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At least 1,207 records · Page 67
All sourcesNASA NTRSDOE OSTI
NASA NTRS2010

Expedition Earth and Beyond: An Introduction to Remote Sensing

This slide presentation reviews some of the current usages of remote sensing, and the science of remote sensing. Included as examples of remote sensing, are emissivity (i.e., infrared) and reflectance (i.e., visible to shortwave infrared) graphs of several minerals, and vegetation spectra. Also, there are pictures of several places on Earth from the photographs that were taken by Astronauts during the earliest missions to later missions.

Stefanov, William L.↗
NASA NTRS2013

Visible-Infrared Hyperspectral Image Projector

The VisIR HIP generates spatially-spectrally complex scenes. The generated scenes simulate real-world targets viewed by various remote sensing instruments. The VisIR HIP consists of two subsystems: a spectral engine and a spatial engine. The spectral engine generates spectrally complex uniform illumination that spans the wavelength range between 380 nm and 1,600 nm. The spatial engine generates two-dimensional gray-scale scenes. When combined, the two engines are capable of producing two-dimensional scenes with a unique spectrum at each pixel. The VisIR HIP can be used to calibrate any spectrally sensitive remote-sensing instrument. Tests were conducted on the Wide-field Imaging Interferometer Testbed at NASA s Goddard Space Flight Center. The device is a variation of the calibrated hyperspectral image projector developed by the National Institute of Standards and Technology in Gaithersburg, MD. It uses Gooch & Housego Visible and Infrared OL490 Agile Light Sources to generate arbitrary spectra. The two light sources are coupled to a digital light processing (DLP(TradeMark)) digital mirror device (DMD) that serves as the spatial engine. Scenes are displayed on the DMD synchronously with desired spectrum. Scene/spectrum combinations are displayed in rapid succession, over time intervals that are short compared to the integration time of the system under test.

Bolcar, Matthew↗
NASA NTRS2013

Towards Calibrating the Vestan Regolith: Correlating the Petrology, Chemistry and Spectroscopy of Howardites

The Dawn spacecraft carries a visible and infrared mapping spectrometer (VIR) [1] that has acquired spectra for the wavelength range 0.25-5.0 μm at various spatial resolutions covering much of the vestan surface [2]. Through comparison of VIR spectra with laboratory spectra of howardite, eucrite and diogenite meteorites, the distribution of more diogenite-rich and more eucrite-rich terranes on Vesta have been mapped [3], but these maps are qualitative in nature. The available laboratory spectra are not well-integrated with detailed sample petrology or composition limiting their utility for lithologic mapping. Importantly, howardites are now recognized to come in two subtypes, regolithic and fragmental [4]. The former are breccias assembled in part from true regolith, while the latter have had much less exposure to the space environment. We are attempting to develop a more quantitative basis for mapping the distribution of lithologic types on Vesta through acquiring laboratory spectra on splits of howardites that have been petrologically and chemically characterized [5]. Noble gas analyses have been done on some allowing identification of those howardites that have been exposed in the true regolith of Vesta [6].

Mittlefehldt, D. W.↗
NASA NTRS1986

IUE observations of V Sagittae

Observations of the nova-like variable V Sge are discussed, and the ground-based light curve is analyzed, compensating for the component interaction effect. Low-dispersion IUE spectra indicate that interstellar reddening is smaller than suggested from visible-band observations. The UV and visible continuum are modeled by a He-rich model and by a simple accretion disk, and the UV spectrum emission lines are used to determine ionization temperatures and a lower N(e) limit. The present data are consistent with the picture of the companion to the He star being embedded in an accretion disk, with the disk being large (of dimension comparable to that of the embedding Roche lobe as a result of vigorous mass transfer) at the time of the ground-based data, and with the disk having been diminished to a radius of the order of 200 times of the neutron star, at the time of the IUE spectra.

