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At least 1,207 records · Page 67
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NASA NTRS1982

Impact cratering experiments in Bingham materials and the morphology of craters on Mars and Ganymede

Results from a series of laboratory impacts into clay slurry targets are compared with photographs of impact craters on Mars and Ganymede. The interior and ejecta lobe morphology of rampart-type craters, as well as the progression of crater forms seen with increasing diameter on both Mars and Ganymede, are equalitatively explained by a model for impact into Bingham materials. For increasing impact energies and constant target rheology, laboratory craters exhibit a morphologic progression from bowl-shaped forms that are typical of dry planetary surfaces to craters with ejecta flow lobes and decreasing interior relief, characteristic of more volatile-rich planets. A similar sequence is seen for uniform impact energy in slurries of decreasing yield strength. The planetary progressions are explained by assuming that volatile-rich or icy planetary surfaces behave locally in the same way as Bingham materials and produce ejecta slurries with yield strenghs and viscosities comparable to terrestrial debris flows. Hypothetical impact into Mars and Ganymede are compared, and it is concluded that less ejecta would be produced on Ganymede owing to its lower gravitational acceleration, surface temperature, and density of surface materials.

Fink, J. H.↗
NASA NTRS1982

Sources of atmospheric ammonia

The information available on factors that influence emissions from the principal societal sources of ammonia to the atmosphere, namely combustion processes, volatilization of farm animal wastes, and volatilization of fertilizers, is reviewed. Emission factors are established for each major source of atmospheric ammonia. The factors are then multiplied by appropriate source characterization descriptors to obtain calculated fluxes of ammonia to the atmosphere on a state-by-state basis for the United States.

Harriss, R. C.↗
NASA NTRS1982

Airborne aerosol measurements in the quiescent plume of Mount Saint Helens September, 1980

A study of the emissions from the Mt. St. Helens volcano was conducted to obtain data for an assessment of the importance of volcanoes as a global source of volatile trace elements to the atmosphere and to the global biochemical cycles of these elements. Sampling was done on board an Orion P-3 turboprop aircraft modified for tropospheric aerosol and gas sampling. Two filter collection systems were used. Samples were collected on a single flight on September 22, 1980, at which time the volcano was emitting a stable plume to an altitude of between 2 and 3 km. The results regarding the concentrations of aerosols obtained for this mission are presented in a table. Attention is also given to data concerning particulate vs. gas phase sulfur in the Mt. Saint Helens plume, and the estimated volcanic particle flux of selected volatile elements.

Phelan, J. M.↗
NASA NTRS1982

Dustsonde measurements of the Mount St. Helens volcanic dust cloud over Wyoming

Numerous balloon soundings of the aerosol and condensation nuclei (CN) concentrations were made over Laramie, Wyoming following the eruption of Mount St. Helens in May of 1980. On several occasions the volatility of the particles was tested. In addition, special instrumentation was used to observe the evolution of particle size after the eruption. The particles in the initial cloud were relatively large and nonvolatile. In a relatively short time, however, the aerosol began showing a dominant volatile component. Although there were probably no CN in the original cloud due to the expected very short coagulation life time, high concentrations of unusually small CN particles were observed about a month after the eruption. By the end of September the CN profiles and associated particle size were practically back to normal. At present the aerosol particles show about a three times larger concentration than before the eruption, most of the new material being in a layer centered around 19 km. The net effect of the more recent series of eruptions during the last half of October 1980 seems to be negligible.

Rosen, J. M.↗
NASA NTRS1982

A CO2-rich coma model applied to the neutral coma of Comet West

Models of the cometary coma in which the dominant volatile is CO2 have been constructed for a range of heliocentric distances. Model coma abundances of C2, C3, and CN are compared with the abundances observed in Comet West and are found to be in good agreement. Furthermore, the variation with heliocentric distance of C2, C3, and CN model abundances agree well with the observed variation in Comet West. The present work lends detailed support to a previous suggestion that a substance more volatile than water, such as CO2, controls the evaporation of the nucleus of Comet West. The implications for cometary formation are briefly discussed.

Mitchell, G. F.↗
NASA NTRS1982

Chemical composition of cometary nuclei

Observational evidence pertaining to the origin and composition of cometary material is reviewed. Arguments favoring the undifferentiated character of the icy conglomerate are summarized. Theoretical descriptions of the sublimation of a cometary nucleus and the velocity field of the expanding gas are presented and compared with observations. The nature of cometary dust and the atomic abundances of H, C, N, O, and S in the volatile fraction are examined, and data on the dust and volatile fractions are combined to derive elemental abundances. It is shown that O, N, and S in cometary nuclei appear to have essentially cosmic abundances but that both H and C are drastically depleted with respect to the cosmic abundances. The apparent depletion of C by a factor of more than three is discussed. It is suggested that the missing carbon might be hidden in the dust fraction in the form of heavy organic molecules or might have remained in either the primeval solar nebula or interstellar space.

