Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “surface passivation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,207 records · Page 67

Characterization of the land surface freeze/thaw state with SMAP-Reflectometry (SMAP-R)

The use of the Soil Moisture Active Passive (SMAP) radar in received mode has allowed for a new dataset of Global Navigation Satellite System – Reflectometry (GNSS-R) measurements. GNSS-R techniques have been used for more than two decades and have proven successful perform altimetry studies and to retrieve ocean wind speed and soil moisture, monitor wetland dynamics, estimate snow depth, detect sea ice and determine sea ice types. In this paper, the SMAP-Reflectometry measurements are used to classify freeze/thaw (F/T) state over Alaska, studying the differences in the SNR signal at both V and H polarizations.

Podest, Erika↗

Detection of soil moisture and snow characteristics from Skylab

The author has identified the following significant results. The most significant result is the good response of the passive radiometers, particularly the L-band radiometer, to changing soil moisture conditions near the surface of the earth. Radiometer response was very good for the five complete data sets consisting of three passes across Texas and two passes across Kansas. When data from the five different passes were combined, the correlation between the S194 radiometric temperature and soil moisture content remained high with a value of -0.96. The performance of the S193 passive radiometer was less consistent; however, one data set gave a very high correlation of -0.95. The scatterometer response to soil moisture at incidence angles near 30 deg was not as good as for the radiometers.

Eagleman, J. R.↗

Toward an Integrated Solution to Mitigate the Impact of Volcanic Ash to Aviation

The science community is making a concerted effort to improve the reliability of dispersion models for the forecasting of volcanic ash plumes. Toward this end, it has been observed that the assimilation of diverse, accurate and frequent surface, airborne and satellite observations of the source and distal ash plumes may hold the key. Various international research organizations and operational agencies make these observations using a variety of active and passive remote sensing systems and use them to initialize atmospheric trajectory and dispersion models. These observation systems range from surface LIDAR and ceilometers, to airborne radiometers and nephelometers, to satellite radiometers, multi-spectral imagers, LIDAR and UV-photometers. None of these systems alone is a panacea, however, their synergistic application holds great promise toward solving this complex problem. Additionally, the aeronautical and science communities are working to better understand the quantitative thresholds and tolerances of aviation systems to volcanic ash to better inform scientists of the accuracy requirements for dispersion model forecasts. A number of the most recent and promising efforts in all of these area are discussed in this presentation.

Murray, John J.↗

On-Surface Reactions of Electronically Active Self-Assembled Monolayers for Electrode Work Function Tuning

Self-assembled monolayers (SAMs) help improve the performance of organic electronic devices through interface passivation and enhanced carrier transport. Yet, there is limited information regarding the chemical structure of the SAMs upon functionalization and subsequent thermal treatment. Here, we studied the on-surface reaction of carbazole-derived SAMs on model gold electrodes, focusing on the chemical structure changes induced by thermal treatments. Furthermore, we correlate the microscopic changes with their impact on the electrode’s work function. The carbazole-based SAMs first transform into organometallic complexes. At higher annealing temperatures, SAMs convert to oligomeric complexes. The observed chemical reactions significantly reduce the electrode work function and facilitate electron injection in n-type organic thin-film transistors. Our results highlight the on-surface synthesis of electronically active SAMs as an alternative approach for modifying the work function of electrodes for organic electronics.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Coloring Tetrahedral Semiconductors: Synthesis and Photoluminescence Enhancement of Ternary II-III 2 -VI 4 Colloidal Nanocrystals

