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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,207 records · Page 67

Assessment of the use of space technology in the monitoring of oil spills and ocean pollution: Technical volume. Executive summary

The potential of space systems and technology for detecting and monitoring ocean oil spills and waste pollution was assessed as well as the impact of this application on communication and data handling systems. Agencies charged with responsibilities in this area were identified and their measurement requirements were ascertained in order to determine the spatial resolution needed to characterize operational and accidental discharges. Microwave and optical sensors and sensing techniques were evaluated as candidate system elements. Capabilities are described for the following: synthetic aperture radar, microwave scatterometer, passive microwave radiometer, microwave altimeter, electro-optical sensors currently used in airborne detection, existing space-based optical sensors, the thematic mapper, and the pointable optical linear array.

Alvarado, U. R.↗

Gamma ray interaction processes

Gamma ray detection in the energy region above 1 keV involves measurements of the energy exchange or energy loss between the gamma ray and the mass of the detector. In most cases of interest, it is the kinetic energy imparted to charged particles by the gamma ray which is lost in the detector and measured in order to obtain spectral knowledge between the incident gamma ray photon and the direction of the secondary particles contains important energy information. The interaction gamma ray removal processes in matter are considered. This interaction removal process is characterized by the fact that each gamma ray is removed individually from the incident beam. The number of photons removed in this manner is proportional to the thickness of matter traversed.

Source record↗

Fragmentation of 710 and 1050 MeV/nuc Fe nuclei in CH2 and C targets - Isotopic cross sections for H targets

Fe nuclei of incident energies of 710 and 1050 MeV/nuc in CH2 and C targets are fragmented in order to measure isotopic cross sections in hydrogen targets. The telescope used to measure the charge and mass of the fragments is a Cerenkov x total energy telescope. The data are reported for z = 20-25 fragments. The number of individual events corresponding to each charged fragment is obtained and analyzed. Ratios of partial cross sections on C and CH2 targets indicate that simple scaling exists for isotope fractions as well as for charge fractions in different targets. The cross sections in hydrogen are obtained directly by a simple subtraction. Excitation functions for Mn and Cr nuclei are presented.

Webber, W. R.↗

Ground testing in a simulated auroral environment

Shuttle polar orbit missions are being planned in which astronaut extravehicular activities (EVA) will eventually include external operations or repair and refurbishment of satellites. Recent satellite data and model calculations show that significant spacecraft charging and differential charging occurs in that environment and could endanger equipment and personnel involved in the EVA. These spacecraft charging events take place in response to an intense flux of high energy electrons accompanied by a large drop in the ambient plasma density. The extent of which the auroral environment can be simulated in a large vacuum chamber are determined so that conditions which lead to significant charging and discharging may be observed and controlled. A large chamber would be required in order to simulate the effects of an aurora-like, large cross-section, energetic electron precipitation on a target system the size of an astronaut with a life support system. The precipitating electrons can be simulated with an array of multipactor sources and the background ionization produced by the beam can be limited to the range of the auroral density if the chamber pressure is not significantly above 1 x .000001 Torr. Some small chamber work has shown that the plasma in the beam will diffuse radially at a rate determined by the Bohm diffusion coefficient.

Mcintyre, Bernard↗

Satellite sweeping in offset, tilted dipole fields

The paper presents a theory for the longitudinally averaged satellite sweeping rate in an offset, tilted dipole magnetic field. It includes the reductions in the sweeping rate when the moon radius is not large compared to the gyroradius or the azimuthal drift distance during a bounce period. With a large tilt angle between the magnetic and rotation axes, moons make large excursions in dipole L value, and more than one moon can sweep at a given L. The sweeping rate peaks at the minimum L for each moon. If the gyroradius is large, additional peaks can occur when the particle mirrors near the moon latitude. To illustrate the theory, sweeping rates are evaluated for parameters relevant to the observations at Uranus by the Voyager 2 Low Energy Charged Particles Experiment. Calculated sweeping rates for ions and electrons are typically two or three orders of magnitude less than the strong-diffusion loss rate. The observation of sweeping signatures at Uranus would imply that pitch-angle scattering there occurs at a rate far below the strong-diffusion limit, contrasting with the situation for energetic ions in the inner Jovian magnetosphere.