Delsemme, A. H.↗
NASA NTRS1982

Observations of the red auroral oxygen lines in nine comets

The digital sky-subtracted spectra of nine cometary nuclei are used to measure the 6300, 6363-A Auroral red doublet of the O I forbidden line, and in view of the confinement of the cometary oxygen lines to their nuclear source, a small but variable correction for NH2 blending in different comets is made. For seven of the comets measured, and under the assumption of H2O's exclusive role as the oxygen parent, the average Q(H2O)/Q(O I) ratio is about 20. This is in excellent accord with theory, and it is conjectured that the O I production rate can be used to scale the total cometary volatile loss in even faint, distant comets. The data obtained are consistent with heliocentric production rates that vary as power laws, with n values of 2.0 for 'gassy' comets and nearer to 5.0 for dusty ones. The comets with the greatest volatile mass-loss rates all were found to have dusty spectra.

Spinrad, H.↗
NASA NTRS1982

Magma vesiculation and pyroclastic volcanism on Venus

Theoretical consideration of the magma vesiculation process under observed and inferred venusian surface conditions suggests that vesicles should form in basaltic melts, especially if CO2 is the primary magmatic volatile. However, the high surface atmospheric pressure (about 90 bars) and density on Venus retard bubble coalescence and disruption sufficiently to make explosive volcanism unlikely. The products of explosive volcanism (fire fountains, convecting eruption clouds, pyroclastic flows, and topography-mantling deposits of ash, spatter, and scoria) should be rare on Venus, and effusive eruptions should dominate. The volume fraction of vesicles in basaltic rocks on Venus are predicted to be less than in chemically similar rocks on earth. Detection of pyroclastic landforms or eruption products on Venus would indicate either abnormally high volatile contents of Venus magmas (2.5-4 wt%) or different environmental conditions (e.g., lower atmospheric pressure) in previous geologic history.

Garvin, J. B.↗
NASA NTRS1983

Ice in Comet Bowell

Results of observations of the reflected light in the 1-5 micron region of the spectrum from the Comet Bowell are presented as part of the attempt to directly detect the presence of frozen volatiles in the nucleus of a comet. A deep absorption at 3.25 microns is detected in Comet Bowell which is due to the presence of H2O ice. While other volatile ices have absorption features near 3 microns, it is shown that only H2O ice is a plausible identification at the heliocentric distance of Comet Bowell during the observations (3.4 AU) since only H2O grains are stable enough to have produced the observed absorption. The implications of these findings for models of cometary nuclei are examined.

Campins, H.↗
NASA NTRS1983

Vapor flow into a capillary propellant-acquisition device

An analytical model is described that specifies the conditions needed to cause a flow of vapor through the screens of a start basket. The analytical model is composed of several original submodels that interrelate the evaporation of the liquid in the basket, the bubble-point change of a screen in the presence of wicking, the drying out of a screen through a combination of evaporation and pressure difference, the vapor flow rate across a wet screen as a function of pressure difference, and the effect on wicking of a difference between the static pressure of the liquid reservoir and the vapor surrounding the screen. Most of the interrelations were demonstrated by a series of separate-effects tests, which were also used to determine certain empirical constants. The equations of the model were solved numerically for typical start basket designs. A simplified start basket was constructed and tested to verify these predictions, using both volatile and non-volatile liquids. The test results verified the trends predicted by the model.

Dodge, F. T.↗
NASA NTRS1984

Supercritical solvent coal extraction

Yields of soluble organic extract are increased up to about 50% by the supercritical extraction of particulate coal at a temperature below the polymerization temperature for coal extract fragments (450 C.) and a pressure from 500 psig to 5,000 psig by the conjoint use of a solvent mixture containing a low volatility, high critical temperature coal dissolution catalyst such as phenanthrene and a high volatility, low critical temperature solvent such as toluene.

Compton, L. E.↗
NASA NTRS1983

Light element geochemistry and spallogenesis in lunar rocks

Abundance and isotopic compositions are measured for the very volatile elements carbon, nitrogen and sulfur in 11 lunar rocks representing a wide spectrum of textures and compositions. Samples were combusted sequentially at three temperatures in order to remove terrestrial contaminants before melting the lunar rock and liberating lunar volatiles. The combustion results indicate very little terrestrial sulfur contamination, with sulfur contents correlated with the TiO2 contents of the basalts analyzed. Sulfur isotopic compositions are remarkably uniform and similar to the Canon Diablo meteorite standard. Nitrogen levels are found to be no greater than those obtained with procedural blanks, corresponding to abundances less than 0.1 microg/g. Stable nitrogen isotope measurements indicate a spallogenic N-15 production rate of 4.1 x 10 to the -6th microg N-15/g sample/million years, in agreement with previous estimates. No indigenous carbon in excess of procedural blank levels of about 0.7 microg/g is found in lunar basalts. Levels of 1 to 5 microg/g found in highland rocks may derive from meteoritic or terrestrial sources. The average measured spallogenic C-13 production rate is 4.1 x 10 to the -6th microg C-13/g sample/million years.

