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At least 1,207 records · Page 67

Lower Snake River Dams Contribution to Grid Services

Hydroelectric generation and water storage have long been components of the clean energy mix, providing both reliable steady output and operational flexibility. As variable renewable energy sources such as wind and solar increasingly replace traditional generation, the role of all flexible resources—including hydropower—in balancing supply and demand continues to evolve. This study examined the contribution of the Lower Snake River (LSR) Dam plants to Bonneville Power Administration grid services in maintaining power system reliability within the Western Interconnection. By analyzing publicly available data, the study evaluated various reliability services through performance metrics including energy capacity, balancing and ramping, voltage and reactive power support, frequency response, and transmission impact. Results indicated that the LSR plants deliver services as expected based on their size, contributing to the balancing process, ramping capabilities, and operational reserves, particularly during peak load conditions and weather events, while also providing measurable frequency and voltage support to the grid.

13 HYDRO ENERGY↗

USAF solar thermal applications case studies

The potential of solar energy technologies to meet mission related applications for process heat was investigated. The reduction of the dependence of military installations on fossil fuels by promoting the use of more abundant resources where liquid hydrocarbons and natural gas are now used is examined. The evaluation and utilization of renewable energy systems to provide process heat and space heating are emphasized. The application of thermal energy systems is divided into four steps: (1) investigation of the potential operational cost effectiveness of selected thermal technologies; (2) selection of a site and preliminary design of point focussing solar thermal plant; (3) construction and test of an engineering prototype; and (4) installation and operation of a solar thermal energy plant.

Source record↗

In-situ Raman Instrumentation and Measurements in Supercritical Water Oxidation Systems

Due to the advent of recent advances in reactor designs and operational procedures, renewed attention has been given to a host of supercritical water oxidation (SCWO) technology applications. This includes resource recovery, water reclamation, and solid waste destruction. SCWO is often recognized as a “green technology” because of its ability to extract useful energy while producing benign products from environmentally challenging waste streams (e.g., wet organic wastes, pharmaceutical wastes, military wastes). The present work was motivated by NASA’s interests in solid waste management and water recovery for long-duration space missions. To that end, the main focus of this paper is to present work on characterizing the behavior of supercritical water oxidation systems utilizing state of the art laser Raman spectroscopy. The main benefit of Raman diagnostics is its ability to identify chemical composition and to measure concentrations of the compounds involved in the reaction. Two separate Raman systems for SCWO measurements that have been developed for this study will be described. The first system is a 2-D traversing system useful for making in-situ measurements in conditions where spatial gradients of species and temperature are important and has been successfully utilized in making species (ethanol, oxygen, water, nitrogen and carbon dioxide) concentrations and temperature measurements in ethanol hydrothermal jet flames. The second system is a packaged modular Raman probe unit for portable deployment to different reactors and is more suitable for relatively homogeneous systems such as a batch reactor. The design, development, and examples of obtained results from both systems will be presented for various reactant streams. Reaction rate and fuel conversion estimates from chemistry models will also be presented.

supercritical water oxidation↗

Análisis de Tareas del Inspector de Control de Calidad [Quality Control Inspector Job Task Analysis (Spanish Translation)]

El Laboratorio Nacional de Energía Renovable (NREL) ha sido contratado por el Programa de Asistencia para la Climatización (WAP) del Departamento de Energía de EE.UU. (DOE) para desarrollar y mantener los recursos en el marco del proyecto de Directrices para Profesionales de la Energía Doméstica (GHEP). El objetivo del proyecto GHEP es aumentar la calidad del trabajo realizado para la remodelación energética residencial en Estados Unidos a través de WAP y otros programas de remodelación residencial. Para cumplir el objetivo de “Establecer certificaciones nacionales de la mano de obra y normas de formación”, el DOE encargó al NREL el desarrollo de recursos GHEP, incluido un conjunto de certificaciones avanzadas, basadas en aptitud, para el personal de los profesionales de la energía doméstica (HEP). Desde 2010, el NREL ha reclutado voluntarios expertos en la materia de WAP y de la industria del mantenimiento del hogar para que formen parte de comités que desarrollen y actualicen programas de certificación y sus análisis de tareas (JTA) necesarios como base de programas de certificación y formación estandarizados. Las certificaciones HEP apoyan al WAP y al sector del mantenimiento de viviendas residenciales en general mediante el proceso de acreditación y el desarrollo de JTA definidos para auditores energéticos (EA) e inspectores de control de calidad (QCI). Este informe es un resumen de las actualizaciones más recientes (2022) del JTA del QCI. [The National Renewable Energy Laboratory (NREL) is contracted by the U.S. Department of Energy (DOE) Weatherization Assistance Program (WAP) to develop and maintain the resources under the Guidelines for Home Energy Professionals (GHEP) project. The purpose of the GHEP project is to increase the quality of work conducted for residential energy retrofits in the United States through the WAP network and other residential retrofit programs. This is the Spanish translation of NREL/TP-7A40-85789.]