Koch, R. H.↗
NASA NTRS1993

Theoretical calculations on the electron absorption spectra of selected Polycyclic Aromatic Hydrocarbons (PAH) and derivatives

As a theoretical component of the joint effort with the laboratory of Dr. Lou Allamandola to search for potential candidates for interstellar organic carbon compound that are responsible for the visible diffuse interstellar absorption bands (DIB's), quantum mechanical calculations were performed on the electron absorption spectra of selected polycyclic aromatic hydrocarbons (PAH) and derivatives. In the completed project, 15 different species of naphthalene, its hydrogen abstraction and addition derivatives, and corresponding cations and anions were studied. Using semiempirical quantum mechanical method INDO/S, the ground electronic state of each species was evaluated with restricted Hartree-Fock scheme and limited configuration interaction. The lowest energy spin state for each species was used for electron absorption calculations. Results indicate that these calculations are accurate enough to reproduce the spectra of naphthalene cation and anion observed in neon matrix. The spectral pattern of the hydrogen abstraction and addition derivatives predicted based on these results indicate that the electron configuration of the pi orbitals of these species is the dominant determinant. A combined list of 19 absorptions calculated from 4500 A to 10,400 A were compiled and suggested as potential candidates that are relevant for the DIB's absorptions. Continued studies on pyrene and derivatives revealed the ground state symmetries and multiplicities of its neutral, anionic, and cationic species. Spectral calculations show that the cation (B(sub 3g)-2) and the anion (A(sub u)-2) are more likely to have low energy absorptions in the regions between 10 kK and 20 kK, similar to naphthalene. These absorptions, together with those to be determined from the hydrogen abstraction and addition derivatives of pyrene, can be used to provide additional candidates and suggest experimental work in the search for interstellar compounds that are responsible for DIB's.

Du, Ping↗
NASA NTRS2006

Computational Spectroscopy of Polycyclic Aromatic Hydrocarbons In Support of Laboratory Astrophysics

Polycyclic aromatic hydrocarbons (PAHs) are strong candidates for the molecular carriers of the unidentified infrared bands (UIR) and the diffuse interstellar bands (DIBs). In order to test the PAH hypothesis, we have systematically measured the vibronic spectra of a number of jet-cooled neutral and ionized PAHs in the near ultraviolet (UV) to visible spectral ranges using the cavity ring-down spectroscopy. To support this experimental effort, we have carried out theoretical studies of the spectra obtained in our measurements. Ab initio and (time-dependent) density.functiona1 theory calculations are performed to obtain the geometries, energetics, vibrational frequencies, transition dipole moments, and normal coordinates of these PAH molecules. Franck-Condon (FC) calculations and/or vibronic calculations are then performed using the calculated normal coordinates and vibrational frequencies to simulate the vibronic spectra. It is found that vibronic interactions in these conjugated pi electron systems are often strong enough to cause significant deviations from the Born-Oppenheimer (BO) approximation. For vibronic transitions that are well described by the BO approximation, the vibronic band profiles are simulated by calculating the rotational structure of the vibronic transitions. Vibronic oscillator strength factors are calculated in the frame of the FC approximation from the electronic transition dipole moments and the FC factors. This computational effort together with our experimental measurements provides, for the first time, powerful tools for comparison with space-based data and, hence, a powerful approach to understand the spectroscopy of interstellar PAH analogs and the nature of the UIR and DIBs.

Tan, Xiaofeng↗
NASA NTRS1990

Quantitative lithologic mapping in spectral ratio feature space - Volcanic, sedimentary and metamorphic terrains

The nature of spectral lithologic mapping is studied utilizing ratios centered around the wavelength means of TM imagery. Laboratory-derived spectra are analyzed to determine the two-dimensional relationships and distributions visible in spectral ratio feature space. The spectral distributions of various rocks and minerals in ratio feature space are found to be controlled by several spectrally dominant molecules. Three study areas were examined: Rawhide Mining District, Nevada; Manzano Mountains, New Mexico; and the Sevilleta Long Term Ecological Research site in New Mexico. It is shown that, in the comparison of two ratio plots of laboratory reflectance spectra, i.e., 0.66/0.485 micron versus 1.65/2.22 microns with those derived from TM data, several molecules spectrally dominate the reflectance characteristic of surface lithologic units. Utilizing the above ratio combination, two areas are successfully mapped based on their distribution in spectral ratio feature space.

