Crystal structure of a thermophilic fungal cyanase and its implications on the catalytic mechanism for bioremediation
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In response to increasingly severe weather conditions, optimization of building performance and investment provides an opportunity to consider co-benefits of thermal resilience during energy efficiency retrofits. This work aims to assess thermal resilience of buildings using building performance simulation to evaluate the indoor overheating risk under nine weather scenarios, considering historical (2010s), mid-term future (2050s), and long-term future (2090s) typical meteorological years, and heat wave years. Such an analysis is based on resilience profiles that combine six integrated indicators. A case study with a district of 92 buildings in Brazil was conducted, and a combination of strategies to improve thermal resilience was identified. Results reflect the necessity of planning for resilience in the context of climate change. This is because strategies recommended under current conditions might not be ideal in the future. Therefore, an adaptable design should be prioritized. Cooling energy consumption could increase by 48 % by the 2050s, while excessive overheating issues could reach 37 % of the buildings. Simple passive strategies can significantly reduce the heat stress. A comprehensive thermal resilience analysis should ultimately be accompanied by a thorough reflection on the stakeholders’ objectives, available resources, and planning horizon, as well as the risks assumed for not being resilient.
As the distributed solar market evolves toward more dynamic forms of deployment, interest in paired solar-plus-storage applications continues to gain steam, but details on the current state of the market are relatively sparse. To fill that void, Berkeley Lab has released an in-depth analysis of this budding market segment. This report draws on the Lab’s Tracking the Sun dataset to characterize trends in deployment, system sizing and equipment selection, installer-market development, and system pricing. The report also provides indicative analyses of the financial and resilience value that host customers in several key markets presently receive by pairing storage with solar.
Natural gas furnaces are the most common space heating equipment in the U.S. residential and commercial building markets. However, current residential natural gas condensing furnaces generate substantial acidic condensate as well as significant emissions of sulfur oxides (SOx), nitrogen oxides (NOx), carbon monoxide (CO), hydrocarbons (HC), and methane (CH 4 ) contributing to environmental degradation of air, water, and soil. This report describes a novel solution to reduce the environmental impact of natural gas condensing furnaces based on the technology of a monolithic acidic gas reduction (AGR) catalyst for SOx trapping, NOx redox to nitrogen, and oxidation of formic acid, CO, HC, and CH 4 . The AGR technology offers the following benefits: (1) a neutral furnace condensate with a pH of ~7, allowing its safe release into the sewer system thus eliminating a second drainage system; (2) trapping and removing nearly all SOx emissions; (3) NOx emissions nearly at nearly 1-2 ng/J, more than 95% lower than new emissions standards in California; (4) the use of a low-cost heat exchanger as a condensing heat exchanger (HX) since the condensate is not acidic, avoiding the need for expensive stainless steel alloys; and (5) unburnt fuel energy recovery to boost efficiency.The AGR component and AGR-enabled furnace performance were broadly tested to determine their effects on long-term reliability and durability, as well as SOx storage and regeneration activity. The AGR regeneration does not impair the performance in achieving neutral condensate and ultra-low NOx emissions, and the AGR catalyst subjected to regeneration activities continued to function well and achieved slightly better annual fuel utilization efficiency (AFUE). The 400-hour reliability and durability test of the retrofitted condensing furnace with the AGR component shows that the furnace unit still achieves a neutral furnace condensate with a pH of ~7 and enables 0~3 ng/J of NOx emissions. However, the 400-hour operation slightly degraded the AFUE because of soot particle accumulation caused by frequent incomplete combustion owing to inappropriate condensate drainage during testing. Thus, proper condensate drainage is critical for AGR-enabled furnaces. Furthermore, neutron computed tomography was employed to survey the aged AGR component and demonstrate high-resolution 2D and 3D representations for the nondestructive diagnosis of the AGR component. The tomography showed that the AGR component did not deform or suffer broken AGR channels. A new AGR catalyst with low precious metal loading was preliminarily explored to identify a pathway of optimizing AGR material loading and maximizing acidic gas reduction at low cost. The new AGR component can reduce precious metal loading by 38% and still achieve neutral condensate and ultralow NOx emissions. The furnace with the AGR component of low Pt/Rh loading enables a maximum AFUE of 97%, which is meaningfully higher than the original furnace. Long-duration testing for the furnace enabled with the low precious metal loading AGR component will be vital in future research. Although the current work demonstrates a proof of concept for the AGR-enabled furnace, the AGR assembly needs to be optimized and integrated into the design of new OEM furnace products. Furthermore, the AGR technology can be applied not only for residential gas furnaces, but also for commercial rooftop units, gas heat pumps, gas-fired water heaters, combustion boilers, and other systems.
