Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “plasma processing”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,207 records · Page 67

Magnetic Reconnection in Solar Flares [Slides]

Magnetic reconnection is the underlying mechanism in solar flares. Magnetic reconnection is an astrophysical process in an electrically conducting plasma where neighboring magnetic field lines running anti-parallel break and reconnection therefore exchanging the direction of their paths. The result of this process is the magnetic field energy converting to kinetic and thermal energy which is explosively released. The scale of a solar is extremely large compared to Earth so kinetic simulations are unable to portray an accurate model. In this project, we are using an astrophysical magnetohydrodynamic (MHD) simulation code known as Athena++ with the reconnection problem generator file created by Li et al. 2018. To further study this simulation, we began testing a heating/cooling term. The results of the original file will be compared with the modified file with an implemented heating/cooling term to better understand how solar flares function.

79 ASTRONOMY AND ASTROPHYSICS↗

Imaging Thermal He(+) from the Lunar Surface

Extreme ultraviolet observations of He(+) ions by the EUV instrument on the IMAGE spacecraft have dramatically improved our ability to observe plasmasphere dynamics in the inner magnetosphere. These primarily high latitude observations have revealed the phenomenology of thermal density structures and continue to lead us toward a more complete understanding of inner magnetospheric electric fields and plasmaspheric refilling. Recent analyses have brought attention to the disposition of thermal plasma eroded from the plasmasphere and convected into the outer dayside magnetosphere. The extent to which this plasma is lost into the solar wind or recirculated across the polar cap or through the magnetospheric flanks is an important outstanding question that relates to the influence this plasma has on space weather processes in Geospace. A concept for implementation of enhanced EUV observations from the lunar surface to resolve questions about the global circulation of He(+) plasma in the magnetosphere will be presented. The instrument and science package subsystem elements, including anticipated component capabilities and limitations will be discussed. Attention will also be given to the potential impact of dust contamination.

Gallagher, D. L.↗

Densification of non-radioactive porous siliceous particles loaded with cesium potassium copper hexacyanoferrate by spark plasma sintering

In the development of a conditioning process for cesium-bearing sorbents from the decontamination of aqueous waste streams, the treatment of a granular material composed of (Cs,K) 2 CuFe(CN) 6 loaded onto mesoporous silica particles has been investigated in an additive-free two-step conditioning process involving (i) calcination at 1000 °C to remove volatile species and (ii) densification by spark plasma sintering. A 92.0 % dense pellet was obtained after 10 min sintering at 850 °C under 100 MPa. Density and microstructural measurements indicate that densification is first driven by the viscous flow of a vitreous phase containing Cs, formed during calcination. Additionally, the density of the sample then increases further during sintering by grain boundary diffusion. However, a limited but non negligible part of cesium is lost during densification.

36 MATERIALS SCIENCE↗

Research on solar-wind and magnetospheric electric fields and plasmas

Attempts were made to determine the role of the interplanetary magnetic field in controlling: (1) particle acceleration processes in the earth's polar cap; (2) plasma convection patterns at high latitudes; and, (3) the topology of magnetic field lines in the earth's polar cusps. The primary result of the study on polar-cap particle acceleration regions was that they tend to occur in only one polar cap at a time, and that they occur in the hemisphere for which the magnetospheric tail-lobe field lines have solar-magnetospheric x components that are antiparallel to those of the interplanetary and tail-lobe magnetic field. Southward-directed interplanetary magnetic fields give rise to broad convection throats which cover several hours of local time across the dayside cleft. Under such conditions, solar-wind plasma is channeled efficiently through the polar cusps to populate the plasma mantle and dayside boundary layer. On the other hand, the appearance of strong northward components in the interplanetary magnetic field result in a very constricted throat, resulting in inefficient plasma entry at the cusps by diffusion processes.

Burch, J. L.↗

Three-dimensional calculation of shuttle charging in polar orbit

The charged particles environment in polar orbit can be of sufficient intensity to cause spacecraft charging. In order to gain a quantitative understanding of such effects, the Air Force is developing POLAR, a computer code which simulates in three dimensions the electrical interaction of large space vehicles with the polar ionospheric plasma. It models the physical processes of wake generation, ambient ion collection, precipitating auroral electron fluxes, and surface interactions, including secondary electron generation and backscattering, which lead to vehicle charging. These processes may be followed dynamically on a subsecond timescale so that the rapid passage through intense auroral arcs can be simulated. POLAR models the ambient plasma as isotropic Maxwellian electrons and ions (0+, H+), and allows for simultaneous precipitation of power-law, energetic Maxwellian, and accelerated Gaussian distributions of electrons. Magnetic field effects will be modeled in POLAR but are currently ignored.

