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At least 1,207 records · Page 67

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NASA NTRS1979

Investigations of submicron sized metal particles in glass coatings of lunar breccia 15286

Almost all the submicron metal particles in the glass coating of breccia 15286 are rounded and contain two phases, metal and sulfide (FeS). The Ni content of the metal phase as determined by scanning transmission electron microscope X-ray analysis ranged from 9.4 to 15.5 wt %. The sulfide was nearly stoichiometric troilite containing up to 1.3 wt % Ni. The close chemical and microstructural similarities between the coarse (greater than 1-micron) and the submicron sized metal indicate a common origin probably as meteoritic debris. Metal-silicate melt experiments under controlled oxygen partial pressured indicate that the metal particles may have formed from a fine dispersion of immiscible metal-sulfide droplets into an impact-generated silicate melt.

Mehta, S.↗

NASA NTRS1980

Infrared reflectance spectra of asteroids - A search for water of hydration

Infrared reflectance spectra have shown the presence of an absorption feature in the 3-4 micron region for seven C and U asteroids. By comparison with laboratory spectra of terrestrial silicates and meteorites, it is concluded that this band is probably due to water in the form of hydrated salts and silicates (clay minerals), implying that the surface material of these asteroids may be analogous to the CI and CM carbonaceous chondritic meteorites. The presence of other hydrated minerals, however, cannot be ruled out. The depths of the water bands in the spectra vary from asteroid to asteroid, though no asteroid spectrum shows a band as deep as was detected on 1 Ceres. On four other C asteroids, no water band was detected. The implications of these observations for the mineralogy of these asteroids are discussed

Lebofsky, L. A.↗

NASA NTRS1980

Predicting major element mineral/melt equilibria - A statistical approach

Empirical equations have been developed for calculating the mole fractions of NaO0.5, MgO, AlO1.5, SiO2, KO0.5, CaO, TiO2, and FeO in a solid phase of initially unknown identity given only the composition of the coexisting silicate melt. The approach involves a linear multivariate regression analysis in which solid composition is expressed as a Taylor series expansion of the liquid compositions. An internally consistent precision of approximately 0.94 is obtained, that is, the nature of the liquidus phase in the input data set can be correctly predicted for approximately 94% of the entries. The composition of the liquidus phase may be calculated to better than 5 mol % absolute. An important feature of this 'generalized solid' model is its reversibility; that is, the dependent and independent variables in the linear multivariate regression may be inverted to permit prediction of the composition of a silicate liquid produced by equilibrium partial melting of a polymineralic source assemblage.

Hostetler, C. J.↗

NASA NTRS1981

Europa's petrological thermal history

A path of geophysical development which takes into account the petrological sequence is presented to describe the thermal evolution of Europa. On the basis of considerations of the likely temperature-pressure conditions in the Europa zone of the circumjovian nebula during the condensation of the satellite on the one hand and of the early thermal evolution on the other, it is argued that most of the water of Europa can be in the form of hydrated silicates in a thick convective boundary layer or throughout the body of the satellite. Such silicates would include the minerals chlorite and/or serpentine, and brucite, and could be maintained in hydrated states by solid state convection within the body. The model predicts that the ice layer on the surface of Europa is considerably thinner than the 150 km that had been estimated before the Voyager mission.

Ransford, G. A.↗

NASA NTRS1980

Infrared spectroscopic observations of the outer planets, their satellites, and the asteroids

An infrared spectroscopic data base is described for such planetary studies as (1) the detection of atmospheric constituents, (2) the establishment of the column abundances of known atmospheric constituents, and (3) the determination of the thermal properties of planetary atmospheres. Jupiter, Saturn, Uranus, Neptune, Titan and Triton are discussed with reference to middle- and far-IR data, the chemical and thermal properties of their atmospheres, atmospheric constituents and absolute reflectivities, or albedos. Attention is also given to infrared spectroscopic studies of satellite and asteroid surfaces. It is noted that the most abundant surface materials are condensed volatiles and silicate minerals. Water ice has been detected on many surfaces and on the rings of Saturn; CH-4 has been found on Pluto, and CO2 has been identified as a component of the polar caps on Mars. It is concluded that some asteroid surfaces are mineralogically compatible with the relatively unevolved low-temperature remnant of nebular condensation, while others are composed of high-temperature silicates spectrally identical to the products of magmatic differentiation.

Larson, H. P.↗

NASA NTRS1980

Physical characteristics of cometary dust from optical studies

Observations of the sunlight scattered and thermal emission from cometary dust, which may be used to infer the physical properties of the dust grains, are reviewed. Consideration is given to the observed wavelength dependence of the scattered light from cometary coma and tails, the average scattering function of the dust grains, the average grain Bond albedo, the polarization of the scattered light, and grain temperatures deduced from thermal infrared emission. The thermal properties of dust grains are illustrated for models based on magnetite or olivine grain materials, with consideration given to the variation of thermal properties with particle radius and heliocentric distance. Comparison of the models with observations indicates that a disordered or amorphous olivine composition can give a reasonable fit to the data for appropriate grain sizes and temperatures. The observations acquired are noted to indicate an optically important particle size of 1 micron, with silicate particles not larger than a few microns usually present although pure silicate grains can not be responsible for the thermal emission, and the cometary dust grains are most likely not spherical. Further observations needed in the infrared are indicated.