The purpose of this Cooperative Research and Development Agreement (CRADA) was to test a heat exchanger defrosting approach using radiant energy, including ultraviolet-C, -B, and -A. A preliminary test conducted at Oak Ridge National Laboratory demonstrated the concept of ultraviolet-based defrosting, which melts frost on the fin surface of a heat exchanger without increasing its overall temperature, thereby offering a new defrosting method that does not interrupt heat exchanger operation. Building on this key finding, this CRADA outlines a plan for upgrading the test equipment and for further testing to bridge the gap between the concept and its feasibility for industrial applications. This report also provides a brief review of existing defrosting technologies, the current state of the experimental system, and future parametric experiment plans.
This study investigates potential economic and groundwater driven transitions from irrigated maize production—the dominant irrigated cropping system in the High Plains Aquifer (HPA) region—to alternative crops such as sorghum and switchgrass, two common bioenergy feedstocks. Unsustainable groundwater extraction in the U.S. High Plains presents critical challenges including reduced irrigation capacities, diminished crop yields, lower land values, and escalating energy costs. Using a spatially explicit optimization framework combined with comprehensive economic and hydrogeological data, we evaluate optimal land-use strategies and irrigation system investments over a 30-year planning period. Results indicate significant regional variability in the future economic viability of irrigated agriculture, driven by differences in aquifer recharge rates, groundwater availability, and market conditions. Nebraska and parts of northern Texas can sustain irrigated maize profitability due to relatively favorable groundwater conditions and lower land rents, respectively. In contrast, many portions of Kansas and southern Texas are more likely to transition to dryland agriculture within two decades. Colorado and New Mexico show potential for significant adoption of switchgrass production as an alternative biomass-based energy crop. Overall, over the 30-year horizon, our model implies that approximately 23% of currently irrigated maize area across the HPA region may transition to dryland farming under business-as-usual conditions. This transition is complemented by a threefold increase in non-irrigated sorghum production, from 0.20 to 0.77 Mt yr−1, indicating that groundwater-driven shifts in agricultural production may support a larger regional base for bioenergy feedstocks. The study also reveals opportunities for producers to optimize economic returns and biomass production potential.
Fast charging batteries are critical to the widespread adoption of electric vehicles to compete with refueling times of combustion-based vehicles. In the near term, adapting current commercial battery technologies to perform better under fast charging conditions through engineering optimizations will greatly expedite the process while exploratory fast-charging electrode materials are being pursued. To do so, the degradation modes in optimized Li-ion batteries need to be completely explored to understand fast charging limits while maintaining a high energy density and a long cycle life. While lithium plating on graphite still remains a challenge, cathode degradation also plays a key role in battery performance. In this work, we used nano- and micro-X-ray computed tomography to characterize the mechanical degradation of LiNi 0.5 Mn 0.3 Co 0.2 O 2 (NMC532) in optimized Li-ion batteries cycled at three rates, 1C, 6C, and 9C, and at different stages of cycle life, 225 and 600 cycles. We report despite using a conservative upper voltage cutoff limit aimed to minimize extensive cathode degradation, higher charging rates and increased cycling caused the polycrystalline NMC532 particles to fracture and pulverize, which likely drives cathode capacity fade and contributes to the decrease in overall cell performance.
