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At least 1,207 records · Page 67

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DOE OSTI2020

A lithium-sulfur battery with a solution-mediated pathway operating under lean electrolyte conditions

Lithium-sulfur (Li-S) battery is one of the most promising candidates for the next generation energy storage systems. However, several barriers, including polysulfide shuttle effect, the slow solid-solid surface reaction pathway in the lower discharge plateau, and corrosion of Li anode still limit its practical applications, especially under the lean electrolyte condition required for high energy density applications. Here, we propose a solution-mediated sulfur reduction pathway to improve the capacity and reversibility of the sulfur cathode and suppress dendrite growth on the Li metal anode simultaneously. With this method, a high coulombic efficiency (99%) and stable cycle life over 100 cycles were achieved under application-relevant conditions (S loading: 6.2 mg cm-2; electrolyte to sulfur ratio: 3 mLE gs-1; sulfur weigh ratio: 72 wt%). This result is enabled by a specially designed Li2S4-rich electrolyte, in which Li2S is formed through a chemical disproportionation reaction instead of electrochemical routes. A diglyme solvent was used to obtain electrolytes with the optimum range of Li2S4 concentration. Operando X-ray absorption spectroscopy confirms the solution pathway in a practical Li-S cell. This solution pathway not only introduces a new electrolyte regime for practical Li-S batteries, but also provides a new perspective for bypassing the inefficient surface pathway for other electrochemical processes.

Wang, Hui↗

NASA NTRS2012

Sensitivity of Mission Energy Consumption to Turboelectric Distributed Propulsion Design Assumptions on the N3-X Hybrid Wing Body Aircraft

In a previous study by the authors it was shown that the N3-X, a 300 passenger hybrid wing body (HWB) aircraft with a turboelectric distributed propulsion (TeDP) system, was able to meet the NASA Subsonic Fixed Wing (SFW) project goal for N+3 generation aircraft of at least a 60% reduction in total energy consumption as compared to the best in class current generation aircraft. This previous study combined technology assumptions that represented the highest anticipated values that could be matured to technology readiness level (TRL) 4-6 by 2030. This paper presents the results of a sensitivity analysis of the total mission energy consumption to reductions in each key technology assumption. Of the parameters examined, the mission total energy consumption was most sensitive to changes to total pressure loss in the propulsor inlet. The baseline inlet internal pressure loss is assumed to be an optimistic 0.5%. An inlet pressure loss of 3% increases the total energy consumption 9%. However changes to reduce inlet pressure loss can result in additional distortion to the fan which can reduce fan efficiency or vice versa. It is very important that the inlet and fan be analyzed and optimized as a single unit. The turboshaft hot section is assumed to be made of ceramic matrix composite (CMC) with a 3000 F maximum material temperature. Reducing the maximum material temperature to 2700 F increases the mission energy consumption by only 1.5%. Thus achieving a 3000 F temperature in CMCs is important but not central to achieving the energy consumption objective of the N3-X/TeDP. A key parameter in the efficiency of superconducting motors and generators is the size of the superconducting filaments in the stator. The size of the superconducting filaments in the baseline model is assumed to be 10 microns. A 40 micron filament, which represents current technology, results in a 200% increase in AC losses in the motor and generator stators. This analysis shows that for a system with 40 micron filaments the higher stator losses plus the added weight and power of larger cryocoolers results in a 4% increase in mission energy consumption. If liquid hydrogen is used to cool the superconductors the 40 micron fibers results in a 200% increase in hydrogen required for cooling. Each pound of hydrogen used as fuel displaces 3 pounds of jet fuel. For the N3-X on the reference mission the additional hydrogen due to the increase stator losses reduces the total fuel weight 10%. The lighter fuel load and attendant vehicle resizing reduces the total energy consumption more than the higher stator losses increase it. As a result with hydrogen cooling there is a slight reduction in mission energy consumption with increasing stator losses. This counter intuitive result highlights the need to consider the full system impact of changes rather than just at the component or subsystem level.