Hanner, M. S.↗

NASA NTRS1980

Io - Energy constraints and plume volcanism

Observational and theoretical considerations, including near-surface energy constraints, suggest a model of Io that features a surface layer of sulfur overlying an active silicate crust. Such a model would imply frequent contact between silicate magma intrusions and the sulfur layer. This contact could produce volcanic plumes driven by high-temperature sulfur vapor. Plumes driven by sulfur vapor meet observational constraints for a wide range of possible conditions, in contrast to the special conditions required for plume generation by SO2. Characteristics of the two models are compared, and it is suggested that high-spatial-resolution infrared radiometry could identify the driving volatile.

Reynolds, R. T.↗

NASA NTRS1981

Thermal barrier coatings for thermal insulation and corrosion resistance in industrial gas turbine engines

Four thermal barrier coatings were subjected to a 500-hour gas turbine engine test. The coatings were two yttria stabilized zirconias, calcium ortho silicate and calcium meta titanate. The calcium silicate coating exhibited significant spalling. Yttria stabilized zirconia and calcium titanate coatings showed little degradation except in blade leading edge areas. Post-test examination showed variations in the coating due to manual application techniques. Improved process control is required if engineering quality coatings are to be developed. The results indicate that some leading edge loss of the coating can be expected near the tip.

Vogan, J. W.↗

NASA NTRS1980

The galactic center - 16-30 micron observations and the 18 micron extinction

Within the galactic center, ionized gas, stars, and heated dust are in close proximity to each other. Observations of the galactic center were made during two flight series on NASA aircraft flying at altitudes of more than 12 km. In both series the instrument used was a 10-channel liquid helium cooled grating spectrometer. Three 16-30 micrometers continuum spectra are presented along with two-color scans of the galactic center. No 18.71 micrometers line emission has been detected from Sgr A West. This is consistent with large dust extinction and normal S III/H II abundances. All three 16-30 micrometers continuum spectra show a broad depression centered at about 18 micrometers. This observation is attributed to absorption by cold silicate dust grains. The characteristics of a silicate model are discussed.

Mccarthy, J. F.↗

NASA NTRS1981

Melt segregation from partially molten source regions - The importance of melt density and source region size

An investigation is conducted regarding the changes expected in the density contrast between basic melts and peridotites with increasing pressure using the limited data available on the compressibilities of silicate melts and data on the densities of mantle minerals. It is concluded that since compressibilities of silicate melts are about an order of magnitude greater than those of mantle minerals, the density contrast between basic melts and mantle minerals must diminish significantly with increasing pressure. An earlier analysis regarding the migration of liquid in partially molten source regions conducted by Walker et al. (1978) is extended, giving particular attention to the influence of the diminished density contrast between melt and residual crystals with increasing source region depth and to the influence of source region size. This analysis leads to several generalizations concerning the factors influencing the depths at which magmas will segregate from their source regions and the degrees of partial melting that can be achieved in these source regions before melt segregation occurs.

Stolper, E.↗

NASA NTRS1982

Impact of an asteroid or comet in the ocean and extinction of terrestrial life

Finite difference calculations describing the impact mechanics associated with a 10 to 30 km diameter silicate or water object impacting a 5 km deep ocean overlying a silicate solid planet demonstrate that from 12 to 15% of the bolide energy resides in the water. It is speculated that minimal global tsunami run-up heights on the continents would be 300-400 meters, and that such waves would inundate all low altitude continental areas, and strip and silt-over virtually all vegetation. As a result the terrestrial animal food chain would be seriously perturbed. This could in turn cause extinction of large terrestrial animals.

Ahrens, T. J.↗

NASA NTRS1982

Advanced ceramic coating development for industrial/utility gas turbines

A program was conducted with the objective of developing advanced thermal barrier coating (TBC) systems. Coating application was by plasma spray. Duplex, triplex and graded coatings were tested. Coating systems incorporated both NiCrAly and CoCrAly bond coats. Four ceramic overlays were tested: ZrO2.82O3; CaO.TiO2; 2CaO.SiO2; and MgO.Al2O3. The best overall results were obtained with a CaO.TiO2 coating applied to a NiCrAly bond coat. This coating was less sensitive than the ZrO2.8Y2O3 coating to process variables and part geometry. Testing with fuels contaminated with compounds containing sulfur, phosphorus and alkali metals showed the zirconia coatings were destabilized. The calcium titanate coatings were not affected by these contaminants. However, when fuels were used containing 50 ppm of vanadium and 150 ppm of magnesium, heavy deposits were formed on the test specimens and combustor components that required frequent cleaning of the test rig. During the program Mars engine first-stage turbine blades were coated and installed for an engine cyclic endurance run with the zirconia, calcium titanate, and calcium silicate coatings. Heavy spalling developed with the calcium silicate system. The zirconia and calcium titanate systems survived the full test duration. It was concluded that these two TBC's showed potential for application in gas turbines.