A solar sailing mission architecture, which requires a t least ten 160-m, 300-kg solar sail spacecraft with a characteristic acceleration of 0.5 mm/sqs, is proposed as a realistic near- term option for mitigating the threat posed by near-Earth asteroids (NEAs). Its mission feasibility is demonstrated for a fictional asteroid mitigation problem created by AIAA. This problem assumes that a 200-m asteroid, designated 2004WR, was detected on July 4, 2004, and that the expected impact will occur on January 14, 2015. The solar sailing phase of the proposed mission for the AIAA asteroid mitigation problem is comprised of the initial cruise phase from 1 AU t o 0.25 AU (1.5 years), the cranking orbit phase (3.5 years), and the retrograde orbit phase (1 year) prior to impacting the target asteroid at its perihelion (0.75 AU from the sun) on January 1, 2012. The proposed mission will require at least ten kinetic energy interceptor (KEI) solar sail spacecraft. Each KEI sailcraft consists of a 160- m, 150-kg solar sail and a 150-kg microsatellite impactor. The impactor is to be separated from a large solar sail prior to impacting the 200-m target asteroid at its perihelion. Each 150-kg microsatellite impactor, with a relative impact velocity of at least 70 km/s, will cause a conservatively estimated AV of 0.3 cm/s in the trajectory of the 200-m target asteroid, due largely to the impulsive effect of material ejected from the newly-formed crater. The deflection caused by a single impactor will increase the Earth-miss-distance by 0.45Re (where Re denotes the Earth radius of 6,378 km). Therefore, at least ten KEI sailcraft will be required for consecutive impacts, but probably without causing fragmentation, to increase the total Earth-miss-distance by 4.5Re. This miss-distance increase of 29,000 km is outside of a typical uncertainty/error of about 10,000 km in predicting the Earth-miss- distance. A conventional Delta I1 2925 launch vehicle is capable of injecting at least two KEI sailcraft into an Earth escaping orbit. A 40-m solar sail is currently being developed by NASA and industries for a possible flight validation experiment within 10 years, and a 160-m solar sail is expected to be available within 20 years.
The Metropolitan Council administered a system-wide transit on-board survey between September and November 2010 as part of the 2010 Travel Behavior Inventory to provide detailed transit usage patterns and rider information to support modeling and planning efforts. The study’s focus was to capture only the most current and reliable data necessary to determine future public transportation needs in the Minneapolis region. The study was structured to collect detailed transit ridership data for different routes during different times of day to develop a disaggregate transit trip table that will support advanced travel demand modeling. The study was designed to leverage existing data sources, such as the 2005 on-board survey, to provide the best quality data to update the Travel Behavior Inventory in the Minneapolis-Saint Paul metropolitan area.
This study collected automated vehicle (AV) performance data on public roadways in Athens, Ohio. The route for the study contained a combination of roads with different functional classifications, conditions, annual average daily traffic, and ownership responsibilities for maintenance and repair. Preparation for the public road deployment was done in a controlled environment at Transportation Research Center’s SMARTCenter, a dedicated AV test facility in East Liberty, Ohio. Researchers analyzed data and extracted insights relevant for both AV developers and infrastructure owners and operators. The study found that rural environments offer a unique set of roadway features such as hills and curves, which can challenge the driving behavior of an AV. Rural regions can also contain a large number of low-traffic gravel roads that lack pavement markings, which appear to be a crucial infrastructure element for operation of current generation AVs. Similarly, the presence of well-maintained lane lines along curves can influence the AV’s roadway departure tendencies. The study found that curvature-related behavior of an AV is also influenced by driving speed on the roadway segment. Such findings were consistent regardless of the time of day along the route or season of data collection. However, commentary about AV performance in active adverse weather cannot be made, as this is still an area of active research.
In recent years, the buildings sector has seen major pushes towards decarbonization through innovations that promote deep electrification. 20% of an average household's energy use comes from water heating, and in the US, over half of all households still use gas water heaters. Of those that use electricity for water heating, the majority use resistive elements rather than heat pump water heaters (HPWHs), the latter of which use 60-70% less energy than the former. However, HPWHs tend to have larger dimensions, preventing current 50-80-gallon tanks on the market from fitting into smaller utility closets sized for 30-40 gallons, such as those found in manufactured housing. Additionally, these smaller HPWHs tend to underperform relative to their larger counterparts. One solution that addresses both space and performance concerns is thermal energy storage, and in particular, phase change materials (PCMs). This study outlines the design process used to produce novel PCM heat exchangers for use in small-volume HPWH tanks, including the identification of design constraints and performance targets relevant to real-world applications. To ensure optimal PCM utilization and tank storage capacity, this works seeks to co-maximize surface area and PCM volume; therefore, this research targets triply periodic minimal surface (TPMS) lattices, which boast enhanced heat transfer capabilities compared to traditional heat exchanger geometries. Starting with a suite of TPMS lattices, we demonstrate a systematic approach for narrowing down feasible designs that comply with identified constraints while meeting PCM performance objectives. Our current results indicate that tuning lattice properties can effectively produce geometries that provide enough energy storage to achieve a 50-gallon capacity out of a 40-gallon HPWH, even when placing the PCM heat exchanger inside the tank. Additionally, we demonstrate successful fabrication of lattices with these tuned properties.