Paonessa, Mark T.↗

The effect of hydrogen on deformation substructure, flow and fracture in a nickel-base single crystal superalloy

The room temperature flow and fracture of a nickel-base single crystal gamma/gamma-/prime superalloy in the presence and absence of hydrogen is explored. The procedure of hydrogen-charging employed in this study provides a very high and uniform hydrogen concentration of the order of 5000 at.-ppm in the material. It is shown that the most compelling hydrogen-induced changes in deformation behavior are enhanced dislocation accumulation in the gamma matrix and extensive cross-slip of super-dislocations. The explanation of these changes is proposed. Both effects contribute to the increase of flow stress and the notable work hardening that occurs prior to fracture. Hydrogen enhanced strain localization in the gamma matrix leads to the dramatic loss of ductility and premature cracking, which manifests as failure macroscopically parallel to the 100-plane-oriented faces of gamma-prime precipitates. On the microscale, cracking, while limited to the gamma matrix, occurs parallel to multiple 111-plane-oriented slip systems.

Dollar, M.↗

Optical rate sensor algorithms

Optical sensors, in particular Charge Coupled Device (CCD) arrays, will be used on Space Station to track stars in order to provide inertial attitude reference. Algorithms are presented to derive attitude rate from the optical sensors. The first algorithm is a recursive differentiator. A variance reduction factor (VRF) of 0.0228 was achieved with a rise time of 10 samples. A VRF of 0.2522 gives a rise time of 4 samples. The second algorithm is based on the direct manipulation of the pixel intensity outputs of the sensor. In 1-dimensional simulations, the derived rate was with 0.07 percent of the actual rate in the presence of additive Gaussian noise with a signal to noise ratio of 60 dB.

Uhde-Lacovara, Jo A.↗

Radiation Effects on Advanced Flash Memories

Flash memories have evolved very rapidly in recent ears. New design techniques such as multilevel storage have been proposed to increase storage density, and are now available commercially. Threshold voltage distributions for single- and three-level technologies are compared. In order to implement this technology special circuitry must be added to allow the amount of charge stored in the floating gate to be controlled within narrow limits during the writing and also to detect the different amounts of charge during reading.

Nguyen, D. N.↗

Effect of Single-Electron Interface Trapping in Decanano MOSFETs: A 3D Atomistic Simulation Study

We study the effect of trapping/detrapping of a single-electron in interface states in the channel of n-type MOSFETs with decanano dimensions using 3D atomistic simulation techniques. In order to highlight the basic dependencies, the simulations are carried out initially assuming continuous doping charge, and discrete localized charge only for the trapped electron. The dependence of the random telegraph signal (RTS) amplitudes on the device dimensions and on the position of the trapped charge in the channel are studied in detail. Later, in full-scale, atomistic simulations assuming discrete charge for both randomly placed dopants and the trapped electron, we highlight the importance of current percolation and of traps with strategic position where the trapped electron blocks a dominant current path.

Asenov, Asen↗

Characterization of a 2-mm thick, 16x16 Cadmium-Zinc-Telluride Pixel Array

The detector under study is a 2-mm-thick, 16x16 Cadmium-Zinc-Telluride pixel array with a pixel pitch of 300 microns and inter-pixel gap of 50 microns. This detector is a precursor to that which will be used at the focal plane of the High Energy Replicated Optics (HERO) telescope currently being developed at Marshall Space Flight Center. With a telescope focal length of 6 meters, the detector needs to have a spatial resolution of around 200 microns in order to take full advantage of the HERO angular resolution. We discuss to what degree charge sharing will degrade energy resolution but will improve our spatial resolution through position interpolation. In addition, we discuss electric field modeling for this specific detector geometry and the role this mapping will play in terms of charge sharing and charge loss in the detector.