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Análisis de Tareas del Auditor Energético [Energy Auditor Job Task Analysis (Spanish Translation)]

El Laboratorio Nacional de Energía Renovable (NREL), bajo el contrato con el Programa de Asistencia para la Climatización (WAP) del Departamento de Energía de EE.UU. (DOE), desarrolla y mantiene los recursos en el marco del proyecto Directrices para Profesionales de la Energía Doméstica (GHEP). El objetivo del proyecto GHEP es aumentar la calidad del trabajo de remodelación energética residencial realizado por WAP y otros programas de remodelación residencial en Estados Unidos. Para cumplir el objetivo de “Establecer certificaciones nacionales de la mano de obra y normas de formación”, el DOE encargó al NREL el desarrollo de recursos GHEP, incluido un conjunto de certificaciones avanzadas, basadas en aptitud, para el personal de los profesionales de la energía doméstica (HEP). Desde 2010, el NREL ha reclutado voluntarios expertos en la materia de WAP y de la industria del mantenimiento del hogar para que formen parte de comités que desarrollen y actualicen programas de certificación y sus análisis de tareas (JTA) necesarios como base de programas de certificación y formación estandarizados. Las certificaciones HEP apoyan al WAP y al sector del mantenimiento de viviendas residenciales en general mediante el proceso de acreditación y el desarrollo de JTA definidos para auditores energéticos (EA) e inspectores de control de calidad (QCI). Este informe es un resumen de las actualizaciones más recientes (2022) del JTA del EA. [The National Renewable Energy Laboratory (NREL) is contracted by the U.S. Department of Energy (DOE) Weatherization Assistance Program (WAP) to develop and maintain the resources under the Guidelines for Home Energy Professionals (GHEP) project. The purpose of the GHEP project is to increase the quality of work conducted for residential energy retrofits in the United States through the WAP network and other residential retrofit programs. This is the Spanish translation of NREL/TP-7A40-85300.]

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Hawai‘i Play Fairway (Final Report)