We present a detailed characterization of the structure and evolution of differentially rotating plasmas driven on the MAGPIE pulsed-power generator (1.4 MA peak current, 240 ns rise time). The experiments were designed to simulate physics relevant to accretion discs and jets on laboratory scales. A cylindrical aluminium wire array Z pinch enclosed by return posts with an overall azimuthal off-set angle was driven to produce ablation plasma flows that propagate inwards in a slightly off-radial trajectory, injecting mass, angular momentum and confining ram pressure to a rotating plasma column on the axis. However, the plasma is free to expand axially, forming a collimated, differentially rotating axial jet that propagates at ${\approx }100\,{\rm km}\,{\rm s}^{-1}$ . The density profile of the jet corresponds to a dense shell surrounding a low-density core, which is consistent with the centrifugal barrier effect being sustained along the jet's propagation. We show analytically that, as the rotating plasma accretes mass, conservation of mass and momentum implies plasma radial growth scaling as $r \propto t^{1/3}$ . As the characteristic moment of inertia increases, the rotation velocity is predicted to decrease and settle on a characteristic value ${\approx }20\,{\rm km}\,{\rm s}^{-1}$ . We find that both predictions are in agreement with Thomson scattering and optical self-emission imaging measurements.
Investigations carried out at STL on three current problems involving instability of thin shells in applications to aerospace vehicles are discussed. The first concerns the experimental determination of the buckling behavior of longitudinally stiffened pressurized cylinders; the second, the analytic prediction and experimental confirmation of the buckling behavior of multi-layer cylinders and the third involves the behavior of cylinders under combined axial load and lateral pressure. In each case the background of the application is reviewed, followed by a short description of the work. It is indicated that the longitudinally stiffened cylinder shows considerable promise in taking maximum advantage of the strengthening effect of internal pressure, that the use of an external low modulus layer as an insulator can have a significant effect on the buckling capability of a shell, and that the assumption of a linear interaction for pressure and axial load is unnecessarily conservative.
Here, we report on an analytical and numerical study of the dynamics of a three-dimensional array of identical magnetic flux tubes in the reduced-magnetohydrodynamic description of the plasma. We propose that the long-time evolution of this system is dictated by flux-tube mergers, and that such mergers are dynamically constrained by the conservation of the pertinent (ideal) invariants, viz. the magnetic potential and axial fluxes of each tube. We also propose that in the direction perpendicular to the merging plane, flux tubes evolve in a critically balanced fashion. These notions allow us to construct an analytical model for how quantities such as the magnetic energy and the energy-containing scale evolve as functions of time. Of particular importance is the conclusion that, like its two-dimensional counterpart, this system exhibits an inverse transfer of magnetic energy that terminates only at the system scale. We perform direct numerical simulations that confirm these predictions and reveal other interesting aspects of the evolution of the system. We find, for example, that the early time evolution is characterized by a sharp decay of the initial magnetic energy, which we attribute to the ubiquitous formation of current sheets. We also show that a quantitatively similar inverse transfer of magnetic energy is observed when the initial condition is a random, small-scale magnetic seed field.
NextGen Profiles' EVSE characterization efforts explored performance variability in production EVSE through the use of EV emulation equipment and assessed how different operational conditions influence charging behavior. Data were collected at a frequency of 10 Hz from both the EV emulator and EVSE during each charge session and stored in a time-series database for further analysis. As part of the NextGen Profiles project, characterization of high-power EVSE was performed on both conductive and wireless charging infrastructure; however, only conductive charging data are currently included in this repository. This EVSE characterization was performed over a range of DC output currents and voltages, covering both nominal and off-nominal test conditions. This EVSE characterization dataset includes high-power charging data from two types of 350-kW-capable EVSE using liquid-cooled Combined Charging System-1 (CCS1, North American version) cables and connectors. To protect confidentiality, all EVSE metadata are anonymized, and the publicly released datasets are metered at 10-Hz frequency.