Felder, James L.↗

NASA NTRS1974

Comparison of experimental and predicted performance of 150-millimeter-bore solid and drilled ball bearings to 3 million DN

Seven 150-millimeter-bore ball bearings were run under 8900-newton (2000-lbf) thrust load at speeds from 6670 to 20,000 rpm (1 million to 3 million DN). Four of the bearings had conventional solid balls, and three bearings had drilled (cylindrically hollow) balls with 50-percent mass reduction. The bearings were under-race cooled and slot lubricated with a type 2 ester oil at flow rates from 4.35 x 0.001 to 5.94 x 0.001 cubic meter/min (1.15 to 1.57 gal/min). Friction torque and temperature were measured on all bearings. While there was considerable spread in the temperature data, the drilled ball bearings tended to run slightly cooler than the solid ball bearings at higher speeds. No significant difference in torque was noted, however, between the solid and drilled ball bearings. One bearing of each type was rerun at 17,800-newton (4000-lbf) thrust load. The solid ball bearings performed satisfactorily at 3 million DN. However, at about 2 million DN the drilled ball bearing experienced a broken ball, and cracks appeared in other balls as a result of flexure fatigue. Metallurgical examination of the cracked balls indicated a brittle structure in the bore of the drilled balls.

Scibbe, H. W.↗

DOE OSTI2022

Studies of CO2 hydrogenation over cobalt/ceria catalysts with in situ characterization: the effect of cobalt loading and metal-support interactions on the catalytic activity

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99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2024

Rapid detection of rare events from in situ X-ray diffraction data using machine learning

High-energy X-ray diffraction methods can non-destructively map the 3D microstructure and associated attributes of metallic polycrystalline engineering materials in their bulk form. These methods are often combined with external stimuli such as thermo-mechanical loading to take snapshots of the evolving microstructure and attributes over time. However, the extreme data volumes and the high costs of traditional data acquisition and reduction approaches pose a barrier to quickly extracting actionable insights and improving the temporal resolution of these snapshots. This article presents a fully automated technique capable of rapidly detecting the onset of plasticity in high-energy X-ray microscopy data. The technique is computationally faster by at least 50 times than the traditional approaches and works for data sets that are up to nine times sparser than a full data set. This new technique leverages self-supervised image representation learning and clustering to transform massive data sets into compact, semantic-rich representations of visually salient characteristics ( e.g. peak shapes). These characteristics can rapidly indicate anomalous events, such as changes in diffraction peak shapes. It is anticipated that this technique will provide just-in-time actionable information to drive smarter experiments that effectively deploy multi-modal X-ray diffraction methods spanning many decades of length scales.

Zheng, Weijian↗

DOE OSTI2023

Conservation Voltage Reduction with Distributed Energy Resource Management System, Grid-Edge, and Legacy Devices

Distribution utilities use conservation voltage reduction (CVR) to obtain energy savings and lower peak demand by reducing bus voltages. Traditionally, the CVR is accomplished by controlling the legacy assets such as load tap changers, voltage regulators, and capacitor banks. The deployment of the advanced distribution management system (ADMS) and distributed energy resource management system (DERMS) enables the integration of distributed energy resources into the distribution networks and provide the grid services including CVR. This paper studies the coordinated operation of an ADMS and a DERMS in achieving CVR and voltage regulation. A commercial ADMS uses legacy devices and Edge-of-Network Grid Optimization (ENGO) devices to obtain energy savings through CVR. A prototype DERMS dispatches the photovoltaic smart inverters based on real-time optimal power low to ensure voltage regulation across the feeder. The results show that the coordinated operation of ADMS and DERMS is effective in achieving CVR and voltage regulation. Specifically, energy savings of up to 4.7% are observed in the real utility distribution system used in this study.

