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At least 1,207 records · Page 67

Evapotranspiration partitioning estimates from 8 methods from 47 NEON sites, 2019-2021

This dataset provides daily estimates of evapotranspiration (ET) and the transpiration-to-evapotranspiration ratio (T/ET) across 47 terrestrial National Ecological Observatory Network (NEON) sites spanning diverse environmental and biome conditions in the United States across three years of data (2019-2021). Daily ET is reported in both energy units (MJ m⁻² day⁻¹) and equivalent water depth (mm day⁻¹), assuming a constant latent heat of vaporization of 2.45 MJ/kg. The primary method uses a hybrid recurrent neural network–Penman–Monteith framework (RNN-PM), which integrates physically based surface energy balance constraints with data-driven learning to partition ET into transpiration and evaporation components. Model inputs include in situ meteorological observations (air temperature, vapor pressure deficit, wind speed, and radiation) combined with satellite-derived land surface temperature, leaf area index, and soil moisture. For benchmarking and uncertainty assessment, T/ET estimates from seven additional models are included: Priestley-Taylor Jet Propulsion Laboratory (PT-JPL), Penman-Monteith (P-M), Two-Source Energy Balance (TSEB), Support Vector Regression (SVR), and Categorical Boosting (CatBoost), among others—spanning empirical, machine-learning, and process-based approaches (see methods section or linked publication for detailed descriptions). Data Package Contents: The dataset a csv files containing daily ET and T/ET estimates for each site and model, along with associated metadata files these variables. Data can be accessed using common spreadsheet software (e.g., Microsoft Excel, LibreOffice) or programming environments such as R or Python. Together, these data support cross-site comparisons of ecosystem water use, evaluation of ET partitioning methods, and development of improved land–atmosphere exchange models.

EARTH SCIENCE > ATMOSPHERE↗

Influence of Pore Water on the Fracture of Silica Sand at Particle Scale

The fracture of particles has a significant influence on the engineering behavior of granular materials. There are no reported conclusive answers in the literature to explain the influence of pore water on the fracture of sand, gravel, railroad ballast rock, aggregates, rockfill, and so on. Here, in this paper, two novel techniques were adopted to investigate the influence of pore water on the fracture of natural silica sand at the particle scale. The three-dimensional (3D) synchrotron microcomputed tomography (SMT) imaging technique was used to acquire and analyze multiple 3D images of specimens composed of wetted silica sand that were subjected to confined one-dimensional (1D) compression loading up to the fracture stage. A few representative particles were identified and digitally separated from the liquid water and gas phases. The 3D SMT images offer clear experimental evidence of the phase transition of water from liquid to gas within the opening cracks. In addition, a computational fluid dynamics numerical simulation framework for water flow into an opening crack was adopted and the results show that the fast opening of the crack induced cavitation, water phase transition, and water hammer effects. The results of the numerical simulations agree with the confined 1D compression experiments where the onset of the bubbles (gas phase) within the crack is mainly generated during the secondary cavitation stage, and the generated bubble near the crack mouth opening resulted from the primary cavitation, which was directly caused by the crack expansion. The results reported in this paper present a new cavitation phenomenon that occurs during particle fracture, which offers a physics-based explanation of why water-wetted sand fractures at smaller stresses than dry and can pave the way for more in-depth future studies on the fracture of water-wetted sand.

cavitation↗

Multispectral VNIR Observations by the Opportunity Rover Pancam of Multiple Episodes of Aqueous Alteration in Marathon Valley, Endeavour Crater, Mars

