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At least 1,207 records · Page 67

Persistent Quasi-Periodic Pulsations During a Large X-Class Solar Flare

Solar flares often display pulsating and oscillatory signatures in the emission, known as quasi-periodic pulsations (QPP). QPP are typically identified during the impulsive phase of flares, yet in some cases, their presence is detected late into the decay phase. Here, we report extensive fine structure QPP that are detected throughout the large X8.2 flare from 2017 September 10. Following the analysis of the thermal pulsations observed in the Geostationary Operational Environmental Satellite/X-ray sensor and the 131 Å channel of Solar Dynamics Observatory/Atmospheric Imaging Assembly, we find a pulsation period of ~65 s during the impulsive phase followed by lower amplitude QPP with a period of ~150 s in the decay phase, up to three hours after the peak of the flare. We find that during the time of the impulsive QPP, the soft X-ray source observed with the Reuven Ramaty High Energy Solar Spectroscopic Imager rapidly rises at a velocity of approximately 17 km/s following the plasmoid/coronal mass ejection eruption. We interpret these QPP in terms of a manifestation of the reconnection dynamics in the eruptive event. During the long-duration decay phase lasting several hours, extended downward contractions of collapsing loops/plasmoids that reach the top of the flare arcade are observed in EUV. We note that the existence of persistent QPP into the decay phase of this flare are most likely related to these features. The QPP during this phase are discussed in terms of magnetohydrodynamic wave modes triggered in the post-flaring loops.

Hayes, Laura A.↗

On-orbit RNA Purification and qRT-PCR Capabilities of the WetLab-2 System

NASA Ames Research Center’s WetLab-2 system brings new capabilities to the ISS for researchers. The system can lyse cells and extract RNA on-orbit from different sample types ranging from microbial cultures to animal tissues. Our purification method has the advantage of using non-toxic chemicals and does not require alcohols or other organics. The purified RNA can then either be stabilized for return to Earth or can be used to conduct on-orbit quantitative Reverse Transcriptase PCR (qRT-PCR) analysis without the need for sample return. qRT-PCR reactions are performed by dispensing the RNA into reaction tubes that contain all lyophilized reagents needed to perform the analysis. The system uses a Cepheid® SmartCycler that allows for multiplexing of assays, this can be used to normalize for RNA concentration and integrity and to study multiple genes of interest in each tube. There are a total of 16 independent PCR modules each capable of detecting up to four fluorescent channels. The WetLab- 2 system can downlink data from the ISS to the ground after a completed run and uplink new thermal cycling programs. The ability to purify and stabilize RNA on-orbit can eliminate the confounding effects of reentry stresses and shock acting on live cells and organisms or the concern of RNA degradation of some samples. It also has the benefit of minimizing the needed downmass. Conducting qRT-PCR and generating results on-orbit is also an important step towards utilizing the ISS as a National Laboratory facility. Specifically, the ability to get on-orbit data will provide investigators with the opportunity to adjust experimental parameters in real time without the need for sample return and re-flight. On orbit gene expression analysis can also provide benchmarking prior to sample return. The system can also be used for analysis of air, surface, water, and clinical samples to monitor environmental pathogens and crew health. The validation flight of the WetLab-2 system using E. coli bacteria and mouse liver is scheduled to launch on SpaceX-8 this spring. Pending operations, the preliminary results from the validation flight will be presented. To support the needs of future researchers, we are adapting our system to purify RNA from two additional sample types: fibrous tissue such as muscle and mammalian adherent cells grown on alginate beads. Progress of this work will also be presented. The WetLab-2 Project is supported by the Research Integration Office in the ISS Program.

Parra, Macarena↗

Automatic variable selection in ecological niche modeling: A case study using Cassin’s Sparrow (Peucaea cassinii)

MERRA/Max provides a feature selection approach to dimensionality reduction that enables direct use of global climate model outputs in ecological niche modeling. The system accomplishes this reduction through a Monte Carlo optimization in which many independent MaxEnt runs, operating on a species occurrence file and a small set of randomly selected variables in a large collection of variables, converge on an estimate of the top contributing predictors in the larger collection. These top predictors can be viewed as potential candidates in the variable selection step of the ecological niche modeling process. MERRA/Max’s Monte Carlo algorithm operates on files stored in the underlying filesystem, making it scalable to large data sets. Its software components can run as parallel processes in a high-performance cloud computing environment to yield near real-time performance. In tests using Cassin’s Sparrow (Peucaea cassinii) as the target species, MERRA/Max selected a set of predictors from Worldclim’s Bioclim collection of 19 environmental variables that have been shown to be important determinants of the species’ bioclimatic niche. It also selected biologically and ecologically plausible predictors from a more diverse set of 86 environmental variables derived from NASA’s Modern-Era Retrospective Analysis for Research and Applications Version 2 (MERRA-2) reanalysis, an output product of the Goddard Earth Observing System Version 5 (GEOS-5) modeling system. We believe these results point to a technological approach that could expand the use global climate model outputs in ecological niche modeling, foster exploratory experimentation with otherwise difficult-to-use climate data sets, streamline the modeling process, and, eventually, enable automated bioclimatic modeling as a practical, readily accessible, low-cost, commercial cloud service.