Most of Hawai'i's geothermal resources are blind—their manifestations, such as hot springs and steam vents, do not appear on the ground surface because the heated water flows far below. With the exception of $K\bar{i}lauea East Rift Zone$, in most areas of Hawai'i, high lateral permeability in the first kilometer below ground surface prevents surface thermal features from developing. As a methodology for discovering these blind resources, Play Fairway Analysis (PFA) involves finding potential locations of blind hydrothermal systems and describing potential geothermal sources in rift-zone settings. Using the PFA to find Hawai'i's geothermal resources, the University of Hawai'i (UH) conducted the Hawai‘i Play Fairway Project, Hawai'i's first statewide geothermal resource assessment since 1985. Sponsored by the U.S. Department of Energy, the Hawai'i Play Fairway Project provided an updated resource assessment, a roadmap for additional exploration activities, and the identification of areas for further exploration. Benefitting from UH's core competency in earth sciences and experienced geothermal researchers, the project comprised three phases. During the first phase, the team identified, compiled, and ranked existing geologic, groundwater, and geophysical datasets relevant to subsurface heat, fluid and permeability. Using a Bayesian statistical approach, the team developed a statistical methodology to integrate these data into a resource probability map. The team evaluated the confidence in the probability value and considered development viability of areas with geothermal resources. With these analyses, the team identified 10 locations in the Hawaiian Islands for exploration activities. For the second phase, the team collected new groundwater data in 10 locations across the state and new geophysical data on $L\bar{a}na‘i, Maui$, and central Hawai'i Island and modeled topographically induced stress to better characterize subsurface permeability. Analyzing the subsurface stresses, the team evaluated the potential for fracture-induced permeability. The team inverted the MT and gravity data to produce 3D models of resistivity and density, respectively, on $L\bar{a}na‘i$, across $Haleakal\bar{a}'s$ SW rift (Maui), and surrounding Mauna Kea (Hawai‘i Island). The team developed and applied a new method for incorporating depth information about resistivity, density, and potential for fracture-induced permeability into the statistical method for computing resource probability in these three focus areas. The team incorporated the new groundwater results with the new geophysical results and the calculations of potential for fracture-induced permeability to produce updated maps of resource probability and confidence. Through combining data from the first and second phases, the team determined locations for further exploration during the third phase. For MT and gravity surveys, the team recommended $Kaua'i's$ $L\bar{i}hu'e$ $Basin$, the east rift of $Maui's$ $Haleakal\bar{a}$ volcano, and the southwest rift of Hawai'i Island's Mauna Loa volcano. The MT and gravity surveys aimed to enable improved confidence in the resource potential in these locations. For drilling deep groundwater well(s), the team recommended Southeast Mauna Kea and $L\bar{a}na's$ $P\bar{a}l\bar{a}wai$ $Basin$. During the third phase, further exploration involved drilling a groundwater well in $L\bar{a}na's$ $P\bar{a}l\bar{a}wai$ $Basin$ and performing more geophysical surveys. We deepened an existing water well proximal to our target area on $L\bar{a}na'i$ due to funding constraints that precluded us from spudding a new well that would exceed 1km depth. Drilling was preceded by a number of substantial elements including: writing an Environmental Assessment and the subsequent legal process, performance of deviation logging, lowering a camera down the well, coordinating site preparation with $P\bar{u}lama$ $L\bar{a}na'i$, shipping the UH-owned rig interisland, procuring supplies, and leading 3 community meetings on $L\bar{a}na'i$. Drilling occurred 24/7 the entire month of June 2019 over which time $L\bar{a}na'i$ $Well$ 10 was deepened from 427 m to 1057 m, with continuous core collected. We measured a roughly linear temperature gradient averaging 42°C/km and a maximum bottom hole temperature of 66°C. This gradient is more than twice the background for Hawai'i and within a range of gradients measured in this depth range for some exploration wells within KERZ. We consider these results encouraging for $L\bar{a}na'i's$ resource potential and recommend following with a slim hole within $L\bar{a}na'i's$ caldera (our target zone) to ~ 2 km. Further, the positive implications such results have for the island of O‘ahu are substantial - the shield stage of O'ahu's volcanoes ended 1-2 My earlier. However, O'ahu uses more electricity than the rest of the islands combined, and the utility recently called for 500-700MW of firm, dispatchable renewable electricity on O'ahu by 2033. In Phase 3, we also collected limited new encouraging groundwater data, and updated our thoughts on the probabilities of fluid and permeability at resource depths (Pr F = 1; Pr P = mostly unconstrained). Ultimately, we advocate for using our final probability of heat, and confidence in this probability, to drive the next phase of exploration. We contend further development of geothermal in Hawai‘i will enable the state to achieve its 100% renewable policy objective and Hawai'i to transition off of fossil fuels through geothermal discovery and development. The project not only produced a large amount of data and expanded the existing knowledge of Hawai'i's geothermal resources, but also produced publications, theses, presentations, core photos, datasets, media reports, television interviews, community events, and a blog. Students and new professionals benefitted from the project's hands-on research experiences and educational opportunities and earned awards and recognition.

15 GEOTHERMAL ENERGY↗

Grid Value Propositions for Tidal Generation Resources - a Temporal Analysis

As the energy sector experiences a paradigm shift towards cleaner and greener generation sources, the need for evaluating the applicability of marine energy for grid-based applications has intensified. This is because marine energy (ocean, wave and tidal) may be utilized to provide unique benefits to electric grid operations, especially in conjunction with other established renewable technologies (such as wind and solar) or technologies like energy storage. In this work, we focus our attention on some specific characteristics of two types of marine energy resources i.e. tidal and ocean current based resources. Specifically, we perform a comprehensive temporal analysis using a suite of metrics on resource data to characterize the inherent predictability of the resource across various time scales of interest. We also investigate the correlation of tidal power generation profiles with energy demand and comment on the effectiveness of having such resources in the overall generation portfolio.