A multi-stage electrochemical hydrogen compressor incorporates membrane-electrode-assemblies (MEAs) separated by proton exchange membranes (PEMs) in series to reach higher pressures, when a current is passed through the MEA protons and electrons are generated at the anode. The protons are electrochemically driven across the membrane to the cathode, after which they combine with the rerouted electrons to form hydrogen, which is fed to the hydrogen compressor to be oxidized at the anode of each cell to form protons and electrons. This type of compressor has no moving parts and can be applied to refrigeration systems technologies. This project investigated the viability of commercialization of heat pumps based on electrochemical compressor technology.
Ecological restoration programs in dynamic coastal environments can benefit from adaptive management, including an iterative process for identifying and addressing critical uncertainties. We highlight key developments under the three pillars that have increased the rate of restoration by the Columbia Estuary Ecosystem Restoration Program (CEERP) over 20 years: science, coordination, and management. We show how such programs can be institutionalized to ensure that estuary ecosystems are better understood, conserved, and restored. The principal conservation effort under CEERP is to reconnect historical floodplain wetlands to the mainstem. The program also supports other restoration actions that demonstrate a high potential to benefit ecosystem function and endangered salmon populations, however, there is greater uncertainty regarding these less-utilized techniques. Through adaptive management, we address both technical uncertainty regarding benefits to the environmental resource and programmatic uncertainty pertaining to decision-making. Here, we examine three periods of CEERP growth to establish how complementary research and restoration actions have improved program outcomes over time. We highlight the tools and processes that were developed and integrated into the program to refine program strategy, improve project design, and maximize ecological benefits. CEERP supported 77 restoration projects and reconnected over 7,000 acres of floodplain habitat to the lower Columbia River between 2004 and 2021. Building on these successes, we outline current plans to better engage landowners and local communities, solicit new project types, and maintain enough flexibility within the program to adapt to new priorities.
Under the U.S. Department of Energy Office of Nuclear Energy Advanced Modeling and Simulation (NEAMS) Program, an integrated multiphysics approach is being developed to model the core bowing phenomena important to liquid metal-cooled fast reactors. Core bowing is an important passive safety mechanism in liquid metal-cooled fast reactors and involves multiphysics effects including radiation transport, fluid flow, heat transfer, and mechanical response to temperature and flux gradients. This report summarizes recent progress on developing a multiphysics, MOOSE-based workflow to predict core bowing and associated reactivity feedback. Significant new capabilities in the reactor physics code Griffin - sodium backfill and pin power reconstruction for deformed geometries - were applied in this effort. This year’s work included verification, code comparisons, sensitivity studies, and coupled demonstrations that advance the state of MOOSE-based core bowing workflow. Griffin’s sodium backfill capability was verified by demonstrating that its automated treatment of geometry expansion and material-density updates reproduces manual calculations exactly, confirming solid mass conservation and proper coolant backfilling in expanded geometries. Reconstructed pin powers were compared for Griffin’s ductheterogeneous and ring-heterogeneous treatments in single-, seven-, and nineteen-assembly cases, with best agreement observed in lower-leakage configurations and the duct-heterogeneous approach offering substantially lower computational cost. Thermal-hydraulic sensitivity sensitivities showed that MOOSE SCM, SAM, and CFD are expected to produce similar deformation predictions despite variances in their temperature predictions, and that explicit treatment of inter-assembly flow becomes increasingly important as gap flow rate increases. Finally, coupled demonstrations on small multi-assembly configurations using Griffin, MOOSE Solid Mechanics, MOOSE SCM, and Heat Conduction produced physically consistent reactivity feedback from thermal expansion and bowing. The coupled demonstrations simulated grid plate expansion as well as resultant core bowing at full power conditions. Simplifications were made in current workflow, namely the assumption of instantaneous full power conditions following hot zero power, and pre-expanding the Griffin geometry axially due to lack of an axial fuel pin expansion model and temperature feedback to Griffin.