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The possibility of hydrogen-water demixing in Uranus, Neptune, K2-18 b and TOI-270 d
Context. The internal structures of Uranus and Neptune remain unknown. In addition, sub-Neptunes are now thought to be the most common type of exoplanets. Improving our understanding of the physical processes that govern the interiors of such planets is therefore essential. Phase separation between planetary constituents may occur, in particular, hydrogen-water immiscibility in cold, water-rich intermediate-mass planets. Aims. We assess whether hydrogen-water demixing could occur in Uranus, Neptune, K2-18 b and TOI-270 d, and investigate its effect on the planetary evolution and inferred internal structure. Methods. We couple planetary evolution models with recent ab initio calculations of the hydrogen-water phase diagram, allowing for temperature shifts to account for uncertainties in miscibility gaps. Results. We find that demixing may occur and could lead to a complete depletion of water in the outermost regions of Uranus and Neptune. Temperature offsets of up to 1100 K lead to a depleted region comprising as much as 16% of the planet’s mass, and an increase in planetary radius by nearly 20%. For K2-18 b, our models suggest that hydrogen-water demixing is ongoing and may explain the absence of water features in its JWST spectrum. A temperature offset of 500 K is required to get a complete depletion of water in the atmosphere of K2-18b. TOI-270d may also have experienced hydrogen-water demixing. When applying a similar temperature offset on the phase diagram as for K2-18 b, we find a partial depletion of water in the atmosphere of TOI-270 d, consistent with JWST’s detection of water. Conclusions. Hydrogen-water immiscibility may play a key role in shaping the structure and evolution of both Solar System giant planets like Uranus and Neptune, and cold/temperate exoplanets such as K2-18 b and TOI-270 d. Accounting for such internal processes is crucial to accurately interpret atmospheric observations from current (e.g., JWST) and upcoming (e.g., ARIEL) missions.
Influence of the proton relay spacer on hydrogen electrocatalysis by cobalt hangman porphyrins
A cobalt hangman porphyrin system with a phenyl spacer between the porphyrin ring and an internal carboxylic acid group as well as its non-hangman analogue were synthesized and utilized for the study of the proton-coupled electron transfer (PCET) kinetics attendant to electrocatalytic hydrogen evolution. Cyclic voltammetry (CV) together with simulations show that a short distance between the proton relay and the redox active cobalt center as well as the increased proton donating strength results in superior catalytic activity. Here, the mechanism of hydrogen generation is at the nexus of proton transfer–electron transfer (PTET) and concerted proton–electron transfer (CPET), as opposed to an ETPT mechanism that is characteristic of hangman systems with longer proton relay networks.
Decarbonizing the US Energy System
Recent rapid and unexpected cost reductions in decarbonization technologies have accelerated the cost-effective decarbonization of the US economy, with greenhouse gas (GHG) emissions falling by 20% from 2005 to 2020. The literature on US economy-wide decarbonization focuses on maximizing long-term GHG emissions reduction strategies that rely mostly on renewable energy expansion, electrification, and efficiency improvements to achieve net-zero GHG emissions by 2050. While these studies provide a valuable foundation, further research is needed to properly support decarbonization policy development and implementation. In this review, we identify key decarbonization analysis gaps and opportunities, including issues related to cross-sectoral linkages, spatial and temporal granularity, consumer behavior, emerging technologies, equity and environmental justice, and political economy. We conclude by discussing the implications of these analysis gaps for US decarbonization pathways and how they relate to challenges facing major global emitters.
2020 Annual Technology Baseline (ATB) Cost and Performance Data for Electricity Generation Technologies
Starting in 2015 NREL has presented the Annual Technology Baseline (ATB) in an Excel workbook that contains detailed cost and performance data, both current and projected, for renewable and conventional technologies. The workbook includes a spreadsheet for each technology. This updated version of the workbook provides data for the 2020 ATB. In 2019 and 2020, NREL has also provided selected data in Tableau workbooks and structured summary csv files. A website documents this data at https://atb.nlr.gov .
The atmosphere of Titan
Titan, a satellite of Saturn, is unique in that it is the only satellite in the solar system with an extensive atmosphere, possibly more massive than that of the earth. Methane and hydrogen have been discovered, and a greenhouse effect is apparent from infrared measurements. It may be enshrouded by clouds, and this intriguing body may, in time, provide clues to the evolution of the major planets and their satellites. At present, interpretation of the observational evidence concerning the properties of Titan is somewhat speculative and controversial. The status of the observations and theoretical studies is assessed.
Interior structure of Jupiter - Theory of gravity sounding
Using relatively simple interior models and a fourth-order theory of figures, it is found that there are basically two extremes of interior structure which agree with current gravity data. One extreme is a 'solar'-composition envelope with 10 to 15 earth masses of heavy material in a core; the other extreme has nearly uniform 'solar' composition but with approximately an additional 30 earth masses of heavy material distributed essentially uniformly. Thus, Jupiter is not of 'solar' composition. It is shown how additional gravity data and improvement in knowledge of the molecular hydrogen equation of state will permit a significant reduction in the number of possible models.
