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At least 1,207 records · Page 67

Tuning magnetism and band topology through antisite defects in Sb-doped MnBi 4 ⁢Te 7

The fine control of magnetism and electronic structure in a magnetic topological insulator is crucial in order to realize various novel magnetic topological states including axion insulators, magnetic Weyl semimetals, Chern insulators, etc. Through crystal growth, transport, thermodynamic, neutron diffraction measurements, we show that under Sb doping the newly discovered intrinsic antiferromagnetic (AFM) topological insulator MnBi 4 Te 7 evolves from AFM to ferromagnetic (FM) and then ferrimagnetic. We attribute this to the formation of Mn(Bi,Sb) antisites upon doping, which results in additional Mn sublattices that modify the delicate interlayer magnetic interactions and cause the dominant Mn sublattice to go from AFM to FM. We further investigate the effect of antisites on the band topology using the first-principles calculations. Without considering antisites, the series evolves from AFM topological insulator (x=0) to FM axion insulators. In the exaggerated case of 16.7% of periodic antisites, the band topology is modified and a type-I magnetic Weyl semimetal phase can be realized at intermediate dopings. Therefore, this doping series provides a fruitful platform with continuously tunable magnetism and topology for investigating emergent phenomena, including quantum anomalous Hall effect, Fermi arc states, etc.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Thermodynamic stability and contributions to the Gibbs free energy of nanocrystalline Ni 3 Fe

In this work, the heat capacities of nanocrystalline Ni 3 Fe and control materials with larger crystallites were measured from 0.4–300 K. The heat capacities were integrated to obtain the enthalpy, entropy, and Gibbs free energy and to quantify how these thermodynamic functions are altered by nanocrystallinity. From the phonon density of states (DOS) measured by inelastic neutron scattering, we find that the Gibbs free energy is dominated by phonons and that the larger heat capacity of the nanomaterial below 100 K is attributable to its enhanced phonon DOS at low energies. Besides electronic and magnetic contributions, the nanocrystalline material has an additional contribution at higher temperatures, consistent with phonon anharmonicity. The nanocrystalline material shows a stronger increase with temperature of both the enthalpy and entropy compared to the bulk sample. Its entropy exceeds that of the bulk material by 0.4 $k_B$/atom at 300 K. This is insufficient to overcome the enthalpy of grain boundaries and defects in the nanocrystalline material, making it thermodynamically unstable with respect to the bulk control material.

36 MATERIALS SCIENCE↗

Low Thermal Resistance (0.5 K/W) Ga 2 O 3 Schottky Rectifiers With Double-Side Packaging

The low thermal conductivity of Ga 2 O 3 has arguably been the most serious concern for Ga 2 O 3 power and RF devices. Despite many simulation studies, there is no experimental report on the thermal resistance of a large-area, packaged Ga 2 O 3 device. This work fills this gap by demonstrating a 15-A double-side packaged Ga 2 O 3 Schottky barrier diode (SBD) and measuring its junction-to-case thermal resistance (R θJC ) in the bottom-side- and junction-side-cooling configurations. The R θJC characterization is based on the transient dual interface method, i.e., JEDEC 51-14 standard. The R θJC of the junction- and bottom-cooled Ga 2 O 3 SBD was measured to be 0.5 K/W and 1.43 K/W, respectively, with the former R θJC lower than that of similarly-rated commercial SiC SBDs. This low R θJC is attributable to the heat extraction directly from the Schottky junction instead of through the Ga 2 O 3 chip. Here, the R θJC lower than that of commercial SiC devices proves the viability of Ga 2 O 3 devices for high-power applications and manifest the significance of proper packaging for their thermal management.