Gaskin, Jessica↗

Compton Polarimetry for Neutral Weak Form Factor Measurements in 208Pb and 48Ca

Atomic nuclei contain a number of protons and neutrons. Most heavy nuclei contain more neutrons than protons in order to remain stable. The nuclear proton distribution can be measured via elastic scattering of charged particles, but the neutron distribution remains poorly constrained. Nuclear structure theory also predicts a "neutron skin" ?Rnp where the mean radii of neutrons in the nucleus exceeds that of protons. Two experiments were run in 2019 and 2020 to measure the neutron skin in two different nuclei. The first experiment, PREX-II, was designed to measure the neutron skin in 208Pb, while the second experiment, CREX, was designed to measure the neutron skin in 48Ca. Both experiments employed the parity-violating electron scattering (PVES) technique in which longitudinally spin-polarized electrons are scattered off an unpolarized target.

Zec, Allison↗

Observations of thermal ion influxes about the space shuttle

Ion mass spectrometer measurements made as part of the University of Iowa's Plasma Diagnostic Package on the STS-3 and Spacelab 2 Space Shuttle missions sampled a variety of ion composition and collected ion current responses to gas emissions from the vehicle. The only other shuttle ion measurements were made by an Air Force Geophysics Laboratory (AFGL) quadrupole spectrometer flown on STS-4. Gas emissions change the distribution of the incoming plasma through scattering and charge transfer processes. A background flux of contaminant ion species (mostly relating to water) always exists in the near vicinity of the shuttle with a magnitude which is dependent on the look direction of the spectrometer but which varies differently with changes in the angle of attack than that of the ambient ions. There is a near shuttle wake cavity in the contaminant ion distributions which has a different spatial configuration than the wake of the ambient ions. Although water dumps produce the most persistent ion perturbations, the sources for ion current modification were best delineated from measurements made when only one or two of the Reaction Control System thrusters fired for a relatively long duration. Contaminant ion perturbations associated with such firings were observed to persist for the order of a second after the cessation of the firings. The dense thruster plumes are efficient collisional, charge exchange barriers to the passage of ambient ions. Collected ion current perturbations were more evident for firings of the rear verniers, whose plumes scatter off projecting surfaces, than for the nose thrusters. The effect of the Vernier firings was found to depend not only on the location and attitude of the spectrometer with respect to the shuttle and thruster plume direction, but also on the orientation of the local magnetic field with respect to the shuttle velocity.

Grebowsky, Joe M.↗

First Global Extraction of Generalized Parton Distributions from Experiment and Lattice Data with Next-to-Leading-Order Accuracy

We report the first global extraction of generalized parton distributions, GUMP 1.0, by combining deeply virtual Compton scattering and 𝜌-meson production data from Jefferson Lab and the Hadron-Electron Ring Accelerator with global fits of parton distribution functions, charge form factors, and lattice quantum chromodynamics simulations. Using a conformal moment space parametrization, we achieve a unified description across low- and high-𝑥 regions at next to leading order accuracy in perturbative corrections. The results provide state-of-the-art generalized parton distributions consistent with almost all known facts, enabling three-dimensional nucleon imaging in impact parameter space and, at the same time, establishing a benchmark for future theoretical and experimental studies of the nucleon structure.

Form factors↗

A new platform for development of photosystem I based thin films with superior photocurrent: TCNQ charge transfer salts derived from ZIF-8

The transmembrane photosynthetic protein complex Photosystem I (PSI) is highly sought after for incorporation into biohybrid photovoltaic devices due to its remarkable photoactive electrochemical properties, chiefly driving charge separation with ~1 V potential and ~100% quantum efficiency. In pursuit of these integrated technologies, three factors must be simultaneously tuned, namely, direct redox transfer steps, three-dimensional coordination and stabilization of PSI aggregates, and interfacial connectivity with conductive pathways. Building on our recent successful encapsulation of PSI in the metal–organic framework ZIF-8, herein we use the zinc and imidazole cations from this precursor to form charge transfer complexes with an extremely strong organic electron acceptor, TCNQ. Specifically, the PSI-Zn-H 2 mim-TCNQ charge transfer salt complex was drop cast on ITO to form dense films. Subsequent voltammetric cycling induced cation exchange and electrochemical annealing of the film was used to enhance electron conductivity giving rise to a photocurrent in the order of 15 μA cm -2 . This study paves the way for a myriad of future opportunities for successful integration of this unique class of charge transfer salt complexes with biological catalysts and light harvesters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Polymer Coatings on Virus-like Particle Nanoreactors at Low Ionic Strength—Charge Reversal and Substrate Access