Since early 2015, the Mars Exploration Rover Opportunity has been exploring the break in the rim of Endeavour Crater dubbed Marathon Valley by the rover team. Marathon Valley was identified by orbital hyperspectral data from the MRO CRISM as having a relatively strong spectral feature in the 2.3 micrometer region indicative of an Mg or Fe-OH combination overtone absorption band indicative of smectite clay. Earlier in its mission, Opportunity examined the Matijevic Hill region on the more northerly Cape York crater rim segment and found evidence for smectite clays in a stratigraphically lower, pre-impact formed unit dubbed the Matijevic formation. However, the smectite exposures in Marathon Valley appear to be associated with the stratigraphically higher Shoemaker formation impact breccia. Evidence for alteration in this unit in Marathon Valley is provided by Pancam multispectral observations in the 430 to 1010 nm visible/near infrared (VNIR) spectral range. Sinuous troughs ("red zones") contain fragmented cobbles and pebbles displaying higher blue-to-red slopes, moderately higher 535 nm band depths, elevated 754 to 934 nm, and negative 934 to 1009 nm slopes. The lack of an absorption at 864 to 904 nm indicates the lack of crystalline red hematite in these red zones, but likely an enrichment in nanophase ferric oxides. The negative 934 to 1009 nm slope is potentially indicative of the presence of adsorbed or structurally bound water. A scuff in a red zone near the southern wall of Marathon Valley uncovered light-toned soils and a pebble with an 803 to 864 nm absorption resembling that of light-toned Fe-sulfate bearing soils uncovered by the Spirit rover in the Columbia Hills of Gusev crater. APXS chemical measurements indicated enrichments of Mg and S in the scuff soils and the pebble, Joseph Field, with the strongest 803 nm band- consistent with Mg and Fe sulfates. The presence of Fe and Mg sulfates can be interpreted as evidence of a potentially later episode of aqueous alteration with an earlier, neutral to alkaline pH episode forming the Fe/Mg smectites and a later acid pH episode forming the Fe and Mg sulfates.

Farrand, William H.↗

Linking groundwater variability to ecosystem carbon and water use efficiencies across India

Carbon use efficiency (CUE) and water use efficiency (WUE) are important indicators of ecosystem health, reflecting the balance between carbon uptake and allocation, and the relationship between carbon assimilation and water loss. Although India shows large spatiotemporal variation in water table depth (WTD), and increasing groundwater stress, the influence of WTD on ecosystem functioning remains underexplored. This study uses satellite-based, modeled, and in-situ datasets to (1) quantify variations in CUE and WUE under shallow (SWTD) and deep (DWTD) WTD conditions across six homogeneous meteorological regions (HMRs), (2) evaluate temporal roles of gross primary productivity (GPP), net primary productivity (NPP), and evapotranspiration (ET) in driving these efficiencies, and (3) examine temporal responses to WTD shifts. SWTD regions generally showed 12 to 18 % higher GPP, 10 to 15 % higher NPP, and 10 to 20 % higher ET than DWTD zones, especially in semi-arid croplands and forests, leading to 8 to 12 % higher CUE and WUE. However, in humid and heavily irrigated regions such as northeastern and hilly India, CUE was up to 10 % higher in DWTD zones, possibly due to reduced respiration and better soil aeration compared to SWTD areas affected by waterlogging. During the Kharif (wet) season, DWTD croplands in humid zones had higher efficiencies, while in the Rabi (dry) season, SWTD croplands in northern India benefited from irrigation and cooler temperatures. These results highlight strong influence of WTD on carbon and water use processes and support the need for region-specific groundwater strategies.

Carbon use efficiency↗

Projected changes in extreme streamflow and inland flooding in the mid-21st century over Northeastern United States using ensemble WRF-Hydro simulations

Study region: Northeastern United States (NEUS). Study focus: We investigate the potential impacts of climate change on precipitation, streamflow, and inland flooding in the NEUS during the mid-21st century. Dynamically downscaled climate projections from three global climate models for historical (1995-2004) and future (2045-2054) periods under business-as-usual scenarios were used to force the hydrologic model WRF-Hydro at 200-meter resolution and create ensemble hydrologic simulations. Additionally, an extreme value model was developed to project the risks associated with low-frequency hydrologic events. New hydrological insights for the region: Results from four major watersheds indicate a significantly wetter regime in winter months and potential drier conditions during late spring to early summer. Discharges in fall are projected to decrease in the northern watersheds and increase toward the south. Extreme flow and water depths resulting from extreme inland flooding are projected to increase by 5-20% and > 100%, respectively. The extent of the total flooded area is likely to be 20% greater by the mid-century. These increased risks can be attributed to (i) an approximate 25% increase in decadal mean and > 40% increase in decadal extreme precipitation intensity, (ii) up to 30% lower snow availability and 5-25% higher evapotranspiration throughout the year, and (iii) a projected 5% increase in soil moisture in all seasons except summer. Furthermore, rapid snow melting in winter will likely cause an earlier peak flow in the rivers.