Des Marais, D. J.↗
NASA NTRS1983

El Chichon - Composition of plume gases and particles

Aircraft measurements were made of trace gases, atmospheric particles, and condensed acid volatiles in the plume of El Chichon volcano, Chiapas, Mexico, in November 1982. Hydrogen sulfide was the primary gaseous sulfur species in the plume at the time of collection. Concentrations of 28 elements were determined by neutron activation analysis of particulate material from the plume. The volatile elements sulfur, chlorine, arsenic, selenium, bromine, antimony, iodine, tungsten, and mercury were enriched relative to bulk pyroclastic material by factors of 60 to 20,000. Arsenic, antimony, and selenium were associated predominantly with small (not greater than 3 micrometer) particles. Calcium and sodium were present almost exclusively on larger particles and aluminum and manganese were bimodally distributed. Ashladen particulate material injected into the stratosphere during the early violent eruptions was enriched by factors of 10 to 30 relative to ash in some of the same elements observed in the quiescent plume.

Kotra, J. P.↗
NASA NTRS1983

Frost grain size metamorphism - Implications for remote sensing of planetary surfaces

The effective grain size of a material on a planetary surface affects the strength of absorption features observed in the reflectance of a particulate surface. In the case of a planetary surface containing volatile ices, the absorption characteristics can change in connection with processes leading to a change in the grain size of the material. The present investigation is concerned with an evaluation regarding the occurrence of such processes and the implications for remote sensing applications. It is found that quantitative modeling of the kinetics of grain growth and destruction by thermal and nonthermal processes can provide a means to reconcile apparent optical paths in the volatile portions of planetary surfaces with the physical history of those surfaces. Attention is also given to conditions in the case of the Pluto/Triton system, Uranus and Saturnian satellites, and the Galilean system.

Clark, R. N.↗
NASA NTRS1983

Morphology and chemistry of projectile residue in small experimental impact craters

Small-scale impact craters (5-7 mm in diameter) were produced with a light gas gun in high purity Au and Cu targets using soda lime glass (SL) and man-made basalt glass (BG) as projectiles. Maximum impact velocity was 6.4 km/s resulting in peak pressures of approximately 120-150 GPa. Copious amounts of projectile melts are preserved as thin glass liners draping the entire crater cavity; some of this liner may be lost by spallation, however. SEM investigations reveal complex surface textures including multistage flow phenomena and distinct temporal deposition sequences of small droplets. Inasmuch as some of the melts were generated at peak pressures greater than 120 GPa, these glasses represent the most severely shocked silicates recovered from laboratory experiments to date. Major element analyses reveal partial loss of alkalis; Na2O loss of 10-15 percent is observed, while K2O loss may be as high as 30-50 percent. Although the observed volatile loss in these projectile melts is significant, it still remains uncertain whether target melts produced on planetary surfaces are severely fractionated by selective volatilization processes.

Horz, F.↗
NASA NTRS1983

Aubrites and diogenites - Trace element clues to their origin

A typically igneous siderophile element pattern emerges from an RNAA analysis of 25 aubrite and nine diogenite samples for 13-29 siderophile, volatile, and lithophile trace elements, although it is noted that abundances are about 10 times higher in the case of aubrites. Se is also surprisingly abundant in aubrites. Factor analysis shows several parallel groupings for aubrites and diogenites. Several element pairs that differ greatly in volatility correlate closely in aubrites, in approximately C1-chondrite proportions, suggesting that aubrites originated by igneous processes in their parent body.

Wolf, R.↗
NASA NTRS1984

Micas in experimentally shocked gneiss

Powder-propellant guns are used to shock biotites and muscovites from a gneiss at pressures between 18 and 70 GPa. It is shown that shock in biotite and muscovite can produce homogeneous and devolatilized glasses within microseconds. Shock-deformed micas are found to exhibit fracturing, kinking, and complex extinction patterns over the entire pressure range investigated. Localized melting of micas commences at 33 GPa and reaches completion at 70 GPa. Even though melted biotite and muscovite are opaque optically, they exhibit extensive microvesiculation and flow when observed with the SEM. It is confirmed through electron diffraction that biotite and muscovite have transformed to a glass. The distribution of vesicles in shock-vitrified mica reveals escape of volatiles within the short duration of the shock experiment. It is noted that experimentally shocked biotite and muscovite undergo congruent melting. It is noted that the compositions of the glasses are similar to the unshocked micas except for volatiles (H2O loss and and K loss). These unusual glasses produced from mica can be quenched by rapid cooling conditions during the shock experiment. On the basis of the results, it is pointed out that the extremely low H2O content of tektites can be reconciled with a terrestrial origin by impact.

Lambert, P.↗
NASA NTRS1984

Large seasonal variations in Triton's atmosphere

Consideration is given to the consequences of Triton's surface covering of volatile substances in view of the circularity of Neptune's orbit, which implies that Triton would have virtually no seasonal variations in either surface temperature or atmospheric bulk despite the complex precessional effects of its orbit. It is hypothesized that Triton's most volatile surface substances are probably relegated to latitudes higher than 35 deg, probably forming polar caps whose temperatures would be nearly equal even during the midwinter/midsummer peak insolation of the summer pole. If the summer pole completely sublimates during one of the 'major' summers, Triton's atmosphere may begin to freeze out over the winter caps and yield large and complex seasonal variations.

Trafton, L.↗