42 ENGINEERING↗

Endogenous Retroviral Elements Generate Pathologic Neutrophils in Pulmonary Arterial Hypertension

Rationale: The role of neutrophils and their extracellular vesicles (EVs) in the pathogenesis of pulmonary arterial hypertension is unclear. Objectives: To relate functional abnormalities in pulmonary arterial hypertension neutrophils and their EVs to mechanisms uncovered by proteomic and transcriptomic profiling. Methods: Production of elastase, release of extracellular traps, adhesion, and migration were assessed in neutrophils from patients with pulmonary arterial hypertension and control subjects. Proteomic analyses were applied to explain functional perturbations, and transcriptomic data were used to find underlying mechanisms. CD66b-specific neutrophil EVs were isolated from plasma of patients with pulmonary arterial hypertension, and we determined whether they produce pulmonary hypertension in mice. Measurements and Main Results: Neutrophils from patients with pulmonary arterial hypertension produce and release increased neutrophil elastase, associated with enhanced extracellular traps. They exhibit reduced migration and increased adhesion attributed to elevated β1-integrin and vinculin identified by proteomic analysis and previously linked to an antiviral response. This was substantiated by a transcriptomic IFN signature that we related to an increase in human endogenous retrovirus K envelope protein. Transfection of human endogenous retrovirus K envelope in a neutrophil cell line (HL-60) increases neutrophil elastase and IFN genes, whereas vinculin is increased by human endogenous retrovirus K deoxyuridine triphosphate diphosphatase that is elevated in patient plasma. Neutrophil EVs from patient plasma contain increased neutrophil elastase and human endogenous retrovirus K envelope and induce pulmonary hypertension in mice, mitigated by elafin, an elastase inhibitor. Conclusions: Elevated human endogenous retroviral elements and elastase link a neutrophil innate immune response to pulmonary arterial hypertension.

60 APPLIED LIFE SCIENCES↗

Calibration and validation of the foundation for a multiphase strength model for tin

In this work, the Common Model of Multi-phase Strength and Equation of State (CMMP) model was applied to tin. Specifically, calibrations of the strength-specific elements of the CMMP foundation were developed with a combination of experiments and theory, and then the model was validated experimentally. The first element of the foundation is a 10 multi-phase analytic treatment of the melt temperature and the shear modulus for the solid phases. These models were parameterized for each phase based on ab initio calculations using the software VASP (Vienna Ab initio Simulations Package) based on density functional theory (DFT). The shear modulus model for the ambient β phase was validated with ultrasonic sound speed measurements as a function of pressure and temperature. The second element of the foundation is a viscoplastic strength model for the β phase, upon which strength for inaccessible higher-pressure phases can be scaled as necessary. The stress-strain response of tin was measured at strain rates of 10 -3 to 3 x 10 3 s -1 and temperatures ranging from 87 to 373 K. The Preston-Tonks-Wallace (PTW) strength model was fit to that data using Bayesian model calibration. For validation, six forward and two reverse Taylor impact experiments were performed at different velocities to measure large plastic deformation of tin at strain rates up to 10 5 s -1 . The PTW model accurately predicted the deformed shapes of the cylinders, with modest discrepancies attributed to the inability 20 of PTW to capture the effects of twinning and dynamic recrystallization. Some material in the simulations of higher velocity Taylor cylinders reached the melting temperature, thus testing the multiphase model because of the presence of a second phase, the liquid. In simulations using a traditional modeling approach, the abrupt reduction of strength upon melt resulted in poor predictions of the deformed shape and non-physical temperatures. With CMMP, the most deformed material points evolved gradually to a mixed solid-liquid but never fully liquid state, never fully lost strength, 25 stayed at the melt temperature as the latent heat of fusion was absorbed, and predicted the deformed shape well.

36 MATERIALS SCIENCE↗

Low level moisture from VAS

Previous research and current opinion are too pessimistic concerning the capability of defining moisture fields from satellite measurements. The TIROS-N sounder is a close analogue to what will fly on GEOS-D and can be used to investigate the probable capability of VAS. Basically, there are three frequencies applied to sensing moisture in the troposphere. The ability of these three measurements to define the moisture pattern is assessed. It is certainly true that one cannot achieve the detail available with a radiosonde hygristor. Sharp discontinuities cannot be sensed by a passive sounder, especially since the measurement tends to "saturate" with the first moisture layer encountered. However, the satellite measurements demonstrate a high degree of skill in defining the horizontal gradient. Moisture "tongues" and "dry lines" are readily delineated with some, perhaps two layers, of vertical definition. These attributes allow both the calculation of important advective quantities as well as (in concert with the temperature sounding) a gross definition of the vertical stability. The skill is demonstrably commensurate with subsynoptic forecast models and perhaps even to regional scale models.