Ternary tetrahedral II-III 2 -VI 4 semiconductors, where II is Zn or Cd, III In or Ga, and VI S, Se, or Te, are of interest in UV radiation detectors in medicine and space physics as well as CO 2 photoreduction under visible light. We synthesize colloidal II-III 2 -VI 4 semiconductor nanocrystals from readily available precursors and ascertain their ternary nature by structural and spectroscopic methods, including 77 Se solid-state NMR spectroscopy. The pyramidally shaped nanocrystals range between 2 and 12 nm and exhibit optical gaps of 2–3.9 eV. In the presence of excess anions on the particle surface, treatment with Lewis acidic, Z-type ligands results in better passivation and enhanced photoluminescence. Electronic structure calculations reveal the most stable, lowest energy polymorphs and coloring patterns. This work will pave the way toward more environmentally friendly, ternary semiconductors for optoelectronics and electrocatalysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The 4-8 GHz Microwave Active and Passive Spectrometer (MAPS). Volume 1: Radar section

The performance characteristics of the radar section of the prototype 4-8 GHz Microwave Active and Passive Spectrometer system are reported. Active and passive spectral responses were measured of natural, cultivated, and human-made surfaces over the 4-18 GHz region of frequencies for look angles between zero and 70 degrees and for all possible linear polarization combinations. Soil and plant samples were collected to measure their dielectric properties and moisture content. The FORTRAN program for area calculation is provided.

Ulaby, F. T.↗

The Earth and Ocean Physics Applications Program (EOPAP). Ocean dynamics program

SEASAT-A is a research oriented program consisting of a spacecraft, precision ground tracking systems, and data processing and modelling capabilities that address both scientific and application programs problems in ocean surface dynamics for the EOPAP program. An array of active radar and passive microwave and infrared instruments allows for quantitative measurements of oceanic, atmospheric, and geodetic parameters under stormy wind and wave conditions, as well as over regions lying under a cloud cover.

Apel, J. R.↗

The Shuttle imaging microwave system experiment

The purpose of the Shuttle microwave system experiment (SIMS) is to utilize the capabilities of the Space Shuttle to perform passive microwave measurements of thermal emission from the earth's atmosphere and surface, which can be interpreted in terms of meaningful atmospheric and geophysical parameters. The paper is a status report of an ongoing definition phase study of SIMS. The wavelengths and observable parameters for the SIMS channels are identified. The SIMS instrument is discussed with particular reference to the antenna system. A system consisting of a parabolic torus reflector offset fed by a number of feeds and radiometers on a rotating wheel is determined to be the best antenna configuration for SIMS. A tentative data flow diagram for SIMS is also provided.

Waters, J. W.↗

A comparison between active and passive sensing of soil moisture from vegetated terrains

A comparison between active and passive sensing of soil moisture over vegetated areas is studied via scattering models. In active sensing three contributing terms to radar backscattering can be identified: (1) the ground surface scatter term; (2) the volume scatter term representing scattering from the vegetation layer; and (3) the surface volume scatter term accounting for scattering from both surface and volume. In emission three sources of contribution can also be identified: (1) surface emission; (2) upward volume emission from the vegetation layer; and (3) downward volume emission scattered upward by the ground surface. As ground moisture increases, terms (1) and (3) increase due to increase in permittivity in the active case. However, in passive sensing, term (1) decreases but term (3) increases for the same reason. This self conpensating effect produces a loss in sensitivity to change in ground moisture. Furthermore, emission from vegetation may be larger than that from the ground. Hence, the presence of vegetation layer causes a much greater loss of sensitivity to passive than active sensing of soil moisture.

Fung, A. K.↗

A comparison between active and passive sensing of soil moisture from vegetated terrains

A comparison between active and passive sensing of soil moisture over vegetated areas is studied via scattering models. In active sensing three contributing terms to radar backscattering can be identified: (1) the ground surface scatter term; (2) the volume scatter term representing scattering from the vegetation layer; and (3) the surface volume scatter term accounting for scattering from both surface and volume. In emission three sources of contribution can also be identified: (1) surface emission; (2) upward volume emission from the vegetation layer; and (3) downward volume emission scattered upward by the ground surface. As ground moisture increases, terms (1) and (3) increase due to increase in permittivity in the active case. However, in passive sensing, term (1) decreases but term (3) increases for the same reason. This self compensating effect produces a loss in sensitivity to change in ground moisture. Furthermore, emission from vegetation may be larger than that from the ground. Hence, the presence of vegetation layer causes a much greater loss of sensitivity to passive than active sensing of soil moisture.