Cooke, D. L.↗

Etching of Si 3 N 4 induced by electron beam plasma from hollow cathode plasma in a downstream reactive environment

An etching system based on the interaction of electrons extracted from a direct current (DC) hollow-cathode (HC) Ar plasma and injected towards a Si3N4 covered silicon substrate located in the downstream reactive environment created by an additional remote CF 4 /O 2 plasma source was developed and evaluated. By controlling the properties of the injected beam electrons, this approach allows to deliver energy to a surface functionalized by exposure to reactive species, and initiate surface etching. The energy of the primary beam electrons is controlled by the acceleration voltage relative to the HC discharge. Ar atoms flow from the high-pressure HC discharge into the low pressure downstream reactive environment in the process chamber. For an acceleration voltage greater than the ionization potential of Ar and/or process gas species, the energetic primary beam electrons produce a secondary plasma in the process chamber, and can also cause additional dissociation. We have characterized the properties of the secondary plasma and also surface etching of Si 3 N 4 as a function of process parameters, including acceleration voltage (0-80 V), discharge current of the HC discharge (1-2 A), pressure (3.5-20 mTorr), source to substrate distance (1.5 to 5 cm), and feed gas composition (20% and 80% O2 in CF 4 /O 2 ). The electron energy probability function (EEPF) measured with a Langmuir probe about 2.5 cm below the extraction ring suggests several major groups of electrons for this situation, including high energy primary beam electrons with an energy that varies as the acceleration voltage is changed and low energy electrons produced by beam electron-induced ionization of the Ar gas in the process chamber. When a remote CF 4 /O 2 plasma is additionally coupled to the process chamber, Si 3 N 4 surfaces can be functionalized, and by varying the energy of the beam electrons, Si 3 N 4 etching can be induced by electron-neutral synergy effect with plasma-surface interaction. For conditions without beam electron injection, the remote plasma etching rate (ER) of Si 3 N 4 depends strongly on the O 2 concentration in the CF 4 /O 2 processing gas mixture and can be suppressed for O 2 -rich process conditions by the formation of a SiONF passivation layer on the Si 3 N 4 surface. The combination of the HC electron beam source with the remote plasma source (HCEB-RP) makes it possible to induce Si 3 N 4 etching for O 2 -rich remote plasma conditions where remote plasma by itself produces negligible Si 3 N 4 etching. The electron enhanced etching of Si 3 N 4 depends strongly on O 2 /CF 4 mixing ratio reflecting changing arrival rates of O and F species at the surface. Optical emission spectroscopy was used to estimate the ratio of gas phase F and O densities and found to be controlled by the gas mixing ratio and independent of HC EB operating conditions. At this time the detailed sequence of events operative in the etching mechanism is unclear. While the increase of the electron energy is ultimately responsible for initiating surface etching, at present we cannot rule out a role of ions from the simultaneously produced secondary plasma in plasma surface interaction mechanisms.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Plasma Abatement of Volatile Organic Compounds

One difficulty with crewed space operations is the potential for the contamination of the spacecraft habitable volume from volatile organic compounds (VOCs) that may be present. One possible VOC abatement process is to apply a plasma to the contaminated gases. Plasmas provide high energy electrons and ions that are capable of breaking down gaseous organic species generally into smaller compounds. To explore plasma VOC abatement, the authors constructed a plasma gas system that recirculates a particular VOC-laden gas mixture through a plasma torch. This allows for the periodic collection of aliquots of gaseous samples for subsequent analyses via gas chromatography mass spectrometry, designed to quantify the remaining VOC materials. The VOCs evaluated included 100 ppm of acetone, benzene, ethanol, and pentane in a background of carbon dioxide. The plasma conversion of all analytes followed first-order rate kinetics, and VOC elimination was observed after 10 min or less of treatment for all analytes measured. Additionally, it was observed that the plasma caused the conversion of CO 2 into oxygen and CO.

Joel A. Olson↗

Identification of the weak-to-strong transition in Alfvénic turbulence from space plasma

Abstract Plasma turbulence is a ubiquitous dynamical process that transfers energy across many spatial and temporal scales in astrophysical and space plasma systems. Although the theory of anisotropic magnetohydrodynamic (MHD) turbulence has successfully described natural phenomena, its core prediction of an Alfvénic transition from weak to strong MHD turbulence when energy cascades from large to small scales has not been observationally confirmed. Here we report evidence for the Alfvénic weak-to-strong transition in small-amplitude, turbulent MHD fluctuations in Earth’s magnetosheath using data from four Cluster spacecraft. Our observations demonstrate the universal existence of strong turbulence accompanied by weak turbulent fluctuations on large scales. Moreover, we find that the nonlinear interactions of MHD turbulence are crucial to the energy cascade, as they broaden the cascade directions and fluctuating frequencies. The observed connection between weak and strong MHD turbulence systems may be present in many astrophysical environments, such as star formation, energetic particle transport, turbulent dynamos, and solar corona or solar wind heating.