54 ENVIRONMENTAL SCIENCES↗

Permafrost Promotes Shallow Groundwater Flow and Warmer Headwater Streams

Abstract The presence of permafrost influences the flow paths of water through Arctic landscapes and thereby has the potential to impact stream discharge and thermal regimes. Observations from 11 headwater streams in Alaska showed that July water temperatures were higher in catchments with more near‐surface permafrost. We apply a fully coupled cryohydrology model to investigate if the impact of permafrost on flow path depth could cause the same pattern in temperatures of groundwater discharging from hillslopes to streams. The model simulates surface energy and water balances, snow, and subsurface water and energy balances for two‐dimensional hillslope model cases with varying permafrost extent. We find that hillslopes with continuous permafrost have more shallow flow paths and twice as high rates of evapotranspiration, compared to hillslopes with no permafrost. For our simulated cases, 6.7% of the horizontal water flux moves through the top organic soil layers when there is continuous permafrost, while only 0.5% moves through organic layers without permafrost. The deeper flow paths in permafrost‐free simulations buffer seasonal temperature extremes, so that summer groundwater discharge temperatures are highest with continuous permafrost. Our results suggest that permafrost thawing alters groundwater flow paths and can lead to decreases in summer stream temperatures and reductions in evapotranspiration in headwater catchments. These changes are of potential importance for stream biotic components of ecosystems, however, the full impact remains unknown.

54 ENVIRONMENTAL SCIENCES↗

NETL Plastic Pipes Project - June 2022 Progress Report

Plastic or composite pipelines have been the bane of the utility locating industry because conduits are neither conductive nor magnetic, which are the properties traditionally used to locate buried utilities. Ground penetrating radar (GPR) is an effective geophysical tool for locating plastic/composite pipeline where the resistive cover allows for adequate penetration of radar energy. However, GPR cannot be used in areas where the soil cover is conductive due to significant clay and/or salt content. This study takes a comprehensive look at near-surface geophysical methods that potentially are useful for locating buried plastic/composite pipelines, either singly or in combination with other geophysical methods. Specifically, this modeling study uses computational numerical methods to forward model the response of GPR, resistivity, seismic, and gravity gradiometry methods to plastic/composite pipelines for various scenarios including: (1) pipe diameters ranging between 2 in. to 12 in.; (2) burial depths ranging between 3 ft to 4 ft; (3) various degrees in contrast in physical properties (i.e., permittivity, elasticity, electrical resistivity, density); and (4) various experimental acquisition choices (e.g., GPR radar frequencies, seismic source frequency, electrode spacing).

47 OTHER INSTRUMENTATION↗

Microwave properties of geological materials: Studies of penetration depth and moisture effects

Summarized are the results of two of a series of controlled experiments performed during the summer of 1970. The first series of experiments to determine penetration depth showed the value of having a modeled response and data reduced in real time for examination in the field. The results suggest a radiometric method for measuring the microwave properties of materials in bulk and are applicable to studies of sea ice and other naturally layered media. The sensitivity of the microwave emission to changes in moisture content has inspired a number of airborne and ground based investigations. Although the effect is dominent under certain conditions, the complicating factors of soil type, roughness, vegetation, etc. seem to govern the conclusions regarding its application at this time.

Blinn, J. C., III↗

Provenance of Apollo 15 deep drill core sediments

Modal analysis and electron probe microanalysis were performed on polished thin sections prepared from Apollo 15 deep drill core soils in an effort to characterize their provenance. The particles were in the 0.25-1.00 mm size range. The particles were classified into mineral fragments, agglutinates, glasses, rock fragments, and breccias. The results show that highland and mare material occur in the core in an approximately 60:40 ratio, with mare component generally increasing from bottom to top in the core. Quartz-normative basalts are nearly twice as abundant as olivine basalts. Nonmare sources include KREEP basalt flow units from some depth in the crust, excavated by cratering events and supplied to the site as 'rays'.

Basu, A.↗

Snowcover influence on backscattering from terrain

The effects of snowcover on the microwave backscattering from terrain in the 8-35 GHz region are examined through the analysis of experimental data and by application of a semiempirical model. The model accounts for surface backscattering contributions by the snow-air and snow-soil interfaces, and for volume backscattering contributions by the snow layer. Through comparisons of backscattering data for different terrain surfaces measured both with and without snowcover, the masking effects of snow are evaluated as a function of snow water equivalent and liquid water content. The results indicate that with dry snowcover it is not possible to discriminate between different types of ground surface (concrete, asphalt, grass, and bare ground) if the snow water equivalent is greater than about 20 cm (or a depth greater than 60 cm for a snow density of 0.3 g/cu cm). For the same density, however, if the snow is wet, a depth of 10 cm is sufficient to mask the underlying surface.