Fung, A. K.↗

Passive laminar flow control of crossflow vorticity

A passive laminar flow crossflow vorticity control system includes an aerodynamic or hydrodynamic surface having geometric perturbations. The perturbations include peaks and valleys having a predetermined spacing and aligned approximately in a streamline direction to force the formation of crossflow vortices. This minimizes amplification and growth of the vortices, thus delaying transition to turbulence and reducing overall drag.

Holmes, Bruce J.↗

Advanced two-phase heat transfer systems

Future large spacecraft, such as the Earth Observing System (EOS) platforms, will require a significantly more capable thermal control system than is possible with current 'passive' technology. Temperatures must be controlled much more tightly over a larger surface area. Numerous heat load sources will often be located inside the body of the spacecraft without a good view to space. Power levels and flux densities may be higher than can be accommodated with traditional technology. Integration and ground testing will almost certainly be much more difficult with such larger, more complex spacecraft. For these and similar reasons, the Goddard Space Flight Center (GSFC) has been developing a new, more capable thermal control technology called capillary pumped loops (CPL's). CPL's represent an evolutionary improvement over heat pipes; they can transport much greater quantities of heat over much longer distances and can serve numerous heat load sources. In addition, CPL's can be fabricated into large cold plates that can be held to tight thermal gradients. Development of this technology began in the early 1980's and is now reaching maturity. CPL's have recently been baselined for the EOS-AM platform (1997 launch) and the COMET spacecraft (1992 launch). This presentation describes this new technology and its applications. Most of the viewgraphs are self descriptive. For those that are less clear additional comments are provided.

Swanson, Theodore D.↗

A high power lithium thionyl chloride battery for space applications

A high power, 28 V, 330 A h, active lithium thionyl chloride battery has been developed for use as main and payload power sources on an expendable launch vehicle. Nine prismatic cells, along with the required electrical components and a built-in heater system, are efficiently packaged resulting in significant weight savings over presently used silver-zinc batteries. The high rate capability is achieved by designing the cells with a large electrochemical surface area and impregnating an electrocatalyst, polymeric phthalocyanine, into the carbon cathodes. Passivation effects are reduced with the addition of sulfur dioxide into the thionyl chloride electrolyte solution. The results of conducting a detailed thermal analysis are utilized to establish the heater design parameters and the thermal insulation requirements of the battery. An analysis of cell internal pressure and vent characteristics clearly illustrates the margins of safety under different operating conditions. Performance of fresh cells is discussed using polarization scan and discharge data at different rates and temperatures. Self-discharge rate is estimated based upon test results on cells after storage. Results of testing a complete prototype battery are described.

Shah, Pinakin M.↗

Detection and Monitoring of Stratigraphic Markers and Temperature Trends at the Greenland Ice Sheet Project 2 Using Passive-Microwave Remote-Sensing Data

Satellite passive-microwave sensors provide a sensitive means of studying ice-sheet surface processes that assists ice-core interpretation and can extend local observations across regional scales. Analysis of special sensor microwave/imager (SSM/I) brightness temperature (TB) data supports ice-core research in two specific ways. First, the summer hoar complex layers used to date the Holocene portion of the Greenland Ice Sheet Project 2 ice core can be defined temporally and spatially by SSM/I 37-GHz vertically (V) and horizontally (H) polarized B ratio (V/H) trends. Second, comparison of automatic weather station temperatures to SSM/I 37-GHz V TB data shows that they are an effective proxy temperature record in this region. Also, the TB data can be correlated with proxy temperature trends from stable-isotope-ratio (delta O-18 and delta-D) profiles from snow pits and this allows the assignment of dates to specific snow depths.