Bhattacharya, Saptarshi↗

Estimating the impacts of natural gas power generation growth on solar electricity development: PJM's evolving resource mix and ramping capability

Abstract Expansion of distributed solar photovoltaic (PV) and natural gas‐fired generation capacity in the United States has put a renewed spotlight on methods and tools for power system planning and grid modernization. This article investigates the impact of increasing natural gas‐fired electricity generation assets on installed distributed solar PV systems in the Pennsylvania–New Jersey–Maryland (PJM) Interconnection in the United States over the period 2008–2018. We developed an empirical dynamic panel data model using the system‐generalized method of moments (system‐GMM) estimation approach. The model accounts for the impact of past and current technical, market and policy changes over time, forecasting errors, and business cycles by controlling for PJM jurisdictions‐level effects and year fixed effects. Using an instrumental variable to control for endogeneity, we concluded that natural gas does not crowd out renewables like solar PV in the PJM capacity market; however, we also found considerable heterogeneity. Such heterogeneity was displayed in the relationship between solar PV systems and electricity prices. More interestingly, we found no evidence suggesting any relationship between distributed solar PV development and nuclear, coal, hydro, or electricity consumption. In addition, considering policy effects of state renewable portfolio standards, net energy metering, differences in the PJM market structure, and other demand and cost‐related factors proved important in assessing their impacts on solar PV generation capacity, including energy storage as a non‐wire alternative policy technique. This article is categorized under: Photovoltaics > Economics and Policy Fossil Fuels > Climate and Environment Energy Systems Economics > Economics and Policy

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Bipolar Membranes Electrodialysis for Water Purification and Resource Recovery

Reverse osmosis concentrate (ROC) from inland brackish water desalination and wastewater recycling presents moderate salinity, posing significant challenges for treatment and disposal. Existing treatment technologies predominantly rely on energy-intensive thermal methods, large-area evaporation strategies, or deep-well disposal, which often result in the loss of water value. Electrified membrane brine treatment offers a promising alternative by utilizing renewable energy sources, enabling complete water recycling. This work proposes the development of next-generation bipolar membrane electrodialysis (BMED) systems capable of desalinating brine while simultaneously recovering valuable resources. However, several critical challenges remain in the areas of membrane engineering for BMED. These include: 1) decreased current efficiency during desalination due to the low conductivity of feed chambers, 2) fouling and scaling from multivalent ions and contaminants in the feed, and 3) the retention and carryover of ROC contaminants, including PFAS compounds. Our research focuses on the development of novel anion exchange membranes (AEMs) and cation exchange membranes (CEMs) based on synthesized multiblock copolymers. We investigate the effects of block length, ion exchange capacity (IEC), and polymer backbone structure on cation and anion transport (e.g., Na+, Cl-, OH-, H+) for both our synthesized membranes and commercial membranes. Fundamental properties of these membranes, such as water uptake, IEC, and ionic conductivity, are also evaluated to optimize performance for BMED applications.

08 HYDROGEN↗

GMLC Technical Assistance to States

This presentation provides an overview of the U.S. Department of Energy's Grid Modernization Laboratory Consortium (GMLC) efforts to provide customized technical support specific to state public utility commissions (PUCs), specifically on the integration of distributed energy resources (DERs). The goals are to increase awareness of existing materials and support to help state PUCs move forward on DER interconnection activities, to help participants make connections to colleagues with similar challenges (and solutions), and to help the GMLC/National Renewable Energy Laboratory project team understand context and implementation challenges.

DER↗

Transactive Campus Energy Systems: An R&D Testbed for Renewables, Integration, Efficiency, and Grid Services (CRADA 356 / Amendment 1)

The Clean Energy and Transactive Campus (CETC) work described in this report was done as part of Amendment 1 to Campus Cooperative Research and Development Agreement (CRADA) 356, the Transactive Campus CRADA with the Washington State Department of Commerce (Commerce) between the U.S. Department of Energy’s (DOE’s), Pacific Northwest National Laboratory (PNNL) and the Commerce through the Clean Energy Fund (CEF). The original project team consisted of PNNL, the University of Washington (UW) and Washington State University (WSU), to connect the PNNL, UW, and WSU campuses to construct and operate the testbed as both a regional flexibility resource and as a platform for research and development (R&D) for buildings/grid integration. Building on the foundational transactive system established by the Pacific Northwest Smart Grid Demonstration (PNWSGD), the purpose of the project was to construct the testbed as both a regional flexibility resource and as a platform for R&D on buildings/grid integration and information-based energy efficiency. The testbed supports the integration of renewables and other regional needs, using the flexibility provided by building loads, energy storage, and smart inverters for batteries and photovoltaic (PV) solar systems, at four physical scales: multiple campuses, campus, microgrid and building.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Integration of DER Adoption Forecasting into Distribution Planning: Cooperative Research and Development Final Report, CRADA Number CRD-11-00430 (Project H)