Vogan, J. W.↗

NASA NTRS1981

Relict grains in chondrules

Attention is given to the fact that a significant fraction of the chondrules from ordinary chondrites contain silicate grains that survived the chondrule formation process without melting. Typically, these grains consist of coarse olivine, rarely orthopyroxene, crystals located in the core of chondrules and displaying a zoning that is inconsistent with crystallization from a silicate melt. It is noted that the relict grains still preserve the imprint of processes that occurred in the solar nebula and, in some cases, may include the isotopic record of interstellar grains. Information is presented on the chondrule precursor materials and the process of chondrule formation which was acquired by a compositional and textural study of three of the most unequilibrated type 3 ordinary chondrites.

Rambaldi, E. R.↗

NASA NTRS1980

High temperature crystal field spectra of transition metal-bearing minerals - Relevance to remote-sensed spectra of planetary surfaces

It is pointed out that transition metal ions in silicate minerals, glasses, and crystalline and amorphous oxyhydroxides and salts contribute to the visible-near infrared spectral profiles of planetary surfaces. Investigations are conducted to obtain spectral information which might be helpful in the interpretation of the remote-sensed spectra of planetary surfaces. A description is presented of the results of high temperature crystal field spectral measurements of a variety of heated minerals containing Cr(3+), Fe(3+), Fe(++), and Mn(++) ions in different coordination symmetries, taking into account a correlation of the temperature-induced variations with those previously observed for octahedrally coordinated Fe(++)-bearing silicates. The employed experimental methods are also discussed, giving attention to the preparation of the samples, the determination of the absorption spectra, electron microprobe analyses, and the curve fitting procedure.

Parkin, K. M.↗

NASA NTRS1980

Interplanetary dust collected in the earth's stratosphere - The question of solar flare tracks

The negative result of a transmission electron microscope (TEM) search for solar flare tracks in 10 micron interplanetary dust particles (Flynn et al., 1978) which have been collected in the earth's stratosphere with a program of sampling initiated by Brownlee et al. (1976) has been reported previously. In this paper, it is shown that silicates in the particles record laboratory iron-ion tracks which are detectable in the TEM. The absence of tracks in the silicates could be due to track annealing on atmospheric entry, and may indicate a particle emissivity below 0.3, or that many of the particles broke up on encounter with the atmosphere. Alternatively, the lifetime of 10 micron dust particles at 1 AU could be shorter than that given by previous estimates.

Fraundorf, P.↗

NASA NTRS1980

Thermal evolution of Ganymede and Callisto - Effects of solid-state convection and constraints from Voyager imagery

The imaging experiments of the Voyager 1 and 2 fly-by missions have provided a large amount of information about the nature of the surfaces of the Galilean satellites. The present investigation is concerned with the development of models regarding the thermal evolution of Ganymede and Callisto, taking into account the approach of parameterized convection. Attention is given to the physical, chemical, and geological data which are available as constraints on the thermal evolution of Ganymede and Callisto. Both satellites appear to possess surfaces composed of silicates and ice. However, their surface features are distinctly different from each other. In the discussion of thermal evolution models, attention is given to ice-dominant rheology, silicate-dominant rheology, and aspects of phase changes and solid-state convection.

Thurber, C. H.↗

NASA NTRS1982

Carbon in the Allende meteorite - Evidence for poorly graphitized carbon rather than carbyne

A carbon-rich acid residue from the Allende carbonaceous chondrite was examined by high-resolution transmission electron microscopy (HRTEM) and also by analytical electron microscopy. A TEM mount of this residue that has previously been reported to contain carbyne forms of carbon was shown to contain sheet silicate contaminants. These sheet silicate grains give electron diffraction patterns similar to those reported for carbynes, thus raising questions about the previous report of carbynes in this residue. Furthermore, two crystals from a glacier microspherule, which had previously been identified as carbyne VIII, were shown by microanalysis to be talc. In view of these observations it is suggested that identifications of carbyne by electron diffraction should be supported by microanalyses of the individual grains. HRTEM investigations of the Allende carbon indicate that it is a poorly crystalline graphite, structurally similar to 'glassy' carbon

Smith, P. P. K.↗

NASA NTRS1982

Metamorphism in mesosiderites

Previous studies of mesosiderites have identified a metamorphic overprint in these meteorites. However, the effects and implications of this overprint have not yet been explored in detail. The present study documents several important textural and chemical features of the mesosiderites. The components of mesosiderites are examined, taking into account orthopyroxenites, olivine in clasts, mesosiderite mafic clasts, and metal. The characteristics of the silicate matrix of the mesosiderites is explored, and textural and chemical evidence of metamorphism is discussed, giving attention to coronas on olivine clasts, overgrowths on Mg-pyroxene clasts, rims on iron rich pyroxene grains, poikiloblasts of plagioclase, and resorption of clasts. Aspects of redox formation of merrillite are considered along with the causes and the implications of metamorphism. It is found that metamorphism has radically changed the texture of the silicate fraction of the mesosiderites.

Delaney, J. S.↗