John L. Schnase↗

Transient Aircraft Soot Emissions Indicate That Steady-State Measurements Likely Underestimate Real-World, Take-Off Emissions: Time-Varying Aircraft Take-Off Emissions Indices Measured at Los Angeles International Airport

Aircraft engine emissions are unique among mobile pollution sources in that their impacts affect the local air quality near airports as well as upper tropospheric composition and climate over regional-to-hemispheric scales. Furthermore, air travel and its resulting emissions are expected to rebound from the recent COVID-related lows to increase dramatically over the next several decades. Given the multi-decade service lifetime of many commercial aircraft, it is critically important to quantitatively understand the real-world emissions coming from these engines in order to inform environmental assessment and modelling activities. Here, we present a detailed analysis of aircraft emissions during take-off operations at Los Angeles International Airport. The data were collected as part of the NASA Alternative Fuel Effects on Contrails and Cruise Emissions (ACCESS) project in May 2014, and the dataset is publicly available as described by Moore et al. [1]. In particular, we focus on the time-varying nature of the plume concentrations where clear differences in particle size and non-volatile particle fraction are observed during the early portion of the take-off plume relative to the later portion of the plume. We compare the transient emissions indices measured here to engine certification values in the International Civil Aviation Organization (ICAO) Emissions Databank, which suggests that steady-state measurements may underestimate the real-world, non-volatile particle emissions. The implications of this finding for modelling aircraft particle emissions will be discussed.

Richard H. Moore↗

Design, Fabrication, Testing and Validation of a Ruggedized Fiber Optic Sensing System (FOSS) for Launch Application

Fiber-optic sensors based on fiber Bragg grating (FBG) is desirable for structural health monitoring and is used for various aerospace applications such as measuring strain and temperature, where a single optical fiber can multiplex hundreds of FBG sensors. The National Aeronautics and Space Administration (NASA) Armstrong Flight Research Center (AFRC) (Edwards, California) has been developing an optical fiber-based sensing suite called Fiber Optics Sensing System (FOSS) over the past two decades. Successful strain monitoring flight demonstrations such as the NASA Ikhana (General Atomics, San Diego, California) remotely piloted aircraft and the X-56A Multi-Utility Technology Testbed (Lockheed Martin Corporation, Bethesda, Maryland) remotely piloted subscale aircraft have been performed. Interest in adapting fiber-optic sensors for aerospace applications has led to commissioning the development of a ruggedized FOSS system for spaceflight through the NASA Launch Services Program (LSP) at the NASA Kennedy Space Center (KSC) (Merritt Island, Florida). In this paper, a ruggedized FOSS suitable for a launch environment is discussed in detail. Thermal analysis and enclosure design will be discussed as well as environmental testing such as shock, random vibration, thermal vacuum, and electromagnetic interference/electromagnetic compatibility (EMI/EMC). With all relevant environmental testing completed, a ruggedized FOSS unit has successfully passed all testing and is now deemed space-launch ready.

Allen R. Parker, Jr↗

2.3.4.501 - Synthesis and Analysis of Performance-Advantaged Bioproducts

This project focuses on the synthesis and analysis of performance-advantaged bioproducts (PABPs). We have established collaborations with other BETO-funded projects and academic and industrial collaborators to source new molecules that have promising manufacturing pathways and that could be serve as performance-advantaged biochemicals or biopolymers. We conduct synthesis and characterization of biochemicals and biopolymers alongside techno-economic analysis and life cycle assessment to estimate their cost and environmental impacts relative to incumbent materials. As part of the project, Profs. Linda Broadbelt and Brent Shanks are developing computational pathway prediction tools to identify optimal production pathways for bio-based compounds via biological and chemo-catalytic transformations. When coupled to the polyID tool from the Inverse Design project, these tools will ultimately enable a narrowing of design space for PABPs. From FY21-FY23, we described a framework for benchmarking PAPBs, estimated the energy and GHG emissions for commodity organic chemicals, developed performance-advantaged nylons and polyesters from beta-ketoadipic acid, and produced lignin-based plasticizers. We have shown that aromatic amines can be used in performance thermosets and that polyhydroxyalkanoates with crosslinked side chains can exhibit rubber-like properties, along with repair and degradability. We are working actively with industry partners on scale-up and validation of multiple PABPs.