Ulaby, F. T.↗

Controls on Martian Hydrothermal Systems: Application to Valley Network and Magnetic Anomaly Formation

Models of hydrothermal groundwater circulation can quantify limits to the role of hydrothermal activity in Martian crustal processes. We present here the results of numerical simulations of convection in a porous medium due to the presence of a hot intruded magma chamber. The parameter space includes magma chamber depth, volume, aspect ratio, and host rock permeability and porosity. A primary goal of the models is the computation of surface discharge. Discharge increases approximately linearly with chamber volume, decreases weakly with depth (at low geothermal gradients), and is maximized for equant-shaped chambers. Discharge increases linearly with permeability until limited by the energy available from the intrusion. Changes in the average porosity are balanced by changes in flow velocity and therefore have little effect. Water/rock ratios of approximately 0.1, obtained by other workers from models based on the mineralogy of the Shergotty meteorite, imply minimum permeabilities of 10(exp -16) sq m2 during hydrothermal alteration. If substantial vapor volumes are required for soil alteration, the permeability must exceed 10(exp -15) sq m. The principal application of our model is to test the viability of hydrothermal circulation as the primary process responsible for the broad spatial correlation of Martian valley networks with magnetic anomalies. For host rock permeabilities as low as 10(exp -17) sq m and intrusion volumes as low as 50 cu km, the total discharge due to intrusions building that part of the southern highlands crust associated with magnetic anomalies spans a comparable range as the inferred discharge from the overlying valley networks.

Harrison, Keith P.↗

An all-digital associated particle imaging system for the 3D determination of isotopic distributions

Associated particle imaging (API) is a non-destructive nuclear technique for the 3D determination of isotopic distributions. By detecting the alpha particle associated with the emitted neutron in the deuterium–tritium fusion reaction with a position- and time-resolving detector, the direction of the 14.1 MeV neutron and its time of emission can be determined. Employing this method, isotope characteristic gamma rays emitted in inelastic neutron scattering events can be correlated with the neutron interaction location. Here, an API system consisting of a sealed-type neutron generator, gamma detectors, and a position-sensitive alpha detector was designed, constructed, and characterized. The system was tested with common soil elements and shown to be sensitive to 12 C, 16 O, 28 Si, 27 Al, and 56 Fe. New aspects of our approach are the use of a yttrium–aluminum–perovskite scintillator, using a sapphire window instead of a fiber-optic faceplate for light transport to the photomultiplier, and the all-digital data acquisition system. We present a description of the system with simulations and experimental results that show a position resolution on the alpha detector of 1 mm, a depth resolution using a LaBr 3 detector of 6.2 cm, and an angular resolution of 4.5°. Additionally, we present single-element gamma response measurements for the elements mentioned above together with a comparison to Monte Carlo simulations (MCNP6).

47 OTHER INSTRUMENTATION↗

A Tower-based Prototype VHF/UHF Radar for Subsurface Sensing: System Description and Data Inversion Results

Knowledge of subsurface characteristics such as permittivity variations and layering structure could provide a breakthrough in many terrestrial and planetary science disciplines. For Earth science, knowledge of subsurface and subcanopy soil moisture layers can enable the estimation of vertical flow in the soil column linking surface hydrologic processes with that in the subsurface. For planetary science, determining the existence of subsurface water and ice is regarded as one of the most critical information needs for the study of the origins of the solar system. The subsurface in general can be described as several near-parallel layers with rough interfaces. Each homogenous rough layer can be defined by its average thickness, permittivity, and rms interface roughness assuming a known surface spectral distribution. As the number and depth of layers increase, the number of measurements needed to invert for the layer unknowns also increases, and deeper penetration capability would be required. To nondestructively calculate the characteristics of the rough layers, a multifrequency polarimetric radar backscattering approach can be used. One such system is that we have developed for data prototyping of the Microwave Observatory of Subcanopy and Subsurface (MOSS) mission concept. A tower-mounted radar makes backscattering measurements at VHF, UHF, and L-band frequencies. The radar is a pulsed CW system, which uses the same wideband antenna to transmit and receive the signals at all three frequencies. To focus the beam at various incidence angles within the beamwidth of the antenna, the tower is moved vertically and measurements made at each position. The signals are coherently summed to achieve focusing and image formation in the subsurface. This requires an estimate of wave velocity profiles. To solve the inverse scattering problem for subsurface velocity profile simultaneously with radar focusing, we use an iterative technique based on a forward numerical solution of the layered rough surface problem. The layers are each defined in terms of a small number of unknown distributions as given above. An a priori estimate of the solution is first assumed, based on which the forward problem is solved for the backscattered measurements. This is compared with the measured data and using iterative techniques an update to the solution for the unknowns is calculated. The process continues until convergence is achieved. Numerical results will be shown using actual radar data acquired with the MOSS tower radar system in Arizona in Fall 2003, and compared with in-situ measurements.