79 ASTRONOMY AND ASTROPHYSICS↗

Identification of the weak-to-strong transition in Alfvénic turbulence from space plasma

Plasma turbulence is a ubiquitous dynamical process that transfers energy across many spatial and temporal scales in astrophysical and space plasma systems. Although the theory of anisotropic magnetohydrodynamic (MHD) turbulence has successfully described natural phenomena, its core prediction of an Alfvénic transition from weak to strong MHD turbulence when energy cascades from large to small scales has not been observationally confirmed. Here we report evidence for the Alfvénic weak-to-strong transition in small-amplitude, turbulent MHD fluctuations in Earth’s magnetosheath using data from four Cluster spacecraft. Our observations demonstrate the universal existence of strong turbulence accompanied by weak turbulent fluctuations on large scales. Moreover, we find that the nonlinear interactions of MHD turbulence are crucial to the energy cascade, as they broaden the cascade directions and fluctuating frequencies. The observed connection between weak and strong MHD turbulence systems may be present in many astrophysical environments, such as star formation, energetic particle transport, turbulent dynamos, and solar corona or solar wind heating.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ion-beam-induced topography and surface diffusion

It is pointed out that the development of surface topography along with enhanced surface and bulk diffusion processes accompanying ion bombardment have generated growing interest among users of ion beams and plasmas for thin film or material processing. Interest in these processes stems both from attempts to generate topographic changes for specific studies or applications and from the need to suppress or control undesirable changes. The present investigation provides a summary of the current status of impurity-induced texturing, with emphasis on recent developments. Particular attention is given to the texturing accompanying deposition of an impurity material onto a solid surface while simultaneously etching the surface with an ion beam. A description of experimental considerations is provided, and a thermal-diffusion model is discussed along with the development of sputter cones, and aspects of impact-enhanced surface diffusion.

Robinson, R. S.↗

Stimulated plasma instability and nonlinear phenomena in the ionosphere

Several hundred topside ionograms were used to study simulated wave-particle interactions in the ionosphere. The study combined the benefits of high-frequency-resolution Alouette 2 analog sounder data with advanced digital graphics techniques. The study shows that the sounder phase can cause significant plasma heating when the plasma parameter is confined to specific ranges. The observations support the Harris instability generation process and the nonlinear Landau damping maintaining process for long-duration diffuse resonances. The observations also suggest that the so-called Q resonances have characteristics which imply that generation processes in a sounder-stimulated plasma turbulence may be involved.

Benson, R. F.↗

Fusion Propulsion Z-Pinch Engine Concept

Fusion-based nuclear propulsion has the potential to enable fast interplanetary transportation. Due to the great distances between the planets of our solar system and the harmful radiation environment of interplanetary space, high specific impulse (Isp) propulsion in vehicles with high payload mass fractions must be developed to provide practical and safe vehicles for human spaceflight missions. The Z-Pinch dense plasma focus method is a Magneto-Inertial Fusion (MIF) approach that may potentially lead to a small, low cost fusion reactor/engine assembly1. Recent advancements in experimental and theoretical understanding of this concept suggest favorable scaling of fusion power output yield 2. The magnetic field resulting from the large current compresses the plasma to fusion conditions, and this process can be pulsed over short timescales (10(exp -6 sec). This type of plasma formation is widely used in the field of Nuclear Weapons Effects testing in the defense industry, as well as in fusion energy research. A Decade Module 2 (DM2), approx.500 KJ pulsed-power is coming to the RSA Aerophysics Lab managed by UAHuntsville in January, 2012. A Z-Pinch propulsion concept was designed for a vehicle based on a previous fusion vehicle study called "Human Outer Planet Exploration" (HOPE), which used Magnetized Target Fusion (MTF) 3 propulsion. The reference mission is the transport of crew and cargo to Mars and back, with a reusable vehicle.

Miernik, J.↗

Magnetic Shielding of the Acceleration Channel Walls in a Long-Life Hall Thruster

In a Qualification Life Test (QLT) of the BPT-4000 Hall thruster that recently accumulated greater than 10,000 h it was found that the erosion of the acceleration channel practically stopped after approximately 5,600 h. Numerical simulations of this thruster using a 2-D axisymmetric, magnetic field-aligned-mesh (MFAM) plasma solver reveal that the process that led to this significant reduction of the erosion was multifaceted. It is found that when the channel receded from its early-in-life geometry to its steady-state configuration several changes in the near-wall plasma and sheath were induced by the magnetic field that, collectively, constituted an effective shielding of the walls from any significant ion bombardment. Because all such changes in the behavior of the ionized gas near the eroding surfaces were caused by the topology of the magnetic field there, we term this process "magnetic shielding."