BIOMASS FUELS↗

2023 JISEA Annual Meeting: JISEA Catalyzer Spotlight - Energy and Atmospheric Systems Catalyzer

The Energy and Atmospheric Systems Catalyzer has been running for 1.5 years, with many successes to report. This presentation reviews the goals and scope of the dual catalyzer themes of climate systems and air quality, summarizes new and ongoing projects, and looks into the future of how catalyzer-enabled capabilities can synergize across NREL and partners. Technical outcomes of catalyzer-supported analysis include (1) quantification of air quality, health, and equity (environmental justice) benefits of H2 substitution for fossil process heat in three industries (steelmaking, petroleum refining, and cement making) and (2) a roadmap for understanding renewable energy feedbacks into climate.

air quality↗

The development of STS payload environmental engineering standards

The presently reported effort to provide a single set of standards for the design, analysis and testing of Space Transportation System (STS) payloads throughout the NASA organization must be viewed as essentially experimental, since the concept of incorporating the diverse opinions and experiences of several separate field research centers may in retrospect be judged too ambitious or perhaps even naive. While each STS payload may have unique characteristics, and the project should formulate its own criteria for environmental design, testing and evaluation, a reference source document providing coordinated standards is expected to minimize the duplication of effort and limit random divergence of practices among the various NASA payload programs. These standards would provide useful information to all potential STS users, and offer a degree of standardization to STS users outside the NASA organization.

Bangs, W. F.↗

Annual Status Report (FY 2020): Performance Assessment for the Environmental Restoration Disposal Facility

DOE O 435.1 and DOE M 435.1-1 require that a determination of continued adequacy of the performance assessment (PA) (CP-60089), composite analysis, and disposal authorization statement (DAS) be made annually, and these guidelines must be used to consider the results of data collection and analysis from research, field studies, and monitoring as well as provide the need to update any radioactive waste management basis documents. Beginning in 1996, the Environmental Restoration Disposal Facility (ERDF) started accepting low-level radioactive, hazardous, and mixed wastes generated during cleanup activities at the Hanford Site. ERDF is composed of a series of cells or disposal areas and can accommodate future design expansions as needed. Currently, there are 10 cells. During this reporting period (fiscal year 2020, which extended from October 1, 2019, through September 30, 2020), approximately 3.39E+04 U.S. tons (3.07E+04 metric tons) of waste was disposed at ERDF. From ERDF inception through September 30, 2020, approximately 18.5 million U.S. tons of waste has been disposed at ERDF, which equates to the consumption of approximately 88% of the disposal volume. As a condition of the DAS, disposal operations within ERDF must be in accordance with the waste acceptance criteria (ERDF-00011) that provide specific radionuclide disposal limits, waste form restrictions, and descriptions of acceptable waste packages in compliance with DOE M 435.1-1 requirements. The ERDF waste acceptance criteria stipulate that waste destined for disposal at ERDF be controlled based on source, physical form, and contaminant concentration and activity levels. There have been no changes to the physical configuration of ERDF or to the waste forms (source, physical form, etc.). No new Unreviewed Disposal Question Screenings or Evaluations have been generated during this reporting period. Therefore, there are no noted impacts to the PA, composite analysis, DAS, or radioactive waste management basis documents resulting from the evaluations and screenings. Sum of fraction analysis shows that the disposed inventory meets both the concentration and inventory threshold requirements. A sum of fractions value is computed for ERDF sensitive radionuclides contributing to the all pathways and air pathway inventory limits. Computed values were 8.85E-02 and 1.78E-01, respectively. The disposed waste inventory remained well under the PA imposed limits. Required monitoring was satisfactorily completed during the fiscal year reporting period (fiscal year 2020). Compliance with performance objectives were met as each of the reported values were well below the established limit. Overall, there are no substantive changes to primary PA assumptions nor changes to the PA analysis conclusion; therefore, compliance with DOE O 435.1 and the DAS is maintained.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Impact resistance of fiber composites: Energy absorbing mechanisms and environmental effects

Energy absorbing mechanisms were identified by several approaches. The energy absorbing mechanisms considered are those in unidirectional composite beams subjected to impact. The approaches used include: mechanic models, statistical models, transient finite element analysis, and simple beam theory. Predicted results are correlated with experimental data from Charpy impact tests. The environmental effects on impact resistance are evaluated. Working definitions for energy absorbing and energy releasing mechanisms are proposed and a dynamic fracture progression is outlined. Possible generalizations to angle-plied laminates are described.