Moghaddam, Mahta↗

Effective use of ERTS multisensor data in the Great Plains

The author has identified the following significant results. It appears that identification of corn and soybeans as separate classes may not be feasible for the part of the growing season around August 15. It is hoped that at other points in the growing season separation of corn from soybeans will be possible. Visual examination of September 5 imagery indicates that later in the growing season, it is possible. The resolution of the 1:300,000 scale enlargement remained sharp enough to distinguish features important for making soil association maps. The land use pattern (range vs cultivated) was sharp as were the stream bottoms, stream valley sides, and stock ponds. The resolution of the 1:1,000,000 scale enlargement was less sharp on detail but it appears that some features could be quantitatively analyzed. Among these are the hydrologic features present such as stock ponds and the streams. It would appear that the total area of stock pond water on a frame could be measured, and, after ground truth established their average depth, the volume of water stored could be calculated and be monitored.

Myers, V. I.↗

Effects of Horizontal Resolution, Domain Size, Boundary Conditions, and Surface Heterogeneity on Coarse LES of a Convective Boundary Layer

Atmospheric properties in a convective boundary layer vary over a wide range of spatial scales and are commonly studied using large-eddy simulations (LES) in various configurations. We examine how the boundary layer depth and distribution of variability across scales are affected by LES grid spacing, domain size, inhomogeneity of surface properties, and external forcing. Two different setups of the Weather Research and Forecasting (WRF) model are analyzed. A semi-idealized configuration uses a periodic domain, flat surface, prescribed homogeneous surface heat fluxes, and horizontally uniform profiles of large-scale advective tendencies. A nested LES setup employs a larger domain and realistic initial and boundary conditions, including an interactive land surface model with representative topography and vegetation and soil types. Subdomains of identical size are analyzed for all simulations. Characteristic structure sizes are quantified using the variability scales L 50 and L 95 , defined such that features smaller than that contain 50% and 95% of the total variance, respectively. Progressive increase in L 50 from vertical velocity to temperature and moisture structures is systematically reproduced in all simulation configurations. This dependence of L 50 on the considered variable complicates the development of scale-aware parameterizations for models with grid spacing in the “terra incognita”. In simulations using a larger domain with heterogeneous surface properties, the development of internal mesoscale patterns significantly affects variance distributions inside analyzed subdomains. Sizes of boundary layer structures also strongly depend on the LES grid spacing and, in case of heterogeneous surface and topography, on location of the subdomain inside a larger computational domain.

54 ENVIRONMENTAL SCIENCES↗

Near-complete depolymerization of polyesters with nano-dispersed enzymes

Successfully interfacing enzymes and biomachinery with polymers affords on-demand modification and/or programmable degradation during the manufacture, utilization and disposal of plastics, but requires controlled biocatalysis in solid matrices with macromolecular substrates. Embedding enzyme microparticles speeds up polyester degradation, but compromises host properties and unintentionally accelerates the formation of microplastics with partial polymer degradation. Here we show that by nanoscopically dispersing enzymes with deep active sites, semi-crystalline polyesters can be degraded primarily via chain-end-mediated processive depolymerization with programmable latency and material integrity, akin to polyadenylation-induced messenger RNA decay. It is also feasible to achieve processivity with enzymes that have surface-exposed active sites by engineering enzyme-protectant-polymer complexes. Poly(caprolactone) and poly(lactic acid) containing less than 2 weight per cent enzymes are depolymerized in days, with up to 98 per cent polymer-to-small-molecule conversion in standard soil composts and household tap water, completely eliminating current needs to separate and landfill their products in compost facilities. Furthermore, oxidases embedded in polyolefins retain their activities. However, hydrocarbon polymers do not closely associate with enzymes, as their polyester counterparts do, and the reactive radicals that are generated cannot chemically modify the macromolecular host. This study provides molecular guidance towards enzyme-polymer pairing and the selection of enzyme protectants to modulate substrate selectivity and optimize biocatalytic pathways. Furthermore, the results also highlight the need for in-depth research in solid-state enzymology, especially in multi-step enzymatic cascades, to tackle chemically dormant substrates without creating secondary environmental contamination and/or biosafety concerns.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Comets, Asteroids, and the Origin of the Biosphere