Shuman, C. A.↗

Evaluation of Improvements to the TRMM Microwave Rain Algorithm

Improvements made to the Version 5 TRMM passive microwave rain retrieval algorithm (2A-12) are evaluated using independent data. Surface rain rate estimates from the Version 5 TRMM TMI (2A-12), PR (2A-25) and TMI/PR Combined (2B-31) algorithms and ground-based radar estimates for selected coincident subset datasets in 1998 over Melbourne and Kwajalein show varying degrees of agreement. The surface rain rates are then classified into convective and stratiform rain types over ocean, land, and coastal areas for more detailed comparisons to the ground radar measurements. These comparisons lead to a better understanding of the relative performances of the current TRMM rain algorithms. For example, at Melbourne more than 80% of the radar-derived rainfall is classified as convective rain. Convective rain from the TRMM rain algorithms is less than that from ground radar measurements, while TRMM stratiform rain is much greater. Rain area coverage from 2A-12 is also in reasonable agreement with ground radar measurements, with about 25% more over ocean and 25% less over land and coastal areas. Retrieved rain rates from the improved (Version 6) 2A-12 algorithm will be compared to 2A-25, 2B-31, and ground-based radar measurements to evaluate the impact of improvements to 2A-12 in Version 6. An important improvement to the Version 6 2A-12 algorithm is the retrieval of Q1/Q2 (latent heating/drying) profiles in addition to the surface rain rate and hydrometeor profiles. In order to ascertain the credibility of the new products, retrieved Q1/Q2 profiles are compared to independent ground-based estimates. Analyses of dual-Doppler radar data in conjunction with coincident rawinsonde data yield estimates of the vertical distributions of diabatic heating/drying at high horizontal resolution for selected cases over the Kwajalein and LBA field sites. The estimated vertical heating/drying structures appear to be reasonable. Comparisons of Q1/Q2 profiles from Version 6 2A-12 and the ground-based estimates are in progress. Retrieved Q1/Q2 structures will also be compared to MM5 hurricane simulations for selected cases. The results of these intercomparisons will be presented at the conference.

Yang, Song↗

A Compact, Continuous Adiabatic Demagnetization Refrigerator with High Heat Sink Temperature

In the continuous adiabatic demagnetization refrigerator (ADR), the existence of a constant temperature stage attached to the load breaks the link between the requirements of the load (usually a detector array) and the operation of the ADR. This allows the ADR to be cycled much faster, which yields more than an order of magnitude improvement in cooling power density over single-shot ADRs. Recent effort has focused on developing compact, efficient higher temperature stages. An important part of this work has been the development of passive gas-gap heat switches that transition (from conductive to insulating) at temperatures around 1 K and 4 K without the use of an actively heated getter. We have found that by carefully adjusting available surface area and the number of He-3 monolayers, gas-gap switches can be made to operate passively. Passive operation greatly reduces switching time and eliminates an important parasitic heat load. The current four stage ADR provides 6 micro W of cooling at 50 mK (21 micro W at 100 mK) and weighs less than 8 kg. It operates from a 4.2 K heat sink, which can be provided by an unpumped He bath or many commercially available mechanical cryocoolers. Reduction in critical current with temperature in our fourth stage NbTi magnet presently limits the maximum temperature of our system to approx. 5 K. We are developing compact, low-current Nb3Sn magnets that will raise the maximum heat sink temperature to over 10 K.

Shirron, P. J.↗

Development of SMAP Mission Cal/Val Activities

The Soil Moisture Active Passive (SMAP) mission is a NASA directed mission to map global land surface soil moisture and freeze-thaw state. Instrument and mission details are shown. The key SMAP soil moisture product is provided at 10 km resolution with 0.04cubic cm/cubic cm accuracy. The freeze/thaw product is provided at 3 km resolution and 80% frozen-thawed classification accuracy. The full list of SMAP data products is shown.

Colliander, A.↗