Virus-like particles (VLPs) are a class of biomaterials which serve as platforms for achieving the desired functionality through interior and exterior modifications. Through ionic strength-mediated electrostatic interactions, VLPs have been assembled into hierarchically ordered materials. This work builds on predictive models to prepare polymer-coated VLP dusters at very low ionic strength. Zeta potential measurements showed that the clusters carried a strongly positive charge, a complete charge reversal from the VLP building block. SAXS analysis confirmed polymer adsorption onto the VLP exterior. Furthermore, we then studied the activity of an encapsulated enzyme toward small molecular and macromolecular substrates to determine the effect of each component of the hierarchically assembled material. We found that while encapsulation and polymer coating did not have a large effect on access to the enzyme by its native, small molecular substrate, substrate modification with a macromolecule caused the polymer coating and encapsulation to affect the access to the enzyme.

59 BASIC BIOLOGICAL SCIENCES↗

Thermal modeling of a Ni-H2 battery cell

The nickel-hydrogen secondary battery has many desirable features which make it attractive for satellite power systems. It can provide a significant improvement over the energy density of present spacecraft nickel-cadnium batteries, combined with longer life, tolerance to overcharge and possibility of state-of-charge indication. However, to realize these advantages, accurate thermal modeling of nickel-hydrogen cells is required in order to properly design the battery pack so that it operates within a specified temperature range during the operation. Maintenance of a low operating temperature and a uniform temperature profile within the cell will yield better reliability, improved cycle life and better charge/discharge efficiencies. This research has the objective of developing and testing a thermal model which can be used to characterize battery operation. Primarily, temperature distribution with the heat generation rates as a function of position and time will be evaluated for a Ni-H2 cell in the three operating modes: (1) charge cycle, (2) discharge cycle, and (3) overcharge condition, if applicable. Variables to be examined include charging current, discharge rates, state of charge, pressure and temperature. Once the thermal model has been developed, this resulting model will predict the actual operating temperature and temperature gradient for the specific cell geometry to be used.

Ryu, Si-Ok↗

Discrete breakup arcs and kinetic Alfven waves

Attention is confined to the extremely narrow auroral structures whose characteristic dimensions perpendicular to the magnetic fields are of the order of several hundred meters or even less. The starting point of the model used here is the assumption that discrete breakup arcs are caused by a change in the magnetosphere convection pattern that is localized in space. Particular attention is given to the shear Alfven mode. It is proposed that discrete breakup arcs are a direct manifestation of kinetic interaction between charged particles and an 'mhd' perturbation. It is stressed that the model applies only to narrow structures (thickness of the order of the plasma skin depth) and to short-lived phenomena (time scales shorter than a dispersion time). It is shown that a change of convection pattern in a spatially limited region leads to the emission of a shear-Alfven wave packet which propagates along the magnetic field line with a characteristic velocity.

Goertz, C. K.↗

Atomic-Scale Structure and Catalysis on Positively Charged Bimetallic Sites for Generation of H 2

In this paper, we report that a cationic bimetallic site consisting of one Pd and three Zn atoms (Pd 1 Zn 3 ) supported on ZnO (Pd 1 Zn 3 /ZnO) exhibits an extraordinarily high catalytic activity for the generation of H 2 through methanol partial oxidation (MPO) that is 2–3 orders of magnitude higher than that of a metallic Pd–Zn site on Pd–Zn nanoalloy (Pd–Zn/ZnO). Computational studies uncovered that the positively charged Pd atom of the subnanometer Pd 1 Zn 3 bimetallic site largely decreases the activation barrier for dehydrogenation of methanol as compared to a metallic Pd atom of Pd–Zn alloy, thus switching the rate-determining step of MPO from methanol dehydrogenation over a Pd–Zn alloy with high barrier to the O 2 dissociation step on a cationic Pd 1 Zn 3 site with a low barrier, which is supported by our kinetics studies. The significantly higher catalytic activity and selectivity for H 2 production over a cationic bimetallic site suggest a new approach to design bimetallic catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