Campos-Marquetti, Raul, Jr.↗
DOE OSTI2016

Investigation of electrical and optical properties of MEH-PPV: ZnO nanocomposite films for OLED applications

Recent investigations of the promising materials for optoelectronic have been demonstrated by introducing n-type inorganic material into conjugated polymer. The optical and electrical of nanocomposite films based on poly[2-methoxy-5-(2’-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) and zinc oxide (ZnO) nanostructured of various deposition layers (1 to 3 layers) have been investigated. The MEH-PPV: ZnO nanocomposite films were deposited using spin-coating technique. The surface morphology nanocomposite films were characterized using field emission scanning electron microscope. From surface profiler measurement, we found that the thickness of nanocomposite films increased as deposition time increased. The optical properties were measured using photoluminescence spectroscope. The photoluminescence (PL) spectra showed that two deposition layers is the highest intensity at visible region (green emission) due to high energy transfer from particles to the polymer. The current density for two layers sample is due to aggregation of conjugated polymer chain hence form excited interchain exciton for optical excitation. This study will provide better performance and suitable for optoelectronic device especially OLEDs application.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Emission Spectra of Uranium Particulates at High Temperature

The emission spectrum of micron-scale uranium particulates at high temperatures in the ultraviolet, visible, and near-infrared spectral regions is investigated using a heterogeneous shock tube. Temperatures from 3000 to 9000 K are characterized in an inert argon environment and with incremental amounts of added oxygen. Atomic line spectra do not emerge above the continuum emission spectrum until between 4500 and 5000 K in pure argon, and 6100 and 6600 K in 1% oxygen. For 5% oxygen, however, the threshold for atomic emission drops below 3800 K. Uranium monoxide molecular emission in the strongest visible band at 595.4 nm is not observed at any condition. Uncertainties in particle temperature determination in high-temperature shock tube environments are discussed, and limitations to such measurements are presented, such as those from experimental factors such as the powder loading method and expected detection limits of uranium species in relevant conditions.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2015

Synthesis and properties of (Yb, N)-TiO{sub 2} photocatalyst for degradation of methylene blue (MB) under visible light irradiation

Highlights: • The (Yb, N)-TiO{sub 2} nanoparticles were prepared and characterized. • The spectrum absorption region of (Yb, N)-TiO{sub 2} is red-shifted to visible light. • The recombination of the photo-generated electron–hole pairs of (Yb, N)-TiO{sub 2} is suppressed. • The photocatalytic activity of (Yb, N)-TiO{sub 2} is more higher than that of TiO{sub 2}-P25, N-TiO{sub 2} and the Yb-TiO{sub 2}. - Abstract: (Yb, N)-TiO{sub 2} photocatalyst has been synthesized by sol–gel method combined with microwave chemical synthesis. Also, the efficiency of the (Yb, N)-TiO{sub 2} as a photocatalyst for the degradation of methylene blue (MB) using visible light irradiation has been evaluated. The prepared samples were characterized by XRD, TEM, XPS, UV–vis-DRS and PL. The results show that the (Yb, N)-TiO{sub 2} photocatalyst has the anatase TiO{sub 2} crystalline phase. The TEM micrograph demonstrated that the average particle size of the sample was about 12 nm. The band-gap energy absorption edge shifted to longer wavelength as compared to commercial TiO{sub 2}-P25, N-TiO{sub 2} and the Yb-TiO{sub 2} prepared by our group. Results of degradation revealed that the (Yb, N)-TiO{sub 2} has shown much more higher photocatalytic activity than that of the TiO{sub 2}-P25, the N-TiO{sub 2} and the Yb-TiO{sub 2} under the visible light.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS2017