Observation of Fe II (26.0 microns) in SN 1987A
The first observation of the 26-micron line from singly ionized iron in SN 1987A is reported. The total flux is 4.5 + or - 0.9 x 20 to the -18th W/sq cm. The line width (FWHM) is 4000 + or - 600 km/s. The minimum iron mass is found to be about 0.02 solar, indicating that the emission originates in the heavy element mantle and not in the hydrogen-rich envelope. Since this mass is less than estimates based on near-infrared measurements or the optical light curve, the emission is probably optically thick. In this case, the flux measurement together with the observed line width suggest a temperature of 3500 + or - 1500 K for the mantle. The broad line width suggests that mixing of the ejected iron with lighter elements in overlying layers has occurred.
What sort of standard candle is Orion for studying molecular hydrogen line emission in galaxies
The total shocked and fluorescent molecular hydrogen 1-0 S(1) line luminosities from Orion have been measured to be about 2.5 solar luminosity and about 2.0 solar luminosity, respectively. The implications for using Orion to study the interstellar medium in galaxies is discussed.
Diffusion effects on the helium abundance of the solar transition region and corona
The diffusion of helium in the solar transition region is studied by solving the mass and momentum conservation equations for a hydrogen-helium plasma given a representative temperature profile. Steady state solutions show that two distinct atmospheres may result. In cases where the thermal force on alpha-particles is balanced by the partial pressure gradient force, helium is the dominant coronal species. On the other hand, if it is the frictional force between protons and alpha-particles which balances the thermal force on alpha-particles then hydrogen is the major coronal component. In order to explore which of these solutions are attainable within reasonable time scales, the time-dependent equations are solved, starting from an initial state with a uniform helium abundance of 10 percent. The atmosphere as a whole is close to hydrostatic equilibrium, but due the thermal forces the individual elements are not. This force inbalance leads to a differential flow between species. It is found that this differential flow leads to a significant enhancement of the coronal helium abundance. Even for the relatively shallow temperature gradient used the helium abundance in the lower corona increases to 30 percent over a 24 hr period.
EOTV propellant tank pressure control and liquid dynamics
The solar-powered Electric Orbit Transfer Vehicle (EOTV) will transfer payloads from LEO to higher orbits, using hydrogen propellant and low-thrust arcjet propulsion to provide specific impulse in the range to 1,200 to 1,400 seconds. All the boiloff from the tank provides the vaporized propellant for the arcjet thrusters, with no boiloff being vented to space. The system consists of an insulated lightweight tank where the cryogenic hydrogen is stored subcritically at low pressure, a compressor to raise the pressure of the hydrogen vapor flow for the arcjets to the proper level, an accumulator, and mass flow controllers. The results of studies of the management of the tank pressure and liquid dynamics are presented.
Origin of the hydrocarbon component of interplanetary dust particles
Using experiments as a basis, we have developed a scenario for the origin of the hydrocarbon material of carbonaceous chondrites. This scenario can also serve as an explanation for the origin of the hydrocarbon component of interplanetary dust particles (IDP's). The formation of polycyclic aromatic hydrocarbon (PAH) molecules in the atmospheres of C stars undergoing a late stage of stellar evolution is indicated by the observed unidentified infrared (UIR) emission bands. Those molecules are then transported through interstellar space where they become enriched with D through ion molecule reactions when passing through cold, dark clouds. Many of those PAH molecules are subsequently hydrogenated and cracked in a H-dominated plasma such as would have occurred in the solar nebula. The resulting mixture of alkanes and residual D-rich PAH molecules was then incorporated into the mineral fraction of the parent bodies of carbonaceous chondrites and IDP's.
An HST study of galactic inerstellar zinc and chromium
We present a survey of interstellar Zn II and Cr II absorption extracted from the Hubble Space Telescope Goddard High Resolution Spectrograph (HST GHRS) data archive. We find clear evidence for an enhanced depletion of Zn from the gas phase with increasing fractional abundance of molecular hydrogen f(H2). Our lower limit to the Galactic interstellar metallicity is approximately 65% of the solar value as determined by the measured Zn abundances in the lowest f(H2) sightlines, (N(Zn)/N(H(sup 0)(sub tot)) = -0.19 +/- 0.04. The correspondingly high depletion of Cr with respect to solar (N(Cr/N(H(sup 0)(sub tot)) = -1.44 +/- 0.26 indicates that there are significant amounts of dust present in these lines of sight. The Galactic abundances of Zn and Cr in the ISM provide a fundamental reference point which is used to understand the metal enrichment and dust formation history of damped Lyman alpha QSO absorption-line systems, normally believed to arise from intervening precursors to modern disk galaxies. Although the spread in Zn abundances is large for both the local ISM and in damped Lyman alpha systems, we still find a substantial difference (factor of 4-10) in metallicity between the two sets. This survey and future observations of more distant objects which probe the full extent of the Milky Way halo provide a more complete picture of the enrichment and depletion characteristics of present-day galaxies.