advanced distribution management system↗

DOE OSTI2020

Meso-Structured Polymer Electrolyte Fuel Cell Electrode

Increasing the utilization of Pt and Pt alloy catalysts in polymer electrolyte fuel cell cathodes is critical to improving the high power density operation, particularly at low Pt loadings. State of the art electrodes are fabricated in an ink deposition process that leads to uncontrolled electrode architecture with random aggregates of functional domains (catalyst, ionomer, and pore volume) (1). The randomness in the domains induces high tortuosity transport pathways for ions and fluids, which cause severe transport resistance during high current density operation. Thin ionomer films cause additional transport resistance and poisoning of the Pt catalyst, which becomes more significant at low Pt loadings. Reducing the amount of ionomer in the catalyst domain without affecting the ionic transport resistance is key to improving the utilization of the Pt and reducing the transport resistance at low Pt loading. Rational design of the electrode structure with controlled low tortuous ionic transport pathways could improve performance. The introduction of the ionomer pathways could also enable reduction of the ionomer volume in the catalyst domain, reducing the transport resistance. Middelmen et al. proposed electrode structures consisting of aligned components in a low tortuosity configuration to improve performance (2). In this work, we present an alternative electrode structure based on a vertically aligned array of Nafion pillars in the cathode catalyst layer, as shown in Figure 1a. Figure 1b shows the SEM image of the Nafion pillars. Furthermore, Pt supported on carbon catalyst was deposited on the Nafion pillars to fabricate a meso-structured electrode. Nafion pillars provide high conductive and low tortuous pathways for protons, reducing the effective transport distance, and enabling reduction of the ionomer binder in the catalyst domain.

25 ENERGY STORAGE↗

DOE OSTI2023

Faster-than-real-time Simulation with Demonstration for Resilient DER Integration

The US electric grid is facing operational, stability, and security challenges. Transmission system operators need some measure of visibility into distribution system renewable generation. Distribution system generation needs to support transmission system voltage. The grid is experiencing an expansion in measurement systems. How to take full advantage of this expansion and defend against attacks, both cyber and physical, poses additional challenges. The Faster-than-real-time Simulation with demonstration for Resilient DER Integration project set out to do the following: a. Flatten the voltage profile through the feeders and system for cost saving and voltage stabilization needs. b. Increase the amount of intermittent distributed energy resources (IDERs) that could be deployed on a utility feeder and provide 100% or more energy needed for the demands on that feeder, and c. based on an accurate model (Digital Twin) of the utilities system, be able to detect any abnormalities on the utilities distribution system. To manage the voltage and increase IDER penetration (a,b), Graph Trace Analysis is employed in a time-series, optimal power flow to coordinate the time-varying feedback control setpoints of a distribution feeder’s utility control devices. Under the coordinated control are a Load Tap Changing Transformer, a voltage regulator, and five switched capacitor banks. The feeder serves over 2000 customers, the feeder secondaries are modeled, and the feeder has 2.3 MW of PV generation, corresponding to a 17.4% penetration of PV generation. The feeder model has over 12,000 components, where every customer load bus and PV generator are modeled. The accuracy of the power flow solution is compared against historical meter voltage measurements, the improvement in conservation voltage reduction energy savings as a function of the coordinated control desired voltage profile is investigated, and the increase in PV penetration of the coordinated control over the existing control is presented. To achieve improved control performance while observing system operation constraints, bellwether Advanced Metering Infrastructure (AMI) voltage measurements are used to adjust the desired voltage profile used by the optimal power flow analysis. To detect and alleviate or negate attacks or failures on the distribution and transmission utility grids (c) the grid needs to be resilient and self-healing. In this project software was designed to do just that. At the center of the software is an Integrated System Model (ISM) that spans from transmission to secondary distribution. The ISM is employed in real-time abnormality detection, voltage stability forecasting, and multi-mode control. Testing results are presented for: 1—attacks on utility infrastructure; 2—energy savings from optimal control; 3—distribution system control response during a low voltage transmission system event; 4—cyber-attacks on PV inverters, where physical inverters are used in hard-ware-in-the-simulation-loop studies. Contributions of this work include real-time analysis that spans from three-phase transmission through secondary distribution; an approach for detecting abnormalities that employs measurements from three independent measurement systems; and a multi-mode distribution system control that responds to cyber-attacks, physical attacks, equipment failures, and transmission system needs.

Integrated System Model, Graph Trace Analysis, Adv↗

DOE OSTI2025

FY25 Theory and Simulation Performance Target: Development of an integrated modeling framework for fusion reactor design and assessment (Final Report)