The objective of this project is to improve distributed energy resources (DER) technology, time, and locational impact analysis by incorporating customer adoption intentions and preferences into distribution planning and operations. The National Renewable Energy Laboratory (NREL) shall collaborate with EPRI staff to contribute to the development of methodology, literature review, analysis, and write-up for two sections of a report "Identification and Overview of Methods for Mapping DER Adoption Forecasts” and “Comparative Analysis of Methods for Mapping DER Adoption Forecasts."

14 SOLAR ENERGY↗

Real Time - Optimal Power Flow Based Distributed Energy Resources Management System (DERMS) (CRADA Number CRD-20-16909 Final Report)

The integration of behind-the-meter distributed energy resources (DERs) into distribution systems brings transformative changes to power systems. This requires operators and planners to find solutions to modernize electric grids and to effectively manage DERs for grid services. NREL developed novel DER management algorithms (referred to as Real-Time Optimal Power Flow, RT-OPF) through U.S. Department of Energy (DOE)-funded efforts, including Advanced Research Projects Agency–Energy (ARPA-E) Network Optimized Distributed Energy Systems (NODES) funding. This cutting-edge control technology aims to modernize distribution systems with large amounts of DER integration, which will help utilities solve issues brought by renewable integration and build resilient and renewable-based electric grids nationwide. Utilidata worked with NREL to investigate the commercialization opportunity of this RT-OPF-based distributed energy resource management system (DERMS). In this project, NREL performs the technology transfer of the RT-OPF to Utilidata to help them fully understand the RT-OPF solution, to identify potential engineering hurdles, and to assess the expected commercial value of various RT-OPF use cases and deployment. The technology transfer work includes two major tasks. First, NREL performs an in-depth knowledge transfer of the entire RT-OPF solution to Utilidata to help them gain an extensive and detailed understanding of the complete RT-OPF solution. In this task, NREL provides exhaustive information (e.g., documentation, code packages, laboratory and field trial data, performance results) while conducting in-depth training sessions to provide a thorough explanation of the entire solution. NREL hosts meetings to present different topics related to the RT-OPF solution, and question-and-answer sessions are included in each meeting to better explain the RT-OPF-related work. Second, the RT-OPF simulations are performed in a laboratory environment. The main objectives of this task are to walk through with Utilidata engineers how to set up a simulation of RT-OPF, identifying each RT-OPF code block/component in operation, learning how these components interact with each other, and eventually running RT-OPF simulations under various system conditions. This task helps Utilidata engineers understand performance limitations and constraints while also quantifying the commercial value of the RT-OPF for different use cases. Based on these two tasks, Utilidata engineers should be able to define and prioritize the next steps of RT-OPF implementation with an eye toward commercial success and scalability of the solution. The next steps are expected to be part of a new project following the conclusion of this project.

24 POWER TRANSMISSION AND DISTRIBUTION↗

A comparison study on trading behavior and profit distribution in local energy transaction games

With the increasing integration of distributed energy resources, localized peer-to-peer energy transactions are receiving more attention since they could absorb more distributed renewables locally and stabilize the power grid. To better study the trading behavior and provide guidance for a viable local market design, different game-theoretical frameworks including cooperative and non-cooperative games are established and compared here. For the cooperative grand coalition, the maximum social welfare is guaranteed, the Shapley value and bargaining based approaches are implemented for further profit redistribution. It is shown that the asymmetrical bargaining power can be critical in the final payment clearing and it is equivalent to the Shapley value allocation if prosumers bargain based on their marginal contributions. Non-cooperative trading is formulated by using a Stackelberg bilevel model in which the upper level has the privilege in internal price setting. However, system optimum is not obtained due to competition, and the selfish leader could take away 89% of the collective benefit by price-gap based arbitraging. Aiming for a long-lasting trading market, a virtual benevolent leader and a uniform price structure in which purchase price equals selling price are tested. Experimental results indicate that maximum social welfare and a fairer profit allocation can be achieved with a uniform price structure, regardless of the selfish or benevolent attitude.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Electrocatalytic Hydrogenation of Biomass-Derived Organics: A review