life modeling↗

Integrated modelling: Coupling of surface evolution and plasma-impurity transport

During the interaction of the scrape off layer (SOL) plasma with the first wall the evolution of both wall and plasma are tightly coupled: The erosion of the first wall leads to an impurity concentration in the plasma which affects the particle and power balance in the plasma. In turn the impurities, when leaving the plasma via transport, can form deposits and mixed materials, far away from their initial source location. These deposits can be eroded, allowing the impurities to stepwise migrate through the fusion device until they end up at a location where the plasma at the wall is cold enough and no further erosion occurs. To describe these processes an integrated model of surface evolution and plasma transport of impurities is needed. The WallDYN code achieves this required coupling of processes by parameterising the output of surface evolution- and plasma impurity-migration-codes by analytical models. For a given fixed background plasma it evolves the surface composition, derives impurity flux into and from the plasma and can from this derive the impurity densities in the plasma. This paper will show the importance of including this recycling of impurities at the wall in impurity migration modelling: The 13 CH 4 seeding experiment performed in the Wendelstein 7-X Stellerator is modelled using the recent extension of the WallDYN code to 3D plasma and wall geometries. A comparison with post mortem analysis of the 13 C deposition shows both qualitative and quantitative agreement with the WallDYN calculations.

36 MATERIALS SCIENCE↗

Particle simulation of plasmas on the massively parallel processor

Particle simulations, in which collective phenomena in plasmas are studied by following the self consistent motions of many discrete particles, involve several highly repetitive sets of calculations that are readily adaptable to SIMD parallel processing. A fully electromagnetic, relativistic plasma simulation for the massively parallel processor is described. The particle motions are followed in 2 1/2 dimensions on a 128 x 128 grid, with periodic boundary conditions. The two dimensional simulation space is mapped directly onto the processor network; a Fast Fourier Transform is used to solve the field equations. Particle data are stored according to an Eulerian scheme, i.e., the information associated with each particle is moved from one local memory to another as the particle moves across the spatial grid. The method is applied to the study of the nonlinear development of the whistler instability in a magnetospheric plasma model, with an anisotropic electron temperature. The wave distribution function is included as a new diagnostic to allow simulation results to be compared with satellite observations.

Gledhill, I. M. A.↗

Dehydrogenation vs Apparent Hydrogenation: Unraveling the Mechanisms of He and O 2 Plasma Etching on Colloidal Nanocrystal Films

Removing organic ligands from colloidal nanoparticles is critical for fabricating solid-state devices, yet accurately quantifying this removal remains a significant analytical challenge. Here, we establish a robust and accessible method for this quantification by calibrating Raman spectroscopy against precise ion beam analysis (IBA) for nanoparticle assemblies (CNAs) processed by helium (He) and oxygen (O 2 ) plasmas. We demonstrate that the calibration curves are remarkably independent of plasma power and pressure, depending critically only on the choice of feed gas. He plasma induces rapid dehydrogenation and cross-linking, evidenced by a much faster decrease in the C–H Raman signal relative to the actual carbon loss. Conversely, O 2 plasma leads to a surprising “apparent hydrogenation”, where the carbon backbone is removed significantly faster than the C–H signal diminishes. This counterintuitive effect is explained by a serial mechanism of oxidative fragmentation; β-scission cleaves the alkyl chains, and subsequent stabilization steps enrich the remaining film with hydrogen-rich methyl-terminated fragments, while carbon is efficiently removed as volatile CO. This work provides calibrated functions that enable the rapid determination of absolute carbon content in processed CNAs using simple Raman spectroscopy with uncertainties of ∼8% for O 2 and ∼12% for He plasma, offering a vital tool for both process diagnostics and fundamental studies of plasma–matter interactions in colloidal nanocrystal films.

Animal feed↗

Plasma Assisted Catalytic Conversion of Carbon Dioxide (CO2) and Propane to Propylene and Carbon Monoxide (CO)

Presented at the NETL Project Review Meetings (virtual) in 2021, the presentation summary includes the following status updates: -Initiated synthesis, characterization and testing of various supported metal catalysts -Some catalysts show greater than 90% propylene selectivity -Plasma testing shows greater than 80% propane conversion without a catalyst -Feasibility of the CO2-ODH reaction with plasma demonstrated at much lower temperatures than conventional processes -Presence of CO2 enhances propane conversion in the plasma reactor

Zhou, S. James↗

Preparation Of Sources For Plasma Vapor Deposition

Multicomponent metal targets serving as sources of vapor for plasma vapor deposition made in modified pressureless-sintering process. By use of targets made in modified process, one coats components with materials previously plasma-sprayed or sintered but not plasma-vapor-deposited.

Waters, William J.↗