During the past few decades, the role of comets in the delivery of water, organics, and prebiotic chemicals to the Biosphere of Earth during the Hadean (4.5-3.8 Ga) period of heavy bombardment has become more widely accepted. However comets are still largely regarded as frigid, pristine bodies of protosolar nebula material that are entirely devoid of liquid water and consequently unsuitable for life in any form. Complex organic compounds have been observed comets and on the water rich asteroid 1998 KY26, which has color and radar reflectivity similar to the carbonaceous meteorites. Near infrared observations have indicated the presence of crystalline water ice and ammonia hydrate on the large Kuiper Belt object (50000) Quaoar with resurfacing that may indicate cryovolcanic outgassing and the Cassini spacecraft has detected water-ice geysers on Saturn s moon Enceladus. Spacecraft observations of the chemical compositions and characteristics of the nuclei of several comets (Halley, Borrelly, Wild 2, and Tempel 1) have now firmly established that comets contain a suite of complex organic chemicals; water is the predominant volatile; and that extremely high temperatures (approx.350-400 K) can be reached on the surface of the very black (albedo-0.03) nuclei when the comets are with 1.5 AU from the Sun. Impact craters and pinnacles observed on comet Wild 2 suggest a thick crust and episodic outbursts and jets observed on the nuclei of several comets are interpreted as indications that localized regimes of liquid water and water vapor can periodically exist beneath the crust of some comets. The Deep Impact observations indicate that the temperature on the nucleus of of comet Tempel 1 at 1.5 AU varied from 330K on the sunlit side to a minimum of 280+/-8 K. It is interesting that even the coldest region of the comet surface was slightly above the ice/liquid water phase transition temperature. These results suggest that pools and films of liquid water can exist in a wide range of temperatures in cavities and voids at different depths just beneath the crust of a comet. The possibility that liquid water may exist over a wide range of temperatures on comets significantly enhances the possibility that these bodies may harbor niches suitable for microbial communities and ecosystems. Such niches would by ideal for the growth of psychrophilic, mesophilic, and possibly even thermophilic chemolithotrophs and photoautotrophs such as the motile filamentous cyanobacteria (e.g., Calothrix, Oscillatoria, Phormidium, and Spirulina) that can grow in geothermal springs and geysers at temperatures ranging from 320K to 345K and in cold polar desert soils. This paper reviews the observational data in support of the hypothesis that liquid water can exist in permafrost-like active regions just beneath the surface of comets when near perihelion and provides additional arguments in support of the hypothesis that comets, carbonaceous meteorites, and asteroids may have played a significant role in the origin and evolution of the Biosphere and in the distribution of microbial life throughout the Solar System.

Hoover, Richard B.↗

Regional variability of dust single scattering albedo due to mineral composition

Nearly all Earth System Models (ESMs) assume globally homogeneous dust aerosols, neglecting regional variations of the imaginary refractive index (IRI) due to varying mineral composition. This has led to a range of single scattering albedo (SSA) and direct radiative forcing (DRF) estimates, as models assign global properties using dust measurements from different regions. We use model and observational data to assess to what extent regionally varying mineral composition affects visible-band SSA and short-wave DRF of dust. We run global simulations with NASA GISS ModelE2.1, using optical properties for minerals based on laboratory-derived empirical relationships between dust IRI at visible wavelengths and the mineral content of iron oxides. When allowing mineral variations instead of homogeneous dust, we find regional differences in dust SSA up to ~0.06 and consequent variations in DRF up to ~6 and ~5 W/m2, at surface and top-of-atmosphere respectively. We compare model SSA with AERONET inversion data (Version 3.0, Level 2), filtered by aerosol size and optical properties to identify pure dust scenes. To investigate possible contamination by biomass burning aerosols, we use the dataset of Schuster et al. (2016, doi:10.5194/acp-16-1565-2016), who separately calculated the contribution of iron oxides and carbonaceous species to AERONET extinction and absorption optical depths. Our results show that: (1) the range of observed SSA (even without carbonaceous species) is larger than that resulting from homogeneous dust; (2) residual amounts of fine mode black and brown carbon may affect AERONET SSA even in seasons with limited biomass burning; (3) model SSA from our mineral scheme exceeds the AERONET range, possibly due also to an uncertain treatment of goethite. In summary, homogeneous dust cannot explain the variability of observed SSA, so regionally varying optical properties based on mineral content are necessary. Higher accuracy in soil mineralogy maps is needed to better reproduce SSA variations at regional scales. Also, distinct soil maps for hematite and goethite are required, given the high sensitivity of model SSA to their extreme optical properties.

V. Obiso↗