Chamis, C. C.↗

Impact resistance of fiber composites - Energy-absorbing mechanisms and environmental effects

Energy absorbing mechanisms were identified by several approaches. The energy absorbing mechanisms considered are those in unidirectional composite beams subjected to impact. The approaches used include: mechanic models, statistical models, transient finite element analysis, and simple beam theory. Predicted results are correlated with experimental data from Charpy impact tests. The environmental effects on impact resistance are evaluated. Working definitions for energy absorbing and energy releasing mechanisms are proposed and a dynamic fracture progression is outlined. Possible generalizations to angle-plied laminates are described.

Chamis, C. C.↗

Review of multi-faceted morphologic signatures of actinide process materials for nuclear forensic science

Particle morphology is an emerging signature that has the potential to identify the processing history of unknown nuclear materials. Using readily available scanning electron microscopes (SEM), the morphology of nearly any solid material can be measured within hours. Coupled with robust image analysis and classification methods, the morphological features can be quantified and support identification of the processing history of unknown nuclear materials. The viability of this signature depends on developing databases of morphological features, coupled with a rapid data analysis and accurate classification process. With developed reference methods, datasets, and throughputs, morphological analysis can be applied within days to (i) interdicted bulk nuclear materials (gram to kilogram quantities), and (ii) trace amounts of nuclear materials detected on swipes or environmental samples. In conclusion, this review aims to develop validated and verified analytical strategies for morphological analysis relevant to nuclear forensics.

36 MATERIALS SCIENCE↗

Rapid characterization of MSW and RDF feedstocks for waste-to-energy process using LIBS and ML techniques

The heterogeneity in the composition of municipal solid wastes (MSW) poses significant challenges in the production of biofuel and bioproducts. This research aims to enhance the accuracy and efficiency of waste analysis and characterization by introducing a fast characterization approach for MSW-derived refuse-derived fuels (RDF) by combining Laser-Induced Breakdown Spectroscopy (LIBS) with advanced machine learning (ML) techniques. The approach combines data pre-processing of LIBS spectra of RDF, and the development of ML models trained on domain and theory-based spectral features for predicting process parameters. These models are adept at predicting key process parameters like High Heating Value (HHV), carbon content, and volatile matter. This approach can achieve an average RRMSE of 2.13% and R 2 of 0.98 or higher for all considered parameters on testing data. This work demonstrates significant potential for improving waste sorting, processing efficiency, and environmental compliance over traditional labor- and time-intensive laboratory waste analysis and characterization.

09 BIOMASS FUELS↗

Testing and Analysis of a Composite Non-Cylindrical Aircraft Fuselage Structure: Ultimate Design Loads - Part 1

The Environmentally Responsible Aviation Project aimed to develop aircraft technologies enabling significant fuel burn and community noise reductions. Small incremental changes to the conventional metallic alloy-based 'tube and wing' configuration were not sufficient to achieve the desired metrics. One airframe concept identified by the project as having the potential to dramatically improve aircraft performance was a composite-based hybrid wing body configuration. Such a concept, however, presented inherent challenges stemming from, among other factors, the necessity to transfer wing loads through the entire center fuselage section which accommodates a pressurized cabin confined by flat or nearly flat panels. This paper discusses finite element analysis and testing of a large-scale hybrid wing body center section structure developed and constructed to demonstrate that the Pultruded Rod Stitched Efficient Unitized Structure concept can meet these challenging demands of the next generation airframes. Part I of the paper considers the five most critical load conditions, which are internal pressure only and positive and negative g-loads with and without internal pressure. Analysis results are compared with measurements acquired during testing. Performance of the test article is found to be closely aligned with predictions and, consequently, able to support the hybrid wing body design loads in pristine and barely visible impact damage conditions.