Organic Molecules On the Surfaces of Iapetus and Phoebe

Absorption bands of both aliphatic and aromatic organic molecules are found in the reflectance spectra of Saturn satellites Iapetus, Phoebe, and Hyperion obtained with the Cassini Visible-Infrared Mapping Spectrometer (VIMS). The VIMS data do not fully resolve the individual bands of C-H functional groups specific to particular molecules, but instead show absorption envelopes representing blended clusters of the bands of aromatic (approximately 3.28 microns) and aliphatic (approximately 3.4 microns) hydrocarbons known in spectra of interstellar dust. In Cruikshank et al. (2014), we matched components of the unresolved hydrocarbon band envelopes with clusters of bands of a range of functional groups in specific types of organic compounds (e.g., normal and N-substituted polycyclic aromatic hydrocarbons, olefins, cycloalkanes, and molecules with lone-pair interactions of N and O with CH3+). In the work reported here, we revisit the spectra of Iapetus and Phoebe using VIMS data processed with improved radiometric and wavelength calibration (denoted RC19). The band envelopes of both aromatic and aliphatic hydrocarbons are now more clearly defined, corroborating the provisional assignment of specific classes of molecules in Cruikshank et al. 2014, but permitting a more reliable quantitative assessment of the relative contributions of those classes, and a revision to the earlier estimate of the ratio of the abundances of aromatic to aliphatic molecules.

Phoeb↗
DOE OSTI2016

Energetic, electronic and optical properties of lanthanide doped TiO{sub 2}: An ab initio LDA+U study

Substitutional energies, thermodynamic charge transition levels and optical properties of lanthanide doped anatase TiO{sub 2} has been investigated using local density approximation with the Hubbard U correction (LDA+U) within the density functional theory formalism. All the lanthanides apart from La introduced impurity states in the host band gap on doping. The calculated substitutional energies indicate that it is possible to dope TiO{sub 2} with lanthanide ions. The optimal doping percentage was predicted to be ~3% and dopant levels resulting from Ce, Nd, Sm, Gd and Tm doping were found to possess negative U characteristics. In addition the calculated thermodynamic transition levels predicted Lu as not having any possible charge transitions within the host band gap. The calculated optical absorption coefficients indicate that lanthanide doping led to optical absorption in the visible regime. - Graphical abstract: Crystal structure of doped Sm doped TiO{sub 2} (RHS). Calculated PDOS and absorption spectra of Sm doped TiO{sub 2}. - Highlights: • Lanthanide doping significantly improved the optical properties of anatase TiO{sub 2}. • Lanthanide doping led to emission in the visible regions of the optical spectrum. • La, Ce, Pm, Sm, Eu, Gd, Tm, Yb and Lu doping gave good photocatalytic properties. • The optimum doping concentration in anatase TiO{sub 2} was found to be 2.78%.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

THE EXTRAGALACTIC BACKGROUND LIGHT, THE HUBBLE CONSTANT, AND ANOMALIES: CONCLUSIONS FROM 20 YEARS OF TeV GAMMA-RAY OBSERVATIONS

Ground-based observatories have been collecting 0.2–20 TeV gamma-rays from blazars for about twenty years. These gamma-rays can experience absorption along the line of sight due to interactions with the extragalactic background light (EBL). In this paper, we show that the gamma-ray optical depth can be reduced to the convolution product of an EBL kernel with the EBL intensity, assuming a particular form for the EBL evolution. We extract the absorption signal from the most extensive set of TeV spectra from blazars collected so far and unveil a broadband EBL spectrum from mid-ultraviolet to far-infrared. This spectrum is in good agreement with the accumulated emission of galaxies, constraining unresolved populations of sources. We propose a data-driven estimate of the Hubble constant based on the comparison of local and gamma-ray measurements of the EBL. After setting stringent upper-limits on the redshift of four TeV blazars, we investigate the 106 gamma-ray spectra in our sample and find no significant evidence for anomalies. The intrinsic TeV spectra are not harder than their GeV counterpart, and no spectral upturn is visible at the highest optical depths. Finally, we investigate a modification of the pair-creation threshold due to Lorentz invariance violation. A mild excess prevents us from ruling out an effect at the Planck energy, and we constrain for the first time the energy scale of the modification to values larger than 60% of the Planck energy.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Luminescence Spectra of High-Power Violet and Ultraviolet Gallium Nitride-Based LEDs

The electroluminescence spectra of high-power light-emitting diodes (LEDs) based on p–n heterostructures of the InGaN/AlGaN/GaN type emitting in the visible short-wavelength and ultraviolet spectral regions (the range from 370 to 460 nm) are investigated. The shape of spectra is described by a model taking into account a two-dimensional combined density of states and potential fluctuations. Additional long-wavelength peaks are found in emission spectra. The emission power of ultraviolet and violet LEDs reaches 233 mW at a current of 350 mA, and the external quantum yield reaches 23% at the maximum (near a current of 100 mA).

