magnitude and pattern of a composite signal like the MPS signal describe the change to reflect any shift in the local environment. Finally, when compared to a baseline pattern, this change in signal magnitude and pattern reveals important information that can be employed to tailor and optimize any condition or process which involves microorganisms.

47 OTHER INSTRUMENTATION↗