NLTE analysis of SUMER filament observations on SOHO
The observations of hydrogen Lyman delta, epsilon, six and seven lines are described. These data were acquired by the solar ultraviolet measurement of emitted radiation (SUMER) spectrograph onboard the Solar and Heliospheric Observatory (SOHO). All the spectral lines were calibrated to absolute intensities. The multilevel NLTE code was used to evaluate the theoretical line profiles of the four Lyman lines studied. The line cores of all these lines are good indicators of the temperature structure of the filament. The study showed that the line wings are sensitive to the gas pressure. A steep temperature increase in the prominence-corona transition region seems to be consistent with the observed intensities in the line cores of the Lyman lines.
Bolide impacts and the oxidation state of carbon in the Earth's early atmosphere
A one-dimensional photochemical model was used to examine the effect of bolide impacts on the oxidation state of Earth's primitive atmosphere. The impact rate should have been high prior to 3.8 Ga before present, based on evidence derived from the Moon. Impacts of comets or carbonaceous asteroids should have enhanced the atmospheric CO/CO2 ratio by bringing in CO ice and/or organic carbon that can be oxidized to CO in the impact plume. Ordinary chondritic impactors would contain elemental iron that could have reacted with ambient CO2 to give CO. Nitric oxide (NO) should also have been produced by reaction between ambient CO2 and N2 in the hot impact plumes. High NO concentrations increase the atmospheric CO/CO2 ratio by increasing the rainout rate of oxidized gases. According to the model, atmospheric CO/CO2 ratios of unity or greater are possible during the first several hundred million years of Earth's history, provided that dissolved CO was not rapidly oxidized to bicarbonate in the ocean. Specifically, high atmospheric CO/CO2 ratios are possible if either: (1) the climate was cool (like today's climate), so that hydration of dissolved CO to formate was slow, or (2) the formate formed from CO was efficiently converted into volatile, reduced carbon compounds, such as methane. A high atmospheric CO/CO2 ratio may have helped to facilitate prebiotic synthesis by enhancing the production rates of hydrogen cyanide and formaldehyde. Formaldehyde may have been produced even more efficiently by photochemical reduction of bicarbonate and formate in Fe(++)-rich surface waters.
UVCS Observations of Coronal Streamers During the Galileo and Near Solar Conjunctions
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Stratospheric Ozone Variations Caused by Solar Proton Events between 1963 and 2005
Solar proton fluxes have been measured by satellites for over forty years (1963-2005). Several satellites, including the NASA Interplanetary Monitoring Platforms (1963-1993) and the NOAA Geostationary Operational Environmental Satellites (1994-2005), have been used to compile this long-term dataset. Some solar eruptions lead to solar proton events (SPEs) at the Earth, which typically last a few days. High energy solar protons associated with SPEs precipitate on the Earth's atmosphere and cause increases in odd hydrogen (HOx) and odd nitrogen (NOy) in the polar cap regions (greater than 60 degrees geomagnetic). The enhanced HOx leads to short-lived ozone depletion (~days) due to the short lifetime of HOx constituents. The enhanced NOy leads to long-lived ozone changes because of the long lifetime of the NOy family in the stratosphere and lower mesosphere. Very large SPEs occurred in 1972, 1989, 2000, 2001, and 2003 and were predicted to cause maximum total ozone depletions of 1-3%, which lasted for several months to years past the events. These long-term ozone changes caused by SPES are discussed.
Stratospheric Ozone Variations Caused by Solar Proton Events between 1963 and the Present
Solar proton fluxes have been measured by satellites for over forty years (1963-present). Several satellites, including the Interplanetary Monitoring Platforms (1963-1993) and the NOAA Geostationary Operational Environmental Satellites (1994-present), have been used to compile this long-term dataset. Some solar storms lead to solar proton events (SPEs) at the Earth, which typically last a few days. High energy solar protons associated with SPEs precipitate on the Earth's atmosphere and cause increases in odd hydrogen (HO(x)) and odd nitrogen (NO(y)) in the polar cap region (>60 degrees geomagnetic). The enhanced HO(x) leads to short-lived ozone depletion (-days) due to the short lifetime of HOx constituents. The enhanced NO(y) leads to long-lived ozone changes because of the long lifetime of the NO(y) family in the stratosphere and lower mesosphere. Very large SPEs occurred in 1972, 1989, 2000, 2001, and 2003 and were predicted to cause significant polar upper stratospheric ozone depletion (>10%), which lasted for several weeks past the events. Several satellite instruments (BUV, SBUV, SBUV/2, SAGE II, HALOE, SCIAMACHY, MIPAS, GOMOS, etc.) have measured ozone changes as a result of SPEs. The long-term influence of SPEs on ozone will be discussed in this presentation.