36 MATERIALS SCIENCE↗
DOE OSTI2014

Detection of ℓ = 4 and ℓ = 5 modes in 12 years of solar VIRGO-SPM data—tests on Kepler observations of 16 Cyg A and B

We present the detection of ℓ = 4 and ℓ = 5 modes in power spectra of the Sun, constructed from 12 yr full-disk VIRGO-SPM data sets. A method for enhancing the detectability of these modes in asteroseismic targets is presented and applied to Kepler data of the two solar analogues 16 Cyg A and B. For these targets, we see indications of a signal from ℓ = 4 modes, while nothing is yet seen for ℓ = 5 modes. We further simulate the power spectra of these stars and from this we estimate that it should indeed be possible to see such indications of ℓ = 4 modes at the present length of the data sets. In the simulation process, we briefly look into the apparent misfit between observed and calculated mode visibilities. We predict that firm detections of at least ℓ = 4 should be possible in any case at the end of the Kepler mission. For ℓ = 5, we do not predict any firm detections from Kepler data.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2020

Photometry of Asteroid (101955) Bennu with OVIRS on OSIRIS-REx

NASA’s OSIRIS-REx spacecraft arrived at its sampling target, asteroid (101955) Bennu, in December 2018 and started a series of global observation campaigns. Here we investigate the global photometric properties of Bennu as observed by the OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS) over the time period December 9, 2018, to September 26, 2019. In this study we used observations obtained over wavelengths ranging from 0.4 to 3.7 μm, with a solar phase angle range of 5.3° to 132.6°. Our aim is to characterize the global average disk-resolved photometric properties of Bennu with multiple models. The best-fit model is a McEwen model with an exponential phase function and an exponential polynomial partition function. We use this model to correct the OVIRS spectra of Bennu to a standard reference viewing and illumination geometry at visible to infrared wavelengths for the purposes of global spectral mapping. We derive a bolometric Bond albedo map in which Bennu’s surface values range from 0.021 to 0.027. We find a phase reddening effect, and our model is effective at removing this phase reddening. Our average model albedo shows a blueish spectrum with a >10% absorption feature centered at 2.74 μm. Of all comparisons with previously visited asteroids and comets, only 28P/Neujmin, 2P/Encke, and (162173) Ryugu are darker than Bennu. We find that Bennu is a few percent brighter than Ryugu in the wavelengths respectively observed by the OSIRIS-REx and Hayabusa2 missions (from 0.48 to 0.86 μm). We also compare our spectroscopic photometry of Bennu with the OSIRIS-REx imaging photometry and with ground-based predictions.

Asteroid Bennu↗
DOE OSTI2013

Exciton-phonon bound complex in single-walled carbon nanotubes revealed by high-field magneto-optical spectroscopy

High-field magneto-optical spectroscopy was performed on highly enriched (6,5) single-walled carbon nanotubes. Spectra of phonon sidebands in both 1st and 2nd sub-bands were unchanged by an external magnetic field up to 52 T. The dark K-momentum singlet (D-K-S) exciton, which plays an important role for the external quantum efficiency of the system for both sub-bands in the near-infrared and the visible light region, respectively, was clarified to be the origin of the phonon sidebands.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

Emission intensity in the visible and IR spectral ranges from Si-based structures formed by direct bonding with simultaneous doping with erbium (Er) and europium (Eu)

The photo- and electroluminescence spectra of silicon-based structures formed by direct bonding with simultaneous doping with rare-earth metals are studied. It is shown that emission in the visible and IR spectral ranges can be obtained from n-Si:Er/p-Si and n-Si:Eu/p-Si structures fabricated by the method suggested in the study. The results obtained make this method promising for the fabrication of optoelectronic devices.

36 MATERIALS SCIENCE↗