Hayden, C. M.↗

Intraband optical conductivity sigma/omega,T/ of Cu, Ag, and Au - Contribution from electron-electron scattering

The frequency and temperature dependence of the intraband optical conductivity of the noble metals Cu, Ag and Au is measured and contributions of electron-electron scattering are assessed. Optical measurements were performed at temperatures of 77, 295 and 425 K to obtain values of the Drude electron scattering rate with a linear dependence on temperature which may be attributed to electron-phonon scattering, and a quadratic dependence on photon energy, which is suggestive of electron-electron scattering but is a factor of two to three times greater than would be expected. Comparison of the optical data with dc electrical and thermal resistivity data which also show behavior attributed to electron-electron scattering reveals discrepancies of up to an order of magnitude. Other possible mechanisms for the frequency dependence, including absorptance, electron-surface plasmon interactions, a two-carrier model, and a structure dependence are considered, and it is concluded that the frequency dependence in the Drude scattering rates of the noble metals is not yet quantitatively understood

Parkins, G. R.↗

Far-infrared reflectance spectra of optical black coatings

Far-infrared specular reflectance spectra of six optically black coatings near normal incidence are presented. The spectra were obtained using nine bandpass transmission filters in the wavelength range between 12 and 300 microns. Data on the construction, thickness, and rms surface roughness of the coatings are also presented. The chemical composition of two coatings can be distinguished from that of the others by a strong absorption feature between 20 and 40 microns which is attributed to amorphous silicate material. Inverse relationships between these spectra and coating roughness and thickness are noted and lead to development of a reflecting-layer model for the measured reflectance. The model is applied to the spectra of several coatings whose construction falls within its constraints.

Smith, S. M.↗

Propagation and secondary production of low energy antiprotons in the atmosphere

Current theories, in which the observed antiproton component is attributed strictly to secondary production in high energy inelastic collisions of protons with the interstellar medium or the atmosphere, apparently fail to explain the relatively high p vertical intensities measured at mountain and balloon altitudes. Therefore, a more careful calculation of the theoretical secondary intensity spectra is required before more exotic sources for these excess p's can be explored. A one dimensional diffusion equation is used to calculate the expected vertical intensity of p's due only to secondary production in the atmosphere; any assumed primary p spectrum is also included. Two adjustable parameters, the inelasticity and charge exchange in nucleon-nucleus collisions, were included in the algorithm. In order to obtain an independent estimate of their values the proton vertical intensities in the atmosphere were calculated, adjusting the parameters until the curves fit the experimental proton data, and then assumed that these values were identical in antinucleon-nucleus collisions.

Bowen, T.↗

Far-infrared intensity variations caused by 5 minute oscillations

Observations of solar IR intensity variations at 50, 100, and 200 microns were made simultaneously and cospatially with Doppler measurements in the sodium D1 line at 5896 A. Brightness temperature variations of several K in amplitude are highly correlated with five minute Doppler oscillations. The brightness variations are attributed to work done on the chromospheric medium by compression, driven by the five minute oscillations. The Doppler oscillations lead the brightness variations by about 47 deg in phase at 50 and 100 microns and by about 72 deg in phase at 200 microns.