Sustainable energy generation calls for a shift away from centralized, high-temperature, energy-intensive processes to decentralized, low-temperature conversions that can be powered by electricity produced from renewable sources. Electrocatalytic conversion of biomass-derived feedstocks would allow carbon recycling of distributed, energy-poor resources in the absence of sinks and sources of high-grade heat. Selective, efficient electrocatalysts that operate at low temperatures are needed for electrocatalytic hydrogenation (ECH) to upgrade the feedstocks. For effective generation of energy-dense chemicals and fuels, two design criteria must be met: (i) a high H:C ratio via ECH to allow for high-quality fuels and blends, and (ii) a lower O:C ratio in the target molecules via electrochemical decarboxylation/deoxygenation to improve the stability of fuels and chemicals. The goal of this review is to determine whether the following questions have been sufficiently answered in open literature, and if not, what additional information is required: (1) What organic functionalities are accessible for electrocatalytic hydrogenation under a set of reaction conditions? How do substitutions and functionalities impact the activity and selectivity of ECH? (2) What material properties cause an electrocatalyst to be active for ECH? Can general trends in ECH be formulated based on the type of electrocatalyst? (3) What is the impact of reaction (electrolyte concentration, pH, operating potential) and reactor type conditions?

Catalysts, redox reactions, hydrocarbons, Aromatic↗

Global peak water limit of future groundwater withdrawals

Over the past 50 years, humans have extracted the Earth’s groundwater stocks at a steep rate, largely to fuel global agro-economic development. Given society’s growing reliance on groundwater, we explore ‘peak water limits’ to investigate whether, when and where humanity might reach peak groundwater extraction. Using an integrated global model of the coupled human–Earth system, we simulate groundwater withdrawals across 235 water basins under 900 future scenarios of global change over the twenty-first century. Here we find that global non-renewable groundwater withdrawals exhibit a distinct peak-and-decline signature, comparable to historical observations of other depletable resources (for example, minerals), in nearly all (98%) scenarios, peaking on average at 625 km 3 yr -1 around mid-century, followed by a decline through 2100. The peak and decline occur in about one-third (82) of basins, including 21 that may have already peaked, exposing about half (44%) of the global population to groundwater stress. Most of these basins are in countries with the highest current extraction rates, including the United States, Mexico, Pakistan, India, China, Saudi Arabia and Iran. Furthermore, these groundwater-dependent basins will probably face increasing costs of groundwater and food production, suggesting important implications for global agricultural trade and a diminished role for groundwater in meeting global water demands during the twenty-first century.

58 GEOSCIENCES↗

A portable fiber optic sensor for the luminescent sensing of cobalt ions using carbon dots

Cobalt is critical to energy-relevant technologies, and demand for cobalt will increase significantly with growing global adoption of renewables. However, supply chain stability is threatened by economic and geopolitical factors, incentivizing domestic cobalt production from alternative resources such as coal, coal utilization byproducts (e.g., ash, acid mine drainage) and electronic waste. Rapid, inexpensive, and portable characterization techniques are needed to reduce production costs associated with cobalt prospecting and process monitoring. Here, in this research, we develop a compact, portable fiber optic luminescent probe for cobalt using phosphorus and nitrogen co-doped carbon dots as the sensing material. The carbon dot emission overlaps well with the cobalt absorption band at ~510 nm, leading to a selective decrease in emission as a function of cobalt concentration. The system responds nearly instantly to the presence of cobalt, with detection limits of 0.7 and 3.5 ppm in water and pH 1.68 buffer, respectively, providing comparable performance to a commercial spectrometer at a significantly lower cost. Moreover, the sensor is selective for cobalt in the presence of 13 of the most common metal ions encountered in coal utilization byproducts and is responsive to cobalt when spiked into an acid mine drainage leachate sample, highlighting the sensor's potential for real-world deployment in challenging matrices. In addition, integrating the carbon dots with a filter paper substrate produced ‘test strip’ sensors that exhibited a selective and sensitive visual response to cobalt using a handheld UV lamp. Taken together, the sensing system represents a significant step forward in the development of low-cost practical sensors for high-value metals in complex streams.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