This report documents the FY25 Theory and Simulation Performance Target (TSPT) of developing an integrated modeling framework for fusion reactor design and assessment (FREDA). Over Q1-Q4, new capabilities were developed across both plasma and engineering domains and demonstrated on an example representation of a Compact Advanced Tokamak with a Dual Cooled Lead Lithium blanket. This represents a first-of-a-kind demonstration of coupled core-to-wall-to-engineering for a reactor. Self-consistent CESOL workflows were applied to provide core, pedestal, and SOL prediction; new modules were developed for energetic particle stability (FAR3D) and transport (TGLF-EP) analysis; and boundary plasma modeling (SOLPS-ITER, BOUT++/Hermes-3) was expanded to evaluate wall and divertor heat fluxes and interface with engineering thermal analysis. A parameterized CAD tool, TRACER, was expanded to generate medium-fidelity divertor, blanket, and coil geometries; OpenFOAM and Diablo workflows were applied for first-wall and divertor thermal analyses with helium cooling; and reduced-order models were created for high-mass-flux divertor cooling. Magnet multiphysics capabilities were verified between Elmer, Diablo, and a new MFEM-based solver, and workflows enable stress, thermal, and neutron-fluence analysis of TF coils with neutronics-driven heating. Nuclear and blanket analysis workflows were demonstrated, including tritium breeding, transport, and CFD-informed thermo-mechanical assessment. Preliminary multi-fidelity uncertainty quantification workflows were applied to boundary modeling codes and shown to achieve variance reductions with fewer high-fidelity boundary simulations. Key findings highlight the challenges of resolving the ITEP gap to find suitable balance between wall and divertor loads, neutron heating, and practical limits of PFC cooling. Next step priorities are to develop automated workflows to check boundary code convergence and detachment, implement tighter physics-engineering CAD provenance tracking, and inclusion of plasma-material interface models for SLAG and tungsten cracking behavior. Collectively, these developments establish sophisticated capabilities for predictive, multi-fidelity, whole-device modeling that integrates plasma physics, materials, magnets, and nuclear engineering to guide pathways to viable Fusion Pilot Plant design points.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

NASA NTRS1979

An analysis of thermal stress and gas bending effects on vibrations of compressor rotor stages

A preliminary study conducted by Kerrebrock et al. (1976) has shown that the torsional rigidity of untwisted thin blades of a transonic compressor can be reduced significantly by transient thermal stresses. The aerodynamic loads have various effects on blade vibration. One effect is that gas bending loads may result in a bending-torsion coupling which may change the characteristics of the torsion and bending vibration of the blade. For a general study of transient-temperature distribution within a rotor stage, a finite-element heat-conduction analysis was developed. The blade and shroud are divided into annular elements. With a temperature distribution obtained from the heat-conduction analysis and a prescribed gas bending load distribution along the blade span, the static deformation and moment distributions of the blade can be solved iteratively using the finite-element method. The reduction of the torsional rigidity of pretwisted blades caused by the thermal stress effect is then computed. The dynamic behavior of the blade is studied by a modified Galerkin's method.

Chen, L.-T.↗

NASA NTRS1985

Development and testing of tip devices for horizontal axis wind turbines

A theoretical and field experimental program has been carried out to investigate the use of tip devices on horizontal axis wind turbine rotors. The objective was to improve performance by the reduction of tip losses. While power output can always be increased by a simple radial tip extension, such a modification also results in an increased gale load both because of the extra projected area and longer moment arm. Tip devices have the potential to increase power output without such a structural penalty. A vortex lattice computer model was used to optimize three basic tip configuration types for a 25 kW stall limited commercial wind turbine. The types were a change in tip planform, and a single-element and double-element nonplanar tip extension (winglets). A complete data acquisition system was developed which recorded three wind speed components, ambient pressure, temperature, and turbine output. The system operated unattended and could perform real-time processing of the data, displaying the measured power curve as data accumulated in either a bin sort mode or polynomial curve fit. Approximately 270 hr of perormance data were collected over a three-month period. The sampling interval was 2.4 sec; thrus over 400,000 raw data points were logged. Results for each of the three new tip devices, compared with the original tip, showed a small decrease (of the order of 1 kW) in power output over the measured range of wind speeds from cut-in at about 4 m/s to over 20 m/s, well into the stall limiting region. Changes in orientation and angle-of-attack of the winglets were not made. For aircraft wing tip devices, favorable tip shapes have been reported and it is likely that the tip devices tested in this program did not improve rotor performance because they were not optimally adjusted.