Lindsey, C.↗

On the influence of the magnetization of a modal solar wind on a laboratory magnetosphere

The interaction of a magnetized plasma beam with a stationary dipole field, analogous to the interaction of the solar wind with the earth's magnetosphere, is explored in a laboratory experiment. Experimental parameters are chosen to scale qualitatively similar to the parameters in the earth's magnetosphere. It is found that the magnetization of the laboratory 'solar wind', generated by injecting a plasma across a preexisting magnetic field, requires a certain minimum magnetic field strength. Differences between the resulting magnetospheres for northward and southward 'solar wind' or 'interplanetary' magnetic fields (IMF) are demonstrated by global pictures and by magnetic field measurements above the north polar region. These measurements show patterns of the variation of the transverse field component which are similar to those found by satellite measurements above the earth. This indicates the presence of similar field-aligned current systems. Particularly, the presence (for northward IMF) and absence (for southward IMF) of the pattern attributed to the 'NBZ' (northward Bz) current system are demonstrated.

Rahman, H. U.↗

Measuring uncertainty by extracting fuzzy rules using rough sets

Despite the advancements in the computer industry in the past 30 years, there is still one major deficiency. Computers are not designed to handle terms where uncertainty is present. To deal with uncertainty, techniques other than classical logic must be developed. The methods are examined of statistical analysis, the Dempster-Shafer theory, rough set theory, and fuzzy set theory to solve this problem. The fundamentals of these theories are combined to possibly provide the optimal solution. By incorporating principles from these theories, a decision making process may be simulated by extracting two sets of fuzzy rules: certain rules and possible rules. From these rules a corresponding measure of how much these rules is believed is constructed. From this, the idea of how much a fuzzy diagnosis is definable in terms of a set of fuzzy attributes is studied.

Worm, Jeffrey A.↗

Planetary Radar Astronomy

Radar is a powerful technique that has furnished otherwise unavailable information about solar system bodies for three decades. The advantages of radar in planetary astronomy result from: (1) the observer's control of all the attributes of the coherent signal used to illuminate the target, especially the wave form's time/frequency modulation and polarization; (2) the ability of radar to resolve objects spatially via measurements of the distribution of echo power in time delay and Doppler frequency; (3) the pronounced degree to which delay-Doppler measurements constrain orbits and spin vectors; and (4) centimeter-to-meter wavelengths, which easily penetrate optically opaque planetary clouds and cometary comae, permit investigation of near-surface macrostructure and bulk density, and are sensitive to high concentrations of metal or, in certain situations, ice. Planetary radar astronomy has primarily involved observations with Earth-based radar telescopes, but also includes some experiments with a spaceborne transmitter or receiver. In addition to providing a wealth of information about the geological and dynamical properties of asteroids, comets, the inner planets, and natural satellites, radar experiments have established the scale of the solar system, have contributed significantly to the accuracy of planetary ephemerides, and have helped to constrain theories of gravitation. This review outlines radar astronomical techniques and describes principal observational results.

Ostro, Steven J.↗

Stimulus information contaminates summation tests of independent neural representations of features

Many models of visual processing assume that visual information is analyzed into separable and independent neural codes, or features. A common psychophysical test of independent features is known as a summation study, which measures performance in a detection, discrimination, or visual search task as the number of proposed features increases. Improvement in human performance with increasing number of available features is typically attributed to the summation, or combination, of information across independent neural coding of the features. In many instances, however, increasing the number of available features also increases the stimulus information in the task, as assessed by an optimal observer that does not include the independent neural codes. In a visual search task with spatial frequency and orientation as the component features, a particular set of stimuli were chosen so that all searches had equivalent stimulus information, regardless of the number of features. In this case, human performance did not improve with increasing number of features, implying that the improvement observed with additional features may be due to stimulus information and not the combination across independent features.

NASA Discipline Space Human Factors↗

Pickup Protons: Comparisons using the Three-Dimensional MHD HHMS-PI model and Ulysses SWICS Measurements