Przekop, Adam↗

Refined Analysis of CO2 Emissions in Urban Air Mobility Networks

In this study, we examine the environmental impact of Urban Air Mobility (UAM) operations as measured via carbon dioxide (CO2) emissions by leveraging a computational model from previous studies that has been refined and expanded. Several scenarios are examined in which total transportation emissions for a representative day in a metro area are distributed differently among vehicle types and transportation modes. Specifically, we investigate the use of electric air vehicles in a UAM network; the increasing presence of electric ground vehicles for ground transportation; the impacts from implementing ridesharing in the UAM mode; and the effects of varying the electricity grid emissions. Results for a case study in the Chicago, IL metro area indicate that incorporating electric ground vehicles and UAM ridesharing can both lead to reduced CO2 emissions. These preliminary results indicate that carbon emissions from a UAM system leveraging ridesharing and all-electric aircraft may not be a practical operational limit on UAM, though further improvements to the modeling are warranted.

advanced air mobility↗

Refined Analysis of CO2 Emissions in Urban Air Mobility Networks

In this study, we examine the environmental impact of Urban Air Mobility (UAM) operations as measured via carbon dioxide (CO2) emissions by leveraging a computational model from previous studies that has been refined and expanded. Several scenarios are examined in which total transportation emissions for a representative day in a metro area are distributed differently among vehicle types and transportation modes. Specifically, we investigate the use of electric air vehicles in a UAM network; the increasing presence of electric ground vehicles for ground transportation; the impacts from implementing ridesharing in the UAM mode; and the effects of varying the electricity grid emissions. Results for a case study in the Chicago, IL metro area indicate that incorporating electric ground vehicles and UAM ridesharing can both lead to reduced CO2 emissions. These preliminary results indicate that carbon emissions from a UAM system leveraging ridesharing and all-electric aircraft may not be a practical operational limit on UAM, though further improvements to the modeling are warranted.

advanced air mobility↗

Use of carbonyldiimidazole as a derivatization agent for the detection of pinacolyl alcohol, a forensic marker for Soman, by EI-GC–MS and LC-HRMS in official OPCW proficiency test matrices

Pinacolyl alcohol (PA), a key forensic marker for the nerve agent Soman (GD), is a particularly difficult analyte to detect by various analytical methods. In this work, we have explored the reaction between PA and 1,1'-carbonyldiimidazole (CDI) to yield pinacolyl 1H-imidazole-1-carboxylate (PIC), a product that can be conveniently detected by gas chromatography–mass spectrometry (GC–MS) and liquid chromatography-high-resolution mass spectrometry (LC-HRMS). Regarding its GC–MS profile, this new carbamate derivative of PA possesses favorable chromatographic features such as a sharp peak and a longer retention time (RT = 16.62 min) relative to PA (broad peak and short retention time, RT = 4.1 min). Additionally, the derivative can also be detected by LC-HRMS, providing an avenue for the analysis of this chemical using this technique where PA is virtually undetectable unless present in large concentrations. From a forensic science standpoint, detection of this low molecular weight alcohol signals the past or latent presence of the nerve agent Soman (GD) in a given matrix (i.e., environmental or biological). The efficiency of the protocol was tested separately in the analysis and detection of PA by EI-GC–MS and LC-HRMS when present at a 10 μg/mL in a soil matrix featured in the 44th PT and in a glycerol-rich liquid matrix featured in the 48th Official Organization for the Prohibition of Chemical Weapons (OPCW) Proficiency Test when present at a 5 μg/mL concentration. In both scenarios, PA was successfully transformed into PIC, establishing the protocol as an additional tool for the analysis of this unnatural and unique nerve agent marker by GC–MS and LC-HRMS.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Incremental approach for the life-cycle greenhouse gas analysis of carbon capture and utilization

Electro-fuels (e-fuels) are examples of carbon capture and utilization (CCU) hydrocarbon products that are derived from captured carbon dioxide (CO 2 ), while using renewable electricity as the energy feedstock. The environmental impacts of CCU products (e.g., e-fuel) are systematically quantified through life-cycle analysis (LCA). Previous studies evaluating LCA of e-fuels proposed frameworks with an expanded system boundary approach that included the entire supply chain of the production process generating the CO 2 for CCU, in addition to the supply chain of the CCU product. This expanded system boundary approach evaluates two system boundaries, and uses deduction methods to calculate the carbon intensity (CI) of the CCU product (e-fuel). This paper proposes a simpler system boundary using an incremental approach that can calculate identical CI of the CCU product (e-fuel), while avoiding the extensive calculations in the expanded system boundary framework. The proposed incremental approach allocates the burdens of the CO 2 capturing process to the CO 2 feedstock supplying the CCU production process (e.g., e-fuel production). The CI of the captured CO 2 supplied to CCU process is determined by the energy and material requirements for the CO 2 capturing process and transportation to the CCU plant. Thus, the CI of CO 2 supplied to CCU process can be directly linked to the CI of e-fuel without the need to conduct LCA of the preceding process that generates the CO 2 for CCU.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