Gyatt, G. W.↗

NASA NTRS1989

An integrated model of the Space Station Freedom active thermal control system

A flexible, generic model of the Space Station Freedom active thermal control system has been developed which is designed to analyze dynamic interactions of the major subsystems of the ATCS. Models are described for the components of the central thermal bus, the radiator external thermal environment, and the internal thermal control system. Two programs are described which facilitate the development of the integrated ATCS model. The first, SIMRAD, simplifies an external thermal environment model given a desired level of accuracy in integrated model performance. The model reduction technique is shown to reduce model execution time significantly while maintaining the desired accuracy. The second, GENFLU, generates SINDA/FLUINT input code for the evaporator and load interface models and automates the integration of load submodels. The component submodels and integration techniques were used to create an integrated model of the thermal control system for an early assembly flight configuration. The results demonstrate the utility of the integrated model in studying dynamic interactions of the ATCS subsystems.

Tandler, John J.↗

NASA NTRS1990

Intelligent Data Reduction (IDARE)

A description of the Intelligent Data Reduction (IDARE) expert system and an IDARE user's manual are given. IDARE is a data reduction system with the addition of a user profile infrastructure. The system was tested on a nickel-cadmium battery testbed. Information is given on installing, loading, maintaining the IDARE system.

Brady, D. Michael↗

NASA NTRS1991

High energy efficiency and high power density proton exchange membrane fuel cells: Electrode kinetics and mass transport

The development of proton exchange membrane (PEM) fuel cell power plants with high energy efficiencies and high power densities is gaining momentum because of the vital need of such high levels of performance for extraterrestrial (space, underwater) and terrestrial (power source for electric vehicles) applications. Since 1987, considerable progress has been made in achieving energy efficiencies of about 60 percent at a current density of 200 mA/sq cm and high power densities (greater than 1 W/sq cm) in PEM fuel cells with high (4 mg/sq cm) or low (0.4 mg/sq cm) platinum loadings in electrodes. The following areas are discussed: (1) methods to obtain these high levels of performance with low Pt loading electrodes - by proton conductor impregnation into electrodes, localization of Pt near front surface; (2) a novel microelectrode technique which yields electrode kinetic parameters for oxygen reduction and mass transport parameters; (3) demonstration of lack of water transport from anode to cathode; (4) modeling analysis of PEM fuel cell for comparison with experimental results and predicting further improvements in performance; and (5) recommendations of needed research and development for achieving the above goals.

Supramaniam Srinivasan↗

NASA NTRS1994

Heat dissipation in water-cooled reflectors

The energy balance of a lamp varies with the thermal and optical characteristics of the reflector. The photosynthetic radiation efficiency of lamps, defined as input power divided by photosynthetically active radiation (PAR, 400-700 nm) emitted from the lamp ranges between 0.17 and 0.26. The rest of the energy input is wasted as longwave (3000 nm and over) and non-PAR shortwave radiation (from 700 nm to 3000 nm), convective, and conductive heat from the lamp, reflector, and ballast, and simply for increasing the cooling load. Furthermore, some portion of the PAR is uselessly absorbed by the inner walls, shelves, vessels, etc. and some portion of the PAR received by the plantlets is converted into sensible and latent heat. More than 98% of the energy input is probably converted into heat, with only less than 2% of the energy input being converted into chemical energy as carbohydrates by photosynthesis. Therefore, it is essential to reduce the generation of heat in the culture room in order to reduce the cooling load. Through use of a water-cooled reflector, the generation of convective and conductive heat and longwave radiation from the reflector can be reduced, without reduction of PAR.

Kozai, Toyoki↗

DOE OSTI2021

Low Carbon Technology Strategies: Midrise Apartment

This document includes steps that building owners and operators can implement to achieve smart, healthy, and low-carbon midrise apartment buildings within their existing building portfolios. Midrise apartments may use packaged rooftop units for heating, cooling, and ventilation or central plant systems for larger buildings.

analytics↗

DOE OSTI2021

Low Carbon Technology Strategies: Outpatient Healthcare

This document includes steps that building owners and operators can implement to achieve smart, healthy, and low-carbon outpatient healthcare buildings within their existing building portfolios. Outpatient healthcare includes diagnostic and treatment facilities for outpatient care, and these buildings often use packaged rooftop units for heating, cooling, and ventilation.

analytics↗

DOE OSTI2023

Conservation Voltage Reduction with Distributed Energy Resource Management System, Grid-Edge, and Legacy Devices: Preprint

advanced distribution management system↗