We report the first comparisons of pickup proton simulation results with in situ measurements of pickup protons obtained by the SWICS instrument on Ulysses. Simulations were run using the three dimensional (3D) time-dependent Hybrid Heliospheric Modeling System with Pickup Protons (HHMS-PI). HHMS-PI is an MHD solar wind model, expanded to include the basic physics of pickup protons from neutral hydrogen that drifts into the heliosphere from the local interstellar medium. We use the same model and input data developed by Detman et al. (2011) to now investigate the pickup protons. The simulated interval of 82 days in 2003 2004, includes both quiet solar wind (SW) and also the October November 2003 solar events (the Halloween 2003 solar storms). The HHMS-PI pickup proton simulations generally agree with the SWICS measurements and the HHMS-PI simulated solar wind generally agrees with SWOOPS (also on Ulysses) measurements. Many specific features in the observations are well represented by the model. We simulated twenty specific solar events associated with the Halloween 2003 storm. We give the specific values of the solar input parameters for the HHMS-PI simulations that provide the best combined agreement in the times of arrival of the solar-generated shocks at both ACE and Ulysses. We show graphical comparisons of simulated and observed parameters, and we give quantitative measures of the agreement of simulated with observed parameters. We suggest that some of the variations in the pickup proton density during the Halloween 2003 solar events may be attributed to depletion of the inflowing local interstellar medium (LISM) neutral hydrogen (H) caused by its increased conversion to pickup protons in the immediately preceding shock.

Intriligator, Devrie S.↗

Nuclear Waste Tank Emission Contributions to Particle Size Distribution

Pollutants from anthropogenic activities including industrial processes are ubiquitous to the environment. To understand the impact from industrial aerosol on climate and human health, industrial aerosol needs to be better characterized. Here, in this study, particle number concentrations were used as a proxy for atmospheric pollutants, which include both particles and gases. Particle concentration and size distribution were measured using a scanning mobility particle sizer (SMPS) approximately 4.5 km from primary industrial areas at the Savannah River Site in Aiken, SC. Industrial areas include numerous nuclear waste storage and processing tanks. The SMPS data were divided into two groups depending on the wind direction measured onsite to categorize transport from the industrial area or from elsewhere. Industrial contributions were found to have a higher concentration of particles with sizes less than 200 nm, 859 ± 564 cm -3 , in comparison to non-industrial attributed particles, 733 ± 495 cm -3 on average from March-July 2021. For sizes larger than 200 nm, industrial and non-industrial particles have a similar concentration, 89 ± 59 cm -3 and 99 ± 61 cm -3 , with non-industrial concentrations being slightly larger. To confirm that industrial particles could travel to the sampling location, air dispersion modeling was completed for specific case studies during the sampling period. The atmospheric dispersion modeling results confirmed that particles released at the industrial areas reached the sampling location when the wind direction was favorable for transport from the industrial areas. The greater concentration of smaller-sized particles in industrial emissions has implications for typical particulate measurements (PM2.5), heath impacts, and climatological influences.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Improving the PMU Standard

The Phasor Measurement Unit (PMU) is perhaps the first representational measurement widely dispersed in the electric power system. Its usefulness has been demonstrated on many occasions. It is shown in this paper that the excellent performance of the PMU is a tribute to PMU makers, and not attributable to the standards that are supposed to specify the performance. The IEEE and IEC standards illustrate, by means of a “reference model,” how a PMU can be made. Both standards base the model on two fundamental conceptual errors. Without these errors several improvements in performance could be made. The standards should be revised to remove the restrictive “guidance” that the reference model presently offers, and to correct the text so that the appropriate concepts are presented.

Phasor Measurement, reference model↗

Sensor Technologies for Particulate Detection and Characterization

Planned Lunar missions have resulted in renewed attention to problems attributable to fine particulates. While the difficulties experienced during the sequence of Apollo missions did not prove critical in all cases, the comparatively long duration of impending missions may present a different situation. This situation creates the need for a spectrum of particulate sensing technologies. From a fundamental perspective, an improved understanding of the properties of the dust fraction is required. Described here is laboratory-based reference instrumentation for the measurement of fundamental particle size distribution (PSD) functions from 2.5 nanometers to 20 micrometers. Concomitant efforts for separating samples into fractional size bins are also presented. A requirement also exists for developing mission compatible sensors. Examples include provisions for air quality monitoring in spacecraft and remote habitation modules. Required sensor attributes such as low mass, volume, and power consumption, autonomy of operation, and extended reliability cannot be accommodated by existing technologies.

Greenberg, Paul S.↗